CONSTANTES MODELO BENEDICT-WEBB-RUBIN PARA n-BUTANO

Bo Ao Co b a c α
0.12436 10.0847 0.99283 0.03999 1.88231 0.3164 0.034

Comparació
R 0.0821 L*atm/K*mol 16.0000
V 2.1 L/mol 14.0000
n 10 mol
12.0000
v 21 L
10.0000

8.0000
T(K) P-atm(Benedict) P-atm(Gas ideal)
6.0000
Edna Yuliana 280 9.2417 10.9467
4.0000
Gallo Caceres 290 9.6572 11.3376
2.0000
300 10.0728 11.7286
310 10.4887 0.0000
12.1195280 290 300
320 10.9047 12.5105
330 11.3208 12.9014 P-atm(Be

340 11.7370 13.2924

350 12.1533 13.6833
 ɣ
0.00110132

Comparación Benedict y gas ideal

290 300 310 320 330 340 350

P-atm(Benedict) P-atm(Gas ideal)

 actividad 6
actividad individual

2.5
constantes de modelo Robin
Bo 0.12436 T(K) P-atm (Rubin)
P-atm(gas ideal)
2
Ao 10.0847 280 1.60377307 1.641
Co 9.9283E-07 290 1.66291277 1.69960714 1.5

P(atm)
b 0.03999 300 1.72205247 1.75821429
a 1.88231 310 1.78119217 1.81682143 1
c 3.164E-07 320 1.84033186 1.87542857
0.5
α 0.034 330 1.89947156 1.93403571
ɣ 0.00110132 340 1.95861126 1.99264286
0
350 2.01775096 2.05125 250
Ru 0.08205
volumen molar 14
 P vs T
2.5

1.5
P(atm)

0.5

0
250 270 290 310 330 350 370
T (K)
 CONSTANTES MODELO BENEDICT-WEBB-RUBIN PARA n-BUTANO
B0 A0 C0 * 10^-6 b a c*10^-6 α gamma
0.12436 10.0847 0.99283 0.03999 1.88231 0.3164 0.034 0.00110132

R 0.0821 L*atm/K*mol
V 1.75 L/mol 17
n 8 mol
v 14 L 16

15
T(K) P(Benedict) P(Gas ideal)
280 10.7248 13.1360

Presión (atm)
14
290 11.2254 13.6051
300 11.7267 14.0743 13
310 12.2286 14.5434
320 12.7312 15.0126
12
330 13.2342 15.4817
340 13.7377 15.9509
11
350 14.2417 16.4200

10
270 280
 Comparación Benedict vs gas ideal
17

16

15
Presión (atm)

14

13

12

11

10
270 280 290 300 310 320 330 340 350 360
Temperatura (K)
 Benedict
Gas ideal

350 360