454U1

Chemistry
Paper I
November
2012
I % hour

FINAL SEMESTER 2 EXAMINATION 2012

MAKTAB RENDAH SAINS MARA
FORM 4

CIIEMISTRY
PAPER I
I hour 15 minutes

DO NOT OPEN THIS BOOKLET UNTIL BEING TOLD TO DO SO

L This question paper consists of 50 questions.

2. Answer all questions-
3. Answer each question by blackening the correct space on the answer shest'
4. Blacken only one sPace'
5. If you wish to change your answer, erase the blackened mark that you have made'
Then blacken the space for the new answer'
6. The diagram in the questions provided is not drawn to scale unless stated'
7. You may use a non-progwrmmable scientific calculator'

This question paper consists of2l printed pages including the front page

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Question Lo Question 50 are followed four options +.B,C orD'
by
choose the best option for each qlestion and blackened the corresponding sPace on the obiective
answer sheet.

l. which of the following scientists is involved in the development of the Periodic Table?

A Neils Bohr
B John Dalton
C James Chadwick

D Henry J.G. MoseleY

2. Group l8 elements are known as

A halogens
B noble gases
C alkali metals
D transition metals

3. Which ofthe following elements are in Group l? in the Periodic Table of Elements?

A Fluorine and bromine

B Chlorine and xenon
C Bromine and neon
D Fluorine and helium

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is true?
4. Metal of Group I elements react with water' Which statement
A All the metals react vigorously

B The reaction Produoes white flame

C Solution produced turns red litmus paper to blue
D The gas released ignites a burning wooden splinter

across Period 3?
5. Which statements are true about the properties of elements
I Metallic ProPerties decreases
Il EleotropositivitY increases
III Proton number increases
IV Atomic size decreases
i

A I and Il
B II and III
C I, III, and IV
.D II, III, and IV

6. During the formation of ionic bonds, the atoms ofelements

A transfer electrons
B donate electrons

C accept electrons

D share electrons

7. Which substance.is a covalent compoun$l

A HYdrogen chloride
B Magnesium oxide

. C Sodium chloride
D Lithium oxide

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 4

8. Which statement describes a covalent bond?

A Van der Waals forces between non metal atoms
B Transfer ofelectron between metal and non metal atom
C Metal atom donate electron to achieve a stable electron arrangement
D Non metal atoms share electron to achieve a stable electron arrangement

9. Diagram 1 shows the formation ofa compound.

Calcium chloride

Diagram I
Which of the following compound has the same type of bond as the compound formed in
Diagram l?
A Sulphur dioxide
B Carbon disulphide
C Hydrogen chtoride
D Potassium sulphide

10. Which statement explains why a covalent compound d&s not conduct electricity?
A Insoluble in water
B Ions present are not free
C Consist of neutral molecules
D Insoluble in organic solvents

I l. Which of rhe following substance is an electrolyte?

A Chlorine gas, Cl2

B Hydrochloric acid, HCI
C Carbon tetrachloride, CClr
D Phosphorus pentachloride, PCls

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 5

12. Which ofthe following ions are present in copper(Il) sulphate solution?
A Cul* and H* ions
B Cu2* and So+2- ions

C Cu2*, so+z- and H" ions

D cu?*, soq2-, H* and olf ions

13. Diagram 2 shows the apparatus set-up for the electrolysis

of t '0 mot dm-3

silver nitrate solution.

.0 mol dm-3 silver nitrate solution

Diagram 2
'i

Which of the following are the ions that attracted to anode?

A Ag* ions
B NOs- ions
C Ag* and Ff ions
D NO3- and OH- ions

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 6

14. Diagram 3 shows the apparatus set-up ofa voltaic cell that is made up of iron and zinc as
the electrodes.

Zinc

0.1 mol dm-r 0.1 mol dm-3

iron(ll) nitrate solution zinc nitrate solution

. Salt bridge

Diagram 3

What is the direction of the electron flow in the cell?

A From zinc to iron electrode through salt bridge

B From iron to zinc electrode through salt bridge
C From zinc to iron electrode through extemal circuit
D From iron to zinc electrods tfuough external circuit

15. Diagram 4 shows the apparatus set-up ofa voltaic celt that is made up ofmagnesium and
metal X as the electrodes.

Magnesium MCTAI X
Dilute hydrochloric acid

Diagram 4

Which of the following metal gives the highest voltage reading?

A Iron
B Silver
C Copper
D Aluminium

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 7

properties?
16. Which particle enables acids to show its

A Hydroxide ion
B HYdrogen ion
C HYdrogen atom
D HYdrogen molecule

red to blue?
17. Which of t}le following gases will change damp litmus paper from
A OxYgen

B Ammonia
C Carbon dioxide
D HYdrogen chloride

18. Which of the following are strong acids?

I HYdrochloric acid
II SulPhuric acid
III Ethanoic acid
IV Nitric acid

A I and Il
B lI and III
C I, II and IV
D II, III and IV

-l
19. A student is stung by an insect with an alkaline sting'
Whi.h substancels iuitable to treat tlie student?
A Vinegar
B Detergent
C ToothPaste
D Baking soda

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20. Table I shows the pH values offour solutions with the same concentration'

Solution pH value
P 1.0
a 2.0
R 4.5
S 6.5

Table I

Which solution has the lowest concentration ofhydrogen ions?

AP
BQ
CR
DS

21. Which substance is used by farmers to remove excess acidity in the soil?
A Calcium nitrate
B Calcium chloride
C Calcium sulphate
D Calcium hydroxide

22. Which substance is a soluble salt?

A Silver chloride
B Zinc carbonate
C Sodium nikate
D Barium sulphate

23. Which salt is prepared through precipitation?

A Lead(II) iodide
B Barium chloride
C Potassium iodide
D Ammonium chloride

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 9

24. Which salt can be prepared by reacting a metal with a dilute

acid?

A Silver nitrate
B Lead(ll) nitrate
C CoPPer(II) sulPhate

D Magnesium sulPhate

reactions?
25. Which ofthe foltowing reactions represent double decomposition
I )
Pb(NOr, + NazSO+ PbSOq+ 2NaNO:
II Ba(NOr2 + 2KCl ) BaClz + 2KNO3

IV Ba(NO:): + Na2SO4 ) BaSOa + 2NaNG

A I and III
B II and III
C l, III and IV
D ll, III and IV

] where a
26. Th" follo*ing chemical equation shows a reaction between sodium and oxygen

and c are integers.

,rNa+G, ) d--l
What are the values ofa, c and the formula ofthe product obtained?

a c Formula of Pr9d-uct
4 2 Na2O

B 2 2 NazO
., NaOz
C 2

D 4 2 NaOz

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 the Poriodic Table of Elernents'
Which of the
27. Diagrarn Sshows six transition elements in
follJwing is true about the elemene?

Diagram 5

A Low densitY
B Loli mehing Point
C High solubilitY in water
D High tensile str€ngth

ofan element'
28. The following statements describe the characteristics
brown in oolour
Aqueous solution ofan ion are green or
'
. . Act as a catalyst in the production of ammonta .

. Has Nvo oxidation numbers' +2 and+3'

Which of the follorving is the element?

B Platinum
C Nickel
D Iron

29, Diagram 6 shows the electron anangellent of element X and Y. Which of the bonding
type and formula is true for compound for.med bctween the two elements?

Diagram 5

Formula Bonding'tYPe

A XY ionic bond

B XYz .ionic bond

C XY .
covalent bond

D XYz covalent bond

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 l2

' 30. Table 2 shows the proton number offour elements'

Element Proton number

3
Lithium
t2
Magnesium
t9
.Potassium
20
Calcium

Table 2

Atom Y has 3 shells occupied with electrons. Element Y reacts with chlorine to form
compound T which has strong electrostatic forces.
Which of the following shows element Y and the chemical formula of T?

Element Y CompoundT .

A Lithium YCI
B Calcium YCIu
'C Magaesium YC12

D Potassium YCI

3l . The following statements are some information about the compound formed between
element P and Q.

o Dissolve in water
. High melting point
. Solid at room temperature

Which is true about element P and Q?

A P is a metal element and Q is a non melal element
B P and Q have equal number of electrons
C Both P and Q are non - metal elements
D Both P and Q share electrons

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 IJ

electrolysis of aluminium oxide' AlzOr'

32. Diagrarn 7 shows apparatus set-up of

Molten lead(Il) oxide

Diagram 7
and cathode of this process?
Which ofthe fotlowing is the halfequation at anode

pb2* + 2e --+ Pb
pbz* + 2e --r Pb

Pbz" + 2e '-, Pb

of0'l mol din-3 sodium nitrate solution

33. Diagram 8 shows apparatus set-up for electrolysis
using Platinum electrodes'

0.1 mol dm-3 sodium nitrate solution

Diagram 8
selected discharged at anode and
Which of the following pairs of ions that will be
cathode?

Anode Cathode

A No:- Na'

B oH- Na'
=--
C oH-
D NOr- H'
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 t4

copper(Il) sulphate solution using copper

34. Diagram 9 shows electrolysis of 0'1 mol dm-3
electrodes-

Copper ele.trode

0.1 mol dm-3

copper(Il) sulPhate solution

Diagram 9
after 30 minutes?
Which of the following will be observed at anode

Brown solid dePosited

B Electrode becomes thinner

C Electrode becomes thicker

D Colourless gas bubbles released

35. Diagram I 0 shows the apparatus set-up

for electroplating an iron key with silver'

Iron key

Diagram l0

What is X?
A Silver nitrate
B Iron(II) nitrate
C silver chloride
D Iron(III) chloride

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 15

I shows the apparatus set-uP ofa voltaic cell with magnesium and copper as
36. Diagram I
the electrodes.

CopPer
Magnesium
Copper(Il) sulphate solution
Magnesium nitrate solution

Salt bridge

Diagram 1 I

Whichofthefollowingis.thehalfequationforthereactionatnegativeterminal?
A M{'+2e"-Mg
B Mg--- Mg2* + 2e
C Cu2* + 2e -- Cu

D Cu --- Cul*+ 2e

produce gas bubbles?

37, Which ofthe following substances reacts with calcium carbonate to
A Salt solution
B Ethanol
c Vinegar
D Sugar solution

38. Table 3 shows the concentration and pH values oftwo types ofacid'

Type of acid Conc.ntration / mol dm-' pH value

M 0.1 I

N 0.1 6

Table 3

Which statement is true about the acids?

A Mis a weak acid, Nis a strong acid

B Concentration ofhydrogen ion in Mis higher than tr/

C The degree of dissociation ofacid 7f is higher than acid M
D M ionises partially in water, N ionises completely in water

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 l6

39. Which ofthese are suitable reactants

for neutralisation reaction?

I Sulphuric acid + sodium hydroxide

tl Hydrochloric acid + copper(Il) oxide
III Sulphuric acid + calcium carbonate
IV HYdrochloric acid + magnesium

A I and II
B I and lV
C II and lll
D III and lV

a chemical reaction-
40. The word equation below represents

+ W Salt + water * carbon dioxide

Dilute hydrochloric acid Substance
'

What could substance W be?

A Zinc sulphate
B Zinc carbonate
C CoPPe(Il) oxide
D CoPPer(II) hYdroxide

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 t7

41. Rubidium is below lithium in Group I elements'

What will happen when rubidium reacts with water?
A Reaction produces less gas bubble

B '
Reaction occurs more slowlY
C Produces Yellow flame

D Produces an exPlosion

and element Y are located in Group I and Group 17 in tle-

X nerjo{i1 fatt3 of
42. Element
is the chemrcal rormula or
Element respectively' X reacts with Y to form a compound' What
the compound?

AXY
B x2Y
C XY2
D X2Y3

43. Table 4 shows the electron arrangeinents of four atoms'

Table 4

Arrange the elements in increasing order of electronegativity'

A F, AI, CI, K
B F, CI, AI, K
C K, AI, CI, F
D K, CI, AI, F

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 l8

P' Q and R'

44. Table 5 shows the properties ofcompound

Compound ProPerties

P Soluble in water, does not conduct electricity

Soluble in water, conduct electricity in both

o molten and aqueous state.

I tnsoluble in water, conduct electricity in

I
R I molten state

Table 5

Which of the following represent P, Q and R?

A I and II
B I and III
C II and IV
D III and IV

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 19

45- Diagram 12 shows f}le apparatus set-up of eleotrolysis of concentrated potassium chloride

solution.

Concentrated Carbon elechodes

potassium chloride
solution

Diagram 12

What is the halfequation at cathode?

A K*+ e- ) K
B 2r{+2€ > H2
C 2Cl' ) Clz+ 2e-
D 4OH- ) 2H2O + 02 +4e

46. What is the volume of distilled water required to be added to 25.0 cm3 of 0.5 mol dm-3
nitric acid in order to produce a solution of 0.1 mol dm-' ?

A 5.0 cm3
B 12.5 cm3
C 125-0 cm3

D 150.0 cm1

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 z0

acid and potassium hydroxide solution

47.Diagraml3 shows the titration of hydrochloric

0.2 mol dm-3

hydrochloric acid

50 cm3 of 0.I mol dm-3 of

potassium hYdroxide solution +
phenolphthalein
Diagram 13
needed to neutralize potassium hydroxide
What is the volume ofhydrochloric acid

A 25 cm3
B 50 cm3

C 75 cm3

D 100 cm3

48. Diagram 14 shows a chemical cell

Copper plate Zinc plate

Coppe(II) Zinc sulPhale solution

sulphate solution
Diagram 14

Whatisthechemicalreaotionthattakesplaceatthepositiveterminalofthechemical
cell?
ion
A Copp€r atom loss€s electron to form oopper(Il)
B Copper(ll)ion acc€pt electron to form copper atom

C Zinc ion accept electron to form zinc atom

D Zinc storn loses electron to form zinc ion

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49. Table 6 shows information about three voltaic cells.

Pair of metals Potential difference (Y) Negative terminal

R and copper 0.44 R

S and copper 110 s

T and copper 0.53 Cu

Table 6
What is t}re potential differenbe for the pair of metal S and T?
A 0.97 V
B 2.14 V
c 2.23 Y
2.67 Y

50. 40 cm3 of 0.5 mol dm'3 nitric acid is added to 50 cm3 of 0.2 mol drr3 sodium hydroxide'
Calculate the mass ofthe salt formed in this reaction.
[Relative atomic mass: Na; 23, O; 16, N; 14, H;1]
A 0.85 g
B l l2g
C l.7O g
D 2.55 g

END OF QNESTION PAPER

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4541
Chemistry
Paper 213
November
2012
2 Yz hour

FINAL SEMESTER 2 EXAMINATION 2012

MAKfAB RENDAII SAINS MARA
FORM4

Full
Section Question Marks
mark
CHEMISTRY
1 t2
Paper 2 & 3
2 12
Two hours and thifi minutes
A
3 12
do Nor oppN TrrE eUESTIoN BooKLET
LINTIL BEING TOLD TO DO SO 4 12

L Write your name and oollege number in 5 20

. the space provided.
2. This question booklet consists of Section B
6 20
A, B and C.
3. Answer atl question in Section A and C.
4. Answer any one question from Section B' I
l5
5. You may use a non-Programmable C
sciEntific calculator. 8 t7
6. The diagrams in the questions provided
are not dravr'n to scale unless stated. TOTAL 100

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 SULIT ) 4541D

Section A

148 narksl

Answer all questions in this section.

L Table I shows some elements in Period 3 in the Periodic Table of Elements.

Elernent Sodium Aluminium Silicon Chlorine Argon

Proton number 11 l3 t4 l7 18

Table I

Based on Table 1, answer the following questions:

(a) State one element which is

(D metal

(iD semi-metal

(iii) non-metal

13 marksl

(b) Chlorine is in Group 17 in the Periodic Table. State the common name for
Group 17 elemerits.

11 nark)

(c) Write the electron arrangement of sodium atom.

ll narkl

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4s41/2
SULIT -)

(d) (D State the number of valence electron of argon atom'

fl mark'l

(iD In which group can you find argon in the Periodie Table?

ll marhsl

(iiD Argon is chemically unreactive. Explain.

12 marksl

(e) (D Which element forms an amphoteric oxide?

I I markl

(ii) Write the chemical formula of the oxide of element in l(eXi)'

Il narkl

(i ii) State one chemical property ofthe oxide in l(e)(ii).

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 SULIT 4 4541D

2. Diagram 2 shows the electron arrangement of compound J. Compound J is formed

from the reaction between element X and element Y. The letters used do not
. represent the actual symbols of the elements.

a- -\2a -.+- \.
\iit i ,.-.,. I t /-.,..-\
i{oiiltioiit
I

,l I \C./ i | \\o/./
)
L j \-_ '-r- ) I

Dirgram2
Based on Diagram 2:
(a) State how Y ion and X ion are formed from their atoms.

Y ion:...........
X ion:...........
12 marksj

(b) Write the electron arrangement for atom X and Y

Y:,..--....
12 marks"l

(c) (i) State the type ofcompound for J,

I-r(-lo1

[E ll mark.l

(ir) Write the chernical equation for the reaction between element X
and element Y to form compound J.

12 marks'l

(iii) State two physical properties ofcompound J.

12 marks'l

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 4541D
SULIT

(d) Y exists as diatomic molecules. Draw the electron arrangement for

the molecule,

12 marksl

Name the type of bond in 2(d)(i)'

..,..............-..:,..,-.-..
U narkl

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SULIT 6 4s4ll2

J. Diagram 3 shows the apparatus set-up for the electrolysis of 0.001 mol dm-3
hydrochloric acid solution using carbon electrodes X and Y'

Carbon electrode Carbon electrode X

0.001 mol dm-3
hydrochloric acid

Diagram 3

Based on Diagram 3, answer tlre following questions.

(u) (D What is meant by cation?

ll nmkl

(ii) State all the ions present in hydrochloric acid solution.

11 narkl

(iiD Which electrode is the anode and cathode.

Electrode X: '....'.'.'....'....
Electrode Y:
12 marlcsl

(b) (D Name the gas formed at electrode X.

11 narkl

(iD Write the half equation for the reaction that takes place at electrode
x.

ll markl

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 4541D
SULIT

acid
(c) The electrolvsis is repeated by replacing 0.001 mol dm-3 hydrochloric
solution witlr 1.0 moi dmr hydrochloric acid solution'

trtrr'hat will be observed at the electrodes?

Electrode X:

Electrode Y:
12 narksl

(d) One ofthe usage ofelectrolysis is electroplating' A student intends to

electroplate anlron spoon with silver to make it more attractive'
Suggest the suitable substances as the:

Electrolyte

Anode

Cathode
13 narksl

(e) Write the halfequation for the reaction that takes placeht cathode'

ll nukT

lsce trcxt Plgc

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SULIT 4541D

Table 4 shows the pH values of solutions V, W, X, Y and Z with a concentration

of 2.0 mol dm-3.
Solution w x Y Z

pH value I 4 7 l0 13

Table 4

Based on Table 4, answer the following questions.

(a) State one solution which has the following properties:

(i) Neutal:................

(ii) Alkaline:
12 marksl

(b) Identifu the solution which contains the highest concentration of the
following ions:

(i) Hydrogen ion :

(ii) Hydroxide ion:

12 marksl

(.) Name an example of solution V.

U nark'l

(d) Distilled water is added to 20.0 cm3 of solution Z to make 100-0 cm3 of
solution.
Calculate the new concentration ofsolution Z-

p narksJ

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SULIT 9 4541/2

(e) Diagram 4 shows the preparation ofsalt Q.

Magnesium
carbonate
.F.,",,;;l-.*F;l.m.E
Diagram 4

Answer the following questions based on Diagram 4.

(i) Name salt Q.

ll mark)

State the solubility of salt Q.

, lt markl

Describe briefly how to prepare a solution of mlt Q from

magnesium carbonate.

13 marks]

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SULIT 10 4541D

Section B
[20 rnarks]

Answer any one question from this section.

5. (a) Diagram 5.1 shows the electron arrangement of a molecule XY+. The
letters used do not represent the actual symbols ofthe elements'

@ @:
Diagram 5.1

Based on Diagram 5.1, write the electron arrangement for atom of

elements X and Y.
. l2 marksl

(b) Table 5 shows the proton numbers ofelements P, Q, R and S.

Element Proton Number

P I
a -,
R 6
s 8

Table 5

(D Arrange elements Q, R and S in ascending order of atomic size.

Explain your answer.
14 narksl

(ii) The reaction between elements Q and S form a chemical

comPound.
Describe the formation ofthis compound'

16 narksl

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 l1 4s41D
SULIT

(c) Metal X is
Diagram 52 shows 0rc r€actiol betni'een metal X and watcr'
a Group 1 elemenl

Water

Diagrarr 52 -

Bi using three named aramples ofGroup I elcments' desoribean

to in the rcactivity ofGroup I elements with
"ip".i--*t
water.
"stigarc
of the
inlour des"ription include a batanced chemical equation for one
thrce reactions involved.

lSnwksl

SULIT t2 4541n

6. Diagram 5.1 shox,s two containers ofchloride sah- The sahs can be preparcd
in the school laboratory.

Lchloride M chloride

Diagram 6.1

(a) (D L chloride is soluble in water while M chloride is insoluble in

water-
Suggest a name for L ohloride and M chloride

Vntksl

(iD State suitabte chemicals for the PreParation for M ohloride in

dGXr).
\lhfte a balanced chemical equation to r€present the reaotion'
\ [a narksl

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SULIT 13 4541D

(b) Diagram 6.2 shows the wastewater from a textild-iactory. The water is
found to be contaminated with hydrochloric aoid.

Diagrara 6.2

Describe an experiment to determine the concentration ofa

hydrochloric acid solution using titration method. A standard solution
of 0.1 mol dm-3 sodium hydroxide is provided.

In your description show t}e following aspeots:

. A list of materials and apparatus

o Procedure of the experiment
. A labeled didgram showing the apparatus set-up
o Table of result
o All the calculation steps involved

[4 marks]

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 454112
SULIT

Section C
For
[32 marks]

Answer all questions from this section'

to determine the
7. Diagram 7.1 shows the set-up of apprltul-for. an ?xP€rlneT
p"tiriiJ al*"**e of an electroche#cal cell using zinc and copper as electrodas'

Copper
l-?W:-'=-!W::
.:#.{:j-#=
_-_-lrit_-_---_-_g----.
---'-E*:---':-fi:--. After 30 minutes :;w;=t%
'-:--:-:-:::-::--1r--@::
-::-&----:---#-- .:---------_----------:-.
:_-----------_--------j
sulphate
solution
-
Diagam 7'l
i

this oxperiment after 30

(a) State the observations that can be made from
min8es:
Observation
Description

Zinc elootode

Copper electrode

The copper(Il) zulPhate solution

l3 narks)

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SULIT t5 4s4rD

The experiment is repeated by replacing copper with metals P and Q as For

electrodes.
'Diagram 7.2 shows the voltneter readings of all the experiments'

Zinc I Coppr MetalP I Zinc Zino / Metal Q

Reading: ........ Reading: Reading:

Diagram 7.2

(b) Record the voltmeter readings in the spaces provided in Diagram 7'2'

Il marksl

(c) Construct a table to .""orA tt voltmeter reading for the different pairs
of metal.
"

13 narksl

(d) Based-on the experiment, state the

(0 Manipulated variable :

(iD Responding variable :

(iiD Constant variable :

13 mula]

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 16 454112
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difference in this
(e) State the operational definition for the potential
experiment.

13 narksl

lscc D?It Ptge

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SULIT 17 454tD

Diagram 8 shows two test tubes containing glaoial ethanoic acid in different
solvents.

Clacial
Glacial ethanoic acid
ethanoic acid in dry
in water propanone

Diagram 8

Based on Diagram 8, plan a laboratory experiment to investigate the solvent that

is needed for glacial ethanoic acid to show its acidic properties.

Your planning should include the following aspects:

(a) Problem statement

(b) AII the variables

(c) Statement ofthe hypotlresis

(d) List of substances and apparatus

(e) Procedure for the experiment

.
(0 Tabulation ofdata

|7 narksl

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 IIELAIAN JAWAPANFSEI
NO.SOALIN:

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