CAU HOI Li THUYET VE HOA HOC HUU CO’ THPT Vai sue “giao heu” va sding tao trong nhitng ném gan déy, cdc cdu hoi li theyét hitu co trong dé thi thit DH ngay cing gay ra nhiing khé khan khing nho voi cc si tie. Khéng con chi kiém tra cdc kién thiee co ban va noi bat, cic dé thi gio day bit déu tim dén mang kién thie mé hoc sinh cling nue gido vién it quan tém truéc déy nhue céu tric phan tir, tinh chat vat li, diéu kign phan ing, mg dung thuc té,... Diéu dé dai hoi hoc sinh hon bao gic hét phai doc ki va thyc sv hiéu cdc tri thitc diege cung cdp trong sdch gido khoa THPT dé khong bj be ngé trude cae edu hoi trong dé thi. (lemongrass.31.08@gmail.com) PHAN 2. DAP AN ‘(CAu 1. Cho so dé chuyén héa sau: Benzen + etilen "> X —22"_5 y_8*0._ hon hop ZH khi' T Vay khi Ta A.CO2 B.CH, C.hdn hyp CO: val; D. CéHsCOOH (Cau 2. Cho CHsBr phan img véi NHs, sn pham tao ra amin la A. CHsNHz B. (CHs):NH C. (CHs)sN D. hn hgp CHsNHa, (CH3)2NH, (CH3)sN (Cau 3. Cho so dé chuyén héa sau: Crt, 9 x, 2g x, [|| sy, TE XS] society y. Trong so dé trén, Xs la: ‘A. Caosu cloropren B. Cao su Buna C. Cao su thign nhién D. (-CHs-CH=CH-CHa-CHz-CCICH-CH-)y CAu 4, Phan tir nao sau day 6 g6e CCC 06 dé len xp xi 90"? A. Xiclopropan B. Propen C. Xiclobutan D. Propan Cu 5. Chon nhin dinh diing dudi day. A. Hidrocacbon no Ii hidrocacbon khong ¢6 phan ting eng them hidro. B. Hidrocacbon no 1a hidrocacbon ma trong phin tir chi c6 C lai héa sp", C. Do chi c6 lién két o, ankan trong 46i hoat déng héa hoe. D, Phan irng flo héa C,Hyo tao ra 4 loai din xudt mono khde nhau. Céiu 6. Cho cic chit sau: Bro, HBr, A.2 Bl phan ung v6i xiclohexan la: D.4 ‘Cfu 7. Trong s6 cic hidrocacbon cé ti khdi so véi Hy bing 20, thi sé Iugng chat lim mat mau dung dich thude tim la, Al B.2 a2 D4(Cu 8, Phan img nao sau diy tao ra HBr? (1) Benzen + Bry > (3) CH=CHBr + KOH 2 (5) CH; -OCH, +Br > A. CK2)(3 4), B. C24) Ciiu 9, Hidrocacbon X 06 CTPT Ii C;2Hio, khéng kim mat mau dung dich KMnOs 6 nhiét a9 thong va (2) Xiclopentan + Bry ——> (4) CH}CH=CHCH;Br + HO —> C.(IQ)BKS) D.()GB\4) hi dun néng. Cho X phan ting véi HNOs/H:SO, thu due sin phim C)sHeNOs. $6 lugng chat C)2HyNO> 66 thé tgo ra la: AL B.2 Cfu 10. Cho so dé chuyén héa sau: ca D4 ‘Cumen %"* > C,H, Br 22" > C, Hy, "> X(C, HB) Vay chat X 1a: A, L-brom-2-phenylpropen C. p-bromisopropenylbenzen Cu 11. Cho so dé chuyén héa sau: B. 3-brom-2-phenylpropen D, o-bromisopropenylbenzen CH,OH+CO—*\> X(duy nhat) HA" 5 yHseunnrwe , 720,180.60, yg Vay chit M la: A. CoH B. CHs-CHs C. CHxCHO D. CH;COOGHs (Cau 12. Chuyén héa hidrocacbon X (CsHio) theo so dé sau: X22 C1,0, 2! 50,140, Vay chat X la: A. Naphtalen Cfiu 13. Hidrocacbon X eé ki B. o-Xilen C. Dimetylbenzen D. Etylbenzen Iugng mol bing 100 gam, khi phan img véi clo tao ra hn hop gom 3 dong phan monoclo cia X. $é lugng hgp chat thoa man tinh chat trén cua X 1a: A2 B.3 C4 DS Cfu 14. Khi 6 vong benzen di c6 sin nhém thé day electron cing manh thi phan img vao vong cang dé xiy ra, Trong s6 ede nhém ~CHs, ~OH, -NHz, ~OCHs, nhém nio diy electron yéu nhit? A.-NH> B.-CHy Cfiu 18. Cho eée phan img sau: (1) Gala + KMn0, > (3) CH;COOC(CHs)(C)CH:CI + NaOH ——> (5) CHsCLCH:-CCI + NaOH —> ‘Sé phan img tao ra ancol hode axit da chite li: A.2 BA Cf 16. Cho ede phin img cong sau diy: 1) CH=CH: + HCI 3) CH:CH-CHe + HI > Phan img xay ra dé dang nhat la phan img: A) B.Q) C.-OH D.-OCH; (2) Benzen-1,2-diamin + HNO, —*° (4) Tripanmitin + NaOH — (6) 3-clopropen + H>O “> 2) CH: 4) CH2=CH2 + HBr > c.@) Dd.) Cau héi Ii thuyét vé héa hoc hitu co 2012 ‘emonGrass.31.08@Gmall.com — Trang 2/14Cu 17. Cho ede nhiin din sau: (1) Phan tmg céng Hp vio anken la phiin ting toa nhiét, (2) Tron hex-2-en long vai nude brom, lic ki rdi dé yén thi mau vang cam ciia dung dich bj nhat di. (3) Aken cong nude ludn tgo it nhit 2 ancol. (4) Suc etilen vao dung dich thudc tim thay xuat hign két tua den. (5) Trong phong thi nghiém, etilen duge diéu ché tir etanol. han dinh ding ta: AS B.3 c.2 D4 ‘Cu 18. Cho day bién héa: Cumen 9X —H80.20% yy HHO 7 HOE ny Biét M lam mat mau dung dich nue brom. Vay M la: A. phenol B. axit metaerylic . isopropenylbenzen 1D. axit-2-hidroxylisobutirie ‘Cfiu 19, Hop chat X 6 cng thie cau tao nhu sau: 4CH, ~CH = CH ~CH, ~CH, ~CH =C(Cl)-CH,+, Hay cho biét qua trinh diéu ché chat X tir axetilen (cdc chat v6 co céin thiét c6 dit) phai trai qua it nhdt bao mhiéu giai doan: A.2 B.3 C4 DS (Cfiu 20. Khi dun néng mdi chat toluen, stiren, phenol, anilin vi dung dich KMnO, dae thi c6 phan tmg héa hoe xay ra véi A. toluen B. toluen va stiren CC, toluen, stiren va phenol D, cdi 4 chat toluen, stiren, phenol va anilin Céu 21. Hop chit X khong no mach hé c6 c6ng thie phan tir CsHsOz, khi tham gia phan img xa phong héa thu duge 1 andehit vi 1 mudi cia axit hitu co. Cé bao nhiéu céng thite edu tao pha: hgp voi X (khong ké ding phan cis, trans)? A2 B.3 C4 DS Cau 22. Cho cic chat long hoc dung dich sau: phenol, anilin, natri phenolat, axit axetic, kali axetat, S6 dung dich lam di mau phenolphtalein li A2 B3 C4 D.S Cu 23. Cho anilin tic dung véi nude brom duge két tia A. Cho A tie dung véi HNO> ban diu 6 0°C ~ 5°C, sau d6 dun néng nhe duge két tia B, Vay B I A. Axit picrie B. Mudiciia A voi HNO: —C.2,4,6-tribromphenol—D. ai Cfu 24, Chat A chia C,H, O, mach hi c6 nguén géc tir thye vat va thuong gip trong doi séng. Khi liy cing sé mol cia A cho phan img hét voi NaxCO hoae véi Na thi ti 1¢ sé mol CO; va sé mol H; thu duge tuong ting 1a 3:4, Biét A c6 khdi long mol phan tir i 192 gam va chi chita cde nhom chite phin img v6i Na. Tén goi ciia A 66 thé la: A. axit laurie (trong qua dira) B. axit tactarie (trong qua nho) C. axit malic (trong qua tio) D. axit xitrie (trong qua chanh) CAu 25, Chon nhin xét sai? A. Cac chat hiru co c6 % s6 mol trong hén hyp bing % khdi lugng trong hdn hop dé duoc goi la dng phan eta nhaw, Cau hei lithuyét v8 héa hoc hitu co 2012 LemonGrass,31,08@Gmail.com — Trang 3/14B. Gée lign két HCH trong phan tir C:Hy < CHy < CoH. ‘6 3 céich biéu dign céng thite cau tao cua hgp chat hiru co, ién két ha hoe trong phan tir hop chat khi chu yéu a lién két cOng héa tri. ‘Cfiu 26. Cho cae chat sau: CHjOH, C)HsOH, CHsCHO, C2H2, C2Ha, CsHio, CH}COONa, CHjCN. SO 6 thé tao duge CH;COOH chi bang 1 phan img la: AB B.S c4 D.6 (Cf 27. Chon nhin xét ding. A. Nhiing quy tim vio dung dich axit a-aminoaxetic thay quy tim 46i miu. B. Cac aminoaxit la hgp chat hiru co nén nhigt 46 néng chay tuong doi thip. C. Khi cho a-aminoaxetic tic dung vii C2HsOH (xt: HCI khi) thu duge CI HyN°CH:COOC2Hs. D. c-aminoenantoic 1a nguyén ligu dé sin xudt to nilon-6. (Cfu 28. Chon nbn xét ding. A. Nhigt d s6i etia CHs;COOC:IIs < CHsCHCH2COON < CIis[CUz]sCHZO1. B. Gidng nhur xa phong, chit giat rita tong hgp khong thé gift rim trong nude eimg. C. Ngay nay xa phong con duge san xudt tir ankan. D. MG bj Gi Ia do lign két C-C cita gc axit béo bj oxi hoa chim b6i oxi trong khong Khi. ‘Cfiu 29. Cho so dé phan img: CH, i ye, yr sca y _ emee y Biét cdc chit trong so dé trén déu mach hé va c6 sé C nhw nhau. Phat biéu ndo sau day khong ding’ A. Xa khdng e6 kha niing tham gia phan ting tring hep. B. X; téc dung duge véi Na va giai phong Ho. C. X, cng voi HO (xt H’) thu duge san pham chinh la propan-2-ol. D. Khi thity phan chat béo ta luén thu duge Xs. ‘CAu 30. Chon nhiin xét ding? A. Trong dung dich, andehit c6 ca lién két hido lién phan tir va lién két hidro véi nude, xeton chi cé lién &t hidro voi nuse. B. Day sip xép theo chiéu gidm dan nhiét d6 s6i tir trai sang phai la: n-hexan > isohexan > neohexan. C. Thity phan khong hodn toan n-peptit e6 thé thu duge (n-2) tripeptit. D. Benzen ¢6 mii thom nhe nén durge goi li hidrocacbon thom. ‘Cafu 31. Chon nhin xét diing. A. Khi dun néng hén hop gdm C:HsBr, KOH, C:HsOH thi khong c6 khi thoat ra, B. Trir etin, cdc ankin ¢6 lién két = dau mach khi phan img voi AgNOs/NH; thi khdi hrgng phan tir thay doi 107 dv. C. Khi dun hén hgp C)HsOH va axit HBr dén khi két thiie phan img ta duge dung dich déng nhit. D. Cae ancol CsHs0H, CH:CH3CH;OH, CH;CH;CH:CH,OH tan v6 han trong murdc. (Cu 32. Hop chét Cottiy khi tie dung véi clo c6 chiéu sing tao ra hdn hop 2 efit déng phan CeffisCt. Neu thay 2 nguyén tir H cia Coy, trén bang 2 nguyén tir clo sé tgo ra hn hgp gém sé lugng dong phan la: AA BS C6 D.7 =CHBr; HOOC-CH=CH- Céiu 33. Cho cite chit sau: CHy=CH-CHy-CHs; CHs-CH=C(C:Hs)-CHs; CICH: (CHs; (CH3):C=CH-CHs; CHBr=CH-CHy, 6 dong phan hinh hoc la: A2 B3 C4 D.S Cau hei lithuyét v8 héa hoc hitu co 2012 LemonGrass.31,08@Gmail.com — Trang 4/14