UNIVERSIDAD EL BOSQUE CRSA, 202041 (Week 7-88) WORKSHOP OF MATH SIGNATURES. UNITARY TEACHERS | MONICA MUNOZ CARDENAS: ‘SKILLS OPERATIONS JONATHAN TAPIAS SARABIA “Fractions” Dear students! Both, Monica and Jonathan, are concerned about your math skills. Our deste? Find the difTerent pathways of understanding physical chemistry and unitary operations, employing basic tools acquired in your career. Allis connected, even you may not se it! Off we go! 1. 1.3003 g of NayAsO. are dissolved in 100,0 mL. of water. From this stock solution, 3 serial dilutions are prepared with the following proportions: 2:3; Ps=13 and Py=2'5, Caleulate the concentration in ppm of Na" in the final dilution, 2. The aqueous phate dissociation oF barbiturc acid ean be represented as: oro aye «+H cone emma a 8 8 ‘What is the value of K, if in equilibrium the proportion of H’ fons per barbituric acid molecules is 47/500 from a 102M solution of weak electrolyte? 3. The equilibrium constant ofthe reaction BrO,~ + 2Cr** + AUf,O = Br~ + Cr,0,2 + 8H at 25,0°C is 1.0.x 10". Assume an experiment with pH LS conditions, the concentration of the dichromate ion corresponds to two thirds of the hydronium ion: while 3/5000 pars ofthis is ‘equivalent atthe concentration ofthe chromium ion; the concentration of the bromide ion is 23 times greater than the bromate ion, Otherwise, bromide values is equal to half concentration ofthe dichromate ion, A. According to tis report, which direction will the reaction shif to reach equilibrium sta? BL IFthe stoichiometry ofthe reaction changes to: Uy BrOy + 2/g6r* + 4/qH20 = Y/y Br + 1/46r20," + 8/qH* ‘What ithe value ofthe equa constane? 44. Find the aH forthe eaetions below, given the following reactions and subsequent 4H values Ziyy + WS yy 20,4) > ZnSO yu, Zale) + Y SH) + ZnS) aH=-18392k 2ZaS(9)+3 Og) —+ 220045) +2 808) AH= 927.544 280:()+0:@) + 250.) AH=-196.04 kr Z00(3) +SOx(@) + ZnS04(s) aH=-23032k Cy + 2 Oye + 200 yp) + HO CoHldg) + CHG) +2 He) A= 283.51 HG) +4048) — 10) AH=21371 2COYg) + 31,0) + CHig) + 7h 0x8) AH= 849UNIVERSIDAD EL BOSQUE chemisrey easor weskeat WORKSHOP OF MATH SIGNATURES. UNITARY. | TEacHERs | MONICA MUNOZ CARDENAS ‘SKILLS OPERATIONS JONATHAN TAPIAS SARABIA “Fractions! D2 Hyg * 12 yy + HCley COCK(g) + H20()) -+ CH2Ch() + Oxe) 2HCI(g) + %Ox(g) > H.0() + Chie) CHLCL() + Hg) + *%0.{g) + COCK(g) + 24,01) AH =-402.5 5. Sodium bromide has antiepitetic properties and was used during the 19th and early 20th centuries to teat the symptoms of different types ‘of epilepsy. The following process has been used to obtain sodium bromide: Stage 1 (Yield = 93.2%). Iron molecular bromine —+ iron bromide (ID, ‘Stage 2 (Yield = 708%). Iron (Il) bromide + molecular bromine —> Tr-ron ostabromide Stage 3 (Veld = 82.6%) ‘Tri-ion Octabromide + Sodium Carbonate ~» Sodium Bromide + Carbon Dowie + Tiron Tetroxide How many grams of ion (66,6% purity) and bromine (88.3% purity) are needed in the thi sage? Note: The rules of three are not supported. ist stage, for every kilogram of sodium bromide produced. 6. A substitute fr aspirin, acetaminophen (CsHA0:N) is produced by the following synthesis in 3 steps CollsON a) + Haig) + HClac) * CellyONCle) + Haq GoHlgONChyy + NaOHeqe) + CoHs ON) + HO + Maa, GHyON oy + CaHsOaq) > Celly2N io + HCHO rey If yields reactions are 87%, 98% and 95%, respectively; calculate the amount of CsHsOsNjx necessary (99% purity) forthe production of 40 stones of acetaminophen, “Je ne demande pas de priéres avec votre confiance seulement, je serai heurews." (No pido oraciones solo com tu confianca,seré fll: Extracto tomado del poema “Une saison en enfer 1873)", de Arthur Rimbaud