En la deshidrogenacion del isopropanol inicialmente existe 10 moles de isopropanol, 5

moles de inerte. Determinar el avance de la reaccion en el equilibrio y moles finales de cada

componente, si inicialmete se tiene una Keq. de 0.35 y una presion de 1 atm.

CH3 CHOHCH3-----CH3COCH3 + H2

DATOS

COMPONENTE ∆Gf(KJ/MOL) ∆Hf(KJ/MOL) R( KJ/MOL K) 0.008314

ISOPROPANOL -159.94 -261.3 T eq(K) 298.15
ACETONA -152.61 -216.83
HIDROGENO 0 0

∆G⁰R=Ѵacet ∆G acet + Ѵ H₂ ∆G H₂ + Ѵiso ∆G iso

∆H⁰R=Ѵacet ∆Hf acet + Ѵ H₂ ∆Hf H₂ + Ѵiso ∆Hf iso

∆G⁰R (KJ/MOL) 7.33

∆H⁰R (KJ/MOL) 44.47
−∆𝐺 0 𝑅
𝐾 𝑒𝑞│₂₅ = 𝑒 𝑅𝑇

Keq 0.051971841

0.051970691
ε= 2.601511389
∆𝐻 0 𝑅 1 1
𝐿𝑁 𝐾 𝑒𝑞│𝑇2 = 𝐿𝑁 𝐾 𝑒𝑞│₂₅ + 𝑅 𝑇1
− 𝑇2

LN K eq= -2.661160195
Keq= 0.069867115
TEMPERATURA (K) LN Keq Keq ε
298.15 0 0.05197184 2.60150124 0.05197024
303.15 -2.661160195 0.06986712 2.97079547 0.06986699
308.15 -2.37486941 0.09302664 3.36656266 0.09302654
313.15 -2.097720914 0.12273584 3.78534354 0.12273667
318.15 -1.829283671 0.16052852 4.22235332 0.1605283
323.15 -1.569153321 0.2082214 4.67172578 0.20822154
328.15 -1.316950149 0.26795127 5.12659734 0.26795123
333.15 -1.072317235 0.34221461 5.57956209 0.34221481
338.15 -0.834918772 0.43390973 6.02310186 0.4339095
343.15 -0.60443852 0.54638112 6.45013487 0.54638115
348.15 -0.380578411 0.68346597 6.85448198 0.68346548
353.15 -0.163057255 0.84954255 7.23127419 0.84954297
358.15 0.048390436 1.04958037 7.57714818 1.04958019
363.15 0.254015528 1.28919182 7.89030944 1.28919214
368.15 0.454055259 1.57468501 8.17039039 1.57468552
373.15 0.648734149 1.91311757 8.41822315 1.9131178
378.15 0.838264848 2.31235121 8.63554264 2.31235079
383.15 1.022848901 2.78110659 8.82468666 2.78110716
388.15 1.202677472 3.32901835 8.98832411 3.32901797
393.15 1.377931998 3.96669002 9.12924184 3.96668941
398.15 1.548784804 4.7057483 9.25018408 4.70577389
403.15 1.715399662 5.55889675 9.35372788 5.55889657
408.15 1.877932324 6.53996834 9.44225634 6.53996821
10

5
K eq
4
E eq
3

0
250 270 290 310 330 350 370 390 410 430 450
TEMPERATURA (K)