i. -2- Which ofthe fallowing diagrams showsthe. 4. correct behaviour of protons (p),clectrons (©)and neutrons (n) in an electric field? What is the average relative atomic mass of bromine, given the following isotopie masses and relative abundance? Br 505% "Br 49.5% (A) 80.01 799 7990 @) 78.99 ‘Which of the following is NOT true for Period 3 ofthe periodic table? (A) Argonhas the highest first ionisation energy. (B) Phosphorus has a higher first ionisation energy than sulphur. Aluminium has a higher first ionisation energy than magnesium. First ionisation energies decrease ‘Which of the following paies of elements ‘would beeipected o form the compound with the MOST ionic charactes? (A) LiandF B) RbandF @ LiandI Rband! tom 'S refers to the displayed formula for the amino acid, glycine, given below. What are the approximate values ofthe bond anglee and? in the compound? +) = 106, b= 120° @ a=106, 8-110 (© 4=120,b=120°° @ 2107, b= 1355, How many moles of phosphoric acid are ‘contained in 20 em’ ofa 19.6 gdm? solution? fA) 4 Q@ of 0.04 +@) 0,004 ‘Analysisofan unknown compound, X, shows that it contains 0.4 g of carbon, 0.06 g of hydrogen and0.5 gofoxygen. The empirical formula of X is a : CHO © CHO ©) CAO,-3- Ia the following redox ceactions ivdlving chromium ‘compounds, whatis the oxidation numiberof chromium in each compound? NaOH dilute G0, _Na,Cro, —-——> 1,07 and water 180, cr,07 ‘Na,CrO, Cr, A +6 6 3 (B) 6 6 B : 46 46 8 6 +6 8 9. Which ofthe following does NOT represent a balanced redox equation? @ ®) Zn(s)+2HIO1 (aq) —+ ZnCl, (aq)+ BLE” ‘MnO*, (aq) + 5Fe*(aq) + 8H! —> Ma (aq)+ SFe™* (aq)+ 4H,0() Sn{s) + HINO, (eq) -> SnO,(s) + NO, (g) + 1,00} 3 $0,(¢)+Br,()+21,0() > 4H (aq) > $0,*(aa)+ 28 (ed) 10. . When solutions of iron (HU) nitrate and potassium iodide are mixed and starch added, a blue-black colouris formed, Which of the following reactions are involved? L UL i. Nv @ ® oO © Fel" (aq) + o> Fe™ (aq) Fe™ (aq) + 30" Fe(s) 24 (aq) > Flag +2¢e) 10, (aq) + 6H*(eq} + Se 4I,(2q) + 3H,0 (1) Tend ff only TandIV only Hand Il only TandIV onlyou ‘12. ode 188.0 grams of solid CO, evaporates, how marty litres of CO, as-will be forined at temperature of 27°C anid 2.00 attiosphieres ofpréssure? (Phe universal gasieonstant i, 310.0821 atm Vinol K.) @_ 246 By 985 (©) 1080 ©) ° 2170 Which offthe following statements aboutthe liquid state are true? 1. Volume of liquid is constant at a particulartemperature, > 1. “Density usually decreasés with, increasing temperature. IIL —Teiscifficultto compress. (A) ‘terid only Land Ik onily © Wand Hlonly +O) Mand i 14 15. 298 Items 13 - 14 refer to the following options. (A) | Eothaipy of formation (B) ‘Lattice energy (©). Enthalpy of solution ()— Bnthalpy of hydration ‘Maich EACH item below with one of the options ubove, each of which may be used ‘once, More than once or not at all. X@+V WS XVO XG)+ AY, XVO) What is the standard heat of reaction SO orga at 101.325 kPa of pressure and ‘ie Toriie equation given below? Zin (Sy CuP* (aq) + Za (aq) + Cus) AF atm = +64.AtT/mole for Cu* A ra, -152.4kV/mote for Za AHP ire,., 0 for both Zn and Cu (A) 421 7ksimole +88.0kiMmole -88.0%Nimole OY |-217idinole16. “5. Tom 16 refers to the following reaction which occurs in the presence of dilute acid CH, COCH, (aq) + (aq) -> CH, COCH, (eq) + H°(aq) + Iaq) f the rate equation forthe reaction is ‘Rate = K[CH, CO CH, (aq)] [H"(aq)}, which of the following BEST illustrates the slow step? ° on i | (A) CH, C—CH,+ Ht > CH~ C —CH, + i [ ®) CH-C—cH, +1, + cH—C—cHsr e ° I a he i ©) CH,-C—CH, +1 > CHL ct ® oO On a ll. | Ye D OCHS L4H cH, eH, I17. Which ofthegraphsbelow BEST showsthe 19. change in distribution of molecular energies when a gas at T,, is heated to temperature T? 7A it / i | @) * Number of 20. Kinetic energy 2. 18. The oxidation of ammonia is one step in the commercial mamufacture of nitrie acid. ANI) + 50,(g) 7 ANO(g) + GHO(g) AH =-908 ki mol! Which of the foliowing woulNNOT heve an effect on the position of the equilibritm? (A) Addition ofammonia (8) A decrease in reaction temperature ©} Wweaddition of acatalyst ‘Which of the following statements does NOT rTefortoa system in dynamic equilibrium? (A) Therate of the forward teaction is’ equal to the rate of the backward reaction. ©) Theamountsof all the species inthe system remain constant, ©) _Theconcentrations ofall eustans and products are equal. ©) The reaction is reversible. Which ofthe following are Bronsted -Lowry bases? LOH” T PHY UL. 1,6 iv. HS @® tend iffonly ®e) TandIV only © Mand only (P) Mand IV only Item 21 refers to the following information, Scientistshave invented anew indicetorcalted “Sure pH Check”, shown in the diagram below. Lo ‘What is the H* ion concentr.tion of theacid in container X, shawn below? @® 32x 10°mot anv (B) 3.2.x 10“ mo! dm (C) 32x 10% mol dm? @) 3.2.x 10 mol dm?22, 23. oT ‘Which ofthe following indicatorsare suitable 24, for a titration of aqueous sodium hydroxide with aqueous ethanoic acid? Indicator pH range L Methyl orange 29-40 T. — Methytsed 91-96 TL Thymol blue 42-63 IV. Alizarinyetlow 10.1- 12.0 (A) Land Hf only B) — Yand IV only 8 Hand If oniy 3) Wand IV only ‘The titration curve ofa weak acid/strong alkali is 25. @ iy 324 04 a &| va 8 ‘Volume of alkali added E ‘Which of the mixtures below will form a buffer solution? 1. Aqueous ammonia and equeous caloium hydroxide IL. Aqueous ammonia and aqueous ammonium chloride UL Aqueous ethanoic acid and aqueous calcium ethanoate TV. Aqueous ethanoic acid and aqueous benzoic acid Land Uf only (®) ‘Wand Hil only (©) Land IV only (D) Mand IV only Equal volumes of 0.1 mol dm? squeous ethanoie acid (Ka 1.8 x 10S mol de) and 0.1 mol dm? aqueous sodium ethanoate are mixed. ‘The pH of the resulting solution is 377 (B) 457 415 ) 5.00 ‘The solubility product of iron (IU) hydroxide is affected by a change in L temperature. TH. pressure Til, concentration of Fe* (A) Tonly (8) Land only (C) Land Wl only 1, Wand W-8- 27. Whiel of the fllowing would form part ofa Jom: 29 refers tothe Daniell cel ustrated standard hydrogen electrode? below. L Hydrogen gas at 273K and 1 nantes ‘atmosphere pressure th. 1.0 mol dm? sulphuric acid | Jess ZnSO, UL Alengthof platinum wire. ee 804 (ag) only |_---Blue CuSO, ¢ Monty (©) Tand Donly |_cu electrode ) 1, Wand HE | 29. Which of the following’statements is NOT i 28. Theelectrode potentialgoftwo half cells are true about whet happens in the’cell after it 1 siven below: has been running for some time? ‘ : Tm CF (aq) + eZ CP (aq) -041V @ By ze colour of the CuSO(aq) "za (ag) + 20° 2 Za (3) 2 0.76V (B) Ions in solution exoss the poraus ¢4, ot medium. -* ‘i (©)__ The Zn electrode reduoos in size. : Meppllitied itil etioiaa HaTT OD The Cu clecirode remains } unchanged. nd ® -urv . 1 ° yo . 30. The'unitsofthe rate coristant, k,fora second @) “Hv order process is * By (A) dm’ mol* st (B) dn mol" mot! dar? (D) mot" dm? s* 31. Which of the following elements has the highest electrical resistance? (3 (A) Silicon (B) Phosphorus (C)— Magnesinm © Abmitium «a32. 33. -9- ‘items 32-33 refer to the following oxidation states, (A) @® #8 © # O Match each underlined clement with its oxidation tmumber. Each oxidation number may be used more than once, once or not at all, ‘Which of the following trends is observed on going left to right across Period 3 of the periodic table? (A) Acid strength of the oxide of the ___ element inereases, (B)' _Electropositivity increases, onje rdivs decreases. (D) Metallic character increases. On dese-nding Group If ofthe peridic table, which of the following statements are true about the elements? I, They lose electrons more easily. IL ‘Their atomic radius increases, TI Their first ionization energy decreases. IV, Their electronegativity decreases. (A) Tand Honky 3 1, Hand If only . Il, Hl and tV only () LI Wand iv 36, ot 38. @ SiCI, reacts with water but CCI, doss not because carbon has a higher ionisation energy than sitican () has amore stable +4 oxidation state (©) isanoumetal andsilicon ismetailoid (D) _hasno available orbitals ofthe energy required for coordination with water, Carbon monoxide is easily oxidized to carbon dioxide, whilst lead (IV) oxide is easily reduced to tead (II) oxide, ‘What deductions can be made from this information? 1. The +2 oxidation stete of carbon is Jess stable than the +4 state. I. The 42 oxidation state of lead is fess stable than the + state, If. On descending Group IV, the +4 ‘oxidation state becomes more stable relative tothe #2 state, IV. On descending Group IV, the +2 oxidation state becomes more stable relative to the +4 state. (A) Tanditonty (8) Mand if only (C) Land TV only (D) “GWaid IV only Gn descending Group VII of the periodic tablo, which of the following trends is true? (A) Volatility inoreases.. {B) The colour of the element becomes lighter and less intense, (©) Therelative stability of the hydrides increases. (D) The bonds in the hydrides of the element become weaker.39. 40. at. 42. 43, 10- ‘The precipitate observed when iodide ions react with AgNO,(aq) is (A) soluble inéitute nitricacka (B) soluble in difute squecus ammonia (©) white in colour (D) insoluble in dilute nitric aid and aqueous aminonia A characteristic property of transition metals isthe presence of partially filled (A) s-sublevels (B) — d-sublevels 44, (©) p-sublevels (D) — f-sublevels At] 3éPisths eleétronte configuration shared — __ ‘bybott (Ay Mn and co (B) Mn? arid Fe? 45. (©) Fetand Cr" (D) “' Ce and Mn i te Items 42 - 43 refer to the following options. (A) Acentral'ion itizeomplext (B) ligand (©) Artootahedral éomplex (D) — Atetrshedral complex Match each underlined item below with one of the options above, each of which may be ‘used more than once, once or not at all. {Co (H,0)," [eereny™ ‘Item 44 refers to the following information. iw hie prsptte White recite soluble excess =< Which of the following reagents does NOT aid in the identification of X*? (A) dilute HNO, (B) aqueous KT ©) dilute ©) “Gillie Ht An unknown silt sotution containing a single ‘anign is tested with lead (I) nitrate solution ~ followed by dilute HNO,. Awhite precipitate js observed which dissolves in acid with ‘effervescence. These observations indicate the presence of (A) COX and Cr @) $0, and SOP (© 80; and CO D) SO and Cr {F YOUFINISH BEFORE TIME IS CALLED, CHECK YOUR WORKON THIS TEST.