Cambridge Intormatonal Examinations (Gambrdge International Advanced Subsciry and Athanced Level NUMBER CHEMISTRY Peper? AS Level Stuced Questions Candstes ner on ne Question Paper, ‘ditona Matas: Data Boot [READ THESE INSTRUCTIONS FIRST int your Can nner, ansaste number anc ame nal te wrk you i int in dare or ack pen ‘Yournay use an HB peel fy Sagas or graphs. Donet use sares mapa cps, gue ot erectin le DONOT WRITE ANY BARCODES. ‘Anse al questons learn cleats maybe use, ‘You ose mar you dona show your wal o you donot use appt us ‘Data Bootes roves [Ath endothe examination fasten al your war esc ogee ‘Te aber ofmams sven brace Ja heer of ach nebo OF prt questo. “This doer cont of 10 pied pages and 2 EN pages. CAMBRIDGE ‘7022 Mayisune 2018, hour 5 minutes Tum over 2 ‘Answer all ine question nthe spaces provided. 41 Sodium and magnesium ae the Fst wo elrents nth third perio, (@) Sodium and magnesium both rest wth cold water to produce the same ype of product in ‘Sain. Vy soc te sldon clear but with magnesium ksppeare oud (0) Witte an ecuaton forthe reaction of magnesium with cold water. Mg.22H20.— Mglotde + He in reaction of magnesium wih col wate tec... 19 (Suggest why the solution's Goudy ater Migloa._18._.spaatg.s sol m1 (©) Group 2 element, including magnesium, react with oxygen and wth dlte acids. Thre ore \vends in both the physical ana cnemical properts of te elerents and har compounds down ‘he group. Reactty generally increases rom tg io Ba (0) plan why there is @ genera increase in activity fom Mg to Ba Fish lovisalion enera4 deccensee Rroen tha to BA so C13 troant..casily eS... (i) Give two observations forthe reaction of magnesium with oxygen. Wite an equation for ‘isreadon, nsude sat symbole 5 whe flame [14 equation 2M 6S). ct Oaty......2MgO.¢s>...E0) (0) te an equation forthe recton of magnesium wh sue ac Mg. + H2S04..— MgSO4 + Ha 04: 09 zz ay te = eo een ergs drat ve ent meek re ae ie lig Sm akon ces ord His the, Geacee density OF covtion deorenses done he. w, 8g of oneal is ceayorod =e Hentz, deren eee {o Toe, Geers mefellcc bods. COIS 3.0 valente € paca ‘ata 18) 1112 2. Ammonum rr suit, WH)F(S0,), hs area omsaass, Mo 204 (0) ain te an ete fer oss -Relafve. farneula omss..is the, caro of tne average, 4 formal, unit of an fori {eo “ho. a. 0f, ne, 088, of a caroon= 12 aborn aod (0) One of i caons in armenum ren) stat te armenium on, NH, (0) Oran dot and- xr=6 392. 6 “1 ota 171 (Tum over Je 3 Whole 09, 6 ‘3 Most vice fuels contain hydrocarbons obtained fom erie oi (2) (9 tate the name of the typeof reaction that hydrocarbons undergo when being used a8 ‘ols combuston...[V4 " (0) Wit an equaton for he reaction of cane, i 38 ain (a) Cais + 22.02 —> 860, +420 010g [RY Te supay of mate! sutabo for sea ls drt rom cruge os nt scent 2 moat lomandA process is card otto mae some ofthe lager hysrocarbon molecules more Soa DE Nome process. " [Aswel as producing fuels, tis process produces compounds suitable for usein the production ‘ot polymers An example of sucha compound Is but2-ene, CH,CH=CHCH,, Dis ra oa repent ut tt pana ati occa om bit 28 a Yan. Name the ype of polymerisation that occurs during the production ofthe polymer i i 01 (6) aces produced in internal combustion engines Inchie carbon monoxide, odes of nitrogen sich a8 NO, and unbumt hyéocartons These goes are removed tom he exhaust eos they can eter the atrespere (Sate wnat used rove hese goss om the exhust bbb Se. .cormeAec...EN oO (i) ete one equaton to show how pa carbon monoxide, CO, and nrogen donde, NO, ine °s 260 + NO2 —> 202 +.aN2 TIT (i) State the envroamental consequence of allowing unburnt hyérocarbons to ener the atmosphere. protgevemical smog /fog (hare UI iy (6) Vehicle ues ae teats to remove suf sulfur is present ina fuel when tis burned. SO, is Produced and may be releasodIniothe almosphere wher kcan form ald ain. (Ain can conta a resing ets. Isonty we oer cnsequenes of ald nin the amosphers. C23 deny.2. fora slewess..pH..of rivers Makes /.e¢eaes and kills manse life , tof wild rage | sé i ao. . tt - 2 (NO, iovtved nthe proton of aia om SO, ‘ive wo equations which deseribe hows ain formed heaton of NO, wih SO, N02. 4.502, NO. F808 OV nn S03 + HO —> HaSO, TD a (i) No, deserved a a ata drng ns process. ‘olin, wih the seo an aopropit ecuaion vty NO, sdescbed asa cla. NO+ 3.02. —2 N02. £14 wmla..j,egengmred. E13 foucuesso romans (Turn over ills Crops /4e2es fplon's 4 wis cheook.on, (a) The reaction between W and akalie aqueous iodine produces a yellow preciitate (0) Give he memg of he compound formed at a yellow preiptate in his rection, ticiodomethace Er. m 1) Gio the name ot W. butranone 0 n (b) There are two stuctural isomers of W tat ae alee carhony compounds. Draw the structures ofthese te icmars of W. os, i, CHa ACH2CHO cH ns | oa eB Two eactons of Wr shom, cH,coon,.c, 22%". cr. cHionjcn.cH, Ww |p _ we—¢—cxyon, ee reduckor C13 sence erty We espn recto Nawis...matnarel.OR. He. Ni zheat, oR LIA\Hy » dry etherying a mature of HN and NACN to W. mogure of to omers @ action 26 cated out by We product, Xe formed a (0) Compete the mechanism for hie rection, Include the structure ofthe intermediate formed and all necessary chages, poles, lone Satna atone ws wogr Go alin { 7 = «epee — ige—G—Hals — nerf —onon, 4cN red be 4 wo ‘Bon peck © coneretiode wm 76-143 {W Siate he name ofthe type of tomers shown by X 5-6 +133 -Amaokomensen,.D 3. ss 1 34 DD (8) ein ay why X hows ype soma. 1-2): 013 1a... daca ‘. “ — on " enna 3 904.02, plage. ob Syme yuinieln. owes le. fo... NON Siapec ich posalehe., COMCeC... lenages . wo ‘Question 4 continues on page 10. (6) 10% 8 teated wn ammonia ng the product nydrolysed, a compound, Y, i obtained that contains 51.3% C, 840% H, 120% N and 27.3% 0 by mass. (© Show at te onpicat fom of is C4,NO, / = ty é Mose /9 ae 3 Ro 120 20.3 1 unt fen ts _ z oy peeve i = 4.23] Le _ 4, Be. 4 mo vo aH. a th oa~ > beat"! oe en + AMRAOL formule is Le H,,NO. eB (0) The empiialomala oY I CH,NO, ante 4 of Vis 17 Deduce the molecular formula of. You must expan your essoneg. Let molester formule be CsnHunNa0an » 1 (5x)2.0 + NXD-0F 4.0 # 216-0) S117 , ud ene retcntomsee SHUNO, Cie” BLANK PAGE. 2 BLANK PAGE. a