MATERIAL SAFETY DATA SHEET MSDS No At Date Taner Jan. 24, 2013 Dale Revit Fob. 8, 2013 “Chemica Trade Nam (ny Used on aby Absorptive Glass-fiber Material Lead Acid Battery ‘Ghomica FamigiCasaticaton Electric Storage Battory TMS Kang for Sue ROT 302K ‘Syronyne/Conmon Name AGM Battory ‘Gampany Name Johnson Controls Battery Group Inc. Division or Dapariment Power Solutions ] IMDS Code andiaTA | BATTERIES (Accumuttom), WET, NON SPLLABLE, eect storage UN 280, las 8 Fares ‘tant Tt Andopatesh ‘GONTACT TELEPHONE NUMBER ‘Goesions Conceming MSS Health & Safely SLI Day: sisrmsaw “ransportaton Emergardae CHEMTREC 24 Hours: 10 seur 1, Hazardous Ingrodionts ‘Materia sow ‘Space Chemical ently | Blue Leaa 7439-924 ‘Space Chemical erty Lead Alloys with Traces of As, Sb ‘orsmon Name 7439924 ‘Specie Cherial Keniy Inoranic Lead Compounds ‘Common Name o 30.924 Specils Chemical Wentty Sulfuric Acid Absorbed in Glass-flber Material mo Name 7604-53.9Ii Potential Hazards No hazards in case of an infact ballary and observaion ofthe istrucions forse. Lead-acid batteries have to signifcant characteristics: + They contain diluted sulphuric ac, which may cause severe acid burns + Even the luted sulphuric acid is absorbed in glass-foer materia, it could flow out under condition of a destruction ofthe battery ‘Dating the charging process they develop hydrogen gas and oxygen, which under certain circumstances may tum Into an explosive mire, For this reason, the balleries have been marked with the following hazard symbols! bes Aca Or the recommended BCI label. (MPVs ve SHIELD Eyes EXPLOSIVE Ac SASS ausaie t Etoviele The signieance ofthe hazard symbol 4, No smoking, no open flames, no spars. 2 Wear safety goages. 3. Keep away fom eiliron, 4, Sulphur ac 5, Observe operating instructions. 8. Bxploswe gas mur. FLUSH EVES, IMMEDIATELY WITH WATER GET MEDICAL, ‘Adonai: Do Hot lean balieres with iy WasROTS, uso only Wal WashoTS IV. First Aid ‘GENERAL INFORMATION. ‘Sulphuric Acta GE aS a corosive and damages 1eeue. ‘Lead Compounds Have boan classified as being hazardous to reproduction, Ingestion of load occurs by hand te mouth contamination. Aer handling lea or ts compounds, hands must be washer prior to oating of dridking, Metalic ead eannot be absorbed through the kin. FIRST Al Lead affer contact to akin ‘Clean wit water and soap Sulfuric Acid after contact to Skin, Rinse with wale, remove and wash weited thing ‘Sulfuric Acid aftr inhalation of acid mist Inka res air and seek advice from a doctor ‘Sulfuric Acid aftr contact with eyes Rinse under running water for several minutes and seek advice fom a doctor ‘Sulfuric Acid after swallowing ‘rink aft of water immediately, and ewelow sctvated carbon and seek advicy rom a doctor V. Fire Fighting Measures Suitable extinguishing agente! ‘COpand sold exinguishing agent Unsuitable extinguishing agent Water in case of battery voltages of over 120V. ‘Special protective equipment: Protective goggles, respiratory protective equiprient, acid protecive equipment, ala- ‘equlpment, acl protective equipment, acl battery plants of larger cuantiies siored \Vi._Measures to be taken in ease of unintentional releaso Cleaning /take up procedures Use a bonding agent, such ‘sand, to absorb spilled acid; use limelsodium carbonate for neutralisation; dispose with regard tothe official local regulations; do not permit penetration into tho sewage system, the earth or bodies of water. Vil. Handling and Storago ‘Slofe frst trae under roof provent shot acuts. Do hat store In coaled,urventlated areas. Seok agreement wih local water aulhorles in ‘0280 of largar quantiles, Aold overheating and overcharging. Do not use organic solvents or othor than manufacturers recommended ‘cleaners onthe batteries. Ibiteriss hava to bo stored in storage rooms, ts inperalve that the instuctons for use are cbserved.Vill. Exposure Limits and Personal Protective Equipment sure caused by lead and lead compounds (CAS 7438-82-4 when handled properly ‘exposure caused by sulphuric acid and acid mist during filing and charging. | 7664-93-1 R-Phases R35 Causes severe Burns. ‘Phases Sz Keep locked up and out of reach of children S26 rinse immediately with plenty of water and seok $30 Novor add water to this product (applies for concentrated ackd only, and not for rofiling tho battory with water) S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible). TLV Value, 1.0 main? Hazard symbol , corrosive Personal protective equipment Rubber, PVC gloves, scid-proof gougles, acld-proof clothing, sally boots. IX. Physical and Chemical Properties LEAD APPEARANCE ] Form ‘Solid Color Grey ‘Odor ‘Odoriess. LEAD SAFETY RELATED DATA Solidification Point ‘327°C Bolling Point ‘740°C ‘Solubility in water (25 °C) ‘Low (0.18 mig) = Density 20 °C) 11.36 gicm* ‘SULFURIC ACID APPEARANCE Form Liquid Color Colorless. ‘Odor: Odorless ‘SULFURIC AGID SAFETY RELATED DATA ‘Solidification Point = 38 to = 60°C Bolling Point ‘Approx. 108 t0 144°C ‘Solubility in water (25°C ‘Gompleto Density (20 °C) (1.21013) glen? Vapour pressure (20°C) 146 mbar X. Stability and Reactivity of the Sulphuric Acid (30 to 38.5 %) Corrosive, inflammable liquid (at AGM -Battor ‘Thermal decomposition at 338 °C Destroys organic materials, such as cardboard, wood, textiles. RReacis with metals producing hydrogen, Vigorous reactions with lead and alkalis. 8 adsorbed in glass-ibre matoral) XI, Data on toxicology of the constituents ‘Lead and its inorganic compounds. Way cause damage to the blood, nerves, and Kidneys when Ingested. Lead compounds are considered to be hazardous to reproduction. ‘Sulfuric Acta ‘Acts intensely corrosive on akin and mucous membranes, In Tow concentration. The inhalation of mists may eause damage {0 the respiratory tract. Xl. Data on the Ecology of the Constituents (applies only to rel sse caused by damage to the battery) Lead and its inorganic compounds ‘Sulfa Acie ‘Are poory soluble in water. Lead can be dissolved in an acidic or alkaline environment. Chemical flocculation is required for elimination from water. Waste water containing lead must not be disposed of in untreated condition ‘order to avoid damage to the sewage ayatom, the acid has to i noutrallzed by means of limo or sodium carbonate before disposal. Ecological damago Is possible by chango of pH.Xill,_ Recycling Information Waste Disposal method, Send to lead smelter or reclamation folowing applicable Federal, Stalo and Local regulations, Product can be recycled along with automotive (SL) lead-acid batteries. Deed lead-acld batteries should not be mixed with other batteries In order not to complicate the procossing. By no means may the electrolyte, the diluted sulphuric acid, be emptied in an inexpert manner. This procoss Isto be carried out by the processing companies. XIV. Transport Instructions ‘+ Surface transport / air folght Batteries and outer packaging must be clearly marked "NON-SPILLABLE", NON-SPILLABLE BATTERIES are not subject tot ADR /RID IATA, ifthe following conditions are adhered: + Fornew batteries: (© baleries must be protected against siding, falling over and damages Intall a carrying equipment, unless battrles are stored on pallets: batteries may not show any traces of yes or acids outsides battories must be protected against short circuits + Forused batterie © thelr chassis may not be damaged of any kind jainst sliding, faling over and damages ‘may not show any traces of lyes or acids outsides batteries must be protected against short circuits + Sea transport ‘© Notclassified in IMDG Code, no hazardous good. XV. Regulatory Information eis required that all lead batteries sod tobe abel with a uaiverally accepted reayeing sp mboT, For a better understanding ofthe waste dsposal method the batteries have been marked with these signs: BY, Ke Pb Lead return recycle Battery contains lead, do not ppt fo waste ‘Tho manufacturer, respectively he Importer of the batteries shall be responsible forthe attachment ofthe symbols. In addition, a consumer user Information on the significance of the symbols has tobe attached, which is required by the EC Directives quoted above, technical instructions, leaflets) shal ‘The manufacturers and sellers of the batteries subject to identification requirements (packagi bbe responsible for this information. XVI. Miscellaneous Data ‘The data rondorod above aro based on today's Knowledge, and do not constitu an aseurance of properivs, Existing laws and regulations have to bo obsorved by tho reclplent ofthe product in own responsiblity. has been compltad from sources considered to be dependable and i, to the best of our knowledge ‘and bolle, acourate and reliable as ofthe date compiled. However, ne representation, warranty (other express or Implied) or ‘guarantee ls made to the accuracy, rellabllty of completeness of the information contained herein, This information relates to the ‘spoolfe material designated and may not be valld for such matorlal used in combination with any other matorils or In any process. Its tho usor's responsibilty to satiety himeolf as tothe sultablty and completeness ofthis information for his own particular use. We do not aocopt liability for any loss or damage that may oceur, whether direct, Indirect, incldental or consequontial, from use of this Information.