SUJIT'S CHEMISTRY

CONTENTS:- According to markwnikoff’s rule and kharasch effect.

H H
| |
CH3–CH = CH2 + HBr  CH  CCH
3 | |
Br H
According to Anti Markownikoff rule (Based on F.. R. M)
CH3 – CH = CH2 + HBr Peroxide

H H H H
| | | |
CH  C  C H + CH  C C  H
3 | | 3 | |
Br H H Br
(minor) (major)
(viii) Reaction with hypohalous acids :
 
CH2  CH2  HO Cl  CH2 OH. CH2 Cl
Ethylene Ethylenechlorohydrin

In case of unsymmetrical alkenes markownikoff rule is fol-

lowed.
(ix) Reaction with sulphuric acid :
CH2  CH2  HHSO 4  CH 3 CH 2HSO 4
Ethylene Ethyl hydrogen sulphate

CH3CH2HSO4  CH2 = CH2 + H2SO4

This reaction is used in the separation of alkene from a gas-
eous mixture of alkanes and alkenes.
(x) Reaction with nitrosyl chloride
NO
C=C + NOCl  C = C (NOCl is called Tillden reagent)

Cl

If hydrogen is attached to the carbon atom of product, the

product changes to more stable oxime.
NO
H
C=C C = C= NOH

Cl Cl
Oxime
C C
C=C + NOCl  C–C (Blue colour)
C C
NO Cl
SC Arunodayanagar, Link Road,Cuttack-12,D-232,sec-7,CDA,ctc-14,College Square,ctc-Ph.:9937010955,
GASEOUS 9938339100
STATE 17