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PIII - Quantum Condensed Matter Field Theory - (2006) 65pg
PIII - Quantum Condensed Matter Field Theory - (2006) 65pg
RI-1
φI M ks
(I-1)a Ia (I+1)a
In principle, one can obtain exact solution of discrete equation of motion — see PS I
In this case, it is often permissible to neglect the discreteness of the microscopic entities
of the system and to describe it in terms of effective continuum degrees of freedom.
. Continuum Lagrangian
1 L=N a
Z
X
1/2 3/2
φn → a φ(x) , φn+1 − φn → a ∂x φ(x) , −→ dx
x=na x=na n
a 0
φ(x)
φI
RI
Configurations x(t) that are realised are those that extremise the action
"#(x,t)
!
!(x,t)
x
φ+ x=νt
x=-νt φ–
. Comments
• Low-energy collective excitations – phonons – are lattice vibrations
propagating as sound waves at constant velocity v
• In higher dimensions, field has vector components 7→ transverse and longintudinal modes
∂L
1. Canonical momentum, π(x) ≡ , i.e. applied to chain, π = ∂φ̇ (mφ̇2 /2) = mφ̇
∂ φ̇(x)
2. Classical Hamiltonian
Hamiltonian density H(φ, π)
1 2 ks a2
Z zh }| i{
H[φ, π] ≡ dx π φ̇ − L(∂x φ, φ̇) , i.e. H(φ, π) = π + (∂x φ)2
2m 2
3. Canonical Quantisation
Ĥ represents a quantum field theoretical formulation of elastic chain, but not yet a solution.
As with any function, φ̂(x) and π̂(x) can be expressed as Fourier expansion:
Z L=N a
φ̂(x) 1 X ±ikx φ̂k φ̂k ≡ 1 ∓ikx φ̂(x)
= 1/2 e , dx e
π̂(x) L k
π̂k π̂k L1/2 0 π̂(x)
P
k runs over all discrete wavevectors k = 2πm/L, m ∈ Z, Ex: confirm [π̂k , φ̂k0 ] = −i~δkk0
Advice: Maintain strict conventions(!) — we will pass freely between real and Fourier space.
Hermiticity: φ̂† (x) = φ̂(x), implies φ̂†k = φ̂−k (similarly π̂). Using
δk+k0 ,0
Z L z Z L }| {
X 1 0
X
dx (∂ φ̂)2 = (ik φ̂k )(ik 0 φ̂k0 ) dx ei(k+k )x = k 2 φ̂k φ̂−k
0 0
L 0
k,k k
mωk2 /2
z }| {
Xh 1 ks a2 2 i
Ĥ = π̂k π̂−k + k φ̂k φ̂−k , ωk = v|k|, v = a(ks /m)1/2
2m 2
k
p̂2 1
Ĥ = + mω 2 q̂ 2
2m 2
Defining ladder operators
r r
mω i † mω i 1
â ≡ x̂ + p̂ , â ≡ x̂ − p̂ ; Ĥ = ~ω ↠â +
2~ mω 2~ mω 2
Using commutation relations [â, ↠] = 1, one may then show |ni ≡ â†n |0i
is eigenstate with eigenvalue ~ω(n + 21 )
• In ‘diagonal’ form Ĥ = ~ω(↠â + 21 ) simply counts particles (viz. ↠â|ni = n|ni)
and assigns an energy ~ω to each
Comments:
• Allows many different systems to be mapped onto a few classical field theories;
• Canonical quantisation procedure for point mechanics generalises to quantum field theory;
• Simplest model actions (such as the one considered here) are quadratic in fields
– known as free field theory;
Ĥ|ψλ i = λ |ψλ i
!λ nλ nλ
!4 0 0
!3 1 1
!2 1 1
!1 3 1
!0 5 1
bosons fermions
1 X
|λ1 , λ2 , . . . λN i ≡ p Q∞ ζ P |ψλP1 i ⊗ |ψλP2 i . . . ⊗ |ψλPN i
N ! λ=0 nλ ! P
P
• P: Summation over N ! permutations of {λ1 , . . . λN }
required by particle indistinguishability
• Parity P — no. of transpositions of two elements which brings permutation
(P1 , P2 , · · · PN ) back to ordered sequence (1, 2, · · · N )
In particular, for fermions, hx1 , . . . xN |λ1 , . . . λN i is Slater determinant, det ψi (xj )
Evidently, “first quantised” representation looks clumsy!
motivates alternative representation...
. Second quantisation
Define vacuum state: |Ωi, and set of field operators aλ and adjoints a†λ — no hats!
N
1 Y
aλ |Ωi = 0, pQ∞ a†λi |Ωi = |λ1 , λ2 , . . . λN i
λ=0 nλ ! i=1
a a a
... F 2
F 1
F 0
0
a+ a+
. Fock space: Defining FN to be linear span of all N -particle states |λ1 , . . . λN i,
Fock space F is defined as ‘direct sum’ ⊕∞ N =0 FN
. Change of basis:
a†λ̃ |Ωi a†λ |Ωi
P z}|{ X z}|{
Using resolution of identity 1 ≡ λ |λihλ|, we have |λ̃i = |λi hλ|λ̃i
λ
X X
i.e. a†λ̃ = hλ|λ̃ia†λ , and aλ̃ = hλ̃|λiaλ
λ λ
∞ ∞
oλ a†λ aλ
X X
Since this holds for any basis state, Ô1 = oλ n̂λ =
λ=0 λ=0
X X
Ô1 = hµ|λioλ hλ|νia†µ aν = hµ|ô|νia†µ aν
λµν µν
i.e. Ô1 scatters particle from state ν to µ with probability amplitude hµ|ô|νi
L
p̂2
Z
i.e. Ĥ = T̂ + V̂ = dx a† (x) + V (x) a(x) where p̂ = −i~∂x
0 2m
i.e. annihilation operators check for presence of particles at x and x’ – if they exist, asign the
potential energy and then recreate particles in correct order (viz. statistics)
Z Z
1
N.B. dx dx0 V (x, x0 )n̂(x)n̂(x0 ) does not reproduce the two-body operator
2
. In non-diagonal basis
1 X
e.g. in Fourier basis: a† (x) = eikx a†k can show that (Ex.)
L1/2 k
Z
1
V (q)a†k1 a†k2 ak2 +q ak1 −q
X
dxdx0 a† (x)a† (x0 )V (x − x0 )a(x0 )a(x) =
2
k1 ,k2 ,q
k’,σ’ k,σ
V(q)
k’+q,σ’ k–q,σ
Feynman diagram:
|k1 , k2 , ...i = a†k1 a†k2 · · · |Ωi is eigenstate of Ĥ with energy ~ωk1 + ~ωk2 + · · ·
1 e2
Z Z X
(0)
Ĥ = Ĥ + dx dx0 c†σ (x)c†σ0 (x0 ) c (x0 )cσ (x)
0 | σ0
2 σσ 0
|x − x
. Comments:
To familiarise ourselves with second quantisation, in the remainder of this and the next
lecture, we will explore several case studies: ‘Atomic limit’ of strongly interacting elec-
tron gas: electron crystallisation and Mott transition; Quantum magnetism; and weakly
interacting Bose gas
E
E "1B
s=1 !
1 "1A
"1
s=0 ! "0A
0
"0 "0B
x
V(x)
!/ a
E E
x
0 k
a
(n!1)a na (n+1)a
Weak overlap of tightly bound orbital states 7→ narrow band of Bloch states |ψks i,
specified by band index s, k ∈ [−π/a, π/a] in first Brillouin zone.
Bloch states can be used to define ‘Wannier basis’, cf. discrete Fourier decomposition
B.Z. N
1 X
−ikna 1 X ikna 2π
|ψns i ≡ √ e |ψks i, |ψks i ≡ √ e |ψns i, k= m
N N n=1 Na
k∈[−π/a,π/a]
!n0 (x)
(n!1)a na (n+1)a
In ‘atomic limit’, Wannier states |ψns i mirror atomic orbital |si on site n
∗ 0 = δ(x − x0 )
P
and using completeness ns ψns (x )ψns (x)
i.e. (if we include spin index σ) operators c†nsσ /cnsσ create/annihilate electrons at site n in
band s with spin σ
p̂ 2
where “hopping” matrix elements tmn = hψm |[ 2m + V (x)]|ψn i = t∗nm and “interaction pa-
rameters”
e2
Z Z
1
Umnrs = dx dx0 ψm∗
(x)ψn∗ (x0 ) ψr (x0 )ψs (x)
2 |x − x0 |
(For lowest band) representation is exact:
but, in atomic limit, matrix elements decay exponentially with lattice separation
B.Z.
1
e−ikna c†kσ
X
In discrete Fourier basis: c†nσ = √
N k∈[−π/a,π/a]
δkk0
N z
X 1 X
}| {
† 0
e−i(k−k )na e−ika c†kσ ck0 σ + h.c. = −2t cos(ka) c†kσ ckσ
X X
−t cn+1σ cnσ + h.c. = −t
nσ 0
N n
kk σ kσ
(k)
- /a /a k
B.Z.
i.e. weak ferromagnetic coupling (JF > 0) cf. Hund’s rule in atoms
spin alignment 7→ symmetric spin state and asymmetric spatial state lowers p.e.
N 1 2
N
X
Ĥ = −J Ŝm · Ŝm+1 p.b.c. Ŝn+N = Ŝn
m=1
Our aim is to uncover ground states and nature of low-energy (collective) excitations.
1 + −
(Ŝ Ŝ + Ŝ − Ŝ + )
2 z m m+1}| m m+1 {
Xh i
z z x x y y
Ĥ = −J Ŝm Ŝm+1 + Ŝm Ŝm+1 + Ŝm Ŝm+1
m
−
P
Manifold of degeneracy explored by action of total spin lowering operator m Ŝm
.Elementary excitations
To see this, for large spin S, it is helpful to switch to representation in which spin
deviations are parameterised as bosons:
|S z = Si |n = 0i
|S z = S − 1i |n = 1i
.. ..
. .
|S z = −Si |n = 2Si
. Mapping of operators:
Noting
δkk0
z }| {
X 1 X
−i(k−k0 )m −ika †
X X
†
(am am+1 + h.c.) = e e ak ak0 + h.c. = cos k a†k ak
m kk0
N m k
B.Z.
X
Ĥ = −JN S + 2
ωk a†k ak + O(S 0 ), where ωk = 2JS(1 − cos k) = 4JS sin2 (k/2)
k
N 1 2
δk+k0 ,0
z }| { γk = cos k
N X 1 X N z }| {
X 0
X X 1 ik
am am+1 = ei(k+k )m eik ak0 ak = a−k ak eik ≡ a−k ak (e + e−ik )
m=1 kk0
N m=1 k k
2
ak a†k − 1
X † z}|{
Ĥ = −N JS 2 + JS [ak ak + a†k ak +γk (a−k ak + a†k a†−k )]
k
X 1 γk ak
= −N JS(S + 1) + JS ( a†k a−k ) + O(S 0 )
k
γk 1 a†−k
Experiment?
i.e. quantum fluctuations destroy long range AFM order in 1d – spin liquid
. Frustration
V V X † 1 † †
1/2
2
ĤI = N + N0 2ak ak + a−k ak + ak a−k + O(N0 )
2Ld 0 Ld 2
k6=0
• V a†k ak represents the ‘Hartree-Fock energy’ of excited particles interacting with condensate
N.B. Contact interaction disguises presence of direct and exchange contributions
• V (a−k ak + a†k a†−k ) represents creation or annihilation of particle pairs from condensate
Note that, in this approximation, total no. of particles is not conserved
X † N
Finally, using N = N0 + ak ak to trade N0 for N , and defining density, n = d
L
k6=0
V nN X (0) Vn
Ĥ = + k + V n a†k ak + a−k ak + a†k a†−k
2 2
k6=0
k
z }| {
X 1/2
V nN 1X (0) (0)
2 1
Ĥ = − (k + nV ) + k +Vn 2
− (V n) αk† αk +
2 2 2
k6=0 k6=0
• Real-space representation:
Z
dq|qihq| Z
0 0 0 0 0 0
Ψ(q , t ) ≡ hq |Ψ(t )i = hq |Û (t , t) ∧ |Ψ(t)i = dq U (q 0 , t0 ; q, t)Ψ(q, t),
i 0
where U (q 0 , t0 ; q, t) = hq 0 |e− ~ Ĥ(t −t) |qiθ(t0 − t) — propagator or Green function:
i~∂t0 − Ĥ Û (t0 − t) = i~δ(t0 − t) N.B. ∂t0 θ(t0 − t) = δ(t0 − t)
Feynman’s idea: divide time evolution into N → ∞ discrete time steps ∆t = t/N
e−iĤt/~ = [e−iĤ∆t/~ ]N
Then separate the operator content so that momentum operators stand to the left
and position operators to the right:
hqF |[e−iĤ∆t/~ ]N |qI i ' hqF |∧e−iT̂ ∆t/~ e−iV̂ ∆t/~ ∧ . . . ∧e−iT̂ ∆t/~ e−iV̂ ∆t/~ |qI i
1
Z Z
Inserting at ∧ resol. of id. = dqn dpn |qn ihqn |pn ihpn |, and using hq|pi = √ eiqp/~ ,
2π~
e−iV̂ ∆t/~ |qn ihqn |pn ihpn |e−iT̂ ∆t/~ = |qn ie−iV (qn )∆t/~ hqn |pn ie−iT (pn )∆t/~ hpn |,
1 iqn (pn −pn+1 )
and hpn+1 |qn ihqn |pn i = e
2π~
−1
Z NY N
" N −1 #
Y dpn i X qn+1 − qn
hqF |e−iĤt/~ |qI i = dqn exp − ∆t V (qn ) + T (pn+1 ) − pn+1
n=1 n=1
2π~ ~ n=0
∆t
qN =qF ,q0 =qI
p
phase space
tn t
qF N N–1 0
qI
i.e. at each time step, integration over the classical phase space coords. xn ≡ (qn , pn )
Action
z }| {
Lagrangian
Z hi Z t z }| {i
−iĤt/~
hqF |e |qI i = D(q, p) exp dt0 (pq̇ − H(p, q))
q(t)=qF ,q(0)=qI ~ 0
Quantum transition amplitude expressed as sum over all possible phase space
trajectories (subject to appropriate b.c.) and weighted by classical action
p2
. Lagrangian formulation: for “free-particle” Hamiltonian H(p, q) = 2m
+ V (q)
Gaussian integral on p
z Z }| {
i t 0 p2
Z Rt
Z
dt0 V (q)
hqF |e−iĤt/~ |qI i = Dq e−(i/~) 0 Dp exp − dt − pq̇
q(t)=qF ,q(0)=qI ~ 0 2m
2
p0
p2 1 z }| {2 1 2
− pq̇ 7→ (p − mq̇) − mq̇
2m 2m 2
Functional integral justified by discretisation
Z t 2
i mq̇
Z
−iĤt/~ 0
hqF |e |qI i = Dq exp dt − V (q)
q(t)=qF ,q(0)=qI ~ 0 2
−1
N/2 NY
Nm
Dq → Dq
e = lim dqn
N →∞ it2π~ n=1
V(u)
. Mapping:
Z t 2
i mq̇
Z
0 −iĤt/~ 0
hq |e |qi = Dq(t) exp dt − V (q)
~ 0 2
Wick rotation t → −iτ 7→ imaginary (Euclidean) time path integral
Z t Z τ Z t Z τ
0 0 0
2
idt (∂t0 q) −→ − 2
dτ (∂τ 0 q) , − idt V (q) −→ − dτ 0 V (q)
0 0 0 0
τ
1 m
Z Z
0 −iĤt/~ 0 2
hq |e |qi = Dq exp − dτ (∂τ 0 q) + V (q) N.B. change of relative sign!
~ 0 2
(a) Classical partition function of 1d system coincides with QM amplitude
Z
Z = dq hq|e−iĤt/~ |qi
t=−iτ
(c) Semi-classics
R
As ~ → 0, PI dominated by stationary config. of action S[p, q] = dt(pq̇ − H(p, q))
Z
δS = S[p + δp, q + δq] − S[p, q] = dt [δp q̇ + p δ q̇ − δp ∂p H − δq ∂q H] + O(δp2 , δq 2 , δpδq)
Z
= dt [δp (q̇ − ∂p H) + δq (−ṗ − ∂q H)] + O(δp2 , δq 2 , δpδq)
7→ 0
z }| { 1
f (z) = f (z0 ) + (z − z0 ) f 0 (z0 ) + (z − z0 )2 f 00 (z0 ) + · · ·
2
Z ∞ s
2 00 2π −f (z0 )
I ' e−f (z0 ) dz e−(z−z0 ) f (z0 )/2 = 00
e
−∞ f (z0 )
= s! if s ∈ Z Z ∞ Z ∞
z }| {
s −z
Example : Γ(s + 1) = dz z e = dz e−f (z) , f (z) = z − s ln z
0 0
s s 1
f 0 (z) = 1 − i.e. z0 = s, f 00 (z0 ) = 2 =
z z0 s √
i.e. Γ(s + 1) ' 2πse−(s−s ln s) — Stirling’s formula
. Free particle propagator: Difficult to obtain from PI, but useful for normalization,
and easily obtained from equation for Green function, (i~∂t − Ĥ)Ĝfree (t) = i~δ(t),
which in Euclidean time t = −iτ becomes a diffusion equation,
~2 ∇2
~∂τ − Gfree (qF , qI , t) = ~δ(qF − qI )δ(τ )
2m
Solution: (PS3)
i m(qF − qI )2
m 1/2
−ip̂2 t/2m~
Gfree (qF , qI ; t) ≡ hqF |e |qI iθ(t) = exp θ(t)
2πi~t ~ 2t
e.g. QM amplitude q
Z t 2
i mq̇
Z
−iĤt/~ 0
G(0, 0; t) ≡ h0|e |0i θ(t) = Dq exp dt − V (q)
q(t)=q(0)=0 ~ 0 2
(i) Parameterise path as q(t) = qcl (t) + r(t) and expand action in r(t)
0 r2 00
2 V (q ) +2rV (q ) + V (qcl ) + · · ·
Z t h q˙cl z+ 2}|q˙cl ṙ + ṙ cl cl
2
0 m
{ z }| { i
2
S[q̄ + r] = dt (q̇cl + ṙ) − V (qcl + r)
0 2
δS δ2 S
δq(t0 )
=0 δq(t0 )δq(t00 )
Z t z }| { 1 Z t z }| {
= S[qcl ] + dt0 r(t0 ) [−mq̈cl − V 0 (qcl )] + dt0 r(t0 ) −m∂t20 − V 00 (qcl ) r(t0 ) + · · ·
0 2 0
Many solutions – choose non-singular qcl = 0, i.e. S[qcl ] = 0 and V 00 (qcl ) = mω 2 const.
Z t
i 0 m
Z
0 2 2
0
G(0, 0; t) ' Dr exp dt r(t ) −∂t0 − ω r(t )
r(0)=r(t)=0 ~ 0 2
• Many variables:
Z
1 T Av
dv e− 2 v = (2π)N/2 det A−1/2
∞ ∞ −1/2
2 −1/2
Y Y nπ 2
−∂t2 −1/2 2
det −ω = n = −ω
n=1 n=1
t
Q∞ x 2 −1 x
Applying identity n=1 [1 − ( nπ )] = sin x
mω
r
G(0, 0; t) ' Θ(t)
2πi~ sin(ωt)
. Feynman PI:
Z q(t)=a Z t
i 0 m 2
G(a, −a; t) = Dq exp dt q̇ − V (q)
q(0)=−a ~ 0 2
Combined with small fluctuations, (1) and (2) recover propagator for single well
q
V
-a a a
q
t
-a
ω –1
τ5 τ4 τ3 τ2 τ1 τ
–a
n n
Y 1 Y
An,qu. ∼ p ∼ e−ω(τi+1 −τi )/2 ∼ e−ωτ /2
i
sin(−iω(τi+1 − τi )) i
τ n /n!
zZ }| {
X τ Z τ1 Z τn−1
G(a, ±a; τ ) ' K n e−nSinst. /~ e−ωτ /2 dτ1 dτ2 · · · dτn
n even / odd 0 0 0
X 1 n
= e−ωτ /2 τ Ke−Sinst. /~
n!
n even / odd
P∞
Using ex = n=0 x
n /n!, N.B. non-perturbative in ~!
G(a, a; τ ) ' Ce−ωτ /2 cosh τ Ke−Sinst. /~ , G(a, −a; τ ) ' Ce−ωτ /2 sinh τ Ke−Sinst. /~
A
S
ψ q
In fact, such corrections are bigger but act equally on |Si and |Ai
i.e. ∆ = ~Ke−Sinst. /~ is dominant contribution to splitting
V –V q
q qm q τ
qm
(ii) Unstable States and Bounces: survival probability: G(0, 0; t)? No even/odd effect:
−ωτ /2
h i
−Sinst /~ τ =it −iωt/2 Γ
G(0, 0; τ ) = Ce exp τ Ke = Ce exp − t
2
True decay rate has additional factor of 2: Γ ∼ |K|e−Sinst /~ (i.e. K imaginary)
see Coleman for details
Such eigenstates exist and are known as... reference: Negele and Orland
What are eigenstates of Fock space operators: ai and a†i with [ai , a†j ] = δij ?
(i) a†i |φi = φi |φi? — clearly, eigenstate of a†i can not exist:
if minimum occupation of |φi is n0 , minimum of a†i |φi is n0 + 1
(ii) ai |φi = φi |φi? — can exist and given by: |φi ≡ exp[ i φi a†i ]|0i i.e. φ ≡ {φi }
P
Proof: since ai commutes with all a†j for j 6= i — focus on one element i
∞ ∞
φa† φa†
X φn † n
X nφn
ae |0i = [a, e ]|0i = [a, (a ) ]|0i = (a† )n−1 |0i = φ exp(φa† )|0i
n=0
n! n=1
n!
a(a† )n = aa† (a† )n−1 = (1 + a† a)(a† )n−1 = (a† )n−1 + a† a(a† )n−1 = n(a† )n−1 + (a† )n a
• Hermitian conjugation:
∀i : hφ|a†i = hφ|φ̄i
P
• Overlap: with hθ| = |θi† = h0|e i θ̄i ai
" #
P P X
hθ|φi = h0|e i θ̄i ai |φi = e i θ̄i φi h0|φi = exp θ̄i φi
i
dφ̄i dφi
Z Y P
e− i φ̄i φi
|φihφ| = 1F
i
π
ηi ηj = −ηj ηi
. Grassmann Algebra
(i) ηi2 = 0 (cf. fermions) but note: these are not operators, i.e. [ηi , η̄i ]+ 6= 1
(ii) Elements ηi can be added to, and multiplied, by ordinary complex numbers
c + ci η i + cj η j , ci , cj ∈ C
. Gaussian integration:
Z Z Z Z
−η̄aη
dη̄dη e = dη̄dη (1 − η̄aη) = a dη̄ η̄ dηη = a
Z Y
T
dη̄i dηi e−η̄ Aη = detA (exercise)
i
Using rules
Z Z
dηF (η) = dη [F (0) + ηF 0 (0)] = F 0 (0) ≡ ∂η F [η]
. Differences:
P P
(i) Adjoint: hη| = h0|e− i ai η̄i
≡ h0|e i η̄i ai
but N.B. η̄i not related to ηi !
Z
(ii) Gaussian integration: dη̄dη e−η̄η = 1 N.B. no π’s
Completeness relation
Z Y P
dη̄i dηi e− i η̄i ηi
|ηihη| = 1F
i
Having obtained a complete coherent state basis for the creation and annihilation op-
erators, we could proceed by constructing path integral for the quantum time evolution
operator. However, since we will be interested in application involving a phase transition,
it is more convenient to begin with the quantum partition function.
1
β= kB T
, µ — chemical potential
Note that Ĥ and N̂ even in operators allowing matrix element to be commuted through
Z P
Z = d[ψ̄, ψ]e− i ψ̄i ψi hζψ|e−β(Ĥ−µN̂ ) |ψi
hψ 0 |Ĥ|ψi X X
with H(ψ 0 , ψ) = 0
= hij ψ̄ 0
i ψj + Vij ψ̄i0 ψ̄j0 ψj ψi
hψ |ψi ij ij
n=0
ψ̄N =ζ ψ̄0 ,ψN =ζψ0
Continuum limit N → ∞
N Z β N
X ψn − ψn−1 Y
∆β → dτ, → ∂τ ψ , d[ψ̄n , ψn ] → D(ψ̄, ψ)
n=0 0 ∆β τ =n∆β
n=0
Z Z β
−S[ψ̄,ψ]
Z= D(ψ̄, ψ)e , S[ψ̄, ψ] = dτ ψ̄ · ∂τ ψ + H(ψ̄, ψ) − µN (ψ̄, ψ)
ψ̄(β)=ζ ψ̄(0)
ψ(β)=ζψ(0)
0
Z β X
S= dτ ψ̄k (∂τ + ~ωk − µ)ψk
0 k
2 2
p̂
dr c†σ (r) 2m dr dr0 c†σ (r)c†σ0 (r0 ) |r−r
e 0
P R P R
e.g. Electron gas: Ĥ = σ cσ (r)− σσ 0 0 | cσ 0 (r )cσ (r)
β
p̂2
Z XZ
S= dτ drψ̄σ (r, τ )(∂τ + − µ)ψσ (r, τ )
0 σ
2m
β
e2
Z XZ
− dτ dr dr0 ψ̄σ (r, τ )ψ̄σ0 (r0 , τ ) ψσ0 (r0 , τ )ψσ (r, τ )
0 σ,σ 0
|r − r0 |
Z β Z β
mω 1/2 i
Setting ψ(τ ) = 2~
[q(τ )+ mω p(τ )], with p, q real, and noting dτ q ṗ = − dτ pq̇
0 0
β
p2
Z
1 ipq̇
Z
Z= D(p, q) exp − dτ + mω 2 q 2 −
p.b.c 0 2m 2 ~
i i 0 i ∂q ∂q
cf. (Euclidean time) FPI; β =
t, τ= t, = 0
~ ~ ~ ∂τ ∂t
Z t
i
Z
0
Z = D(p, q) exp dt (pq̇ − H(p, q))
~ 0
J det(∂τ + ~ω)−1
zZ Z}|β { Z Y P
ZB = D(ψ̄, ψ) exp − dτ ψ̄ (∂τ + ~ω) ψ = ( dψ̄ωn dψωn ) e− n ψ̄ωn (−iωn +~ω)ψωn
0 n
∞ 0 Y∞
" 2 #−1
Y J Y −1 J ~ωβ
[β(−iωn + ~ω)]−1 = (~ωβ)2 + (2nπ)2
=J = 1+
ωn
~ωβ n=1
~ωβ n=1
2πn
∞ x 2 −1
J0 Y x
= where 1+ =
2 sinh(~ωβ/2) n=1
πn sinh x
P∞ P1
cf. direct computation: ZB = e−β~ω/2 n=0 e−nβ~ω , ZF = e−β~ω/2 n=0 e−nβ~ω .
Note that normalising prefactor J 0 involves only a constant offset of free energy,
F = − β1 ln Z statistical correlations encoded in content of functional integral
. Quantum partition function of ideal (i.e. non-interacting) gas (from coherent states)
Using identity
P † Y Y
e−β(Ĥ−µN̂ ) = e−β α (α −µ)aα aα e−β(α −µ)n̂α = 1 + e−β(α −µ) − 1 n̂α
=
α α
h−ψ|ψi
Z Y n z }| {
P o
d(ψ̄, ψ)e− α ψ̄α ψα −ψ̄α ψα −β(α −µ)
Z0 = e 1+ e − 1 (−ψ̄α ψα )
α
1 − 2ψ̄α ψα
YZ z }| {
dψ̄α dψα e−2ψ̄α ψα 1 + e−β(α −µ) − 1 (−ψ̄α ψα )
=
α
YZ
dψ̄α dψα 1 − 2ψ̄α ψα − e−β(α −µ) − 1 ψ̄α ψα
=
α
YZ
dψ̄α dψα −ψ̄α ψα (1 + e−β(α −µ) )
=
α
Y
1 + e−β(α −µ)
= i.e. Fermi − Dirac distribution
α
P
. To perform summations of the form, I = ωn h(ωn ), helpful to
introduce complex auxiliary function g(z) with simple poles at z = iωn
β
, bosons
exp(βz) − 1
e.g. g(z) = β
, fermions
exp(βz) + 1
In bosonic case: poles when βz = 2πin, i.e. z = iωn ; close to pole,
β β 1
= '
eβ(iωn +δz) −1 eβ δz−1 δz
noting that g(z) has simple poles with residue ζ,
ζ
I X
I= dz g(z)h(−iz) = ζ Res [g(z)h(−iz)]|z=iωn
2πi γ1 ω n
γ1 ω γ2 ω
Although we could start our analysis of application of the field integral with the weakly
interacting electron gas, we would find that correlation effects could be considered per-
turbatively. Our analysis of the field integral would not engage any non-trivial field con-
figurations of the action: the platform of the non-interacting electron system remains
adiabatically connected to that of the weakly interacting system. In the following we will
explore a problem in which the development of a non-trivial ground state — the Bose-
Einstein condensate — is accompanied by the appearance of collective modes absent in the
non-interacting system.
β
g
Z Z h i
S= dτ dd r ψ̄(∂τ + Ĥ0 − µ)ψ + (ψ̄ψ)2
0 2
Bosons confined to box of size L with p.b.c. and Ĥ0 = p̂2 /2m described by action
Z β Z
p̂2
d g 2
S= dτ d r ψ̄(∂τ + − µ)ψ + (ψ̄ψ)
0 2m 2
Since field integral intractable, turn to mean-field theory
(a.k.a. “saddle-point” approximation – Landau theory) valid for T Tc
1 β ρ β
Z
dτ ∂τ (ρ1/2 ρ1/2 ) = − = 0
2 0 2 0
z }| {
Z β Z β Z β
1/2 1/2
Using 1. dτ ψ̄∂τ ψ = ∂τ ρ dτ ρ + dτ iρ∂τ φ
0 0 0
1/2 iφ iφ 1 1/2
2. ∂(ρ e ) = e ∂ρ + iρ ∂φ
2ρ1/2
Z β Z β β
1
Z
2
3. dτ ψ̄∂ ψ = − dτ ∂ ψ̄ · ∂ψ = − dτ (∂ρ)2 + ρ(∂φ)2
0 0 0 4ρ
β
gρ2
1 1
Z Z
d 2 2
S[ρ, φ] = dτ d r iρ∂τ φ + (∂ρ) + ρ(∂φ) − µρ +
0 2m 4ρ 2
ρ(r)
Superflow imposed by boundary conditions, cf. Coulomb: ∂ 2 φ = −
e.g. φ(r) ' −φ0 ln |x2 + y 2 | translates to a line vortex
Notice that a ‘mass term’ in the phase action (viz. mφ φ2 ) would spoil this property,
i.e. the phenomenon of superflow is intimately linked to the Goldstone mode
But this is not the case here! there is no energy gap (ωk = vs |k|)
In the final section of the course, we will explore a pairing instability of the electron
gas which leads to condensate formation and the phenomenon of superconductivity.
. History:
As a result electrons can condense as pairs into state with energy gap to excitations
. Cooper instability
1
Z
0
X
Vk−k0 gk0 = (E − 2k )gk , Vk−k0 = d dd r V (r)ei(k−k )·r
k0
L
If we assume Vk−k0 = − LVd
{|k − F |, |k0 − F |} < ωD
0
otherwise
V X V X 1 X X V X 1
− d gk0 = (E − 2k )gk 7→ − d gk0 = gk 7→ − d =1
L k0 L k E − 2k k0 k
L k
E − 2k
1 X dd k 1
Z Z Z
Using d = = ν() d ∼ ν(F ) d, where ν() = is DoS
L k (2π) d |∂k k |
Z F +ωD
E − 2F − 2ωD
V X 1 d ν(F )V
− d ' −ν(F )V = ln =1
L k E − 2k F E − 2 2 E − 2F
• i.e. pair forms a bound state (no matter how small interaction!)
gk eik·r ,
P
. Radius of pair wavefunction: g(r) = k
1 ∂k ∂
Using gk = 2k −E
× const., ∂k = ∂k ∂k
= v ∂∂k , and
δ(r − r0 )
z }| {
1 X 0 1
Z Z
ik·(r−r0 )
X
2 d d 0 ∗ 0
|∂k gk | = d r d r r · r d e g(r)g (r ) = dd r r2 |g(r)|2 ,
Ld k L k
R F +ωD 2 ∂ 1
2
d ν() v
R d 2 2
P 2
d r r |g(r)| |∂ k g k | ∂ 2−E
hr2 i = R d = Pk = F R F +ωD
d r|g(r)|2 k |g k |2
F
1
d ν() (2−E) 2
R +ω 4d
vF2 F D
(2−E)4 4 vF2
' R F F+ωD d =
(2−E)2
3 (2F − E)2
F
if binding energy 2F − E ∼ kB Tc , Tc ∼ 10K, vF ∼ 108 cm/s, ξ0 = hr2 i1/2 ∼ 104 Å,
i.e. other electrons must be important
. BCS wavefunction
1
R
where gk = Ld
dd r g(r)eik·r
Then, of the terms in the expansion of
N
" #
Y X
|ψi = gkn c†kn ↑ c†−kn ↓ |Ωi
n=1 kn
. BCS Hamiltonian
However, since we are interested in both the g.s. energy and spectrum of excitations,
we will follow a different route and explore the model Hamiltonian
X V X † †
Ĥ = k c†kσ ckσ − c 0 c 0 c−k↓ ck↑
k
Ld kk0 k ↑ −k ↓
1
R
where gk = Ld
dd r g(r)eik·r denotes pair wavefunction
ξk
X z }| { † V X † †
Ĥ − µN̂ = (k − µ) ckσ ckσ − d c 0 c 0 c−k↓ ck↑ ,
kσ
L kk0 k ↑ −k ↓
X † V X † †
' ξk ckσ ckσ − d b̄k c−k0 ↓ ck0 ↑ + bk ck↑ c−k↓ − b̄k bk + O(small)2
0 0
kσ
L kk0
V X
Setting bk ≡ ∆, obtain the “Bogoliubov-de Gennes” or “Gor’kov” Hamiltonian
Ld k
X Ld |∆|2
¯
X
Ĥ − µN̂ = ξk c†kσ ckσ − † †
∆c−k0 ↓ ck0 ↑ + ∆ck↑ c−k↓ +
kσ k
V
Ld |∆|2
X
ξk −∆ ck↑ X
= c†k↑ c−k↓ ¯ −ξk † + ξk +
−∆ c−k↓ V
k k
OT
z }| {
ck↑ uk vk γk↑
=
c†−k↓ −vk uk †
γ−k↓
As a result,
Ld ∆2 X † 2
X (ξk + ∆2 )1/2 γk↑
Ĥ − µN̂ = ξk + + γk↑ γ−k↓ †
V −(ξk2 + ∆2 )1/2 γ−k↓
k k
X Ld ∆2 X 2 †
= (ξk − (ξk2 + ∆2 )1/2 ) + + (ξk + ∆2 )1/2 γkσ γkσ
k
V kσ
†
Quasi-particle excitations, created by γkσ , have minimum energy ∆
g.s. identified as state annihilated by all the quasi-particle operators γkσ , i.e.
Y Y
|g.s.i ≡ γ−k↓ γk↑ |Ωi = (uk c−k↓ + vk c†k↑ )(uk ck↑ − vk c†−k↓ )|Ωi
k k
Y Y
= vk (uk c−k↓ c†−k↓ + vk c†k↑ c†−k↓ )|Ωi = const. × (uk + vk c†k↑ c†−k↓ )|Ωi
k k
in fact, const. = 1
Note that global phase of ∆ is arbitrary, i.e. |g.s.i continuously degenerate (cf. BEC)
V X V X † † V X
∆≡ b̄ k = hg.s.|c c
k↑ −k↓ |g.s.i = uk vk
Ld k Ld k Ld k
V X V X ∆
= d
sin 2θk = d
p
2L k 2L k 2
ξk + ∆2
V X 1 V ν(µ) ωD 1
Z
i.e. 1 = d
p = dξ p = V ν(µ) sinh−1 (ωD /∆)
2L k 2
ξk + ∆ 2 2 −ωD ξ 2 + ∆ 2
1
if ωD ∆, ∆ ' 2ωD e− ν(µ)V
!
1 1 ξ k
. In limit ∆ → 0, vk2 = cos2 θk = (cos 2θ + 1) = 1− p 2 7→ θ(µ − k ),
2 2 ξk + ∆2
and |g.s.i collapses to filled Fermi sea with chemical potential µ
. Hubbard-Stratonovich decoupling:
Gorkov Hamiltonian Ĝ −1
Nambu spinor Ψ̄
z }| { i
h z }| { [Ĝ(p) ]−1
Z
∆ ψ↑
0
× exp − dx ( ψ̄↑ ψ↓ )
∆¯ (h) −1
[Ĝ0 ] ψ̄↓
Z Z Z
R |∆|2
¯ ∆)e− dx g exp − dx Ψ̄Ĝ −1 Ψ
= D(ψ̄, ψ) D(∆,
i.e. Z expressed as functional field integral over complex scalar field ∆(x)
"Z
β
p̂2
Z X
d
S= dτ d r ψ̄σ (r, τ ) ∂τ + − µ ψσ (r, τ )
0 σ
2m
#
2
1 e
Z X
+ dd rdd r0 ψ̄σ (r, τ )ψ̄σ0 (r0 , τ ) ψσ0 (r0 , τ )ψσ (r, τ )
2 σ,σ 0
|r − r0 |
Z Z
Coulomb interaction decoupled by scalar field, Z = D(ψ̄, ψ) Dφ e−Seff
"Z #
β
p̂2
1
Z X
Seff = dτ dd r ψ̄σ (r, τ ) ∂τ + − µ + ieφ ψσ (r, τ ) + (∂φ)2
0 σ
2m 8π
Z Z −2S2m
X X z }| {
S= dτ ψ̄kσ (∂τ + k − µ)ψkσ + 3U dτ ψ̄m↑ ψ̄m↓ ψm↓ ψm↑
kσ m
1
P
where Sm = 2 αβ ψ̄mα σαβ ψmβ (cf. electron spin operator)
Z Z
Hubbard interaction decoupled by vector field, Z = D(ψ̄, ψ) DM e−Seff
" #
Z X Z X M2 X
m
Seff = dτ ψ̄kσ (∂τ + k − µ)ψkσ + dτ − ψ̄mα Mm · σαβ ψmβ
kσ m
2U αβ
p̂2
Z
p/h
dx hx|tr2 ln Ĝ [∆]|xi −1
[Ĝ0 ]−1 = ∂τ +
/− −µ
2m
(p)
|∆|2
[Ĝ0 ]−1
Z
∆
z }| {
−1
S[∆] = dx − tr ln Ĝ [∆] , Ĝ −1 =
V ∆¯ (h) −1
[Ĝ0 ]
To proceed further, it was necessary to invoke some approximation
δS ∆(x)
i.e. ∆(x) obeys the saddle-point condition: ¯ = − G12 (x, x) = 0
δ∆ V
With the Ansatz ∆(x) = ∆ const., Ĝ|ki = G(k)|ki, with |ki ≡ |ωn , ki and
~2 k 2
−1 −iωn + ξk ∆
G (k) = ¯ , ξk = −µ
∆ −iωn − ξk 2m
1 −iωn − ξk −∆
G(k) = ¯
−ωn2 − ξk2 − |∆|2 −∆ −iωn + ξk
p
with Ek = ξk2 + |∆|2 and k · x = ωn τ − k · r
1 1
with h(−iz) = , zp = ±Ek with residue h(zp ) = ± and
(z − Ek )(−z − Ek ) 2Ek
∆ 1 X 1 1 ∆ 1 X ∆
= d −βE
− βE
= d
tanh(βEk /2)
V L k e k + 1 e k + 1 2Ek L k 2Ek
For T = 0, β → ∞,
1 1 X 1 dξν(ξ) ν(0) ~ωD dξ
Z Z
−1 ~ωD
= d = ' = ν(0) sinh ,
|∆|
p p
V L k 2Ek 2 ξ 2 + |∆|2 2 −~ωD ξ 2 + |∆|2
1
i.e. |∆| ' 2~ωD exp −
ν(0)V
For T = Tc , ∆ = 0,
1 tanh(βc ξ/2) 1
Z ~ωD
' ν(0) dξ ' ν(0) ln(1.14βc ~ωD ), kB Tc ' 1.14~ωD exp −
V −~ωD 2ξ ν(0)V
2 ∞
(−z)n
−1 1 0 ∆ X
tr ln Ĝ [∆] = tr ln Ĝ0−1 − tr Ĝ0 ¯ + ···, ln(1 + z) = −
2 ∆ 0 n
n=1
−1
• Zeroth order term in ∆ ; ‘free particle’ contribution, viz. Z0 = etr ln Ĝ0 = det Ĝ0−1
• First (and all odd) order term(s) absent
(p/h)
|ωn , ki G0 (k)
(p/h)
z}|{ z }| {
Noting Ĝ0 |ki =(−iωn + (~2 k2 /2m − µ))−1 |ki
1
X Z
and using id. = |kihk|, ∆k = p dx e−ik·x ∆(x)
βL d
k
√
βLd∆k0 −k /
z }| {
(h) ¯ ¯
(p)
X (p) (h)
tr[Ĝ0 ∆Ĝ0 ∆] = G0 (k) hk|∆|k 0 i G0 (k 0 )hk 0 |∆|ki
kk0
pairing susceptibility Π(q)
z }| {
q=k0 −k
X
¯q 1 X (p) (h)
= ∆q ∆ G (k)G0 (k + q)
q
βLd k 0
1 X 1 1 ~2 k2
i.e. Π(ωm , q) = , ξk = −µ
βL ω ,k −iωn + ξk −i(ωn + ωm ) − ξk+q
d 2m
n
. ‘Gradient expansion’:
1
Kδαβ , K = ∂q2 Π(0)
z
τ
}|
=0
z }| { { z }| d {
∂ ∂ 1 ∂2 2
Π(q, ωm ) = Π(0) + iωm Π(0) +qα Π(0) + qα qβ Π(0) +O(ωm , q4 )
∂(iωm ) ∂qα 2 ∂qα ∂qβ
K
= Π(0) + iωm τ + q2 + O(ωm 2
, q4 )
2
At large enough temperatures, kB Tc 1/τ , dynamics may be neglected
altogether (viz. ∆(x) ≡ ∆(r)) and one obtains
. Ginzburg-Landau action
Z β Xt
S[∆] = dτ + Kq 2 ¯ q ∆q + O(|∆|4 )
∆
0 q
2
t K
Z
=β d r |∆|2 + |∂∆|2 + u|∆|4 + · · ·
d
2 2
t 1
where = + Π(0), and K, u > 0 (cf. weakly interacting Bose gas)
2 V
. Landau Theory: If we assume that dominant contribution to Z = e−βF arises from
minumum action, i.e. spatially homogeneous ∆ that minimises
S[∆] t
d
= |∆|2 + u|∆|4
βL 2
2
0p t>0
one obtains |∆| t + 4u|∆| = 0, |∆| =
−t/4u t < 0
S [!]
|!|
Im [!]
Re [!]
Tc
t 1
With Π(0) ' −ν(0) ln(1.14β~ωD ) (as before), Tc fixed by condition ≡ + Π(0)|T =Tc = 0,
2 V
1
i.e. = ν(0) ln(1.14βc ~ωD )
V
Therefore
T − Tc T − Tc
t 1 βc T
= + Π(0, T ) = ν(0) ln = ν(0) ln = ν(0) ln 1 + ' ν(0)
2 V β Tc Tc Tc
i.e. physically t is a ‘reduced temperature’
quantum partition function can be expressed as field integral involving complex field
Z
¯
X 1
Z = D[∆, ¯ ∆]e −S[ ∆,∆]
, S= + Π(q) |∆q |2 + O(∆4 )
q
V
EM L
ht z }| {i
K 1
Z
d 2 2 4
S=β d r |∆| + |(∂ − i2eA)∆| + u|∆| + (∂ × A)2
2 2 8π
Factor of 2 due to pairing (focusing only on spatial fluctuations of A)
A 7→ A0 = A − ∂φ(r), ∆ 7→ ∆0 = e−2ieφ(r) ∆
“Below Tc , Goldstone bosons (φ) and gauge field A conspire to create massive
excitations, and massless excitations are unobservable”, cf. electroweak theory
p
Coherence (healing) length ξ = K/t describes scale over which fluctuations
are correlated – diverges on approaching transition
2
Tc T
H
with βHeff [S] constrained (only) by fundamental symmetry (translation, rotation, etc.)
t 2 K
Z
d 2 4
βHeff [S(r)] = d r S + (∂S) + uS + · · · + BS
2 2
cf. Ginzburg-Landau Theory
βF min t 2
4
= S S + uS , etc.
Ld 2