1.

Write equilibrium constant (K) expressions for the following reactions:

(a) I2(g) + 5 F2(g) ↔ 2 IF5(g)
(b) CO(g) + 2 H2(g) ↔ CH3OH (l)
(c) 2 H2S(g) + 3 O2(g) ↔ 2 H2O (l) + 2 SO2(g)
(d) SnO2(s) + 2 H2(g) ↔ Sn(s) + 2 H2O (l)
2. Write the equilibrium constant expressions for the following reactions:
(a) 2 NO3-(aq) + 8 H+(aq) + 3 Cu(s) ↔ 2 NO(g) + 3 Cu2+(aq) + 4 H2O(l)
(b) 2 PbS(s) + 3 O2(g) ↔ 2 PbO(s) + 2 SO2(g)
(c) Ca2+(aq) + CO32-(aq) ↔ CaCO3(s)
3. Consider the system
4 NH3(g) + 3 O2(g) ↔ 2 N2(g) + 6 H2O (l) ∆H = -1530.4 kJ
How will the amount of ammonia at equilibrium be affected by
(a) Removing O2(g)
(b) Adding N2(g)
(c) Expanding the container at constant pressure
(d) Increasing the temperature
4. When carbon monoxide reacts with hydrogen gas, methane and steam are formed.
CO(g) + 3 H2(g) ↔ CH4(g) + H2O(g)
At 1127 oC, analysis at equilibrium shows that PCO = 0.921 atm, PH2 = 1.21 atm, PCH4 = 0.0391 atm,
and PH2O = 0.0124 atm. What is the equilibrium constant, K p, for the reaction at 1127 oC?
5. A mixture of 9.22 moles of A, 10.11 moles of B, and 27.83 moles of C is placed in a one-liter
container at a certain temperature. The reaction is allowed to reach equilibrium. At equilibrium
the number of moles of B is 18.32. Calculate the equilibrium constant for the reaction:
A (g) + 2 B (g) ↔ 3 C (g)
6. At a certain temperature, Kc is 4.13 x 10 -2 for the equilibrium:
2 IBr (g) ↔ I2 (g) + Br2 (g)
Assume that equilibrium is established at the above temperature by adding only IBr (g) to the
reaction flask. What are the concentrations of I 2 (g) and Br2 (g) in equilibrium with 0.0124
moles/liter of IBr(g)?
7. The equilibrium constant for the reaction: 2 NO (g) ↔ N2 (g) + O2 (g) is 2.60 x 10-3 at 1100 °C. If
0.820 mole of NO (g) and 0.223 mole each of N 2 (g) and O2 (g) are mixed in a 1.00 liter container
at 1100 °C, what are the concentrations of NO (g), N 2(g), and O2 (g) at equilibrium?
8. Given the following equilibrium equations and their corresponding equilibrium constants:
(1) 2 CO2(g) + H2O(g) ↔ 2 O2(g) + CH2CO(g) Kc = 6.1 x 10 8
(2) CH4(g) + 2 O2(g) ↔ CO2(g) + 2 H2O(g) Kc = 1.2 x 10 14
Find Kc for the reaction: CH4(g) + CO2(g) ↔ CH2CO(g) + H2O(g)