CSIR-JRF(NET TEST BOOKLET-02 GROUP THEORY Time AuLowen : 90 Mins. Maximum MarKs : 70 MARKS; A. Genera 1, This booklet is your question paper containing 35 questions. 2. Blank paper, clipboard, og tables, side rules calculators, cellular phones, pagers and electronic gadgets in any form are not aliowed to be carried inside the examination hall 3. Fill In the boxes provided below on this page and also write your Name and Roll No. in the space provided of this booklet 4. A separate answer sheet (OMR) is attached with this paper, you have to mark answer on this sheet. B, Fauunc re OMR Sueer Please note that the information about Roll No., Test 1D, Name, Test Date, Batch & Mobile Number. I contains errors, the OMR Scanner will not be able to recognize your OMR Sheet. Besides, the candidates| are advised to read and follow the instructions given below : 1. 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You will be awarded 2 marks for every correct answer, 0.5 mark will be deducted under negative marking. Name : Roll No. : Thave read all the instructions Thave verified all the informations and shall abide by them. filled in by the Candidate, Signature of the Candidate Signature of the Invigilator A Quality Edvcation Centre oa 302018] Ph. : 0141-2703087, 93144-02754BH secssrrne0 reece _ oS ga For which of the following groups C, and Cv are in the same class ? a.c, b.c,, cD, 4. C, (A) a and b (8) Band c (C) b, cand d (0) a'and d The bonding in XH, can be considered in terms of the interactions between the orbitals of atom X and the LGOs of the H, fragment. For the LGOs, when X = B, the in-phase combination of H 1s orbitals has a,' symmetry, but when X = N, it has a, symmetry. This is because: (A) NH, has C,, symmetry, but BH, belongs to the D,, point group (B)NH, has D,, symmetry, but BH, belongs to the C,, point group (C)NH, has C,, symmetry, but BH, belongs to the D,, point group (D) NH, has C,, symmetry, but BH, belongs to the D,, point group An O, XY, molecule exhibits two T,,, IR active modes. Which statement is true? (A) Each’T,, mode is triply degenerate, and each gives rise to one absorption in the IR spectrum of XY, (8)Each T,, mode is triply degenerate, and each gives rise to three absorptions in the IR spectrum of XY, (C)Each 7,, mode is non-degenerate, and gives rise to one absorption in the IR spectrum of XY, (D)One of the 7,, modes is the symmetric stretching mode of XY, The symmetric stretching mode of the SiF4 molecule: (A)is IR active (B) is IR inactive (C)generates a change in molecular dipole moment (D)aives rise to a strong absorption in the IR spectrum CO, has: (A) 3 vibrational modes (8) 4 vibrational modes, 2 of which are degenerate (C) Stretching modes only (D) an IR active symmetric stretch The product of which of the following operations gives the overall result as identity - (A) ,. % 0/.% 9, (B) C0) x 6, (©) Coy F CGF x C2) (0) EX C,00"% Cy) The metrix representation of C,(y) is - 1 00 oot 0041 100 (Ao -1 0 (8) |0.1 0 (©) Jo. =1,0 (2) Jo 1 0 O -10 0. 100 00-1 Reduce the following representation to their irrederible representation in the point group C,h ch Ci o, : . 2a E Peg le ies |e ee T [at |i [a PRR, | 22 Au Cit [ala iz Bu eee |e eee [21 sy Character [3 [-1 [-3 [1 per atom (A)2Ag + Au + Bu (B) 2Ag + 2Bg (C) 2Ag + 8g + Bu —-(D) Ag + 28g + Bu 2 SARASWATI DHAAM’S Page @2 Ce OE cane enteEEE csc 9. 10. iL. 12. 13. 14, 15. 16. 17. Correct statement is- (A)A totally symmetric vibration is always Raman Active in any point group. (B)The IR and Raman Active vibrations always belongs to u and g species, respectively in centrosymmetric molecules (C) Both are correct (D) Only B is correct Find out the point group in IOF, and W[N(CH,),], is respectively - (A) GY, 0, (8) CT, (Cy T, (D) C,, 0, The point group symmetry for the following structures are respectively (A) C, and C,, (8) Chand C, (©) Dy and c,, (0) C, and ¢,, Out of plane bending mode of trans - dichloro ethylene is given below e ® H cl 2 om oe a Belong to which one of the following representation is (A) A, (B) A, (C) E, (D) None Determine the number of IR - active modes for fac-Mo (CO), CN(CH,), as shows in the diagram. = Be acs 3a, a ae T z oR) = 14 1 R, E 2 7 o | Gy (R,R,) = ¥.xy)(xzy2) (A) A, (B)E (C) A, (D) A and B both The reducible representation of NH, molecule is (Basis = 3N co-ordinate) EES ) Tree[ato [1 (8) fran Or >) Find out the point group in Biphenyl (i) planar (ii) staggered (ii) skew forms respectively (A) Day Dar Day (C) Day Dagy Dy (D) Dayy Dagy Cy The point group of 1, 3, 5, 7-tetraflurocyclo-octatetraene is # (A) Da, @)s, ©, (0) ¢,. The reduciable representation for all motions of the water molecule is reduced to : (A) 2A, + 1A, + B, + 2B, (B) 2A, + A, + 38, + 2B, (C) 3A, + 2A, +B, + 2B, (D) None of these. A Ry Ean Cte Page @ | oa SARASWATI DHAAM"—BH secssrrne0 reece 18. Select incorrect statement regarding C,, point group. 1. Total number of symmetry operations (order, h) is 5. 2. Each symmetry operation is in a class. 3. Because there are 5 classes, there must also be 5 irreducible representations. 4 ne DG peeve (A) 1 and 3 (8) 1,3 and 4 (C) 3and 4 (0) 2, 3 and 4 19. Para dichlorobenzene and naphthalene belongs to which point groups? (A) D,,D,, respectively (8) Dy,D,, respectively (C) Both D,, (D) Both D,, 20. — For metal carbonyl cis-M(CO), L, (point group C,,), the number and symmetry of IR active CO stretching modes are respectively : (A) 4, (A, + 2B, + B,) (B) 4, (A, + A, + B, +B) (C) 4, (2A, + B, + B,) (D) 2, (A, + B,) 21. Using the character table of C,, for POCI,. The reducible representation for P = O stret. and P— Ci stret. modes reduced to (AA, +E (8) 20, +E (©) 2A; + 2€ (D) 3A, + 3E 22. How many classes does D, point group have ? (A) Four (8) Three (C) Two (0) One 23. For CH , character table is Ta | 8, 65, 60, | tel x+y? +27 a Sie E 271 ono 22 2 le 0 1 1 (RRR) Po ee ay, 32.28 as | 150 -1 3 Calculate total no. of vibrational mode (A)A, +E #37, (AFA HEFT, (CLA +E + 27 (0) A, +E +T, +37, 24. The point of the compound Guanidine is (A) C, (B) C.,. Osc (0) T, 25. The total number of operations for D,, (A) 16 (8) 8 (c) 12 (0) 20 26. —Non-controsymmetirc molecule which vibration cannot be active in both the IR and Raman spectra I. staggered dibenzene chromium. II. C,H (Regular pentagon, D,,) He I1I.molecules belongs to D,, point group mM poacK) (A) Only T and IV (8) Only HI and Iv (C) I, 1 and Iv (0) I, 1 and m ee 3 SARASWATI DHAAM’S——- Page @ 4 —o A Gait Ednatnn CntEEE csc au Coy AL Ae By By Ay Zz 0 x y A | 0 z y x 8, x Y z ° B, a - o Zz symmetry species > B, Hy > 8, HAY The forbidden transitions is/are - L AOA, IL. B, © B IIL. B, © B, A, OB, (A) Only I and IIT (B) Only I and (C) I, Il and Iv (D) Only If and WT Direction (Qs. 28 to 30) GLE) 2G 3a ee ee Zz Xey ae yl E 2C, 30, Ahh A T f-1 R 202 e |} 2 0 |.06¥) (Rey) a 28. The irreducible representations into rotational modes : (A) 3A, + A, + 4E (8) 2A, + 2E (C)A, +E (D) A, +A, +E 29. — The irreducible representation into inactive vibrational mode: (A) 2A, + 2E (B) A, + A, + 2E (C)A, + 2E (D) None of these 30. — Which rotational mode is Raman active ? (AA, (B) A, (QE (D) A, and € 31. A triatomic molecule of the type AB, shows two. IR absorption lines.and one IR-Raman line. The structure of the molecule is : (A) B—B—A (B) B—A—B a A of, ON, 32. What is the name of IR’s of the LUMO of cis-butadiene ? (A) B, (B) Ay (C) B, (D) A, 33. The correct match is : (A) [TaF,]* — Point group Dd (B) Si(OMe), — Point group S, (C) Fe(Py), — Point group T, (D) All of these correct. 34. Water has‘C,, point group which character table is blow: Cy | E Cy ote) A I 1 1 Ai ono By 1 -1 1 Be 1-1 -1 1 The name of representation of character of the P, orbital of oxygen atom. (A) A, (8) B, toa, (D) PB, 35. 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