‘Structure of Atom 42. 43. 44. 48, 46, 47. In the ground state of Cu’, the number of shells occupied, subshells occupied, filled orbitals and unpaired electrons respectively are (@) 4,8, 15,0 (b) 3,6,15,1 © 3,6, 14,0 (@) 4,7, 14,2 2010) Assume that you are travelling at a speed of 90 km/h in a small car with a mass of 1050 kg. If the uncertainty in the velocity of the car is 1% (Av = 0.9 km/h), what is the uncertainty (in meters) in the position of the car? (@) Avz1x10%m (b) Av>2x10°7 m (©) Ax>2x10"% m (@) Ax>4x10™ m (2010) Smallest wavelength occurs for (a) Lyman series (b)_ Balmer series (©) Paschen series (d)_ Brackett series. (oll) Which of the following is wrong for Bohr model? (a) It establishes stability of atom. (b) It is inconsistent with Hei uncertainty principle (©) Iexplains the concept of spectral lines for hydrogen like species. (@)_ Electrons behave as particle and wave. (oll) ‘Threshold frequency of a metal is 5 x 10" s upon which 1 = 10 s“ frequency light is focused, Then the maximum kinetic energy of emitted electron is (a) 33%10"F — b) 33x 10°F (©) 66%10"F (a) 66x 10°F (2012) enberg th In Bohr’s orbit, “indicates Qn (a) momentum (b) kinetic energy (©) potential energy (@)_ angular momentum, (2012)10 48. 49. 50. 52. 53. 54. 58. A particle is moving 3 times faster than the speed of electron. If the ratio of wavelength of particle and electron is 1.8 * 107, then particle is (a) neutron (b) ocparticle (©) deuteron (@) tritium. (20/3) Which of the following pairs represents isotones? (@)_ GAs, nSe (©) “Ag, '3Cd In a decay process 4X changes into 7 4Y. Which of the following processes represents this? (a) B-decay (b) B*-decay (©) a-decay (@) decay (2015) (b) PL Sos (@) HE Ba (2014) According to Bohr’s theory, which of the following correctly represents the variation of energy and radius of an electron in n" orbit of H-atom? 1 @) Ex rat 0) En? 1 on, rom n (2016) (©) E,enyren® (d) &, Ionisation potential of hydrogen atom is 13.6 eV. Hydrogen atom in ground state is excited by monochromatic light of energy 12.1 eV. The spectral lines emitted by hydrogen according to Bohr’s theory will be (a) one (b) two (©) three (@) four, (2017) Calculate the velocity of an electron placed in the second orbit of Li?* ion. (a) 0.521ms! — (b) 3.27 * 108m = (©) 4.23 «108 mst (@) 3.27 « 108m st (2018) What is the maximum wavelength of line of Balmer series of hydrogen spectrum? (R= 1.09 « 107m!) (a) 400nm (©) 486nm (>) 660nm (d) 434nm (2018) Wavelength of a particular transition for H atom is 400 nm, What can be the wavelength of He* for the same transition? (a) 400nm (>) 100nm (©) 1600nm (@) 200mm (2018) [iiiedl AIMS Chapterwise Solutions Chemistry] ASSERTION AND REASON‘Structure of Atom 10. Assertion : The nuclear isomers are the atoms. with the same atomic number and same mass 1. 72. 74. 75. "1 number, but with different radioactive properties. Reason : The nucleus in the excited state will evidently have a different half-life as compared to that in the ground state. (2010) Assertion : Bohr model fails in case of multi- electron species. Reason : It does not mention electron-electron interactions. (2012) Assertion : The spectrum of He* is expected to be similar to that of hydrogen. Reason : He” is also one electron system. (2012) . Assertion : Number of radial and angular nodes for 3p-orbital are 1, 1 respectively. Reason : Number of radial and angular nodes depends only on prineipal quantum number. (2013) Assertion : For Balmer series of hydrogen spectrum, the value m = 2 and nz = 3, 4, 5 Reason : The value of n, for a line in Balmer series of hydrogen spectrum having the highest wavelength is 6. (2015) Assertion : Fine lines are observed in spectra if an atom is placed in a magnetic field. Reason : Degenerate orbitals split in the presence of magnetic field. (2018)