2 HALF BOOK (OBJECTIVE) Q| a - ‘The deviation of a gas from ideal behavior is maximum 10. Quantum number value for 2p orbitals are: 11. Splitting of spectral lines when atoms are subjected to strong electric field is, 12. ‘Two solutions of Nat 13, An aqueous solution of methanol in water has vapour pressure: (fe fe fe fe fe ef i i af ff ee ere ba 8 incircle the best option, cutting and removing will cause deduction in mark MCQs A filtration process could be very time consuming if it were not a) Ifthe paper covers the funne! up to its circumferences 'b) If the paper has got small sized pores in it ©) Ifthe stem of the funnel is large so that it dips into the filtrate ) If the paper fits tightly Funnel should be large enough so that its rim should extend above the top circumference of the paper for about: led by a gentle suction which is developed: a) 12pm © 12mm b) Lem om Solvent extraction method is particularly useful technique for separation when the product to be separated i: a) Non-volatile or thermally unstable €) Volatile or thermally stable ) _Non-volatile or thermally stable 4) Volatile or thermally unstable ‘Number of molecules in one dm’ of water is close to: oF 28 108 b) pao” €)55.6 x 6.02 x10" Equal masses of methane and oxygen are mixed in an empty container at 25 °C. The fraction of total pressure exerted by oxygen is: a) 13 2 89 bh 19 a 1617 a) 10°C and 5.0 atm ) -10°C and 2.0 Atm b) 100°C and 2.0 atm 6) 0°C and 2.0 atm Pressure remaining constant at which temperature, the volume of a gas will become twice of what iis at 0 a) 546°C ©) 200°C b) 46K @) 273K Rutherford’s model of atom failed because: a) The atom did not have a nucleus and electrons 'b) It id not account forthe attraction between protons and neutrons ©) Hid not account for the stability of the atom 4) ‘There is actually no space between the nucleus and the ‘When 6d orbital is complete, the entering electron goes int ) 1 b) 7p a) b) called: a) Zeeman effect ©) Stark effect b)_ Photoelectric effect 4) Compton effect ‘and KCI are prepared separately by dissolving same amount (moles) ‘of the solute in water. Which of the following statements is true for these solutions? ) KCI solution will have higher boiling point than NaCl solution b) Both the solutions have different boiling points ©) KCl and NaCl solutions possess same vapour pressure 4) KCI solution possesses lower freezing point than NaCl solution a) Equal to that of water ) Equal to that of methanol 2b ap ap ap a ee bab ab ab ap ap af a eb ab ab ab ab ap ag ag ag bb xb ap ab ab ap ae eb ab ab ab ab ab ap a ae ee ab ab ab ap ap af af ag agJono toi teint tonidoiniioiidiiiit tit ttt t iio toiet toittok 'b) More than that of water ‘d) Less than that of water 14.18 g glucose is dissolved in 90 g of water. ‘The relative lowering of vapour pressu ¢ isequal to: a Vs ©) 5.1 bust )6 15. With increases of 10 °C temperature, the rate of reaction doubles. This increase in rate of reaction is due to: ) Decrease in activation energy of reaction 'b) Decrease in the number of collisions between reactant molecules ©) Increase in activation energy of reactants, «) Increase in number of effective collisions 16. If the rate equation of reaction 2A + B-»Produets is, rate = k [AJ [Band A is present in large excess then ord er of reaction i: al 92 bs 4) Pseudo first order 17. HCOOH — 1.0 + CO catalyst in this reaction is: a) Al ©) ALO; b) Cu Pt Bost of Luck Stagg bb bb bp ppg ee bbb bb bf ff ee ee ab ab bb bp ee eb bb ab bp ag ag ap a ee ee a a bb SESEEEEEEEEEEEEEEEEEESE EEE ESSE EEE EEE EEEEEEEEEE EEE EEL EEE EE EE HHH fe ee ee ef ee ee ee ea ee teFAR OI IC i tet te i i i tte tede to tototctete tet ted te te tet t ited * @ ALPINE DEGREE COLLEGE KHANPUR Fos] eran Same] cmon [ome] som Pomme] a _] browne [ [snonrnoe P__[tiveartonen [orn] (Suef omer Section-I 0.2. Write Short answers to any Eight (8) questions: (8x2=16) i, Define mother liquor, Describe method to collect crystals from mother liquor. . Give the silent features of an ideal solvent. . Why sintered glass crucible is preferred over Gooch Crucibles? Iodine is more soluble in water in presence of KI. Discuss. Define Rr value. Ry value is always less than 1. Comment on it. ‘What is plasma? Where itis found? . Convert -48 °F to Centigrade scale and Kelvin scale. ‘Why Pilots feel uncomfortable breathing at high altitude? Give mathematical expression for mean square velocity and root mean square velocity. X. Explain Charles's law according to KMT of gases. xi, Lighter gases diffuse more rapidly than heavier gases explain xii. Why the pressure Correction is done by Vander Waals? £Q3. Write Short answers to any Eight (8) questions: (8x2=16) i, What is cathode ray tube? How the emission of a P-particle results in the increase of atomic number of an element? Give equation. How the mass of electron is calculated by using e/m value? ‘What is plank’s Quantum Theory? Why atomic Spectrum is also called line Spectrum? vi, Calculate the wave no. of photon, when it jumps from Vii. State Hund’s rule & Pauli’s Exclusion principle viii, Differentiate byw molarity and molality x. Many solutions do not behave ideally. Give x. Why Fractional crystallization is carried out xi. State Ebullioscopic constant & eryoscopic Constant. xii. Define Hydration and Hydrolysis with examples. dQ, Write Short answers to any SIX (6) questions: (6x2=12) crystals are dried by different methods? al temperature? It depends upon what factors? Moseley’s Law? Write its importance. iv. What is meant by rate of reaction? Describe graphically. v. Define Instantaneous and average rate of reaction, ‘vi, What is zero order reaction? Give example. oii. What is reaction intermediate? Wii. What is catalytic poisoning? Give example rix. How a catalyst is specific in its action Ston=2 Ye Xb A Hb ae Me ae ab A A A OO ee a a a a A a a a * * Section-II eNote Attempt any THREE question (sx3=24) OS. a)Defin spectrum. Give diference between continuous and line spectrum. o 1) Explain Linds metho forthe iquetaction of gases. ® 26 apDerive an expresion o determine the radius of th bit for hydrogen atom, ® 3) Derive diferent unit and values of eal gas constant (). 397. Give graphical explanation for elevation of boing pont of a solaion ® : 3) What i homogenous and heterogenous catalysis? Give two example of each @ QB. a) Explain the effect of wrnperatur on phenol water system ® * 'b) Describe any four physical methods to determine the rate of reaction. @ HQ9, a) State Rol’ aw in thee different ways @ * 1) Explain the effet of temperature on rat of reaction withthe help of Anenius equation. 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