[Series SSR/1 cose No. 56/1/1 ate 3. Roll No, [Candidates must write the Code No. aaa. ‘on the tile page of the answer-book, Prana s-yferan 3 aye i, sara] era ‘Please check that this question paper contains 15 printed pages Code number given on the right hand side of the question paper should be vriten on the title page ofthe answer-book by the candidate Please check that this question paper contains 30 questions. Please write down the Serial Number of the question before attempting it oe praia wa fe ew mera gh As FI co et ab er A it Pea ate sea aA wa ae HHT | eo pra sia we a fe we aH 30 Te BI 9 Bea sre a a free YR we, ee a mie rare fret CHEMISTRY (Theory) Tarn faa (aarfae) Time allowed : 3 hows ] [Maximum marks: 70 frit aa: 3 002 J [ aftrrae 35 + 70 General Instructions: (All questions are compulsory. (ii) Question nos. 110 8 are very short answer questions and carry 1 mark each, (iii) Question nos. 9 t0 18 are short answer questions and carry 2 marks each, (%) Question nos, 19t0 27 are also short answer questions and carry 3 marks each, (%) Question nos. 28 to 30 are long answer questions and carry 5 marks each, (v) Use log tables fnecessary, use of calculators is not allowed. (PTO.rare fe : wh wer orfrart #1 iy) wr view 1 8 8 9ea AR ay Salta BL a CT Sis BH (iy wor eer 9 18: wer att si % oy ae Te I (0) wore 19 27 He mer of aaa sind & og aaa Tea BF (o) 37 aoa 25 & 30 & we ata-cta sia & aid aria we Fr (oi) staves 8 ta aca wit Ron wad Breage > wt A agatha B ‘What is the coordination number of each type ofions in a rock-salt type crystal structure ? decare wan A Greet dee a res wan & ore A a ae em att 2? Define the term ‘order of reaction’ for chemical reactions. carafe: srfitiaenstt 3 fort ‘afitfien oft ante’ ft ofan fare ‘What causes Brownian movement ina colloidal solution ? tered) faereril A ari af GA an gar er eet 8? In which one of the two structures, NO} and NO}, the bond angle has higher value? @ deemit NO} ait NO) 4 8 feat areas sie aftes ae wae? sein 22 S6/l/1 Write the IUPAC name of the following compound H,C-CH-CH,-CH-CH-CH,OH du, Onc, Freaftafeaa atfire ar TUPAC am ferry, H,C-CH-CH,-CH-CH-CH,OH CH, OH CH, ‘Arrange the following compounds in an inereasing order of their acid strengths: (CH,),CHCOOH, CH,CH,CH(B)COOH, CH,CH(B1)CH,COOH frafatars a are aga gy areta amed % am F orafeaa Fifa: (CH,),CHCOOH, CH,CH,CH(B:)COOH, CH,CH(B)CH,COOH, ‘Write a chemical reaction in which the iodide ion replaces the diazonium ‘group in a diazonium sat. Tee carte afifien fefen fied ws sesifas eam 4 a srs ag reeres saree are Preeaa etar Name a substance that can be used as an entiseptic as well as a disinfectant, ee BR vad a am at fr ae af oer mpAA aT tama 3 [PT0.9. 10. S6rI/1 Explain as to why haloarenes are much less reactive than haloalkanes towards nucleophilic substitution reactions. oR Which compound in each of the following pairs will react faster in Sn2 reaction with -OH ? Why ? @CH,Bror CHI (ii) (CH,),CCI or CH,CI manga f aRasiitics siren attest & vfs teeth tetera Fy otter wat safa am faearefter eich &? waar Frafetiarr sete sitet ft @ ata er aif -OH *% era Sn? sift F afte asf & sfifeen str sit sat? (@) CH,Br sen CHL Gi) (CH,),CCI sta CH,CI (a) State the IUPAC name of the following compound : H, H BN oe wf (’) Complete the following chemical equation : CH,CH,CH=CH, + HBr __peroxideee ms 2 13. soit (2) rear afte an TUPAC at fee, = HOH He, (a) Pree eae asco a AM CH,CH,CH-CH, + HBr SRS, State Henry’s law correlating the pressure ofa gas and its solubility in a solvent and mention two applications forthe law 2 ve er aa te er Ft rer Pre wet ato et sa Fran 3 2 ogre fae, ‘A first order decomposition reaction takes 40 minutes for 30% decomposition. Calculate its 1, value. com erm wife A sreres aftr 30% sremen % fer’ 40 fae a ae ree fg, re FPL ‘What is meant by the “rate constant, ofa reaction ? Ifthe concentration be expressed in mol L” units and time in seconds, what would be the units for(i) fora zero order re fa afer a Feces 4 an ae aed en 8? a ine A mol Lote ea Barwa A a iy eH aA A ore, te Gi) Se A aoa fe aor oa mT Ha? ‘and (ii) fora first orderreaction? 2 5 [Pto,14, Define the following terms in relation to proteins : 2 (Peptide linkage i) Denaturation Shs esd 9 refer A afore eae @ tes ea Gi) ger (Rega) 15. _ List the reactions of glucose which cannot be explained by its open chain structure 2 reggie Al sa sfitireratt a ff’ far’ ger gett Grae dec 3 see we agra ag ST erat 16, Assign a reason for each of the following statements : 2 (@ Ammonia is a stronger base than phosphine. i) Sulphur in vapour state exhibits a paramagnetic behaviour. ‘eaters sat HB seit fer ren fener (@ wrest sate saber ser sect ae 1 i) ae sree A eRe sragERAA oraere wees eat #1 17. Draw the structures of the following molecules : 2 SF, Gi) Xer, Sot 6a Feed sresit A ear itera a, @ sr, Gi) Xer, 18. What are biodegradable and non-biodegradable detergents ? Give one example of each class. 2 Stafircheneta sre oft onda Ftc orem ae wa 2 oa er RG saree AFG) 19, Whatisa semiconductor? Describe the two main types of semiconductors and explain mechanisms for their conduction. 3 cooker ea tear 8 2 2h er wert one om ania oA oie eA en Grofit st ee Fac 20, Calculate the temperature at which a solution containing 54 gof glucose, (CH 09) in 250 g of water will freeze. (K, for water = 1.86 K mol kg) 3 a ay a oftafera Aifare fara a 250 g sat #54 g TFTA, (C,H,,0,) sitet we aa Fer SH THT | (Ky, (FT) = 1.86 K mot kg) 21. What are Iyophilic and lyephobic sols ? Give one example of each type. Which one of these two types of sols is easily coagulated and why? Sol (RTO.A serait et (ool) BATH #7 ares eT eR eT “Afiq) ast sare ata 48 Pre ae ates gue aA aoe | site ai? 22, State briefly the principles which serve as basis for the following ‘operations in metallurgy 3 @ Froth floatation process (ii) Zone refining (iii) Refining by liquation sanguaet & freer sat & sree Fear a ate ferfra « a (Ba) Ser Gi FR Feat) err Gi) wat ara aire 23. Write chemical equations for the following processes 3 (@ Chlorine reacts with a hot concentrated solution of sodium hydroxide Gi) Orthophosphorous acid is heated (ii) PAF, and xenon are mixed together OR Complete the following chemical equations @ CaPys)+H,0M— Sort 8i) Coq) + NH, — (excess) Git) Ff) +H,00) —... | Bam & fe cera water Peer Go aes aun eregiaures % wig aw Prova & safer we 81 Gin sretesieer efes tf Fear ret Bt Git) Per, ste stata a were Frere aTar #1 een Prater reat wet at ae A, () Ca,P,66)* HO) — Gi) Cu(aq) + NH, (aq) —> (enfin) Gil) F,(@) + H,00) — 24. (a) Whatis a ligand ? Give an example of a bidentate ligand. 3 IN) J and Ni(CO),, have different structures but do.not differ in their magnetic 28) (b) Explain as to how the two complexes of nickel, [Nit behaviour. ( (si) fers (ligand) ar Ga 8? Reet Ferra a aw sere (3) aren Afr fH Fa fea % a sitar [NICN),F ste Ni(CO), fire-fira see eae BE oA wa Gera rae wef at i (Ni = 28) SoU ° [Pro. SS28, 26. s6ri/t [Name the reagents which are used in the following conversions: 3 (OA primary alcohol to an aldehyde (ii) Butan-2-one to butan-2-ol (ii) Phenol to2, 4, 6tribromopheaol reaferian vftatit i wges GA are saver ae fee: (we send Reaieter aa eH Orseres # (i) aRA-2- ata aga-2- aa (i) Seer an 2, 4, ogres Account forthe following observations 3 (pK, for aniline is more than that for methylamine, Gi), Methylamine solution in water reacts with ferric chloride solution to give a precipitate of ferric hydroxide. (ii) Aniline does not undergo Friedel-Crafts reaction, ‘freaferfra sractrart & are era’ (0 Bret % fea pk, er arr Heriot wre & safes eer tH Gi) 9a 4 faeries or Hie totes eres % ste @ afte ae Sie wegaares #1 saaty @1 8) Gil) Becta Sa-a after ae att2. 28. Write the names and structures of the monomers of the following polymers : 3 @ Buns (ii) Neoprene (ii) Nyton-6 aes mere 3 eee 8 at oe ash cw ee ws Gi) Fis (ii) WHeI-6 Conductivity of 0.00241M acetic acid solution is 7896 x 10-5 S em Calculate its molar conductivity in this solution, If A°, for acetic acid be 390.5 $ cm? mol", what would be its dissociation constant ? 5 oR ‘Three electrolytic cells A, B and C containing solutions of zine sulphate, silver nitrate and copper sulphate, respectively are connected in series. A steady current of 1.5 ampere was passed through them until 1.45 g of silver were deposited atthe cathode of cell B. How long did the current flow ? What mass of copper and what mass ofzine were deposited in the 5.4, Cu= 63.5) concemed cells ? (Ator masses of Ag = 108, Zn=| 0.00241M Beitieas sect ster A sre 7.896 « 10 S cm! 81 ga Tet ore A ater area a site FHT ae Aefaes Ser | FRA Ag, 390.5 S om? mol! @ at yeaan Prdiae frie war ge? Sell i (PTO.-—— ern ‘fi Pagn-orerest et A, B ste fase aoe: fr act, fer eRe ote sate acts & Proves 1 m8 &, dota NS ge El SH | 1s BA softadt frqqura aa ae wenita A ard & wa ae ferea A 1.45 g HOT ‘re BB Boch ae a a a ah Fs Bs feet eT TS Seif fate ge BA? (con Fe, Ag = 108, Zn = 65.4, Cu = 63.5) 29, Assign reasons for the following 3 (@ The enthalpies of atomisation of transition elements are high. (i) The transition metals and many of their compounds act as good catalyst. (id) From element to element the acti the lanthanoid contraction. id contraction is greater than (iv) ‘The B® value for the Mn®*/Mn** couple is much more positive than that for CBYCE (¥) Scandium (Z = 21) does not exhibit variable oxidation states and yet it is regarded as a transition element, oR (a) What may be the possible oxidation states ofthe transition metals ‘with the following d electronic configurations in the ground state of their atoms = 3a'ds?, 3d°4s* and 30°4s?, Indicate relative stability of oxidation states in each case. S6ni/L 12 Se a(©) Write steps involved in the preparation of (i) Na,CrO, from chromite ore and (i) K,MnO, from pyrolusite ore. frerferftaelt & arco fetta, 6 Harm wedi Hr Te A HARI Te ae i) Haar ee she a7 arEH Bah eB see Ta BL (ii) Pra oer aR are wea we Benin Hg oHengT Seis ager @ sites Gi @1 Gy) Mn**/Mn®* % fe £9 aa CO/Cr* & Boa A ste safirs wearers tat 81 (o) em (= 21) seal sees sree set refit ree Re 3 dae ae wo aT tl ere (3) Se rit Aa sre a Teraegthas Feared are are esi Fens aera oraea a a ed 3dhast, 34%? afte 34s? seek wea fey sees semeesit At ter Frc of ferfere! (2) () Fane 9ereE B Na,CrO, she (il) eRTTTEZ SHI B K,MnO, a & fara wen fer 3,2 S611 B [PTaos RMU, KOH, heat Deseribe the following reactions (@) Cannizaro reaction (ii) Cross aldol condensation OR How would you account for the following : (i) Aldehydes are more reactive than ketones towards nucleophiles. (ii) The boiling points of aldehydes and ketones are Tower than of the corresponding acids. (iii) The aldehydes and ketones undergo a number of addition reactions. Give chemical tests to distinguish between : () Acetaldchyde and benzaldehyde (ii) Propanone and propanot 14 323) onfire ved, sftrere srr zene, sf ate a fea ae ei, sat fered gy Preferfire saftiieen Paarl = gol Aq @ 2<>-0 Zn-H,0 Gi) <2=cn, <>-cHo CH,CH, KMnO, oC ons” rattan satiety Re (BP sar Gi) Bia Uste HeEr aoa frefeftadt % erm fetta : (i) *esieet % of Hert A ater Ofeeeee afte ae wa fi Gi) Bearers othe eats weersies aie steel At otter at eae Gi Deere she HA age AA ar cafteaME Beh #1 Sefofadt 4 oe Rat & feat carats vat at fae @ Beetivees sk aafeer H Gi Atte te tater