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World Bank Group. The new versions of the World Bank Group WORLD BANK GROUP
Environmental, Health, and Safety Guidelines are available at Effective July 1998
http://www.ifc.org/ifcext/enviro.nsf/Content/EnvironmentalGuidelines

Cement Manufacturing

Industry Description and Practices rials-handling operations, such as conveyors, re-


sult in fugitive emissions.
The preparation of cement involves mining; Ambient particulate levels (especially at sizes
crushing, and grinding of raw materials (princi- less than 10 microns) have been clearly demon-
pally limestone and clay); calcining the materi- strated to be related to health impacts. Gases such
als in a rotary kiln; cooling the resulting clinker; as nitrogen oxides (NOx) and sulfur oxides (SOx)
mixing the clinker with gypsum; and milling, are formed from the combustion of the fuel (oil
storing, and bagging the finished cement. The and coal) and oxidation of sulfur present in the
process generates a variety of wastes, including raw materials, but the highly alkaline conditions
dust, which is captured and recycled to the pro- in the kiln can absorb up to 90% of the sulfur
cess. The process is very energy-intensive, and oxides. Heavy metals may also be present in the
there are strong incentives for energy conserva- raw materials and fuel used and are released in
tion. Gases from clinker cooler are used as sec- kiln gases. The principal aim of pollution control
ondary combustion air. The dry process, using in this industry is to avoid increasing ambient
preheaters and precalciners, is both economically levels of particulates by minimizing the loads
and environmentally preferable to the wet pro- emitted.
cess because the energy consumption—200 joules Cement kilns, with their high flame tempera-
per kilogram (J/kg)—is approximately half that tures, are sometimes used to burn waste oils, sol-
for the wet process. vents, and other organic wastes. These practices
Certain solid waste products from other indus- can result in the release of toxic metals and or-
tries, such as pulverized fly ash (PFA) from power ganics. Cement plants are not normally designed
stations, slag, roasted pyrite residues, and to burn wastes, but if such burning is contem-
foundry sand, can be used as additives in cement plated, technical and environmental acceptabil-
production. ity needs to be demonstrated. To avoid the
formation of toxic chlorinated organics from the
Waste Characteristics burning of organic wastes, air pollution control
devices for such plants should not be operated
The generation of fine particulates is inherent in in the temperature range of 230–400°C. (For fur-
the process, but most are recovered and recycled. ther details, see United States1991.)
Approximately 10–20% of the kiln feed can be
suspended in the kiln exhaust gases, captured, Pollution Prevention and Control
and returned to the feed. Other sources of dust
emissions include the clinker cooler, crushers, The priority in the cement industry is to mini-
grinders, and materials-handling equipment. mize the increases in ambient particulate levels
When the raw materials have high alkali or chlo- by reducing the mass load emitted from the
ride content, a portion of the collected dust must stacks, from fugitive emissions, and from other
be disposed of as solid waste, to avoid alkali sources. Collection and recycling of dust in kiln
buildup. Leaching of the dust to remove the al- gases is required to improve the efficiency of the
kali is rarely practiced. Grinding mill operations operation and to reduce atmospheric emissions.
also result in particulate emissions. Other mate- Units that are well designed, well operated, and

275
276 PROJECT GUIDELINES: INDUSTRY SECTOR GUIDELINES

well maintained can normally achieve generation are sensitive to gas characteristics, such as tem-
of less than 0.2 kilograms of dust per metric ton perature, and to variation in voltage; baghouses
(kg/t) of clinker, using dust recovery systems. are generally regarded as more reliable. The over-
NOx emissions should be controlled by using all costs of the two systems are similar. The choice
proper kiln design, low-NOx burners, and an of system will depend on flue gas characteristics
optimum level of excess air. NOx emissions from and local considerations.
a dry kiln with preheater and precalciner are typi- Both ESPs and baghouses can achieve high lev-
cally 1.5 kg/t of clinker, as against 4.5 kg/t for els of particulate removal from the kiln gas
the wet process. The nitrogen oxide emissions can stream, but good operation and maintenance are
be reduced further, to 0.5 kg/t of clinker, by after- essential for achieving design specifications. Two
burning in a reducing atmosphere, and the en- significant types of control problem can occur:
ergy of the gases can be recovered in a preheater/ (a) complete failure (or automatic shutoff) of sys-
precalciner. tems related to plant shutdown and start-up,
For control of fugitive particulate emissions, power failures, and the like, leading to the emis-
ventilation systems should be used in conjunc- sion of very high levels of particulates for short
tion with hoods and enclosures covering trans- periods of time; and (b) a gradual decrease in the
fer points and conveyors. Drop distances should removal efficiency of the system over time be-
be minimized by the use of adjustable convey- cause of poor maintenance or improper opera-
ors. Dusty areas such as roads should be wetted tion. The lime content of raw materials can be
down to reduce dust generation. Appropriate used to control sulfur oxides.
stormwater and runoff control systems should
be provided to minimize the quantities of sus- Emissions Guidelines
pended material carried off site.
SOx emissions are best controlled by using low- Emissions levels for the design and operation of
sulfur fuels and raw materials. The absorption each project must be established through the en-
capacity of the cement must be assessed to de- vironmental assessment (EA) process on the ba-
termine the quantity of sulfur dioxide emitted, sis of country legislation and the Pollution Prevention
which may be up to about half the sulfur load on and Abatement Handbook, as applied to local con-
the kiln. Precalcining with low-NOx secondary ditions. The emissions levels selected must be
firing can reduce nitrogen oxide emissions. justified in the EA and acceptable to the World
Alkaline dust removed from the kiln gases is Bank Group.
normally disposed of as solid waste. When solid The guidelines given below present emissions
wastes such as pulverized fly ash are used with levels normally acceptable to the World Bank
feedstock, appropriate steps must be taken to Group in making decisions regarding provision
avoid environmental problems from contami- of World Bank Group assistance. Any deviations
nants or trace elements. from these levels must be described in the World
Stormwater systems and storage areas should Bank Group project documentation. The emis-
be designed to minimize washoff of solids. sions levels given here can be consistently
achieved by well-designed, well-operated, and
Treatment Technologies well-maintained pollution control systems.
The guidelines are expressed as concentrations
Mechanical systems such as cyclones trap the to facilitate monitoring. Dilution of air emissions
larger particulates in kiln gases and act as or effluents to achieve these guidelines is un-
preconditioners for downstream collection de- acceptable.
vices. Electrostatic precipitators (ESPs) and fab- All of the maximum levels should be achieved
ric filter systems (baghouses) are the principal for at least 95% of the time that the plant or unit
options for collection and control (achieving over is operating, to be calculated as a proportion of
99% removal efficiency) of fine particulates. ESPs annual operating hours.
Cement Manufacturing 277

Air Emissions Maximum allowable log


equivalent (hourly
A maximum emissions level of 50 milligrams measurements), in dB(A)
per normal cubic meter (mg/Nm3), equivalent Day Night
to a maximum of 0.2 kg/t of clinker, for particu- Receptor (07:00–22:00) (22:00–07:00)
lates in stack gases under full-load conditions is
Residential,
to be achieved. This emissions level is based on institutional,
values that are routinely achieved in well-run educational 55 45
plants. Maximum emissions levels for sulfur ox- Industrial,
ides are 400 mg/Nm3; for nitrogen oxides, 600 commercial 70 70
mg/Nm3.
Management’s capacity to maintain the nec- Monitoring and Reporting
essary operational and maintenance standards
should be carefully evaluated. If necessary, train- Frequent sampling may be required during start-
ing for plant personnel should be provided un- up and upset conditions. Once a record of con-
der the project. The EA and the prefeasibility or sistent performance has been established,
feasibility study should examine the effects of sampling for the parameters listed in this docu-
fugitive and stack emissions (including dust, sul- ment should be as described below.
fur oxides, and nitrogen oxides) on ambient air Equipment for continuous monitoring of opac-
quality and implement measures to maintain ac- ity levels (or particulates in the stack exhaust,
ceptable ambient air quality levels. whichever is cost-effective) should be installed.
Measurement of the sulfur content of raw mate-
Liquid Effluents rials and fuel, and direct measurement of particu-
late, SOx, and NOx levels at the plant boundary
Normally, effluents requiring treatment originate levels, should be carried out at least annually.
from cooling operations or as stormwater. Treated When operational upsets occur, the opacity of kiln
effluent discharges should have a pH in the range and clinker cooler exhaust gases should be mea-
of 6–9. Cooling water should preferably be re- sured directly and corrective actions taken to
cycled. If this is not economical, the effluent maintain the opacity level of the stack gases be-
should not increase the temperature of the receiv- low 10% (or an equivalent measurement).
ing waters at the edge of the mixing zone (or 100 The pH and temperature of the wastewater
meters, where the mixing zone is not defined) by effluent should be monitored on a continuous
more than 3° Celsius. If quantities of suspended basis. Suspended solids should be measured
solids in the effluent are high in relation to re- monthly if treatment is provided.
ceiving waters, treatment may be required to re- Monitoring data should be analyzed and re-
duce levels in the effluent to a maximum of 50 viewed at regular intervals and compared with
milligrams per liter (mg/l). Note that the efflu- the operating standards so that any necessary
ent requirements are for direct discharge to sur- corrective actions can be taken.
face waters. Records of monitoring results should be kept
in an acceptable format. The results should be
Ambient Noise reported to the responsible authorities and rel-
evant parties, as required.
Noise abatement measures should achieve either
the levels given below or a maximum increase in Key Issues
background levels of 3 decibels (measured on the
A scale) [dB(A)]. Measurements are to be taken The key production and control practices that will
at noise receptors located outside the project lead to compliance with emissions guidelines can
property boundary. be summarized as follows:
278 PROJECT GUIDELINES: INDUSTRY SECTOR GUIDELINES

Give preference to the dry process with preheat- European Community. 1989. “Technical Note on Best
ers and precalciners. Available Technologies Not Entailing Excessive Cost
for the Manufacture of Cement.” December 7. Pa-
per presented to BAT Exchange of Information
Adopt the following pollution prevention mea-
Committee, Brussels.
sures to minimize air emissions:
Fog, Mogens H., and Kishore L. Nadkarni. 1983. En-
• Install equipment covers and filters for crush- ergy Efficiency and Fuel Substitution in the Cement
ing, grinding, and milling operations. Industry with Emphasis on Developing Countries.
• Use enclosed adjustable conveyors to mini- World Bank Technical Paper 17. Washington, D.C.
mize drop distances.
Sittig, Marshall. 1975. Pollution Control in the Asbestos,
• Wet down intermediate and finished product
Cement, Glass, and Allied Mineral Industries. Park
storage piles. Ridge, N.J.: Noyes Data Corporation.
• Use low-NOx burners with the optimum level
of excess air. United States. 1991. Federal Register, vol. 56, no. 35,
• Use low sulfur fuels in the kiln. February 21. Washington, D.C.: Government Print-
ing Office.
• Operate control systems to achieve the re-
quired emissions levels. World Bank. 1996. “Pollution Prevention and Abate-
ment: Cement Manufacturing.” Draft Technical
Develop a strong unit or division to undertake Background Document. Environment Department,
environmental management responsibilities. Washington, D.C.

References and Sources

Bounicore, Anthony J., and Wayne T. Davis, eds. 1992.


Air Pollution Engineering Manual. New York: Van
Nostrand Reinhold.

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