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Gold Coated Octagonal Photonic Crystal Fiber Biosensor

Using Surface Plasmon Resonance

Abu Bakar Siddiqur Rahman1, Alok Kumar Paul2 and Md. Rasidul Islam3
Dept. of Electrical and Electronic Engineering
Rajshahi University of Engineering & Technology1,2
Khulna University of Engineering & Technolgy3
Bangladesh
bakar121107@gmail.com1, paul10alok@gmail.com2 and ronyrasidul@gmail.com3

sample detection, antibody-antigen interaction, medical


Abstract—In this paper, a two ring octagonal lattice
photonic crystal fiber (PCF) biosensor using surface plasmon diagnosis, bio-imaging, food quality control etc. [3]. SPR
resonance is proposed. A mode solver based on finite element sensors are used in biosensing for its small size, reduced
method (FEM) with a circular perfectly matched layer (PML) cost and design flexibility [4]. It can detect an unknown
and scattering boundary condition is used to evaluate the analyte with a small variation of RI by a large shifting of
performance of the proposed biosensor. In this work, gold is wavelength peak [5]. Gold, silver, copper, and aluminum
used as a plasmonic material. The plasmonic material is used are used as a plasmonic material [6]. Gold is chemically
as an outside layer of the PCF structure that is easy to stable and having larger shifts of resonance wavelength [7].
fabricate rather than inside coating of gold layer of the PCF Silver can oxidized easily in liquid or gaseous environments
structure. The proposed sensor shows that maximum
which prevent Au-Ag bi-metallic SPR sensors [8]-[9].
wavelength sensitivity 10000 nm/RIU and maximum amplitude
sensitivity is 595 RIU-1 based on wavelength interrogation and Recently, researchers have developed in SPR based PCF
amplitude interrogation method, respectively. Also, sensor
bio sensors. A SPR sensor with graphene-silver layer with
resolution is found to 10-5 RIU-1. Therefore, the proposed
structure can be used in various applications such as biological filled analyte channel designed for RI detection [4]. A single
analyte detection and bio-imaging due to higher sensitivity and hexagonal layer where all the air holes are coated with a
simple design. gold layer and titanium oxide [10]. A hexagonal lattice of
polymer PCF deposited with metal oxide where air holes in
second layer are deposited by indium titanium oxide [11]. A
Keywords—photonic crystal fiber; biosensor; finite element
sensor with an elliptical air hole with four micro fluidic slots
method; surface plasmon resonance
is used for multi analytes detection [12]. In the above
sensor, metal layer deposited inside the air holes and also it
I. INTRODUCTION is quite difficult to infiltrate the liquid or analyte in several
Surface plasmon resonance (SPR) is a progressive inside air holes. To overcome these difficulties for practical
technology due to its extensive applications in numerous implementation of PCF based sensor designed a D shaped
fields. Highly sensitive detection properties are one of the PCF. A nanoscale gold film at the flat outer surface of D
major characteristics of SPR. A transverse magnetic or p- shaped sensor has been proposed in [13]. A SPR sensing
polarized light is incident on the prism coupled SPR which layer is installed at the outside portion of the fiber with two
is coated with a thin metal layer. When the frequency of the asymmetrical PCF structures [13].
incident light and plasmonic material matches, it excites the
In this paper, a PCF based sensor is proposed where gold
free electrons of metal surface. Then electron density
is used as a plasmonic material gives a high resonance peak
oscillation occurs at the metal-dielectric surface which is
wavelength shift. A finite element method (FEM) based
known as surface plasmon wave (SPW) [1]. A resonance
software and MATLAB software environment are used to
occurs in this situation when the energy and momentum are
analyze the performance of the proposed biosensor. In this
same for both the incident light and SPW. The essential
work, an outer sensing layer of the proposed PCF biosensor
condition for SPR is shown below [2].
is used for unknown analyte detection purposes that ensures
the real time and label free detection..
2 2  m s
 p Sin  (1)
  m  s
II. STRUCTURAL DESIGN
λ is the wavelength of light, θ is the angle of incident light; Fig. 1 shows the proposed model of the sensor. Two
ɛp, ɛm and ɛs represents dielectric constants of material, metal octagonal layers of air holes are placed into the cladding
and sensing medium, respectively [2]. SPR sensors has region. And, an air hole is located into the center region of
broad applications in many branches such as biological the proposed PCF biosensor. The shape of all air holes is in
circular. The improvement of phase matching condition damping frequency, weighting factor Δɛ = 1.09, spectral
between fundamental core guided mode and surface width ΓL /2π = 104.86 THz and oscillator strength of
40 1.43

Confinement Loss (dB/cm)

Effective Index (Real)


PML
d1
Analyte

dc 20 1.42
Gold Y pol core mode
Y pol spp mode
Fused
Silica Y pol core mode (real)
X pol core mode
Air-
hole

0 1.41
0.75 0.8 0.85 0.9 0.95 1
Wavelength,  (m)
Fig. 1. Cross sectional view of the proposed sensor. Fig. 2. The wavelength dependence dispersion relation of plasmonic mode
fundamental mode (x-polarization), fundamental mode (y-polarization),
plasmon polaritons (SPP) mode can be enhanced by this loss spectra (x-polarization), and loss spectra (y-polarization).
structure. Air holes are set out at a 2.5 µm from the center
with anticlockwise rotation in an increasing manner for the Lorentz oscillators, ΩL /2π = 650.07. The sample or analyte
first ring of octagonal layers. Similarly, in the case of which is situated outside the gold layer. It is actually
second ring, air holes are stationed at 3.55 µm distance from behaves as a dielectric layer. Here, simulation results and
the center with anticlockwise successive rotation. Four air performance analysis have done using finite element
holes in the second ring are omitted so that the evanescent method. The scattered light from the PCF is absorbed into a
field can strike easily to the free electrons of the metal circular perfectly matched layer (PML) and scattering
surface. Hence, surface plasmon wave (SPW) is generated boundary conditions which restricts reflection.
appropriately. The proposed PCF structure can be fabricated
using solid rods and capillary with thicker wall. The III. SIMULATION RESULT AND PERFORMANCE ANALYSIS
diameter of the central air hole is dc=0.8µm and the
diameter of the rest air holes are d1=1µm. Pitch (center to The interaction of evanescent field with surface
center distance between two adjacent air holes) Λ =1.05 µm. electrons is the basic requirements for PCF based SPR
The remaining material and background is considered as a sensors. The SPW is appeared in the metal-dielectric
fused silica. The refractive index of the fused silica can be interface. Light propagates into the core region. Evanescent
calculated using Sellmeier equation which is shown below field which are created by the light coming into the cladding
[1]. region. The proposed structure has ability to generate SPW
striking the evanescent field into the metal surface. For this,
B12 B2 2 B32 the geometrical configuration can be used to detect
2    1 (2)
2  C1 2  C2 2  C3 unknown analyte. Surface plasmon wave is produced when
the evanescent field involved with the free electrons of
where, η is the wavelength dependent refractive index for metal surface. The wavelength and its corresponding
fused silica, λ is the wavelength in µm and B1, B2, B3, C1, confinement losses give a resonance curve where a peak
C2, C3 are Sellmeier constants. In this work, the plasmonic loss established at the resonant wavelength.
material which is placed at the outer surface of the PCF. To
deposit the plasmonic material, different methods such as
radio frequency (RF) sputtering, thermal evaporation, wet-
evaporation and chemical vapor deposition (CVD) can be
used. The dielectric constant of gold can be calculated by
Drude-Lorentz model which is defined as [3].
(a) (b)

D 2  . L 2
 Au      2 (3)
 (  jD) (   L 2 )  jL
(c)
Where ɛAu is the permittivity of gold, permittivity at high
frequency, ɛ∞ = 5.9673, angular frequency, ω = 2πC/λ and C
is velocity of light in vaccum, ωD/2π = 2116.3 THz and ωD Fig. 3. Mode Field Distribution in .880 µm for analyte 1.39 with 30 nm
is the plasma frequency, γD/2π = 15.92 THz and γD is gold layer (a) x polarization (b) y polarization (c) y polarization of SPP
mode
40 40
Confinement Loss Lc (dB/cm)

Confinement Loss Lc (dB/cm)


35 analyte RI=1.33 35 analyte RI=1.33
analyte RI=1.34 analyte RI=1.34
30 analyte RI=1.35 30 analyte RI=1.35
analyte RI=1.36 analyte RI=1.36
analyte RI=1.37 analyte RI=1.37
25 analyte RI=1.38 25 analyte RI=1.38
analyte RI=1.39 analyte RI=1.39
20 20
15 15

10 10

5 5

0 0
0.5 0.6 0.7 0.8 0.9 1 0.5 0.6 0.7 0.8 0.9 1
Wavelength  (m) Wavelength  (m)

Fig. 4. The wavelength dependence loss spectra with d1=1 um, dc=0.8 um, Fig. 5. The wavelength dependence amplitude sensitivity with d1=1 um,
and gold layer thickness tg =30 nm. dc=0.8 um, and gold layer thickness tg =30 nm.

Fig. 3(a)-3(c) shows the fundamental mode field distribution Here, 0.880 µm gives the resonant wavelength where the
(MFD) for x polarization modes, y polarization modes and maximum possible energy is transferred from core guided
SPP mode for y polarization, respectively. The MFD is mode to SPP mode. And therefore, the field for y
taken for resonance wavelength of 0.880 µm at analyte 1.39 polarization is strongly coupled with the free electrons of
for 30 nm gold layer. The resonant wavelength also metal surface as well as both modes is strongly coupled. By
appeared into the condition which is previously considered varying the resonant peak and dispersion relations between
for MFD. From Fig 3(a) and Fig 3(b), it is seen that when core guided mode and SPP mode, the phase matching
the light is guiding into the core, y components light strikes condition can be verified. The confinement loss is defined
more into the metal surface than x components light. For as [1].
that reason, a stronger electric field exist for y polarization
mode compared to x polarization mode. Hence, the sensing  (dB / cm)  8.686  k0 . Im[neff ] 104 (4)
capability is increasing for y polarization mode by easily
interaction of evanescent field with the outer sensing layer. where, k=2π/ λ wave number into the free space, Im (ηeff) is
Fig. 2 shows dispersion characteristics for fundamental core the imaginary part of the effective refractive index and λ is
guided mode and SPP mode. Here, y components gives the wavelength in µm. The real part of ηeff of the SPP mode
higher effective refractive index (ηeff) compared to x is highly sensitive with the change of analyte RI. If the
components. Therefore, the loss is higher for y components analyte RI is varied to a higher value, then the real part of
than x components. From the figure, the real part of ηeff is ηeff of SPP mode is increase to a higher value. This is a cause
the same for fundamental y polarization mode (core guided to shift a resonance wavelength towards the higher value.
mode) and SPP mode. It is known as phase matching Therefore, confinement loss is increased by low variation of
condition or resonance condition. A sharper and higher analyte refractive index. If confinement loss increases, then
resonance peak is obtained from this condition. Resonance more energy will transfer from core guided mode to SPP
peak occurred at resonance wavelength. mode. Consequently, a sharper resonant spectrum will get
from this phenomena.
15 100
analyte RI=1.33
Amplitude Sensitivity (1/RIU)

analyte RI=1.33
analyte RI=1.34 50 analyte RI=1.34 4.5
Confinement Loss Lc (dB/cm)

analyte RI=1.35
analyte RI=1.36 a 0
analyte RI=1.35
4
analyte RI=1.33
c
analyte RI=1.37 analyte RI=1.34
Confinement Loss Lc (dB/cm)

10
analyte RI=1.38 -50 3.5 analyte RI=1.35
analyte RI=1.39 analyte RI=1.36
-100 3 analyte RI=1.37
analyte RI=1.38
5
-150 b 2.5
analyte RI=1.39
-200 2
analyte RI=1.36
-250 analyte RI=1.37 1.5
analyte RI=1.38
0 -300 1
0.5 0.6 0.7 0.8 0.9 1 1.1 1.2 0.5 0.6 0.7 0.8 0.9 1 1.1
Wavelength,  (m) 0.5
Wavelength  (m)
0
0.6 0.7 0.8 0.9 1
100 Wavelength,  (m)
Amplitude Sensitivity (1/RIU)

50
0.9
0 Resonance wavelength
Resonance wavelength (nm)

-50 Linear fit of res. Wa.


0.8
-100
-150 analyte RI=1.33
analyte RI=1.34 0.7
-200 analyte RI=1.35
-250 analyte RI=1.36
analyte RI=1.37
-300 analyte RI=1.38 d 0.6 e
-350
0.6 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1
Wavelength  (m) 0.5
1.33 1.34 1.35 1.36 1.37 1.38 1.39
Refractive index (RIU)
Fig. 6. Confinement loss spectra of the fundamental mode for the proposed biosensor for different analyte RI (a) gold layer thickness =40 nm (c) gold
layer thickness=50 nm and amplitude sensitivity as a function of wavelength for different analyte RI (b) gold layer thickness =40 nm (d) gold layer
thickness=50 nm with, d1= 1 um, and dc=0.8 um and (e) linear fitting of resonance wavelength.
IV. CONCLUSION

100 40 In a sum, a simple design with octagonal structure PCF

Confinement Loss Lc (dB/cm)


na=1.39, d c=0.808 um
Amplitude Sensitivity (1/RIU)

0 35 na=1.39, d c=0.8 um biosensor has been proposed. The guiding parameters and
na=1.39, dc=0.792 um
-100 30
na=1.38, d c=0.792 um
performance of the proposed sensor have been analyzed
-200 25 using FEM based software. The proposed sensor shows that
dc=0.792 um na=1.38, dc=0.8 um
-300 20
dc=0.8 um
na=1.38, d c=0.808 um
the maximum wavelength sensitivity of 10000 nm/RIU on
-400 dc=0.808 um 15
-500 10
the basis of wavelength interrogation technique for sensing
-600 5 layer RI of 1.39, the amplitude sensitivity of 595 RIU-1 on
-700 0 the basis of amplitude interrogation method for the sensing
layer RI of 1.38, the sensor resolution of 10−5 RIU, and high
0.65 0.7 0.75 0.8 0.85 0.9 0.95 1 0.65 0.7 0.75 0.8 0.85 0.9 0.95 1
Wavelength,  (m) Wavelength,  (m)
linearity with R2 is equal to 0.9078. The performance is
investigated with sensing ranges from analyte RI of 1.33 to
Fig. 7. The wavelength dependence amplitude sensitivity for analyte
RI=1.38 and loss spectra with dc variation for gold layer thickness tg =30 1.39. Considering the high sensor performance, this can be
nm. used for unknown analyte detection.
The more evanescent field, then the more transmission loss, REFERENCES
hence more interaction with the metal surface and so design [1] M. R. Hasan, S. Akter, A. A. Rifat, S. Rana, S. Ali, "A highly
gives more sensitivity. For the proposed sensor, we varied sensitive gold-coated photonic crystal fiber biosensor based on
the analyte from 1.33-1.34, 1.34-1.35, 1.35-1.36, 1.36-1.37, surface plasmon resonance," Photonics, vol. 4, no. 1, pp. 18, 2017.
1.37-1.38, and 1.38-1.39 in a regular sequence, then the [2] X. Yang, Y. Lu, B. Liu, J. Yao, "Analysis of graphene-based
resonance wavelength shifted from 0.60 µm to 0.62 µm, photonic crystal fiber sensor using birefringence and surface
plasmon resonance," Plasmonics, vol. 12, no. 2 , pp. 489-496, 2017.
0.62-0.64 µm, 0.64-0.68 µm, 0.68-0.72 µm, 0.72-0.78 µm,
0.78-0.88 µm, respectively. Fig. 4 demonstrates the [3] A. A. Rifat, G.A. Mahdiraji, Y.M. Sua, Y. G. Shee, R. Ahmed, D.
M. Chow, and FR M. Adikan, "Surface plasmon resonance
wavelength dependence loss spectra with analyte RI photonic crystal fiber biosensor: a practical sensing
variation. The maximum wavelength sensitivity is achieved approach," IEEE Photonics Technology Letters, vol. 27, no. 15, pp.
to 10000 nm/RIU for the variation of analyte RI 1.38-1.39. 1628-1631, 2015.
So for wavelength interrogation, its sensitivity can be [4] J. N. Dash and R. Jha, “Graphene-based birefringent photonic
calculated by the equation as [3]. crystal fiber sensor using surface plasmon resonance,” IEEE
Photonics Technology Letters, vol. 26, no. 11, pp. 1092–1095,
 peak 2014.
S ( )  (nm / RIU ) ( 5) [5] B.D. Gupta,; A.K. Sharma, “Sensitivity evaluation of a multi-
na layered surface plasmon resonance-based fiber optic sensor: A
theoretical study,” Sensors and Actuators B: Chemical, vol. 107,
where, Δλpeak is the resonance peak shift and Δna is the no. 1, pp. 40-46, 2005.
analyte’s RI variation . Cross effect variation occurs with [6] K. M. McPeak, S.V. Jayanti, S.J. Kress, S. Meyer, S. Iotti, A.
the resonance peak wavelength magnitude changes by the Rossinelli, D.J. Norris, “A Plasmonic films can easily be better:
variation of analyte RI. The neff of SPP mode, core mode neff, rules and recipes,” ACS Photonics ,vol. 2, no. 3, pp. 326–333, 2015.
penetration depth of the SPP field are include in the cross [7] W. Qin, S. Li, Y. Yao, X. Xin, J. Xue, “Analyte-filled core self-
effect. Fig. 5 also demonstrates the wavelength dependence calibration microstructured optical fiber based plasmonic sensor for
detecting high refractive index aqueous analyte,” Optics and Lasers
amplitude sensitivity with analyte RI variation. In amplitude Engineering, vol. 58, pp. 1–8, 2014
interrogation, amplitude sensitivity is gained using equation [8] H. Moayyed, I.T. Leite, L. Coelho, J. L. Santos, D. Viegas,
(2). The variation of analyte RI is done from 1.33-1.34, “Analysis of phase interrogated SPR fiber optic sensors with
1.34-1.35, 1.35-1.36, 1.36-1.37, 1.37-1.38, 1.38-1.39 in a bimetallic Layers,” IEEE Sensors Journals, vol. 14, no. 10, pp.
regular sequence, the amplitude sensitivity are 100, 130, 3662–3668, 2014.
210, 330, 570, 595 RIU-1 respectively. Amplitude sensitivity [9] X. C. Yang, Y. Lu, M. T. Wang, J. Q. Yao ,’’SPR sensor based on
is defined as exposed-core grapefruit fiber with bimetallic structure, IEEE
Photonics Technology Letters, vol. 28, pp. 649–652, 2016.
1  ( , na ) [10] D. Gao, C. Guan, Y. Wen, X Zhong, L. Yuan, “ Multi-hole fiber
S A ( RIU 1 )   (6)
 ( , na ) na based surface plasmon resonance sensor operated at near-infrared
wavelengths,” Optics Communication, vol. 313, pp. 94–98, 2014.
[11] X. Yang, Y. Lu, B. Liu, J. Yao, “Analysis of graphene-based
The thickness of gold layer has an adverse effect on the photonic crystal fiber sensor using birefringence and surface
performance of the sensor. If the thickness of gold layer is plasmon resonance,” Plasmonics, vol. 12, no. 2, pp. 489-496, 2017.
increased, then both amplitude sensitivity and wavelength [12] E. K. Akowuah, T. Gorman,H. Ademgil, S. Haxha, G. K. Robinson,
sensitivity decreases. The demonstration is given in Fig. 6. and J. V. Oliver, “Numerical analysis of a photonic crystal fiber for
With increasing gold layer thickness, less possibility to biosensing applications,” IEEE Journal Quantum Electronics, vol.
penetrate the evanescent field into the plasmonic material 48, no. 11, pp. 1403–1410, 2012.
and the loss depth will decrease, respectively. So, less [13] G. Wang, S. Li, G. An, X. Wang, Y. Zhao, W. Zhang,H. chen, “
striking of evanescent field into the gold layer decreases the Highly sensitive D-shaped photonic crystal fiber biological sensors
sensor performance. Fig. 7 also discusses the central air hole based on surface plasmon resonance,” Optical and Quantum
diameter variation. When the central air-hole diameter Electronics, vol. 48, no.1, pp. 46, 2016.
decreases, amplitude sensitivity increases. But, there is no
change in wavelength sensitivity.

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