Series : SSO/I Coueno. 56/1/1 rani Candidates must write the Code on one | the title page of the answer-book. waa. rant saat & ye ys 1 aS a. stave fer | © Please check that this question paper contains 12 printed pages. * Code number given on the right hand side of the question paper should be written on the title page of the answer-book by the candidate. * Please check that this question paper contains 30 questions. © Please write down the serial number of the question before attempting it. 15 Minutes time has been allotted to read this question paper. The question paper will be distributed at 10.15 a.m. From 10.15 a.m. to 10.30 a.m., the student will read the question paper only and will not write any answer on the answer script during this period. poe airs ae ot fe ge es a a fe S12 I vrer-as 8 aed aa at ik fea eo ete aay ah ora Se-GeraT HS-TS H fere | pre sire ae ot fap ge ea FE 30 WET I BUT WHA ST Tae Fea YS HEA A Weel, WHA oT es Haya fers 1 Fa reas al aga & feng 15 fae er aaa fear rare | aeaaa a far qater 10.15 ast Pear SAT | 10.15 48 10.30 a4 ae Ora Fae wea a GA ai ge stata ches 3 sega WTS TR et fer eoe ee CHEMISTRY (Theory) Tare faart (tars) Time allowed : 3 hours ] [ Maximum marks : 70 eer ere : 3 TE] [sifirescrn aie : 70 General Instructions : (i) All questions are compulsory. (ii) Marks for each question are indicated against it. (iii) Question numbers 1 to 8 are very short-answer questions and carry I mark each. (iv) Question numbers 9 to 18 are short-answer questions and carry 2 marks each. (v) Question numbers 19 10 27 are also short-answer questions and carry 3 marks each. (vi) Question numbers 28 to 30 are long-answer questions and carry § marks each. (vii) Use Log Tables, if necessary. Use of calculators is not allowed. area Frade: a3 (i) wat aes sifrarté 1 (ii) rarer a aret ae Tee ee | (iii) Wea 1 8 are ot orp se eT E ite wer H fea 1 awe | (iv) Pa a el es palit a (v) Wea 19 F27 & acts wer & aes ate & 1 (vi) FerHOr 28930 Gesamte wer | weraer ois ateF | (vii) HTETRrRCATGAU PHI Seca eT AT HE | PIA STAT Ht TAT ATE | SOUL 1 [P.1.0.1. Which point defect in crystals does not alter the density of the relevant solid ? fee ar a ot ade (erga) ae aera da & orca F ohtads at aa? 2. Define the term “Tyndall effect’. ferser rarer ait ofearen fated 1 3. Why is the froth flotation method selected for the concentration of Sulphide ores ? TERS SRS SH ra & fers hs res fale a aT at eT =? 4. Why is Bi(v) a stronger oxidant than Sb(v) ? Sb(v) # ata Bi(v) aes wae attaetence at & 2 5. _ Give the IUPAC name of the following compound : cH, re = ¢ ~CH,OH CH, Br fre ait a arg gg et (IUPAC) arr aif : Hse = € -CH,OH CH, Br 6. Write the structure of 3-oxopentanal. 3-aeat Ste at aceaT eA FHa | 7. Why is an alkylamine more basic than ammonia ? rete at arta aig Clecreratta aaftres erie ae eta 8? 8 Give an example of elastomers. weit ar oe seeTT AP | SOUL 29. A reaction is of second order with respect to a reactant. How will the rate of reaction be affected if the concentration of this reactant is 2 @ — doubled, (i) reduced to half ? we afrere & caer toe artista facia aie ate aie ge afters aT SiO @ FAR fara, ae (i) swan ar fear are, ch srfittinar at ax 8 wanted et ? 10, Explain the role of 2 (i) — Cryolite in the electrolytic reduction of alumina. (ii) Carbon monoxide in the purification of nickel. fret ai ere aif : @ ephard dee ares Faraone ar art Gi) Face > citer a ar abisieaes a ar | 11. Draw the structures of the following molecules : 2 (i) XeF, Gi) BrF, fre amait at icant antfan aifa : @ XeF, Gi) Br, ’ 12. Complete the following chemical reaction equations : 2 Py + N2OH gq) + HO —> Gi) Fag + HO + 03) fre rari aifitina aetarcot at yet aid : @ Py) +NaOH,g) +H,0,—> GH) Fag) + Hap + O3—q)— 13. Differentiate between molality and molarity of a solution. What is the effect of change in temperature of a solution on its molality and molarity ? 2 facas a facta at store att ater & ate & sie st re se ere fara aT feat oar aT WATE TATE ? /1/1 2% [P.T.0.14. Which ones in the following pairs of substances undergoes S,,2 substitution reaction faster and why ? @ Ceres or Ce @ AAS & AAT fret ares grat a ata eer ate afre ca S,,2 oltre ativan exer tate aa 7 © (ere: ser (cr a) AAS! 8 AASE 15. Complete the following reaction equations : @ Cont soce = CHLOH Wp Co +H] > on Fre aafttirensit ant ot ax feria: @ Con +S0Ch > CH.OH Gi) Cc +HCI > OH 16. Explain what is meant by (@® a peptide linkage (ii) _a glycosidic linkage ere sitar fir Preaferttac a ae art stare: @ Teer i) Tereptarefe feast 17. Name two water soluble vitamins, their sources and the diseases caused due to their deficiency in diet. er 4 erste 3 faerttat & ara feafisd | sb aia a sects aifite athe sa chnktat & a ferfiag sit ea faerie at stor a art & are eich & | 56/1/1 418. 19. 20. 21. S6/1/1 5 [P.7.0. Draw the structures of the monomers of the following polymers : (@) Teflon (ii) Polythene OR What is the repeating unit in the condensation polymer obtained by combining HO,CCH,CH,CO,H (succinic acid) and H,NCH,CH,NH, (ethylene diamine). far agerat & acral at dean sified wifi : @ aR (i) Tietz arat HO,CCH,CH,CO,H (watifrs tg) 3 H|NCH,CH,NH, (chet setts) & a Sona dar agers 4 aa Sart are afte Fae? Iron has a body centred cubic unit cell with a cell edge of 286.65 pm. The density of iron is 7.87 g cm’, Use this information to calculate Avogadro’s number (At. mass of Fe = 56 g mol"), area 1 fren ara Ser sare ae at Tae | ae Uae Ae HS aT ee 286.65 pm eat & | sTa HT FATT 7.87 g om & | Fa GIT HI STANT Bet Ee Caray den ar ofteert Sa | (Fe FT RAM] RAHM = 56 g mol!) 100 mg of a protein is dissolved in just enough water to make 10.0 mL of solution. If this solution has an osmotic pressure of 13.3 mm Hg at 25 °C, what is the molar mass of the protein ? (R = 0.0821 L atm mol"! K-! and 760 mm Hg = | atm.) we wt Ft 100 mg AT al Sage Aer Ara A atereax dew 10.0 mL fares aaa TTS I cafe ga fares ar 25 °C OR TTT Ts 13.3 mm Hg et at ates ae ee FTAA ST TT 2 (R = 0.0821 L atm mol! K-! ait wh arqHSeH a = 760 mm Hg) A first order reaction has a rate constant of 0.0051 min7!. If we begin with 0.10 M concentration of the reactant, what concentration of reactant will remain in solution after 3 hours ? we wan aie at afetinar ar =x fats 0.0051 min! & 1 af er ster F ofr 0.10 M Bian & Grea WT at aT 3 ae Sh oer sates ar feeraT AST By aT?22. 23. S6/1/1 How are the following colloids different from each other in respect of dispersion medium and dispersed phase ? Give one example of each type. (i) An aerosol (ii) A hydrosol (iii) An emulsion fearon area atte afefiaeer at were ded & Pret witenes hd cw eat a fis tid @ 2 ee TR Tae STENT HH SHAT = (i) Wrate Gi) TESA (iii) FA Account for the following (i) NH, is a stronger base than PH. (ii) Sulphur has a greater tendency for catenation than oxygen. (iii) Bond dissociation energy of F, is less than that of Cl,. OR Explain the following situations : (i) In the structure of HNO, molecule, the N — O bond (121 pm) is shorter than N-OH bond (140 pm). (ii) SF, is easily hydrolysed whereas SF, is not easily hydrolysed. (iii) _XeF, has a straight linear structure and not a bent angular structure. Fret & ara yet ee fafa : (@) PH, 3 ten NH, afte vac are | (i) deer at tet ger F faer wah atere atte 1 Gi) F, Share Pats sot CL, aaa facts wat Se ete aaat frer aeereTait sree TASTE : (i) HNO, 27 at eee, N - O 4a (121 pm) N - OH 48 (140 pm) 4 atten FF rR ere | Gi) SE, Waa a He araiee et sree sale SF, PTAA a set HfeT et eta | (ii) XeF, omy Ht aera Area Hotta a eter Sieh tai Sate24. 25, For the complex [Fe(en),C/,]CI, (en = ethylene diamine), identify @ Gi) ii) (iv) ) (vi) the oxidation number of iron, the hybrid orbitals and the shape of the complex, the magnetic behaviour of the complex, the number of geometrical isomers, whether there is an optical isomer also, and name of the complex. (At. no. of Fe = 26) ‘pimetaa (HR) [Fe(en) Cl ICI (whats Seta = en) & fers Ft at Tea SHE @ Gi) Gi) (iv) 9) (vi) Explain the mechanism of the following reactions @ Gi) iii) SA SH ST STEM | Wat anlaert athe BATT FT STAT | ein ae TGS SET | vata aaraaaial at eT | aa gah waters ware te 2 MCT TATA (4H. Fe = 26) Addition of Grignard’s reagent to the carbonyl group of a compound forming an adduct followed by hydrolysis. Acid catalysed dehydration of an alcohol forming an alkene. Acid catalysed hydration of an alkene forming an alcohol. fre afttearett a frentate at area afar : @ Gi ii) S6/1/1 we atfte & aries qe 8 firars afters ar ain ae ta aA ahreet aT er ATA | testis & ane saifta Prieto 3 teas a aT | we teat & oer solfta sorte 8 testi a rT | 7 (P.7.0.26. Giving an example for each describe the following reactions : @ i) Hofmann’s bromamide reaction Gatterman reaction (iii) A coupling reaction wee & fea oe sere tax Pr aaffieenalt ar acre aie : @ we a ates after, Gi) Team afte, ii) FR afafear 1 27. Explain the following types of substances with one suitable example, for each case : wi) Gi) Cationic detergents. Food preservatives. ii) Analgesics. wea oe fered ae ST SET Se ee es et a aT @ taate avarte 1 (i) reais 1 Gi) erent t 28. (a) Define molar conductivity of a substance and describe how for weak and strong electrolytes, molar conductivity changes with concentration of solute. How is such change explained ? (b) A voltaic cell is set up at 25 °C with the following half cells : ‘Ag* (0.001 M) | Ag and Cu?* (0.10 M) | Cu What would be the voltage of this cell ? (E°,_., = 0.46 V) OR (a) State the relationship amongst cell constant of a cell, resistance of the solution in the cell and conductivity of the solution. How is molar conductivity of a solute related to conductivity of its solution ? (b) A voltaic cell is set up at 25 °C with the following half-cells : S6/1/1 Al | AP* (0.001 M) and Ni | Ni* (0.50 M) Calculate the cell voltage [E°_, =-0.25V,E° 4, =-1.66 V] Ni@* [Ni ABT IAL + I29. 56/11 (a) (>) (a) (b) (b) @) uerd at ater crear at after fear 1 sae site varet faye sees at alee aerate Paerearst H arse afta oe Pre wep weer eteit & 2 ea afeacrat ar BROT wre sf | 25 °C WR at Beit Ag* (0.001 M) | Ag ait Cu?* (0.10 M) | Cu # Sits a atteda Ser Tare Tea | SA eT a Stee AT et ? (EP. = 0.46 V) araat frat faeraa at area, dar 4 faces ar ofacte oft de fers & wer dee aT Feige facter at tere arora Sate Perera a area aT TET at feats we ated Gat 25 °C 1 Prt and dat a dala Al | AP* (0.001 M) #4 Ni | Ni2* (0.50 M) ‘Ge Hater afteiea aif | [E° =-0.25V,E° it 166 V1 Ni2* | Ni ABtY Complete the following chemical reaction equations : 5 , peop | Mn yfaq) + C205 (aay * Haq — 7 2 é Gi) CHOF yg) + Fe ag) + Haq) Explain the following observations about the transition/inner transition elements : (There is in general an increase in density of element from titanium (Z=22) to copper (Z = 29). Gi) There occurs much more frequent metal-metal bonding in compounds of heavy transition elements (3 series). Gi) The members in the actinoid series exhibit a larger number of oxidation states than the corresponding members in the lanthanoid series. OR Complete the following chemical equations for reactions : (Mn Ojiqg) + SOF (aq) + HO — Gi) CHOFQq) + Sy) + Haq 9 (P.10.S6//L () (a) (b) (@) (b) Give an explanation for each of the following observations : (i) The gradual decrease in size (actinoid contraction) from element to element is greater among the actinoids than that among the lanthanoids (anthanoid contraction). (ii) The greatest number of oxidation states are exhibited by the members in the middle of a transition series. (iii) With the same d-orbital configuration (d*) Cr2* ion is a reducing agent but Mn** ion is an oxidising agent. Fra carat wale sot gar ae ferfea : @ MnO jg) + Cz0% aq) + Haq —> (i) CrOF faq) + Fe agy + Hag — Sarno ata Sa aa & fae A Paes arate at caret st @ aeehrara (Z = 22) a Fi (Z = 29) aH oS ST aT Gi) et sear rat (are Sot) & eh a ager engage (ii) Ceaas doh} ara acdeeh debra Soh & ast ST Sree rae WEAR FRA | aera Fre Taratre wate at yer ae fetes: @_— Mn0juq) + 830% fay) + HO — CH) Creag) + HS ig) + Haq > Frey sariteat 3 caren afar : @ tenet doe aa a anes aa a ay & are 4 area Bera (Cferes dpe) stare canst & (Cares Hee) ahs tar aT e | Gi) UH term Soh A afm Soe sae soit a ae oat ane wel ett e1 (ii) Tar d-sifaent fare (d+) & aa C+ ae arrears & Safe Mn3+ are STs e | 1056/1/1 @) (b) fre al ore fared aS: @ rr asin tastes se, Gi) Tega aanfeseres | Fra deco 1 fact afters, seme ae ge eu Tera at ta ET aT h Hp @) Cg,COCl Sa Ras0, oO i (i) On cans Anhydrous AICI; Coe = C:- ot 2