3. 5. [Osea te NeOH, (A); Product (A) is: So. dO (4) None of the above Oe sre ee (4); Product (A) is Qe. ate ~, Oe oy CH, Na, CHNNH, ‘Among the givon pais, in which pair first conpoundn reacts faster than second compound in Sy reaction? cH—cH—cH—cr (2) CH= CH-cH—cH, Br oF ees cH, o ) OH; pon CH, gr CHBHGH— CH, Br Br OO (a) OH C CH, og CH E—CH, er Wat is the major product of the following reaction 7 H.C-=CH—CH,—OH iE» product (0) H,cmcH—cH,—Br on 1 I (©) oh—cH—cH,—OH rene beonmon Rate of Sy. will be negligible in : @) e) ) a) O Scanned with CamScanner6. Consider the nucleophilic attacks given below. Select in each pair that shows the greater S,, reaction rate. 9 ay tect son on F cN a HC—Br + H.C—Br + cH,SH co) BOG SH or ™ (rarer Creer (c} or in DMSO. ™ wy Cypser Cy & (2) or in methanol vil) vit) A B c D @ (: ©) a: (eo) @ 0: 7. Select the (8) CH,CH,OK in dimethyl sulfoxide (DMSO) (b) (CH,),COK in dimethy! sulfoxide (DMSO) (c) Bath (a) and (b) will give comparable amounts of substitution (d) Neither (a) nor (b) will gi 8. Rank the following specie: (most — least nucleophilic) : ion on reaction with CH, - CH, — Br ny amount of substitution order of decreasing nucleophilicity in a polar protic solvent. fi CH,CH,CH,OT CH,CHCH,S~ CH,CH.C—O — 1 2 3 (a) 3>1>2 (be) 2>3>1 © 1>3>2 ) 2>1>3 9. What is the major product obtained in the following reaction CH,-Be CK, ior ‘Be ‘CH, -NH, ‘CH,—8r -CH,-NH, ‘CH,~NH, @ Ox ) Cx © CX, @ or ‘Br ‘NH, iH, Scanned with CamScannerCex Me= CH= X MEH X the CmK ‘Which of the following is true about given graphs A and 8? @ A+S, BS, ) A+S, B+S, () ABB +E, More than One Option Correct 11. From each of the following pairs select the compound that will react faster with sodium iodide in acetone ( ASBE, Pair -A- (1) 2-Chioropropane (2) 2- Bromopropane 1 2 Pair -B - (3) 1-Bromobutane (4) 2- Bromobutane 3 4 @ 13 1.4 © 2.3 24 12. Which of the following statements is true 7 (a) CH,CH,S"is both a strongar base and more nucleophilic than CH,CH,O (b) CH,CH;S isa stronger base but is less nucleophilic than CH,CH,O- (c) CH,CH,S is a woaker base bul is more nucleophilic than CH,CH,O" (8) CH,CH,S- is both a weaker base and ess nucteophilic than CH,CH,O- 13, The reaction of 4-bromo benzytchloride with sodium cyanide in ethanol leads to the formation of (a) 4-bromobenzy! cyanide (0) 4-cyanobenzyl chloride {c) 4-cyanobenzyl cyanide (@) 4-vromo-2-cyanobenzy! chloride Scanned with CamScanner