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    14 views9 pages

    SDS Mutual Propane 2017 PDF

    Uploaded by

    Kissa

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    © All Rights Reserved
    Download as PDF or read online from Scribd
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    of 9
    SAFETY DATA SHEET ODORIZED PROPANE Mutual Liquid Gas & Equipment Co., Inc. a 17117 South Broadway Street Gardena, California 90248 sno 154 atm, [SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name Propane - Commer! Grade synonyms Propane, Ugeted Petroleum Gas, LP Gas, HDS Propane S05 Number 08700004725 Version an Product Use Description company Technical information Fuel gas, Liquefied Petroleum Gas (LPG) For: Mutual Liquid Gas & Equipment Co @i9) 515.0553 Chemtree (200) 424-9300 (Emergency Contact) (800) 639-8253, [SECTION 2. HAZARDS IDENTIFICATION Clasiteations: Pictogr Signal Word Hazard Statements Precautionary Statements Preveston Response: Storage Disposal ‘Hammable Gas -Categery 1 Gacos Under Presae = Liqusted Gas Specie Taget Organ Tonaity(Siogle Expos) ~ Category 3 COD Danger ‘Bxemely flammable gas Coatais gassnder prose: aay explode iPhestd May cause rowsions aad dizziness Keep away from heat/sparkvopeeflamehot surfaces. No smoking ‘Avoid beating gas. Use only outdacs oral veatiated sta, Leshing 2 fire: Do net extinguish, unless eka be stopped safely Eliminate all gion sources safeto do so. filed: Remove person to flesh ai aad kao confriabl foc beating. Calla dactr ora emergency medical Serve rove fy fee uel Sore in well vealed place. Protect fom sunighe ‘Reep coutaloestigitly closed. Store locke up. Dispose of contentv/contaner in accordance ith loca region natlonal! international regulations. aoe Fea Beta Supplemental Hazard Information ‘The intensity of he chemical oda (eth mercaptan) may “Zac diminish ue tw chemi oxidation rorption cr absorption Inv wth asl perception peblems ‘may ot be bl to sell the ora. Leaking propane fom underground gas ines may lose itso et pases tough extn soils. No wera festive 10% of he ime Therefore, ecumstances cin exit when indians nthe presence of leaking propane nd at baled by the smal Contact Mata Mopane fr mere information abt oder, Propane ps deecorsand ether safety sonsideraons ascend with he handing. sop uals of propane SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Component caste wag hana Ey! mereaptan 75084 =o /SECTION 4, FIRST AID MEASURES Inhalation Remove o esha. I not breathing, give artical respration, if necessary, provide acitlonal oxygen once breating s restored rained to co so. Seok ‘edoa! tention immecitey Skin contact “Take of contaminated clothing and shoes immediately. Wash of inmeciately with soap ard plenty 3 water Seek maces advice symptoms pers or develop Eye contact In case of eye certact, immediately Much with low pressure cool water frat east ‘TSrminutes. opening eyelcs fo erature furhing Seok medical atenton, Ingestion Ingestionis considered unikly. faccertally swaloned cbiain immediate ‘matical atenton Notes to physician ‘Symtoms: Oizaness, Headache, Naussa, Fostte, Voting, Dissorfor [SECTION 5, FIRE-FIGHTING MEASURES. Suitable extinguishing media Viste pray, Ory chemical, Foam, Carbon Gade (602), Fire shoul nat be ‘tinguished uress flow of gae can be immediately stopped Specific hazards during ire Liguidreleases farnmable vapors at well low arrbert temperatures are realy righting forms a farrmaole mixture wih ar Dangerous fre and explosion hazard when ‘exposed to eat, sparks or ame. Vapors are heave than ar ard may tavel ong tistances to's pont of igtton are fash back Cortaines may exploge in hest fre Da not alow hqaid uno t enter sewers or puble water. |Special protective equipment Firefghting activites that may resultin potertil exposure to high hest, smoke of a8 aoe Fea Beta tor fretighters toxio by produ of combustion should require NIOSHIMSHA- approved pressure- ‘demand set-cortined breating apparetis with ful facepeece and fll protective thing Further information Keep peopie away from and upwind of spivieak Fire should not be extinguished Unless fow of ga can be immediately Lopped.f sil ar leak has not git, ‘Setermine f water spray may assist in cisereng ges oT vapor to protect personnel ‘atempengt stop leak Use water to cool equpmer, surfaces arc containers fxposed to fre and excessive hea. For lange fe the use of unmanned hose Foleere or mont nozzles may be advantageous to fut minimize personne! ‘xposure, Solate area, partculry around ence of storage vesees. thera immreditey inthe evet of rising sourd fom a venting safety device Large fres "ypicalyrequre special tained persornd are equipment to folate and etingush the fre [SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions Evacuate nonessential personnel and remve or secure al igntonsourves. No Feat flares, smotng a lames i fazard ales. Consioer wind erection, say Upwing snd up f possibe. Evaluate he direction of product travel, kg, sewers, etc to certain spl eas. Vapor coud may be wie, bu color wil tSssipate as cous deperees fre explono% may be present iter visible cloud ie tSspersed Vertste and gas textarea befereerterng, Do net ouch spl gue (tosttemeeze burn hazard), Environmental precautions Carefully cortain ae! stop the source othe spa sate to 60 so, Do not fash ‘Son sewer or cainage systems, uniess ystems designed ard permite to Methods for cleaning up ‘The product everorstes eadly. Consider ne use of water spray to csperse gos oF vapors Isolste ees unt gas Mas dlsperses /SECTION 7. HANDLING AND STORAGE Precautions for safe handling Seo also apsicabie OSHA regulations for he handing and storage ofthis produc, Inclucng, but net ited to, 29 CFR 1010 "10 Storage and Handing of Liguelied Petioeum Gaces Keep away tom epen lames, het surfaces and sources of inten. Use ony in \wellvertites seas. Store n a wellvertiaed area ane in accordance with NEPA 58 Liquefied Pet oloum Gas Code" [Conditons for safe storag ‘Stowe only in approved containers. Keep avay fom flame, sparks, excessive Including Incompatabities temperatures are open fame. Keep cortarers closed and cea labeled. Emety product containers or vessels may cortainexplosve vapors. Do Pot pressure, ut heal Weld or expose coflaners fo sources of ignition Keep away fom oxidizing agerts and strongly acid or alkaline materi. Keep ‘away rom food, dirk ang animal feed oep in a dy place. Keep away from heat. No Gecorspositon If stored and applied 2 drectes [SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines ae aoe Fea aT = ae aa fama — [Powe Tone [re ‘ioigee nore Eira Shaan rei | oar Team nara Sane Ra a 0050 in 7ees [1 or Sarena Boremewen | sce | tm sae Engineering measures Eye protection Hand protection ‘Skin and body protection Respiratory protection Hygiene measures Use adequate vertiation to keep gas and vapor concerrations ofthis product Delon ossupatona exposure and flammable. parbeuarl in corti spaces. Use expsion poof equpnert ard igttng in classfiedcontoied areas. \where there 2osibity of tquid contac, wear solash-proot safety goggles and facesreld Ensim thal eyewash stators and safely showers are close tothe \woretation location. \wnere contact wih quid may oocur, wear coldimpervious, insulating gloves. \wmere contact wih quid may oocur, wear apron and faceshield. Farr resistant cotring such as Nomex @ is recommended in areas where malealis sored or are Use a NIOSH MSHA approved postive pressure supped. respirator there is ‘2 potent for uncontalled release, exposure lvels are nol known in oxygen Gefen! atmespreres, or any othe creurslance where an a-purfng respirator ‘nay not prove adequate pretecton. Refer to OSHA 29 CFR 1010.134, ANS! £288.2:1092, NIOSH Respirator Decision Lagi, andthe manufacturer or aditonal ‘guidance on respratryprotectonselecioy Hangs in accordance with good incustral gene and safety pracoe, such 26 washing after handling the materal ard bere eating, cirkng, andor smoking Routinely wash work cating and orotectve equipment fo remove contaminants (Dscard cortamrated cloting and footwear that carr be lesned Practice goed housekeeping |SECTION 9, PHYSICAL AND CHEMICAL PROPERTIES [Appearance odor Odor threshold pH Melting pointtreszing point Initial Boling point & range ‘Colores gas, Cold vapor cloud ray be white but the lack of visible gas cous | oes not incite absence of 98s. colores liquid when pressiized (Cdorants adced to as inthe detection o leaks. One common oderantis thy rmercaptan, CAS No, 75-08-1, Odorat has fou rel ‘Over thveshols or meroaptan adetve i inthe 40 part per billon range. Not apol cable A897 1-500. 5F) =A (43.6°F)at 7018.25 Pa a5 eee Flash point: Evaporation rate: Flammability (solid, gos) Lower flammability limit: Upper lammability mit: Vapor oressure: Vapor density: Relative density: Sotubitty (420): Partition coefficient (ctanotiz20) Auto ignition temperature: Decomposition temperature viscosity: Conductivity: Propane Commercial Grade Paso “104'C (4952°F) Method: ASTM D 92 gh Gas 21560) 95% (y) 4.400 nPa at 20°C (68°F) Yo.at21.C (DOF) (Ar= 1.0) 0521 15° (SF) Miater= 1.0) Negiaive 236 log Pow 50°C (842°F) Heating may cause a fre or explosion Metra does not decompose at ambient temperatures Cafoon monoxide, carbon doxide ar non-combusted hydrocarbons (sTioke) ere possible hazarsous decomposition products No data avaiable Hycrocaroon liquids wehout state dssipler adctive may have conductivity below ‘TpiooSemens vermeter(pSin) The highest slecto state ignition ests are <2esoretec wih uta iow conductvies below 5 pSim. See Secton 7 for sources ot information or cetning sete oaaing end nenaing procedures row ‘conduct products Note hat conduetvty can be reduced by erwirormental ‘actors sueh a8 a deorease intemperate |SECTION 10. STABILITY AND REACTIVITY Reactivity Chemical stabity Hazardous reactions Condos to vole Incompatible materials Hazardous JSecompestion products ‘Vapors may form expose mixture with at, Hazardous polymerization does not ‘Stable under nommatcordtions ‘Can react with song acid, strong oxidizers, and copper. Explosion hazard when| ‘exposed to rick carbonylloxygen mature Koop away tromilame, spars, excessive temperatures and open fame ‘Can reac with song aid, stong oxedzers, and copper ‘Caron monoxide, carbon coxide ane non combusted hydrocarbons emoke) are PPossble hazarcous cesompositon proguss, [SECTION 11. TOXICOLOGICAL INFORMATION Inhalation May cause ventral nervous system disorder (e.g. narcosis involving loss of coordination, weakress falgue, mental confuson ana blurred vsion) andlor ‘damage. Simple s—pysiart Acts by aspiscrg oxygen nthe ings therety ‘diminishing the sumpy of oxygen availabe tthe blood and issues. Sympioms Include shortness cf breath, fgie heart ate, ncoordneton, leeruy, headaches, nausea, vomitng. and asorertaion.CortinJed lack of oxygen may result in 378 eee Propane Commercial Grade Bier doo Skin iitation Eye ination Further information [Component Propane Proplne tana Ey! meteantan [cA Prop 6s convusions, loss of consciousness and death Since exercise increases the tse eed for aygen, stom wil cour mote quekey dung exerion nan oxygen (eficient erwronment Oxygen in enclose spaces should be raitained at 21 pereent by vekume. Direct contacto stn or muzous membranes wih liquefied producto old vapor ‘may cause feeze bums and frost, Direct contactta stn or musous membranes wih liquefied product or cold vapor ‘may cause feeze burns and rostite, CConcerntratiors above the permissible exposure mit may cause dizziness, Feadache and ineriaton. Propane extbis seme degree of anesthetcacton and is ily intatng tothe [Alnigh concentrate propane acts as a single asphyidant without other sigifiant Dhysologcal effects 74905 inten. Caeteatn angio a Ret Sn naton ‘Baliaen-Cosetcton stg eyes osc eye an ‘547 pelnate icy LcSO rade: e58 rot Bulan Chsetcote: tng eyes SU Mi ee ten 7eok9 in taen. Caen iangto ln Ret Sen aton ‘Eisen -Couetcatsn rng ocyes ovat ye aon 75081 fale eal 1050 Doe. 652 mop (BIER Lost com Toot _Bineatn Cerentino tn ous sn in ‘No component ofthis product wich s present at levels greater than or equal 1001 Sols ented ae 9 krown or anopated carcinogen by NTP. "No component ofthis product wich s present at levels orator than or equal 001 36 ented as probabe, possible or confirmed human carcinogen by| rage, ‘No component of ths product which present at levels greater than or equal 100.1 96s ented es a carcingenor potential carcinogen by OSHA, ‘This prod: does not cortain ary chemicals knownto State of California to cause cancer, bt, oF eny ater reprocuctve defects /SECTION 12. ECOLOGICAL INFORMATION Adaltional ecological Information /ompenent: hon Eyl mereaptan igus release is only expected to cause localized, non-peritent environmental

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