2 el ALHCA 0 ‘Test Booklet Code This Booklet contains 24 pages. 1 are asked to do 50. Do not open this Test Booklet until y Read carefully the Instructions on the Back Cover of this Test Booklet. Important Instructions ; 1, The Answer Sheet is inside this Test Booklet. When you are directed to open the Test Booklet, take out the Answer Sheet and fill in the particulars on Side-1 and Side-2 carefully with blue/black balll point pen only. 2. The test is of 3 hours duration and this Test Booklet contains 180 questions. Each question carries 4 marks. For each correct response, the candidate will get 4 marks. For each incorrect response, one mark will be deducted from the total scores, The maximum marks are 720. Use Blue/Black Ball Point Pen only for writing particulars on this page/marking responses. 4. Rough work is to be done on the space provided for this purpose in the Test Booklet only. 5. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator before leaving the Room/Hall. The candidates are allowed to take away this Test Booklet with them. The CODE for this Booklet is ZZ, Make sure that the CODE printed on Side-2 of the Answer Sheet is the same as that on this Test Booklet. In case of discrepancy, the candidate should immediately report the matter to the Invigilator for replacement of both the Test Booklet and the Answer Sheet. 7. The candidates should ensure that the Answer Sheet is not folded. Do not make any stray marks on the Answer Sheet. Do not write your Roll No. anywhere else except in the specified space in the Test Booklet/Answer Sheet. ‘8. Use of white fluid for correction is not permissible on the Answer Sheet.A tuning fork is nse resonance it glass tube. The length o ‘olumn in thi tube can be adjusted by a variable pision, Al room temperatiite of successive Fesonances are produced at 20 ci and 73 emf column length. Ifthe frequency of the tuningif is 320 Hz, the velocity of sound in air at 2790 Bung from the roof of ilding and is moving freely @ simple harmonic oscillator. ‘The! lon of the bob of the pendulum is| er at a distance of 5 m from the Btion. The time period of oscil rs10. u. resistor OF (47 £ 4:7) Ko is of different tion. The colour code sequence will be be marked ae colours for its Yellow ~ Orange — Silver Violet ~ Orange ~ Silver Violet ~ Gold Green — Violet ~ Gold Green » Yellow Orange A set of ‘n’ equal resistors, of value ‘R’ each, are connected in series to a battery of emf ‘E’ and| internal resistance ‘R’. The eurrent drawn is I, Now, the ‘n’ resistors are connected in parallel to the same battery. Then the current drawn from battery becomes 10 I. The value of ‘n' is jw 10 () 11 @) 9 (4) 20 A battery consists of a variable number ‘n’ of identical cells: (having internal resistance‘! each) which are connected in series. ‘The terminals of the battery are short-circuited and the current I is measured. Which of the graphs shows the correct relationship between Land n? a a t 030 I a ft o> I (3) t 12 13. 4, In Young's double slit experiment the separation d between the slits is 2 mm, the wavelength > of the light used is 5896 A and distance D between the screen and slits is 100 em. It is found that the angular width of the fringes is 020°. To increase the fringe angular width to 0-21° (with same h and D) the separation between the slits needs to be changed to @) 18mm @) 19mm @ 17mm 241mm ‘An astronomical refracting telescope will have large angular magnification and high angular resolution, when it has an objective lens of (1) small focal length and large diameter (2) large focal length and small diameter (3) small focal length and small diameter (4) large focal length and large diameter ‘Unpolarised light is incident from air on a plane surface of a material of refractive index ‘y’. At a particular angle of incidence ‘, it is found that the reflected and refracted rays are perpendicular to each other. Which of the following options is eorreet for this situation ? (1) Reflected light is polarised with its electric vector parallel to the plane of incidence (2) Reflected light is polarised with its electric vector perpendicular to the plane of incidenceey of tom, city field ho is its ALHGAIZZIPage § w Hata embination of the talent el ae in terms of inputs A and —— Be i \ bee » AL () A.B+A.B (@ A+B () AVB+A.B g4, In the circuit shown in the figure, the input voltage Vj is 20 V. Vaz and Vop = 0- The ‘values of Tp, Ip and f are given by 20V Re 4kQ Rp & 500 ka. B E wo 40 A, Ig=10 mA, B= 250 2) (9) Tp=40 UA, Fo=5mA, B= 126 1p=20UA, Io= Sma, B= 250 Tp=25uA, Io= BMA, B= 200 w In a p-n junction diode, change in temperate due to heating (a) affects only reverse resistance (@) affects only forward resistance (B) affects the overall V - 1 characteristics of pen junction 27. 29. does not affect resistance of P-® junction “SPACE FOR ROUGH WORK ty about ite Nadine of the Sass 5300) is feel qpticro i rovatins pher®in free space: THe “4 keeping : ng physical quancties would sphere? he follow Wemmain constant for He a) Angular velo (2) Moment of inertia (a) Angular momenta (4) Rotational kinetic enerey rte Kinetic energies of a.planet iD #2 efiptical rest about the Sun, at positions A. B and are Keg, Kp and Ke, respectively. AC i the maior ‘AC at the ania and SB is porpendicular to position of the Sun § as shown im the figure ‘Then B aa © () KyKg>Ke (@) Kp>Ka>Ke () Ky (4) 5016x10'K care 5. ‘Tho volume (¥) of a monatomic gas Varies wit an voesmratute (1D, as stown in the graph. The ® ite wempetrork done by the gas, 10 the hes: ratio ofr by it, when it undergoes @ change fom zi Stave Ato state , is i = { the wit [sr Be oO =*T re 2 a | @ = | 5 @ | "a | @ 4 c ‘ @ ¢ 1 40. | w 5 36." The fundamental frequeney in an open organ pipe is equal to the third harmonic of a closed organ pipe. If the length of the closed organ pipe is 20 cm, the length of the open organ pipe is Q) 132em @) 8am (3) 16cm ts (4) 1250m 37. The efficiency of an ideal heat engine working between the freezing point and boiling point of water, is (1) 268% 2) 20% (@) 125% (4) 625% 3 = ,speed of A body. initial Sites oe open Kl, °S with 2 e from (a 39. Three objects, A : (a solid sphere), B : (a thin circular disk) and C : (a circular ring), each have the same mass M and radius R, They all spin with the same angular speed w about their own, symmetry axes. Tho amounts of work (W) required to bring them to rest, would satiafy the 45. relation (@) We>Wa>Wa | (2) Wa>Wp>We ’ (3) Wa>We> We ) Wp>Wa> We | Which one of the following statements is | incorreet ? (Q) Rolling friction is smaller than sliding friction. ed (2) Limiting value of static friction is directly 2 proportional to normal reaction. (8) Coefficient of sliding friction has dimensions of length (4) Frictional force opposes the relative motion. 41, A moving block having mass m, collides with another stationary block having mass 4m. ‘The Z lighter block comes to rest after collision. When f the initial velocity of the lighter block is v, then. the value of coefficient of restitution (e) will be dy 05. (2) 025 @) 04 ALHGAIZZ/Page 7 z placed on a smooth inclined wedge ABI imation 0 as shown in the figure. The wedge ie given, an acceleration towards the right. The relation between a and 0 for the block to remain stationary on the wedi A EE ¢€ B ay a-—8 eosee 0 @ a=2 ain (3) a=gtane (4) a=geos0 {A toy car with charge q moves on a frictionless horizontal plane surface, under the influence of,a ‘uniform electric field FE . Due to the force aE its velocity increases from 0 to 6 m/s in one second duration, At that instant the direction of the field is reversed. The car continues to move for two more seconds under the influence of this field. The average velocity and the average speed of the toy car between 0 to 3 seconds are respectively (1) 2mvs, 4mis Q) 1mis, 3m/s @) 15m/s, 3m/s (4) ims, 35m/s _, ‘The moment of the foree, F (2, 0,8), about the point ( @ -st-4}-7h @ -at-j-8f (3) -73 -44 -8k (4) -71 -8) -4& ‘A student measured the diameter of a small steel ball using a screw gauge of least count 0/001 em. ‘The main scale reading is 5 mm and zero of circular scale division coincides with 25 divisions above the reference level, If screw gauge has a zero error of ~ 0-004 cm, the correct diamoter of the ball is GQ) 0-521em @) 0625 em @) 0:529cm (4) 0.053 om at +5) 6k at —2,=2), is given by @ 08 ‘SPACE FOR ROUGH WORK Englis. i ravozoe are forineds il vertniation spermatids | 9FS @ 1 cis spermatozoa are formed whi ‘iation spermatozoa are releasec tol eas into the cavity of tos0a from serial wills are released into the cavity of seminiferous tubules, while in spermiation Spermatozoa sre formed 7 The amiion of mammalian embryo is derived (2) eetaderm and mesoderm endoderm and mesoderm ectoderm and endoderm miesoderm and trophoblas 48. The contraceptive ‘SAHELI G) blocks estrogen receptors in the utente, eventing eggs from getting implanted (2) increases the concentration of esttogen and prevents ovulation in females (3) is post-coital contraceptives 4) isan TUL . 49, Hormones seeroted by the placenta to maintain pregnaney are > (1) OG, LPL, progestogens, prolactin (2) OG, hPL, estrogens, relaxin, oxytocin (3) hCG, progestogens, estrogens, glucocorticoids |50. 51. 52, (4) ROG, PL, progestogens, estrogens ALHCAVZZ/Page 8 given in Golimn T with those jg 9g. Ament satah the Hem Ree the COrreCt Vion gig Be GiVERE column TH 3 pelow , Column It @ | Proliferati endometrial a ning, 6. Cony secretory Phase ti Follicular Phasg nutr Fe iii. Luteal Phase a ¢. Menstruation * —- ° @ a 3 ww a sa. Wh @ i i 2 dis oi: 4 a Q) ‘all of the following are part of an operon excep! os (2) amoperator vs al genes (2) structural ge’ a (3) apromoter i 4) an enhancer a ‘A woman has an X-linked condition on one of her ¢ X chromosomes. This chromosome can c inherited by ( () Only daughters 59. (2) Only sons (3) Both sons and daughters (4) Only grandchildren According to Hugo de Vries, the mechanism of evolution is (1) Multiple step mutations (2) Saltation (3) Minor mutations (4) Phenotypie variations AGGTATCGCAT is @ sequence from the coditt strand of a gene. What will be the correspondist Sequence of the transcribed mRNA? 4) AGeuaUcacau @) Ueeroreccar “ (3) UceAUAGCaUA (4) a ee es A|AIL of the following #*° included in: ‘Excite mong the following seta of examples, FF eo, Amngent evolution, select the incorrect option ‘conservation’ except {) Forelimbs of man, bat and cheetah (a) Wildlife safari pave 5) Heart of bat, man and cheetah 2) Sacred groves 3) Bye of octopus, bat and man (3) Seed banks ip Brain of bat, man and cheetah, (4) Botanieal gardens sq, Comyorsion of milk to curd impr ita\ea, Which part of poppy Plant 18 ‘used to obtain the crfritional value by inereasing the amount of drag “Smack” ? @)_ Vitamin D (1) Flowers (2) Vitamin A (2) Latex @) Vitamin B (@) Leaves (4) Vitamin Byy (4) Roots jn. Which of the following is not an zutoimmune| 63, Tn a growing population of acountsy, disease? (a) _ pre-reproductive individuals are more than (1) Psoriasis ire reproductive individuals: (2) Rheumatoid arthritis (a) reproductive individuals are joss than the (3) Vititigo postereproductive individuals: (4) Alzheimer’s disease (g) pro-roproductive individuals ar0 Jess than | su. The similarity of bone structure the forelimbs the reproductive individuals Traaany vertebrates is an example of (4) reproductive and. pre-reproductive (2) Homology inlividuals are equal in namber- (2) Analogy Which one of the following _ population. (@) Adaptive radiation Wt sions is widely used in medical science for (4) Convergent evolution the production of antibiotics ? sa. Which of the following characterise ae eee 3 Wet tance of blood groups’ in humans? (2) Mutualism a, Dominance (3) Amensalism b. Co-dominance (4) Parasitism ple allele Se aaeee 95, Match the items given in Column T with those #9 d, Incomplete dominance ‘Coluran TK and select the correct option given e. _ Polygenic inheritance below : @) bcande Column Column It Q) abande a, Butrophication UV-B radiation () a,cande b, Sanitary Deforestation (4) b,dande ¢, Snow blindness iii, Nutrient eo, In which disease does mosqun? transmitted enrichment pathogen cause clonic ‘emnation of| a TBumultivation iv. Waste Aisposal lymphatic vessels ? a »b © a (4) Blephantiasis ae te HE (2) Ascariasis @ i ii iv (3) Amocbiasis @v a a (4) Ringworm disease @ iH wv ‘SPACE FOR ROUGH WORK , ALHCAIZZIPage 9hn of vaflgf the fllowimgl IAAT AIIINO 8S dy oy WR cay}, Woien 110s oy ’ nd] hormone 66. P asthinit 1) Chie $4 mi ) Bpinephrine ‘emphysema, respe icles; Decreased qs (a) Moe 1) Inflar of bron (2) Bedyeone Par respiratory 5 creased 2) meres + of bronchioles Tn Fail a — — (a) Batradiol 3) Deere ae ia qa. Match t Inflar chile : Cobsenn ratory surface : he following structures oF regions ie Inerens: i Which of the f e y nin Column Tv oe fedulla oblongata : controls respiration , Mr 1¢ correct opt a 1) Medutla oblong: and cardiovascular ae ae Se reflexes. below an 1 a: Golumnt 2) Limbie ayate consists of flbre x. Wiisunalagyaiye i. Between left ote 2) Limbiesystem oa oo nd loft ventricle ee a oe oe pulmonary artery movement. i Raa i een ad right (3) Corpus callosum : _band of fibers @) se ne gand | " = connecting left and ay wines right cerebral . b © er heres. ‘ a hemispheres. 78. Whi @) it it r (4) Hypothalamus production of ni @ i a: ‘releasing hormones @ ii and regulation of Mw temperature, @ i 2 hunger and thirst ee BB. Match the itom in Column I with these if = Column II and select the conreet option given below 71. The transparent lens in the human eye is held in @ Column I Column IT its place by ee @. Tidal volume i, 2500-3000 ml, (1) ligaments attached to the ciliary body 4 ” b. tory Reserve ii, 1100-1200 mi (2) ligaments attached to the iris ( gens (3) smooth muscles attached to the ciliary body c. Expiratory Reserve fii, 500650 mL iy peated oS a a hw inte volume \ d. Residual volume iv. 1000-1100 mL 72. Which of the fol i es can play 4 See ee el significant role in osteoporosis ? Oa eee (1) Aldosterone and Prolactin @ Fo ow ii (2) Progesterone and Aldosterone ae (3) Parathyroid hormone and Prolactin it (4) Bstrogen and Parathyroid hormone aN ALHCAIZZIPage 10 ‘SPACE FOR ROUGH WORK Engi!th 1. 16. ‘Select the incorrect match, ih of the following gastric cols indies 1. elp in erythropoiesis ? (a) Lampbrush — ‘Diplotene bivalents 1) Chief colle | chromosomes aoe = eee 4g) Mucous cells (3) Polytene — Oocytes of amobibian® Parietal cells chromosomes 5 Bakmosacenteit — OI od chromesosmes (a) Goblet cells | @ Se: Ewer’ Match the items given in C olumn 1 with those jn |78- Nisal bodies are mainly ‘composed of alumn TI and select the eorreet option given (a) Proteins and lipids below (2) DNAand RNA Column count (g) Free ribosomes and BER a. Fibrinogen i, Osmotie balance (4) Nucleic acids and SER b, Globulin ‘Blood clotting 79, Which of these statements is incorrect 7 3 7 : Gj aeyane, of Toe ee present in ¢ Albumin ‘Defence mecha! mitochondrial matrix. ia ° (2) Glyeolysis ovcurs jn cytosol. ae OF fa) Osidative proephorsiation take place in @ 5 cater mitochondrial membrane a (4) Glycolysis operates & Jong as it is supplied 2 SA NAD that can pick wp hydroge atoms. wi % 8 . 80. Which of the following events does not occur in rough endoplasmic reticulum ? Which of the following respiratory disorder ? js an occupational () Protein folding (2) Protein glycosylation Phospholipid synthesis () Anthracis 3 @) 2) Silieaes (4) Cleawage of signal peptide (a) Bmphy apnea 81. Many ribosomes may: associate with a single (4) Botulism mRNA to form multiple ‘copies of a polypeptide ma amcously- Such stings of HbOmee Calcium 15 important in skeletal muscle ‘termed as contraction because it SA) Polysome (a) binds to troponin to remove the masking of] (2) Polyhedral bodies active sites on setin for myosin (3) Nucleosome (2) activates the myosi ‘ATPase by binding 9 (4) Plastideme a 22, Which of the following gorins describe human (3) prevents the formation of bonds between dentition? the myosin cross bridges and the actin. (a) Thecodont, Diphyodont, Homodont filament. (2) Thecodont, iphyodont, Heterodont 5 ‘Heterodont (a) detaches’ the myosin head from the actin (3) Pleurodonty Diphyodonts (4) Pleurodent Mo ophyor filament.84. Which of these animale is not the following features is used to identify ockapaghifrom a female cockroach ? wens OF & boat shaped n the shdominal 3) Presence of anal cerci 86. Whieh of the following ore: ar chief producers in the occa Q) Dinoflageliates (2 Diatoms (8) Buglenoids @ Cyanobacter: from all other protozoan in lagella for locomotion (2) having » contractile vacuole for removing! (3) having two types ofimuclet (4) using pseudopodia for eapturing prey Which of the following animals does not undorgo metamorphosis ? () Barthworm 2) Tunieate (3) Starfish (4) Moth satoh the Heer given in ( nd pelect tho correct jm Ht below column Gotan ction) art of Brey e System AL Unrasitration Hse oop c. ransportof i, Urinaty Blades 4. Storage of urine iv Malpighian explo v. Proximal convoluted tubule =o. a Qi oy df ff Oy ow i iti ay &® i it Match the items given in Column I with those in Column II and select the correct option given below Column I Column H 4, Glyeosuria i, Accumulation of uric acid in joints b. Gout, ii, Mass of erysiallised salts within the kidney c Renalcaleuli iii. Inflammation in glomeruli 4. Glomerular iv. Presence of glucose in nephritis urine Qt ae Qi f if @ iv Ri What, is) ths respiration ? G) ttf (@) Wefan (8) Itis the fing respiration 4) Iti Which close telationsh: none of the two the other ? GQ) Hydritta (2) Yucca Viola (4) Banana nuk a me of th 93. Oxygen isnot Q) Green su (2) Nostoc (8) Chara () Cyeas 94, In which of t by plants? () Ferrie (2) Ferrous (3) Both fe 4) Freeal Double ferti () Pasion with t 2) Pusios nuclei (3) Synge (4) Pusio Which of t maintaini () Mag 2) Sodi (3) Cale (4) Pota Pollen gr liquid nit a) 1 (2) = (a) -1 =1 95. 97.ig not a prokaryote? ‘Which among the following st, Nhat is thor wap? in cellular | vesoiration (1) Saccharomsees (1) ifn (2) Mycabacterium It fonctions as a on cartier. (3) Oreillatorta 1 final el iar tie annerobi | mean ee etradi go. ‘The two functional groupe characteristic of nucleotide source for ATP synthesis. sugars are je Which one of the following plants shows & rer () _ hydroxyl and methyl tlose relationship with a s shoves Overs] (2) carbonyl and meth? pone of te two can complet is ie e th. hout| (a) carbonyl and hydroxy? (@) Yucca 100, Which of the flloting is nat 9 prodie of Tight Oy Male yoaetion of photosynthesis (4) Banana Oe 2) NADH 4g, Oxygen is nof prodvced during photosynthesis hy) (8) Syst (2) Green sulphur bacteria (a) NADPH sah dieer 101, Stomatal movement is not affocted Py eh rae (1) Temperature shee (2) Light 4. In which of the following forms is ion absorbed (8) CO, concentration tpplante? (4) Opconcentration Q). Ferrie 4 netics 1102, ‘The Golgi complex participates in (3) Both ferric and ferrous () Fatty acid breakclown (4) Free element (2) Formation of secretory vesicles 96. Double frtilization is (3) Activation of amino acid peat pasion of two male gemetes of «pllen tube (@) Respiration in bacteria with two different eggs 108, Which of the following is true for nucloolus ? (@) Fusion of one male gamete with two polar (a). Larger nucleoli are present in dividing cells auclet (2) It is amembrane-bound structure, (3) Syngamy and triple fusion () It is a site for active ribosomal RNA (4) Fusion of two male gametes with one ©& synthesis. 96, Which o the following elements is responsible for (4) Tetakes part in spindle formation maintaining turgor in cells? 104, Stomata in grass leaf are (@) Magnesium (a) Dumb-bell shaped @) Sodium (@) Kidney shaped (3) Calcium (g) Barrel shaped (4) Potassium (4) Rectangular 97, Pollen grains can be Tiquid nitrogen having # temperature of ay = 120° (2) -80°C (3) stored for several years inwing i eomno" sucing a DNA rage lymphocytes ? 1) Retrovirus 2) ‘Tplasmid (3) pBR 3: Bio-infring Biopiracy Bioexploitation Biodegradation nnsible Indie, the organisation responsible ing the safety of introducing genetically ified organisms for publie use is Research (ICMR) and Industrial Denaturation, Annealing ig, Extension, Denaturation ration, Annealing, Extension uration, Extension, Annealing tthe correct match (2) Ribozyme ~ Nuclei,tive in the organisms age of temperature that the organism nceds to live civatosphere, which of the following elements’ 's a catalyst in degradation of ozone and ase of molecular oxygen ? Carbon a oxygen What type of ecological pyramid would be obtained with the following data ? Secondary consumer : 120 6 Primary consumer : 60 Primary producer : 10.8 (2) _ Inverted pyramid of biomass (2) Pyramid of energy (@) Upright pyramid of biomass re (4) Upright pyramid of numbers 128, Which of the following is « secondary pollutant ? a co 2) CO, () 05 (4) $0, 123. World Ozone Day is celebrated on (1) 5? June @ 3) ® 124, Natality refers to (1) Death rate (2) Birth rate (3) Number of individuals entering & habitat (4) Number of individuals leaving ALHCA/ZZ/Page 15 21" April 224 April 16!" September umn T with those 5 stema given in Col s t option give 125. Mateh the and select the corned Column I below Column T Herbarium i. Column I Iris a place having epllection of preserved plants and animals A list that ;odically all the din an area enumerates Key : species fount ‘with brief description riding identification. Isa place where dried and pressed plant specimens on sheets are Musoum ii mounted kept. ‘A booklet containing a list oftcharacters and their ‘alternates which are helpful in identification of various taxa. a Catalogue iv. b ii wi ii i mi ) @) @ iti ra 126, Which one is wrongly matched ? (1) Uniflagellate gametes — (2) Biflagellate zoospores — (3) Unicellular organism — (4) Gemma cups = Polysiphonia Brown algae Chlorella Marchantia. 197. After karyogamy followed by meiosis, spores 0° produced exogenously in (a) Neurospora: Q) Alternaria (3) Saccharomyces (4) Agaricus 4128, Winged pollen eruins are present in qa ‘Mustard @armylopeetin age and and and mylopectin have 4 oclinkage and 6 Blinkage ing cross-linked or network polymers, of the following statements is incorrect ? contain covalent bonds between various linear polymer chains. hey are formed from bi- and tri-functional hey contain strong covalent bonds in their polymer chains, Examples are bakelite and melamine. uy Acixture of 28 g formic acid and 4°5 ¢ oxalic ed is treated with cone. HyS0,. The evolved jaseous mixture is passed through KOH pellets. Weight (in g) of the remaining product at STP will be (@ 14 (2 30 (9) 44 28 147. ‘The compound A on treatment with Na gives B, and with PCl; gives ©. B and C react together to give diethyl ether. A, B and C are in the order 2) CyH,OH, CyHp, C2H;Cl ©) CyH,OH, CgHyCl, CyH,ONa (8) OgH,OH, CyH,ONa, CHCl (4) CyHH,O1, CyHy, C3H,0H1 148. Hydrocarbon (A) reacts with bromine substitution to form an alkyl bromide whieh by Wurtz reaction is converted to gaseous hydrocarbon containing less than four carbon atoms. (A) is @ CH=cH (2) CH,=CHy @) CH, (4) CH,-CH; ‘The compound C7Hg undergoes the following reactions 149. BCA/A . Bri Ke HCL oe, 2S 6, An/HCL ‘The product ‘Cis 145, Which of the following oxides is most acidie in (a) me-bromptolsone nature? MgO (2) o-bromotoluene eee (3) _p-bromotoluene Pee (4) S-bromo-2,4,6-trichlorotoluene () Bao 16. Nitralion of aniline in strong acidic medium also] 160. Which oxide of nitrogen is mot sommnet ‘ives m-nitroaniline because pollutant introduced into the atmosphere both (Q) Im spite of substituents nitro group always due to natural and human activity? goes to only m-position. ’ (a) N05 @) In electrophilic substitution reactions ‘amino group is meta directive. (2) NOy Mees me “| (8) Imaeidic (strong) medium aniline is present Ke as anilinium ion. ; (4) In absence of substituents nitro group 4 N20. e to-m-position. a se “SPACE FOR ROUGH WORK AWcArzzipage 17 x129, Pneumabophores o2eu in 1) Halophytes Free-floating hydrophy Submerged hydrophvtes 4) Carnivorous plant Plants haying little or no secondary &PO GQ) Grasses (2), Deciduous angiosper™s (8), Cycads “ ors oe strips occur in @) Bpidermis (2) Pericycle (8) Endodermis 4) Cortex Secondary xylem and philoem in dicot stem are roduced by G) Apical mexis ) Vascular e (3) Axillary met (@ Phellogen, Gx members of Fungi Basidiomycete: powerhouse of the coll Mollowing statements is correet ? by ovary wall i Adventitious root Rh151, Which of the following molecules represents the | ¥ ~ bridisation sp”, sp ap, ap from left to on e’ CHCl, + Nao, ——* (@) He=¢-c=ch (@) CH, =CH-c=¢ |. Which of the following is correct with x —Teffeet of the substituents ?(R =a ~NH, <-OR<-FAnia balanced equation are HyCH,CH,Ct ——— - 6 O2- + cit Mn0z; 0,03> ¥ 5 ) 0» @ 16 5 2 ii) Hg0%/A . ad 5 us @ 5 i 2 @ 2 6 P Q R 160. Which one of the following conditions will favour CHO maximum formation of the product in the | 1 Hh roaetion, | go ' J] , cHi,ct, -OF ‘Ag(g) + By (g) = %(@) 4 H=-KkI? ts than Sy * (1) Low temperature and high pressure ols of (2) Low temperature and low pressure cir CH,CH,CH, CHO COOH (3) High temperature and Jow pressure i (4) High tomperature and high pressure ® : r 161. When initial concentration of the reactant is 4 doubled, the half-life period of a zero order boxylic ea zion re (1) ishalved CH(CH)y (2) is doubled 0 CF Cycom | ene t with (4) is tripled i) and 462. The correction factor ‘a’ to the ideal gas equation oristic corresponds to CH(CH,)2 OH (a) density of the gas molecules a or CH,CH(OH)CHs (2) volume of the gas. molecules . (@) forces of attraction between the gas ‘molecules (a) electric field present between the gas molecules AR, Which of the following compounds can form &14¢9, ‘Too bond dissociation ‘energies of Xp, Yp and XY rwitterion ? are in the ratio of 1: 0: 1. AH for the formation fof XY is 200 kJ mol”, The bond dissociation (2) Aniline energy of Xp will be et (2) Acetanilide ® Py (2) 100 ki mot (3) Glycine (@) 400 ks mot (4) Benzoie acid (4) 3005 mot * — “SPACE FOR ROUGH WORK eee products P, Q and R in the 159. For the redox reaction MnO] +C,0$> + H’ —> Mn™ + CO, +H,0 the correct coefficients of the reactants for thein wator is The value of its me g4nx10 ‘eability produc and ira. more a 283 g mol) 41176. Iron earbonyl, Fe(COs 18 1) tetranuclear (2) mononuclear (3) dinuclear (@) trinuclear 177. ‘The type of isomerism shown by the ‘complex 08 x 10°” mol® Ilo : 4 [CoClgfen)g] is 1 dood a = T (1) Geometrical isomerism rat (4) 108<10* mol* 1 (2) Coordination isomerism ed mast (8) Linkage isomerism } 473. Following solutions were prepared by mixin ‘ zed centrations : 178. Which one of the following ions exhibits ded transition and paramagnetism as well ? a 6omb M Hci+40 mt M Non : caper am 10 @ cop M 5 mL 7, HCl +45 mL [5 NaOH (2) 0x02 « Tmb x Hc1+ 25 mi ¥ Naot (3) -Maoy” @) MnO} M M a 100m M Het + 100 mL ml 5 Lp NaOH pH of which one of them will be equal to 1? a) @) (3) 4) onic aoe which of the following properties does th 174. On rer of an ion depend ? ‘ALHCAVZZ/Page 21 179. ‘The geometry and magnetic behaviour of the complex [Ni(CO},] are (2) square planar geometry and diamagnetic (2) tetrahedral geometry and diamagnetic (3) tetrahedral geometry and paramagnetic (4) square planar geometry and paramagnetic 180, Match the metal ions given in Column I with the ‘spin magnetic moments of the ions given in coagulating pow' (The magnitude of the charge on the ion) Colma Thand assign the correct code : nee Column I Column IT (2) Size of the ion alone att ee (B) The sign of charge on the ion alone ¢ (4) Both magnitude and sign of the charge on bo 35 BM. eater eRe i BM, 475. Given van der Waals constant for NHg, Hy, O2| a Ne iy, 42d BM. and CO, are respectively 417, 0244, 1:36 and Aiea 3.59, which one of the following gases is most et ily liquefied ? os rece of a 2) Hy : mo a a 60, @w y @ 4 (a) 0% wv “SPACE FOR ROUGH WORK Byesuully the following instruc 1 didate must show on demand his/her Adv jatendent or Invigilator, would leaye| No candidate, without special permission of the Sup his/her seal sn Hall without handing over their A: svar endance Sheet twice. Cases where 4) will be deemed not to| The candidates should not Ieave the Examin: and sign the Att Sheet to the Invigilator on du E candidate has not signed the Attendance Sheet seeond time have handed over the Answer Sheet and dealt with as an unfa ir means case. 4, Use of Electronic/Manual Caleulator is prohibited The candidates are governed by all Rules and Regulations of the examination with regard to heir conduct in the Examination Hall. 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