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SF Jobs p> hh Jef concentration time" WIS CALE sbsbe (4.2)I4. Debt ws utee- Sumo st ubbiie te Sigh UE Sep Ef ete ELSI G2L wit asl mol L iq Sor ats ®Seu pen Sieur Let hii caren dikes, yah os CyHeCl + H,0 + C,HgOH + HCL wil AE t/s 0 50 100 150 200 300 400 700 800 [C,HgCl]/mol L* 0,100 0.0905 0.0820 0.0741 0.0671 0.0549 0.0439 0.0210 0.017 UPL Pam Sam Asp ESP td Late Gade iee tien Sty ASM Secs. dve (on: AoA AY Pee Cy L OE is Poa Poe EEC oO Ao ees os 0.4 x 104 Le 1.90«104 mol I'S LIS UPbea 44.1 ee Hh bre CRUE Pb LV SIA RAI thts mol LES BIPEAS He SII SI PO PLE By, LO LLG EAM athens Felcher ad perp hid La tdebiz ede rest MesLofes -es =AIR] _ Alp] At At 43) Fae At 042aR] at dt SI UAbuxt= 600 0.08 200 400 600 8001000 Time (3). ———> GPL SGVLvd MLM Levee KU 41 JOOP es CYL PHL WE tangent) Wyte Lte6008-< PW FS AL conti Yuh fe ( 0.0165 - 0.037 So, Ting at 600 s = | P0165 — 0.087 ["a00-400)s | mol Lt = 5.12 x 10° mol L's Att= 2508 —tingg = 1.22 x 10 mol L's t= 350s 1.0 x 10 mol L?'s t= 450s 64x 10% mol Ls Hig) + Ch @ > Hecho) Se Bier ASI tl ode CL ee ui tele Al A[Cl,] _ A[Hgc At SJ br Ge UA Sst oe UA html Jost LAY SYM ait, Sn Url tober oF 2HI@) > HL@) + Le) a2 JSo (CaHgCD) 4,5 6 9 Bel F eiylte © uo(stoichiometric coefficient) 7 bk EL ath i Pmt ee? Lol UPS iI IE PLU PASSEIOIL JOS tolume oe PSPS ithe ASSL nL IP Se Ee beet sWeuuesee of md £ Lege uiite Be wl #¢hs—_1 Alem) _ Al, VAI E 3g at LL Beet 5 Br (aq) + BrOg (aq) + 6 H” (aq) > 3 Brg (aq) + 3 H20 () cfa-}aloe] __a[Br05] __1alie) _ af) _ 1 alt) ro 5 At At 6 At 3 At 3 At ete CL LI 2M LIK ewan PL ae PLUS REM i2 USL vest EE SIL N05 t hab KI 0, INOS N05Z818K 208mol Seb, £22184. 182.93 mol MIE NOs OE ve digwonesh 2N20s (@) > 4NOz(@) + 02 @ UP SL stttg L Op LN ME al PUT Pha SISO) Se _1[AIN,O.]} __1](2.08-2.33)molt* Ure sat rai -}]22szagnmete’) & =6.79 x 10 mol L"!/min = (6.79 x 10 mol L* min“) x (60 min/1h) =4.07 x 10? mol L?/h =6.79 x 104 mol L* x 1min/60s =1.13 x 10° mol L¢st Sete en -}[202 SINGA] 6.79. 10-4 mol L-# min = 2.72 « 10° mot minOT est Ub SUS ct 0.02Me 0.03Myser 25 KITE ER PIB 4d AM Ele PUL UIS leben 04 mol Sef 0.5 mol bt ter 10sIFAE2A UG 4.2 Epps pes ae b ftel hoe & GptbelouD itu cend serge SWELL Geir a2 we 87 es shesi7 gu (Fivclor influencing Rate of a Reaciton) wet iL evens MABE E1421 bebleUpetc tif Rate Law SUPA SII, AL WIL Us (Dependence of were fe SUF Rate on Concentration) AYLI EM el Se bee bela we yes 422 Up ee SUI IL Where OSI UILUAUSL UI seus net he (Rate Bt Sib Boe Expression and Rate aA+bB > cC+dD ey ete £ brute tbe EL ott vita vecbaulg Constant) abner a4 U7 war BY Statin SEL (oaiadac7Se CL ubey nied ae He Ab er ene thet (4.4a) o kak BP a[R] _ By” (4.4b) ar > RUA Be! le < GUE (Aifferential rate equation 26-07 JFL F (4.4drenle ASSUPLR AM eve ZL (rate constant) LUZ e KLE ceed Pipe Were sie Ur bil whe Se Sete ALIN LG, WANE Ue SIGUA LT toLe Ft Fe Lhe EL rive Mo tone ye 2NO(®) + On{@) > 2NO2 (®) Lbee pin Li PUL Sons SUASIeUE ELL SEL ton Sis AL efiGil yee LA bei Ca2JuedutenKe beds UPS eS 04:4. 2Ue Len ee Cea Cn A RT yp eal 0.096 0.30 0.30 a 0.384 0.30 0.60 2 0.92 0.60 0.30 3 0.768 0.60 0.60 4 Je tavhsiG NO PTIOIL One Se bsbege LU8,60 bebe Y1-(0.384 mol L's "40.0982 brite BL ip etse; dues IAL Og sie OP TbIL Norse gL HIE NOMINEE SE ASL OWES be Pe dort sosictel ot eee Usd Lar rietazed Uf = RNOPIOg) ee PU Sees al =k{NoF [0,] Bene rAdnbee wt VL EW Meet we Eee 2 BE MILI Ve IL 3) ue evesae k [CHCl] [Cla]? = UF CHCly + Cl; > CCl, + HCI -1 k [CHsCOOCpHis!" [H0]°=U,/CHyCOOC,Hs + Hy0-+>CHyCOOH+C2H50H -2mut BI ce a nes onl Spee et gle LAF Oh SF IE Got OLS a! SBE SON MoS Oi ee Be BF satay FAS AS ot Ke aS pa HATO OS gage a Se atl ate Pat oe IE Hl gee Soe Sn aa) eeu? = KIA IB te upre bit mi Epa dBASE Sut sh Set uty vix PACS (overall orden HIFL JOE Mo KUMeFuI ta aenliets BLAU BEL UNO Bate Aly al Re He UE IS LPM SOIL uo te tUA AN SIL Ie oe Ft AS Ble nl aos T ES mee IIL sh we Brey ASP esi eh U7 = Kiar? BP? @) UF = kia? Br wy UA kar TBP) ae Bitexey =1/24+3/2=iIEAY OLE FE = 8/24 C1) = 1/2,287 ) ee SUI Be Dee ASL APE Fetuitie WbuIrRG Gast Len Kt bp Se ew ne oe PA er oi oe a —2-ut Lf (elementary reation)= ib) Pei LW comptes reactions) obSrggedW Ie fio vee Ate Fe MHL Ube 10 we Looser i) PrgsidessxtAle PAL Meyer ew deo (ge dst (adn kos BACSE 4.2.3 (Order of a Reaction)(Units of rate constant) ylslS1 4S hime eo JEL aA +bB > cC + dD KP Pe Ad L -c TKS Ex ty =n= le Rate, Karty 707 br GBI" SRL E SL v1, bs Se S01 f mol I ULE SI S61 Sota sue wt vei SEU Pas due Jay Uiied Swe Pesce VTL WL LG tu eAbiow k=2.3x10%Lmolts? (i k=3x 104s? Gi) SULT k= 2.3 x 10% Life mol SUIS BHU ALTE et We Qi VE-UAsin? wy eRe peas x 104s} sade IriS hE 1 -e Vu LEPICL Mit EL (molecularityy ed j FE pF BRU Leste) Ai wu ti bu: CEH SEM -< JI (moteculanity) ede FG Sut LF Sec Ke piriz AL Je bY (unimoteculan UCL LB Fee NH,NO, + Ny + 21,0 Put tl Jee teplluel grin, wes dur» Boxe 2HI > Hy + Ip ol erg seus dur 2NO +0,» 2NO; Letinia Elen Keen Jel wee hed lie Lrelbube ttenede tb Retiing le seo Au suid Miura fi KC10, + 6Fe80, + 311,804 > KCI + 3Fe3{S0,) + 34,0 he PERLE A PTE AS Mer ohg tr MRM SIG Se LeslSbil weber dB Lbdinete HEE tdi hl le. Nee Se PAL berepre LIGA KE Ase dn sk oe Kiigi Abs 6H tL rate determining step) b7 Us AU fib, ES Pad Sud na 21,0 +0, bs we gwen TALE sin : AA] (4,0, 107] we UO a Udrih tiy og tn Mt trot Lae Sy 1,0, +1 51,0410") 1,0) +10" 10+ +0, 2) ed SUG 42.4 (Molecularity of a Reaction)owl WW, Le Pi erio of ue bin dew Yip ude bUpa p Sines tenor Ke duty SLPS EES RFA Ee sido bere vie Instn cep Sy LP tmoleculantyedeytie Crt eee ed ZLusTeye 0 Fn hnEt fc BL LUE SS ped Be taht tingitidiar ay) BONEN £6 ahead Sbpyiee tpesle te beropreiid Letina cid ees TOE SCN e r= kiN? BRACE Las Bot Je 4s vii g pieces ic dndhleviiie boty xd a4 SSR UA SES see P¥Ut ie Wuene-Up SA Owes te Yes eh Uy 43 Luvpt Lut Bl eel SNL St BSE Chitegnated R AP nc SPL Equation lee the MO eT CS ye bee Met eos e3 LUI eerie een Up bed £4 we te PUL Joie te bi teil Por flc-ut bnvtrdbene uti £ eww bh u it ae Lyfe sd Levi iitede es LUC ize BL IR SIOIL HE RUA LE LT UT 4.3.1 -25, (ZeroOrder Reactions) ROP Ure dt kIRI ec US Be ESktet oe Mie =< ISIE RUE ARI, = HIV RE Zt =0 BS (RI UEA. Se ble a5) [Rp =-kx 041 ia VAS IRA. Sebe 0) IR} =-Kt+ [Rig Lvey=mxre ene SZ I 6 (4.6) elo Pr ee Pe LIF VoL ens eAz -- GEE RI lintercept) UE I= kee VS YI4S Poe BHU LI barf aor IR JEG R—> k= -slope wen ot (a7 ke Co utete sey bel ui Lip Padng uF Wrrcw Wr stous Apis eit ert ated Seuwst © a Js. Sty IIIS pw) de “UO Ce OES crs lt 2NH, (8) —wcauaya—? Na (8) 43H, (8) reba = k=U7 ¢ 2 peene Muted ee linia heen UPS day we tus! ar Pa awl oy 4.3 JS2nen Mote Lreneut aa) IR] =-Kt+1 ey OU POSS ile BE tan eI SUIK SE IRIUIER = [Rost = 0-2 OWE Aboed asjenind ut IRly=-kx 041 (R= 1 EWES La ene 49) InfRI = -kt + InfRly fer hipilhete — R] F in rh 4.10) EH Ebe shes a1 ‘InlR], =~ kt, + "IniRl, ghey (4.12) IMIR], =~ kt, + InfR]y BAL Uhre Bits tye) I RLU Zhe aanzaay InfR],~ InfRL, =~ Kt, ~ kt) (Rh - wrk -4) — 1 yy iRh (-4) "RL eo MWe 2 Aboot agen mn !B) ie Rly (4.13) 2 antilogte bus «A Bie? 43.2 ee (First Order Reaction)14 IRI= IRI, e* Lb EL unmnneAgh Lirey = mx +6 ene He Impl CR se = GK te LIGA) et bee a1 tees bied _ 2.303, [R], (4.15) k best] og Ro. _ kt TR] 2.308 W/2.3082 249 45 Put Le Sy L tltog Ros AA ee OM SUR IL AT CoHy(a) + Hz (@) > CoH) Slope = k/2.303 Jog (IRI,/IR) ——> ° Time ——> log IS bw Bi ces 4.5 Se SUS obs Says IRIG/IRT RS IV ee IS og sin£601.24 x 10? mol E61 SEE NOs LUTE Abie, 318K 45d G5 z0.20 x 10 mol L*/€1/N,O5(@) > 2 NOg{g) + 1/202 (@) 6 Nz054 (ees 2LUibie} k(t ~t) - Biel, 2.308 2.303 tog Rh k= @-t) "ini 2.303, Joy 1.24107 mol L™ = (60min-Omin) ” 0.20x107 mol L > - 23819 1og6.2min“ k = 0.0304 min* BLA SAE Ag) > Be) + Ci) PHLE NL Pre nib Kt Sran iba ALB ob ee Ste bb een BLOF p= Dy + Py + BAULEIIL) “UAL CAB Meet Dg Py Bet VEU L6L = Lem ze X atmf CL AytA ~brx atm fei tse Ag > Be) + Clg) At t=0 ptm Oatm Oatm Attimef (j-x atm xatm — xatm bur-opure P= Pi-w) #xEX= pL +x x=(- PD) Pa =P1-X=Pi- (he - PU =2p1-P mM Ylesr)303 » 2.303 jog _Pi_ tap, -p) 2N,0s (g) > 2N20, (8) + 02 (8) ae sy (atm) i) 1 oO 05 2 100 0.512 Ay Jn Bev E005 6642 x atm GE IL w.059 LB vb SOI 2 x atmut IL NOs) Fut Lb IY Li6 Ong) sn NzOs(e) 2N,0,(8) + —On(8) Start t=0 0.5 atm Oatm Oatm Attimet (0.5 ~ 2x) atm 2x atm xatm Px,o, + Pxio. + Po, =(0.5- 2x) + 2x+x=05+% x=p,-0.5 Ps,0,= 0.5 - 2x =0.5-2 (pt-0.5) = 1.5-2pt 0.512 atm = 15-2 0.512 = 0.476 atm Using equation (4.16) 2.303 o.satm = 250344, jog 5am 0.476atm 2:308 9.9216 = 4.98x10"s* 100s 46 de IF chet iti bal iii tesire supassar AMS G43.3 ti Slatin Wl atone E-UZL LLY = fRb=IRI (Half-Life of a Reaction). 1/2IRlo ~ bya R UME RE el ONSIL UO yd ESI Se Cog me he EUR L LL MiiTes =[R], -0.9991R|, 2.303, ,[Rl Ke = 2508 og Ro 1s) t TRI (Ro, 2 eth SIU ori k= 2:303 4g [Rlo ty, [RI/2 (62 = 758 toga RI, 4.16) at tyalRI= tn =22%% 0.001 0.693, ty See ote te Pid LTE AE Ob ils, aU Aid Lettie de tiie Gil -e FSU ELBE ty pb LRT Ae typ aIRg ee LILY PABST _e k= 5.5 x 10M STOOL AG eo fpiid i Seiad 0.693 tat hia ___0.693 4 35x10 S" neh 108 (YY AIR Med LIES oo 9 LIBEL AE eth 9.02 a =1.26x10"'S2.303, [Rl 7-303 jog (Re eee FR) [Ro IR} -0.9991R1, = 2808 jogo" _ 2.303 log. t= 6.909/k LEA aig hs t1/2 = 0.693/k t _ 6.909 k ak yo tn Kk ~ 0.693 uta dere JEL CHL Leu nied SUL Letibiebypaadne prceentrn cone time | (Rlo/2k Kt=[Rlo-(R] | dIRI/dt= -K or mol is time? or s7 In 2/k InfR] vst | [RI=[Rloe™* | dIR]/dt = -K{R] RoP 1 or kt = In(fRIO/IRD UBS LiL nL nethL bir e thn bre o Se tehT fies Le cities o.01mel AL bt rom» tur Joe Ger eit Last bramoar incl nL Wwait=ottysom£ un EAL 44 SaiT (Pseudo firs CH,COOG,H, + 1,0 —#L, cHCOON + CyHOH t=0 0.01 mot 10 mol omol mol © mol 9.9 mol 0.01 mol 0.01 mol Kereosd i dititenien til bowl Jos Uf sk [CHyCOOCHG] [10] deren oA Ler 2L BS io Uf k =ICHgCO0C 2H) KA na “UE Order ReactUlgk = k’ [H,0] SU Te A Wel Pe EA AL Waite Ai ple eb iI AW inversion ESL C1gH20,, + HzO —“ +> CeHy20g + CeHi20¢ et it rad Uf ek ICrala20n1) Lab EEL YUE bbe th CUM L ae i SH UBUT ol et OW LOB Sih Ls Umin oO 30 60 90 C/mol L-1 0.8500 | 0.8004 | 0.7538 | 0.7096 8 Se Ie (65 mol LY LIL it Ua LS Se iS tena Opie U/ k’ICH,COOCH|[H,0] ede ere SAIC mo LE WATE A Be bieen BHU 2d Live jie viet Is f= 2508 tog So t Cc Ue te =fe[1,0] SRL ie Poult t/min ‘C/ mol L* k/mol L7 oO 0.8500 - 30 0.8004 2.004 x 10% 60 0.7538 2,002 x 10% 90 0.7096 2,005 x 10% We Gt £2.004 x 10-3 mine Pkt O) Se Oy ry BESIWL Boer efigle DiiTed k (Hz O] k [55 mol L” k= 3.64 x 107 mol? L min 2.004 x 10° min“ = 2.004 x 10° min ay SEFis sg£ GUL g LISx10%s! LeU PK Te-A, thy Pit 2 6080,Cl, 4.6 Fe POT SIL ety CoOL Se ES mr05¢2L Seu Grunogocut& 5 z25curei2 50°C Cede Ie nrpwoads Nae SEES au Saracen AES airanl Jeet ‘ React WEL utr Fb fi Sevéic und (4.18) -< “te mol manne Ep he ub Surtion H, (g) +1, (g) > 2HI(g) eS WE FT fi bird £ IES are LEAL LeSboIom£dfee ver Se ae SIti— butt ere Seu re we bet zooifevers SEW FL riguel ous PE MLS ILS HE SSF SPL oF Frtien Mil Sith 1 Servet A Seth Lis $097 FH LES sot Le SH 7LZs1p/N) StF 7 vy Uly 4.8 Pe Po” WKS CUE Np ales So Lue (most gti de Sat SKF Sete & 509 F probabbie) we SEL Sud sr dx Faud Sout Lo bev fe Seu pare Shi nibeS Pie sei teow ethlig B49 Me Je Cu Stiei teary BoA ro se WL IL Remit Ke Ls te HPI Fn, Ley te POR, geet bh Eafe ates eUbuisiite gle sy je Breese AS goo le Cree be CHIVES Mpre Sei, Oe SF CaS IS ele yl gulp yale: 4.7 JS ASI Es ab S GIS be —> Most probable netic ene Jw t+ 10) Sky eu doitethno fier EA Set Ludi Wrotia k= ret” Bt ar webeyst be rL arene ese (ais) nk = -2 na ES at (4A) ebLgT eal E, 4.20) Ink yep A ~e iw agen yh i720 Ea (4.20) Ink, =-pr + (eB Leen ALLY (4.20) FU 2g eg wh Tes ei ZAL eal gif eturnen- ft InA. Intercept = In A eu Slope = - B/R (4.22) o ws E, i Ea 294 Shs S1/T NI 4.10 JS ose 2303R| Oe S1/Tys'In ke és EPL Sp sta 10.075 110.0252 7 EU AL isi-700ks'500K 410 die tog - Ea _[E=% 8, *2.308R| TT & 1og.0:07 E, ‘700-500 % 0,02 “|2.303%8.514JK“mot™ |! 700x500 0.544 =E,x5.714 x 10°/19.15 E, = 0.544 x 19.15/5.714 x 107 = 18230.8 J a)SL = Ae BRT o.0n= Ae 1#230:/8.818 500 A = 0.02/0.012 = 1.61 So 1.60 «10-5 AUP Tepe LES ey et zo00K eS tiew CoHigllg) > Coty (@ + HI EE pL 265,700 kc 209 by mol AES LAE B, [2 log ko log ks = 3 55R FT tog kalogk, +5 a 2303R|T, T, 209000 J mol L* [ 1 1 | =lo + 5359x8314.) mol LIK 7 =108(1.60%10")* 9 3938.14) molL"K" | 600K 700K pth See DALAL LAPP ee eis ty asa metre ate VEE AS ESAT pio MPs ttect of 2KCIO, —™™°2_, 2 KCl +302 Ctalyst) GWE LIL He PES gh SOB AoA EPIL bs AMA tbh Retin teal uel oti bibs Cherie iO Sate le brass bot hte thE wes Let at Se bes URGE Gee Se bo Met ee 18 en Sr E SASL F Satie PS dae 9 IU ooh SAT ISSSESS her Alien Sumo ae fog Sho MES WIL GL nF PEST WILL rhs, ILE LAG PronAL Gib Lek Beonl Wi ble LO FetB Udobackward) 2 SF 1! forward 2 SLI bn Pee he Lele Susi te Atle WE Bs 1B Kel a 46 ft oi6-18L Lurk FE cul tr SIL cus Seb WL euPGWl Sie by b AASB L citi ety epuit ire SIL P Seti SE Sine Ju meu LL sebedl ius Sekar A+Boct we Oba kA beet tiuP 4.23) Zye®l™ yd ett Abell et Me Lb her pil Buin hiZ whe (gh Se ebb tiie 6 M23. ebb tL Loe L Bauer? cer phiP aes EEN GAS RHUL ew Pele oes erigtaasyene PR Le Sry mel Vb het rl ath Hh Vee (4 F Sviha) SID reve tepid Later ESS vo eis Ve tHubwl gritos l goon pil ie Fes One 2 LA coe + dH cHon + Mahe. H-CBr OH > USS ! sul “Uf Lb (effective calisions) SES Sate Pir g AL Je H . fa] eB a on iH nee Sev ite be Oa RP Mong Letdy 2 oF Ab ote Dy Sus st ew 4.12 JSo I peas My At S * Wy aanPUI MY See Sou. Srey ttu Sips wpe 12 BOL Wu tur dbl Sie ty LA Pa PL gle te yor! uf Se no eI beureng SOUS a7 WV loKe 298K Lez 4.8 2.2005 kamor fii ysaned CIvpioe 4.9 2H) > Hy +h @ IRE pe Selle teu! PS Bae OAS Sec deh mei UI L dete ite VerSeCrobepetee chee eri vu PEL Lapoidied L dobar is. net Sei ih on oul udnplafar 26. PRP Ute Seleybiz LABS Wher E eS ISU} -<1B) «02 mol MA = 0.1 mol k=2.5% 104 mol! L PL ue Usa t(we ulevi fe Lewwitiow a1 3NO(G) + N20 (g) Rate = KINO]? Hg0> (aq) + 31” (aq) + 2H* > 220 0) + Rate =k[Ha02IIt] i) CH,CHO (g) > CH, (@) + CO(® Rate = kICHyCHO}?/? cui) CgHgCl (g) + CaFy (@) + HCL ®) Rate = KICZHSC] Ov) ce si hayse PEEL Hy niNq-e OS ISN. 2.0 x 10% mol? SU SSK S MAIBLUZE £20 +B AB IE 42 Eohes £610.06 mol L* eS wi SI 49 PeeWee ter toute commen tel Based 44 UA kICH,OCHP? we Py toi Laur Rite Sifu yp Sous tetas A Se Cun viSum netic (ter Sota Sires ps sede on k(Payoo, =e F SZ river 48 DiS he bc WG IG e Mie err SEI 46 Lb w) ebb wo OPENS SAIL eAi7 ging Ue te MC ig BHUZE IG 4.7 te hey Spe EME ML AML ARG 48 vs ° 30 60 90 [Ester] /mol L* 0.55, 0.31 O17 0.085 Eh Upp SWEEE eorg0 SUPE ALL ULE ww OTE LB le OME LASIL 4.9 Foner dy IPL sis bo MPI LS ia hi6 iB! (i) BMG TEL Csi BEB iad woe Abe SUSE IEL YL er Bla 4.10 UEA/ mol L* 0.20 0.20 0.40 B/ mol 0.30 0.10 0.05, r0/molLs+ | 5.07 x 10° 5.07 x 10% 1.43 x 10 feo ie er eS BWIA 2 Labo beeuinl WAL J6 431 2A+B5C+D 1Al/mol | {]/mol L-* orbs D/mol L! min? 1 oO. On 6.0x 10% qn 0.3 0.2 7.2% 107 mm 0.3 04 2.88 x 107 Vv 0.4 O21 2.40 x 107 pete ti SAL LG pee Ch Re ert f Bale Chie ALL x or LBaihe orb Sa 432 Sift Sot due IA mol? | tBI/ mot? vAbuzs /mol Lt min 1 OL OL 2.0 x 107 0 - 02 4.0 x 107 ur oa oa - Vv - 0.2 2.0 x 107 AE PASS Me em SPPUE otis 48 years? 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Fe 1.0 mol LI SUI A Jive ke = 2.0 x 10284 LUA FLA Products HL) 4.24 aE pbiiad n& wt 100 Bee ty 2008S IRL SADIE AKA Rail Sid 4.08 SERAPH iloe Ie WL cub tiger Mitt] 4.26 k= (4.5 x 108s) @28000K/T ESE, einer bos EM ite BS 10, 4.27 log k = 14.34 - 1.25 x 10¢K/T. Srer2s6 As K pe qn Kul eS BLL GU 60 kJ mot SUI ME sie 4.5 x 10° SUIS KELL Bites az 10.9 4.98 6Fr1.s x 10s UBS kzeu7 LwLod sin tsasn,s0sK cht glad wl SiMe} 208K 4.29 EAS canikgaisKivea x 1033S AS e ie PELL Soule deny LG 6 313K = 209K te 2nd ASE 4.90 eR beAL erg SSE een Bebe) weld eo el be aot 4.1 ty = 6.66 x 10° Ms! 42 WUPUASL mia = 0.005 mol litre" 'min™ 43 2 2-5 TKS 44 XoY Of = xx? Beso tes 45 t=444s 4.6 1.925 x 10451 4.8 Ea= 26.43 kJ mol! 4.9 1.462 x 10"