CHEMISTRY Boyle’s Law Charles’ Law GAS LAW’S WORKSHEET Guy-Lassac's Law Combined Gas Law For a given mass of gas at constant temperature, the volume of a gas Kelvin te constant. The volume of a fixed mass of gas is directly proportional to its the pressure is kept emperature if constant, The pressure of a gas is directly proportional to the Kelvin temperature if the volume is kept [Combines Boyle's, Charles’, and the Temperature-Pressure relationship into one Jequation. Each of these fiaws can be derived from| this law. Dalton’s Law Ideal Gas Law bv 7 k V|P|T2 = V2P2T| PY, Graham’s Law [At constant volume and emperature, the total pressure exerted by a mixture of gases is The [deal Gas Law relates the pressure, temperature, volume, and mass of @ gas through the [The rate of effusion/diffusion of] fowo gases (A and B) are inversely] proportional to the square roots Jequal to the sum of the pressures exerted by eacl gas constant “R”, Jof their formula masses. [Jt can be a ratio of molecular speeds, effusion Idiffusion times, distance iraveled by molecules, or amount of gas effused] PtP, +P, +..P, Prout = ‘Abbreviations PV = nRT Rate, _/molar mass, Rate, molar mass, Standard Conditions atmosphere millimeters of mercury another name for mm Hg kPa = kilopascal C= degrees Celsius 3K 760.0 mm Hg = 76 cm Hg kPa = 101, 325 Pa = 29.9 in Hy Conversions Gas Law's Equation Symbols K=°C +273 Fo = 18C° +32 F-32 18 1 cm3 (cubic centimeter) = 1 mL (milliliter) 1000 mL. 1 dm3 (cubic decimeter) = 1 L (liter) [Subscript (1) = old condition or initial condition ‘Subscript (2) = new condition or final condition Temperature must be in Kelvins n= number of moles = grams/Molar mass R= 8.31 L-kPa/ mol-K = 0.0821 L-atm/mol-K (62.4 L-Tort/mol-K ‘You must have a common set of units in the problemCHEMISTRY GAS LAW’S WORKSHEET T. Convert the following temperatures to K. a) 104.C b) 3c [2. Convert the following temperatures to C. a) 67K b) 1671 K S.A sample of nitrogen gas Jnas a volume of 478 cm3 and la pressure of 104.1 kPa, What Volume would the gas occupy| lat 88.2 kPa if the temperature remains constant? l4. 8.98 dm of hydrogen g lis collected at 38.8 °C. Find the volume the gas will occup| lat -39.9 °C if the pressure remains constant. S.A sample of gas has a volume of 215 cm? at 23.5 °C| land 84.6 kPa. What volume Iwill the gas occupy at STP?CHEMISTRY GAS LAW’S WORKSHEET (6. Ata certain temperature, Imolecules of methane gas, ICH have an average velocity lof 0.098 mis. What is the laverage velocity of carbon ldioxide molecules at this same| temperature? I7._ Find the relative rate of diffusion for the gases chlorine, Clz and ethane, ICoHe. I8. 495 cm? of oxygen gas and| 1877 cm? of nitrogen gas, both lat 25.0 °C and 114.7 kPa, are injected into an evacuated 1536 cms flask. Find the total Jpressure in the flask, assuming the temperature remains constant 9. A sample of gas is transferred from a 75 mL. lvessel to a 500.0 mL vessel. I the initial pressure of the gas is 145 atm and if the temperature| is held constant, what is the Jpressure of the gas sample in Ithe 500.0 mL. vessel? 10. A sample of gas occupies a] Volume of 450.0 mL at 740 mm Hg and 16°C. Determine the volume of this sample at 1760 mm Hg and 37°C.CHEMISTRY GAS LAW’S WORKSHEET TT. One mole of gS gas lescapes from a container by leffusion in 77 seconds. How long would it take one mole of INH3 gas to escape from the lsame container? 12, Convert a pressure of [0.0248 mm Hg to the lequivatent pressure in pascals (Pa). the initial pressure is 3.80 atm, lwhat is the final pressure? 14. A bubble of helium gas has} la volume of 0.650 mL near the| bottom of a large aquarium lwhere the pressure is 1.54 atm land the temperature is 12°C. [Determine the bubble’s volum( lupon rising near the top where the pressure is 1.01 atm and 16°C. 15. At what temperature Celsius will 19.4 g of Imolecular oxygen, Op, exert a Ipressure of 1820 mm Hg in a 5.12 L cylinder?CHEMISTRY GAS LAW’S WORKSHEET 16. A sample of nitrogen gas, IN2, is collected in a100 mL. container at a pressure of 688 Imm Hg and a temperature of 565 °C. How many grams of Initrogen gas are present in this lsample? 17. What is the pressure in Imm of Hg , of a gas mixture that contains 1g of H, and 8.0 le of Ar ina 3.0 L container at 27°C. 18. To what temperature must 132.0 ft3 of a gas at 2°C be heated for it to occupy 1.00 x 10? f3 at the same pressure? 19. What is the pressure in atm] lexerted by 2.48 moles of a gas in a 250.0 mL container at Se°c? [20. Determine the molar mass lof a gas that has a density of 12.18 g/L at 66°C and 720 mm He. |(Hint: the number of moles of la substance is its Imass/molecular mass land density is mass/volume.)CHEMISTRY a) 377K b) 270K a) -206 C b) 1398 C 564 em3 6.71 dm3 165 em3 0.059 m/s rate Cl : C2H¢ = 0.650 294 kPa 21.8 atm 470 mL, 54 sec 3.31 Pa 3.94 atm 1.00 mL. 27°C 0.0368 ¢ 4332 mm Hg 586°C 270 atm 64 g/mole GAS LAW’S WORKSHEET