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Ps 2
Ps 2
Problem 1 When rhodium complex 1 is treated with hydrogen gas, ethylene is released and
compound 7 is formed.
(a) Identify the nuclei that would be expected to couple to the bridging hydride nuclei. Are the
hydrogen nuclei magnetically equivalent in the structure shown ?
(b) The far upfield hydride region of the 1H NMR (400 MHz) spectrum of the dimeric complex
in C6D6 (d6-benzene) is shown below with a simulated spectrum. Calculate the coupling
constants associated with this molecule.
H
Ph O Ph -H2O O Cr O
Pd Pd + OC Cr
CO
C
C
C
Ph3P O PPh3 OC H Ph
Pd Pd Ph
H O O
Ph3P H PPh3