Nombres: Paula Andrea Valbuena Sánchez

Lucy Katherine Angarita Chacon

(𝐻_𝑖𝑜−𝐻_𝑖 )=∫1_𝑇^𝑇𝑜▒ 〖𝐶𝑝 ,𝑖 𝑑𝑇 〗

(𝐻_𝑖𝑜−𝐻_𝑖 )=−∫1_𝑇𝑜^𝑇▒(𝛼_𝑖+𝛽_𝑖 𝑇+𝛾_𝑖 𝑇^2 )𝑑𝑇

∑_(𝑖=1)^𝑛▒Θ_𝑖 (𝐻_𝑖𝑜−𝐻_𝑖 )=−∑_(𝑖=1)^𝑛▒∫25_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 (𝛼_𝑖+𝛽_𝑖 𝑇+𝛾_𝑖 𝑇^2 )𝑑𝑇 〗

1)^𝑛▒Θ_𝑖 (𝐻_𝑖𝑜−𝐻_𝑖 )=−∑_(𝑖=1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 (𝛼_𝑖 )𝑑𝑇+∑_(𝑖=1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 (𝛽_𝑖 𝑇)𝑑𝑇 〗〗 +∑_(𝑖=1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 (𝛾_𝑖

Θ_𝑖 (𝐻_𝑖𝑜−𝐻_𝑖 )=−{∑_(𝑖=1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 ( 〖∆𝛼〗 _𝑖 )𝑑𝑇+∑_(𝑖=1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 ( 〖∆𝛽〗 _𝑖 𝑇)𝑑𝑇 〗〗 +∑_(𝑖=1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 (

_𝑖 (𝐻_𝑖𝑜−𝐻_𝑖 )=−{∑_(𝑖=1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 (−𝑎/𝑎 𝛼_𝐴−𝑏/𝑎 𝛼_𝐵+𝑐/𝑎 𝛼_𝑐−𝑑/𝑎 𝛼_𝐷 )𝑑𝑇+∑_(𝑖=1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 (−𝑎/𝑎 𝛽_𝐴−𝑏/𝑎 𝛽_

▒Θ_𝑖 (𝐻_𝑖𝑜−𝐻_𝑖 )=−{∑_(𝑖=1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 ( 〖∆𝛼〗 _𝑖 )𝑑𝑇+∑_(𝑖=1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 ( 〖∆𝛽〗 _𝑖 𝑇)𝑑𝑇 〗〗 +∑_(𝑖=1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 (

INTEGRACION

)^𝑛▒Θ_𝑖 (𝐻_𝑖𝑜−𝐻_𝑖 )=−{∑_(𝑖=1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 (𝛼_𝑖 )(𝑇)𝑑𝑇+∑_(𝑖=1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 (𝛽_𝑖 )(𝑇^2/2)𝑑𝑇 〗〗 +∑_(𝑖=1)^𝑛▒∫1_𝑇𝑜^𝑇▒

(𝑖=1)^𝑛▒Θ_𝑖 (𝐻_𝑖𝑜−𝐻_𝑖 )=−{∑_(𝑖=1)^𝑛▒ 〖 Θ_𝑖 (𝛼_𝑖 )(𝑇)+∑_(𝑖=1)^𝑛▒ 〖 Θ_𝑖 (𝛽_𝑖 )(𝑇^2/2)+ 〗 〗 ∑ _(𝑖=1)^𝑛▒ 〖 Θ_𝑖 (𝛾_𝑖 )(𝑇^3/3) 〗 " " } |_

_(𝑖=1)^𝑛▒Θ_𝑖 (𝐻_𝑖𝑜−𝐻_𝑖 )=−{∑_(𝑖=1)^𝑛▒ 〖 Θ_𝑖 (𝛼_𝑖 )(𝑇−𝑇𝑜)+∑_(𝑖=1)^𝑛▒ 〖 Θ_𝑖 (𝛽_𝑖 )( 〖 (𝑇−𝑇𝑜) 〗 ^2/2)+ 〗 〗 ∑ _(𝑖=1)^𝑛▒ 〖 Θ_𝑖 (𝛾_𝑖 )(

=1)^𝑛▒Θ_𝑖 (𝐻_𝑖𝑜−𝐻_𝑖 )=−{∑_(𝑖=1)^𝑛▒ 〖 Θ_𝑖 (𝛼_𝑖 )(𝑇−𝑇𝑜)+(∑_(𝑖=1)^𝑛▒ 〖 Θ_𝑖 (𝛽_𝑖 ) 〗 )/2 〖 (𝑇−𝑇𝑜) 〗 ^2+(∑_(𝑖=1)^𝑛▒ 〖 Θ_𝑖 (𝛾_𝑖 ) 〗 )/3

=1)^𝑛▒Θ_𝑖 (𝐻_𝑖𝑜−𝐻_𝑖 )=−{∑_(𝑖=1)^𝑛▒ 〖 Θ_𝑖 (𝛼_𝑖 )(𝑇−𝑇𝑜)+(∑_(𝑖=1)^𝑛▒ 〖 Θ_𝑖 (𝛽_𝑖 ) 〗 )/2(𝑇^2− 〖𝑇𝑜〗 ^2)+(∑_(𝑖=1)^𝑛▒ 〖 Θ_𝑖 (𝛾_𝑖 ) 〗 )/
^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 (𝛾_𝑖 𝑇^2 )𝑑𝑇 〗

1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 ( 〖∆𝛾〗 _𝑖 𝑇^2 )𝑑𝑇 〗 " " }

▒ 〖 Θ_𝑖 (−𝑎/𝑎 𝛽_𝐴−𝑏/𝑎 𝛽_𝐵+𝑐/𝑎 𝛽_𝑐−𝑑/𝑎 𝛽_𝐷 )𝑇𝑑𝑇 〗〗 +∑_(𝑖=1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 (−𝑎/𝑎 𝛾_𝐴−𝑏/𝑎 𝛾_𝐵+𝑐/𝑎 𝛾_𝑐−𝑑/𝑎 𝛾_𝐷 )𝑑𝑇 〗 " " }

=1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 ( 〖∆𝛾〗 _𝑖 𝑇^2 )𝑑𝑇 〗 " " }

〗 +∑_(𝑖=1)^𝑛▒∫1_𝑇𝑜^𝑇▒ 〖 Θ_𝑖 (𝛾_𝑖 )(𝑇^3/3)𝑑𝑇 〗 " " }

_𝑖 (𝛾_𝑖 )(𝑇^3/3) 〗 " " } |_𝑇𝑜^𝑇

∑ _(𝑖=1)^𝑛▒ 〖 Θ_𝑖 (𝛾_𝑖 )( 〖 (𝑇−𝑇𝑜) 〗 ^3/3) 〗 " " }

1)^𝑛▒ 〖 Θ_𝑖 (𝛾_𝑖 ) 〗 )/3 〖 (𝑇−𝑇𝑜) 〗 ^3 〗 " " }

𝑖=1)^𝑛▒ 〖 Θ_𝑖 (𝛾_𝑖 ) 〗 )/3(𝑇^3− 〖𝑇𝑜〗 ^3) 〗 " " }

_𝐷 )𝑑𝑇 〗 " " }
 Nombres: Paula Andrea Valbuena Sánchez
Lucy Katherine Angarita Chacon

Fase liquida no va haber cambio en la densidad

−𝒓𝑨=𝒆^((𝟏𝟓,𝟑𝟐−𝟕𝟓𝟓𝟎/𝑻) 𝑪_(𝑨 ) ) [𝒌𝒎𝒐𝒍/(𝒎^𝟑 𝒔)]

𝑨→𝑩

Datos del enunciado Consideraci

Alimentacion Reactor CS
Cao [kmol/m^3] 2.8
To [K] 298
q_o = v_o [m^3/s] 7.00E-05 −𝑋∆𝐻°𝑟𝑥𝑛=∑

V_CSTR [m^3] 0.018 Adiabatico

(-rA) [kmol/m^3s] 0.000125156

Contantes y parametros
ρ_Mezcla [kg/m^3] 1000
Cp_prom [kcal/kmolK] 360
ΔH°_rxn [kcal/kmol] -45000 Negativo rxn Exotermica
Al ser la reaccion exotermica la T debe ser mayor a la registrada en la alimantación
Calculos
T [K] X_BE X_BM
300 0.016 0.013426136934727
301 0.024 0.014579892762993
302 0.032 0.015822579170946
303 0.04 0.017160089243423
304 0.048 0.018598613144839
305 0.056 0.020144643060783
306 0.064 0.02180497687491
307 0.072 0.023586720373819
308 0.08 0.025497287756099
309 0.088 0.027544400205546
310 0.096 0.029736082273019
311 0.104 0.032080655797023
312 0.112 0.034586731080296
313 0.12 0.037263195029087
314 0.128 0.040119195954108
315 0.136 0.043164124727975
316 0.144 0.046407591994262
317 0.152 0.049859401128838
318 0.16 0.05352951666589
319 0.168 0.05742802791999
320 0.176 0.061565107562551
321 0.184 0.065950964947173
322 0.192 0.070595794024414
323 0.2 0.075509715743339
324 0.208 0.080702714905416
325 0.216 0.086184571516275
326 0.224 0.091964786772838
327 0.232 0.098052503926956
328 0.24 0.104456424381598
329 0.248 0.111184719500515
330 0.256 0.118244938745713
331 0.264 0.125643914896795
332 0.272 0.133387667249439
333 0.28 0.141481303833638
334 0.288 0.149928923831854
335 0.296 0.1587335215084
336 0.304 0.167896893079177
337 0.312 0.177419548050222
338 0.32 0.18730062662879
339 0.328 0.197537824856752
340 0.336 0.208127329127827
341 0.344 0.219063761723218
342 0.352 0.230340138931042
343 0.36 0.241947843201119
344 0.368 0.253876610627249
345 0.376 0.26611453484463
346 0.384 0.278648088182995
347 0.392 0.291462160630593
348 0.4 0.304540116846362
349 0.408 0.317863871115386
350 0.416 0.331413979785315
351 0.424 0.345169750359205
352 0.432 0.359109366064704
353 0.44 0.373210024381964
354 0.448 0.387448087704618
355 0.456 0.40179924404004
356 0.464 0.416238675436273
357 0.472 0.430741231660911
358 0.48 0.445281606557338
359 0.488 0.459834514469038
360 0.496 0.47437486415376
361 0.504 0.488877927704106
362 0.512 0.503319502145347
363 0.52 0.517676061588312
364 0.528 0.531924898067047
365 0.536 0.546044249477803
366 0.544 0.560013413347711
367 0.552 0.573812845487276
368 0.56 0.587424242910335
369 0.568 0.600830610728236
370 0.576 0.614016313032983
371 0.584 0.626967108069078
372 0.592 0.639670168249867
373 0.6 0.652114085796485
374 0.608 0.664288864963147
375 0.616 0.676185901960132
376 0.624 0.687797953795104
377 0.632 0.699119097325902
378 0.64 0.710144679855595
379 0.648 0.72087126260671
380 0.656 0.731296558389613
381 0.664 0.741419364734205
382 0.672 0.751239493688479
383 0.68 0.760757699406333
384 0.688 0.769975604554385
385 0.696 0.778895626467112
386 0.704 0.787520903874924
387 0.712 0.795855224923727
388 0.72 0.803902957099782
389 0.728 0.811668979572235
390 0.736 0.819158618369422
391 0.744 0.826377584715056
392 0.752 0.83333191676771
393 0.76 0.840027924932115
394 0.768 0.846472140843982
395 0.776 0.852671270071415
396 0.784 0.858632148525229
397 0.792 0.864361702527442
398 0.8 0.869866912451297
399 0.808 0.87515477981698
400 0.816 0.88023229770404
401 0.824 0.885106424323904
402 0.832 0.889784059583098
403 0.84 0.894272024459309
404 0.848 0.898577043007588
405 0.856 0.902705726812389
406 0.864 0.906664561702093
407 0.872 0.910459896545836
408 0.88 0.914097933957389
409 0.888 0.91758472273712
410 0.896 0.920926151890425
411 0.904 0.924127946069119
412 0.912 0.927195662290903
413 0.92 0.930134687800959
414 0.928 0.932950238948762
415 0.936 0.935647360962256
416 0.944 0.938230928510435
417 0.952 0.940705646954029
418 0.96 0.943076054192404
419 0.968 0.945346523022742
420 0.976 0.947521263935222
421 0.984 0.94960432827511
422 0.992 0.951599611709395
423 1 0.953510857941957
424 1.008 0.955341662627074
425 1.016 0.957095477436557
426 1.024 0.958775614240779
427 1.032 0.960385249368464
428 1.04 0.961927427914344
429 1.048 0.963405068067605
430 1.056 0.964820965437547
431 1.064 0.966177797356051
432 1.072 0.967478127139313
433 1.08 0.96872440829386
434 1.088 0.969918988654202
435 1.096 0.971064114441533
436 1.104 0.972161934234734
437 1.112 0.973214502846601
438 1.12 0.974223785099641
439 1.128 0.975191659497111
440 1.136 0.976119921786063
441 1.144 0.977010288410194
442 1.152 0.977864399851124
443 1.16 0.978683823857535
444 1.168 0.979470058562182
445 1.176 0.980224535487423
446 1.184 0.980948622440339
447 1.192 0.981643626298938
448 1.2 0.98231079569128
449 1.208 0.982951323569634
450 1.216 0.983566349682022
451 1.224 0.984156962943656
452 1.232 0.984724203710977
453 1.24 0.985269065961044
454 1.248 0.985792499379175
455 1.256 0.986295411357732
456 1.264 0.986778668909008
457 1.272 0.987243100495189
458 1.28 0.987689497778318
Consideraciones
Reactor CSTR
𝑄−𝐹𝐴𝑜𝑋∆𝐻°𝑟𝑥𝑛=𝐹𝐴𝑜∑▒ 〖 Θ𝑗𝐶𝑝𝑗(𝑇−𝑇𝑜) 〗

−𝑋∆𝐻°𝑟𝑥𝑛=∑▒ 〖 Θ𝑗𝐶𝑝𝑗(𝑇−𝑇𝑜) 〗

Adiabatico Q=0

𝑈𝐴Δ𝑇(𝑄)=𝑂
Ecuaciones

X=−(∑▒ 〖 Θ𝑗𝐶𝑝𝑗(𝑇−𝑇𝑜) 〗 )/(∆𝐻°𝑟𝑥𝑛(𝑇_𝑅 )+(Δ𝐶) ̂𝑝(𝑇−𝑇_𝑅))

𝑋_(𝑏𝑎𝑙𝑎𝑛𝑐𝑒 𝑑𝑒 𝑒𝑛𝑒𝑟𝑔𝑖𝑎)=−(𝐶 ̂𝑝𝑎(𝑇−𝑇𝑜))/(∆𝐻°𝑟𝑥𝑛)

𝑋_(𝑏𝑎𝑙𝑎𝑛𝑐𝑒 𝑚𝑜𝑙𝑎𝑟)=𝑉_𝐶𝑆𝑇𝑅/(𝑣_𝑜/[𝒆^((𝟏𝟓,𝟑𝟐−𝟕𝟓𝟓𝟎/𝑻) ) ] +𝑉_𝐶𝑆𝑇𝑅

Conversion en funcion de la temperatura _Reactor CSTR

Adiabatico
1.4
1.2
1
0.8
X

0.6
0.4
0.2
0
280 300 320 340 360 380 400 420 440 460 480
T [K]
0.4
0.2
0
280 300 320 340 360 380 400 420 440 460 480
T [K]
uaciones

(∆𝐻°𝑟𝑥𝑛(𝑇_𝑅 )+(Δ𝐶) ̂𝑝(𝑇−𝑇_𝑅))

)=−(𝐶 ̂𝑝𝑎(𝑇−𝑇𝑜))/(∆𝐻°𝑟𝑥𝑛)

_𝑜/[𝒆^((𝟏𝟓,𝟑𝟐−𝟕𝟓𝟓𝟎/𝑻) ) ] +𝑉_𝐶𝑆𝑇𝑅 )
Nombres: Paula Andrea Valbuena Sánchez

𝐴+𝐵→𝐶

K [m^3/kmol*h] - 300 K

Cp_prom (A) [kJ/kmolK]

Cp_prom (B) [kJ/kmolK]
Cp_prom (C) [kJ/kmolK]
Area de superficie [m^2]
 rxn orden 2
𝐴+𝐵→𝐶 −𝑟𝐴=𝐾𝐶_𝐴^2 Balance de energia
𝑄−𝐹𝐴𝑜𝑋∆𝐻°𝑟𝑥𝑛=𝐹𝐴𝑜∑▒ 〖 Θ𝑗𝐶𝑝𝑗(𝑇−𝑇𝑜) 〗
Datos del enunciado
Mezcla equimolar Ecuacion de arrehenius
CAo [kmol/m^3] 2
𝐾=𝐴𝑒^(−𝐸𝑎/𝑅𝑇)
To [K] 300
v_o [m^3/h] 1.8 𝐴=𝐾/(𝑒^(−𝐸𝑎/𝑅𝑇) " " )
V_CSTR [m^3] 1.2
X 0.6
K [m^3/kmol*h] - 300 K 1.035 𝑉_𝐶𝑆𝑇𝑅=(𝐹𝐴𝑜∗𝑋)/([𝐴𝑒^(((−𝐸𝑎)/𝑅𝑇) ) ]( 〖𝐶 _𝐴 〗 ^2))
Ea [kJ/kmol] 10000
ΔH°_rxn [kJ/kmol] 41860
Cp_prom (A) [kJ/kmolK] 83.7 Fao 3.6
Cp_prom (B) [kJ/kmolK] 84.7 CA 0.8
Cp_prom (C) [kJ/kmolK] 167.4 CA^2 0.64
Area de superficie [m^2] 𝑉_𝐶𝑆𝑇𝑅=(𝐹𝐴𝑜∗𝑋)/([𝐴
2 〖〗 ](A〖𝐶a 300
_𝐴 〗 K
^2)) 57.03
Q [kJ/h*m^2*K] 15070
T [K] 399.6537959
R [J/molK] 8.3144 V_CSTR calculado 1.199999838

Diferencia -1.61685E-07
Θ𝑗𝐶𝑝𝑗(𝑇−𝑇𝑜) 〗
"UA(Ta−T)"−𝐹𝐴𝑜𝑋∆𝐻°𝑟𝑥𝑛=𝐹𝐴𝑜∑▒ 〖 Θ𝑗𝐶𝑝𝑗(𝑇−𝑇𝑜) 〗

Volumen CSTR
"T" 𝑎=[(𝐹𝐴𝑜∑▒ 〖 Θ𝑗𝐶𝑝𝑗(𝑇−𝑇𝑜) 〗 +𝐹𝐴𝑜𝑋∆𝐻°𝑟𝑥𝑛" " )/𝑈𝐴]+𝑇

Ta [K] 406.65071