14.

Calcula HR,SR,Hm,Sm, de una mezcla gaseosa a 750K y 15 atm, si su

composición es de 10% mol de metanol, 50% mol de etanol, 30% mol de acetona
y 10% mol de agua. Por medio de la ecuación virial y la correlación de Pitzer-Curl.

Datos
T= 750 K T 298.15 K
P= 15 atm
R= 82.057 cm3atm/molk
R2= 8.314 j/molk

PUROS
ComponenteYi Tc (K) Pc (atm) Vc (cm3/mol)Zc w
Metanol 0.1 512.6 79.9 118 0.224 0.559
Etanol 0.5 516.2 63 167 0.248 0.635
Acetona 0.3 508.1 46.4 209 0.232 0.309
Agua 0.1 647.3 217.5 56 0.229 0.344

MEZCLAS POLARES
ComponenteKij Tcij Vc Zc Wij Pcij
1-1 0 512.6 118 0.224 0.559 79.9
2-2 0 516.2 167 0.248 0.635 63
3-3 0 508.1 209 0.232 0.309 46.4
4-4 0 647.3 56 0.229 0.344 217.5
5-5
1-2 0.00501059 511.8194205 141.08498 0.236 0.597 70.252797
1-3 0.01350342 503.45363638 159.19102 0.228 0.434 59.168615
2-3 0.00209434 511.06140279 187.21554 0.24 0.472 53.759852
1-4 0.02282295 562.87940813 83.188206 0.2265 0.4515 125.75853
2-4 0.04826811 550.14405632 101.61028 0.2385 0.4895 105.96021
3-4 0.06918572 533.81458851 116.22622 0.2305 0.3265 86.870613
CPA CPB CPC CPD CPE Ho*(j/mol) So*(j/molk)
40.046 -3.63E-02 2.45E-04 -2.19E-07 5.99E-11 -201170 239.7
27.091 1.11E-01 1.10E-04 -1.50E-07 4.66E-11 -234810 282.59
35.918 9.39E-02 1.87E-04 -2.16E-07 6.32E-11 -217570 295.35
29.8605 -0.0031522 -7.3037 2.4247E-09 1.809E-06 -241800 188.72

Trij a b Boij B1ij B2ij Bij

1.4631291 0.0878 0.056 -0.153021492 0.122515 0.0062831 -41.195127
1.4529252 0.0878 0.0572 -0.155623385 0.1207537 0.0064529 -48.739636
1.4760874 -0.0309 0 -0.149779707 0.1246699 -0.0029873 -102.65508
1.158659 0.0279 0.0229 -0.255572681 0.0329614 0.0044811 -58.549853

1.4653606 0.0878 0.0566 -0.15222547 0.1228925 0.0062057 -43.433212

1.4897102 0.02845 0.028 -0.1462195 0.1268408 0.0014486 -62.644445
1.467534 0.02845 0.0286 -0.151679606 0.1232576 0.0015187 -71.752967
1.3324346 0.05785 0.03945 -0.189764245 0.0948637 0.006367 -51.626757
1.3632793 0.05785 0.04005 -0.180258858 0.1024961 0.0056547 -53.013028
1.4049822 -0.0015 0.01145 -0.168209759 0.1116544 -0.0009491 -66.913903

Bm -62.397866
 POLAR
Hrªj/mol Srªj/mol
H1* -173395.77 S1* 2.80E+04
H2* -191364.66 S2* 4.37E+04
H3* -168145.22 S3* 4.97E+04
H4* -877782524 S4* -8.78E+08
Hm* -87941718 Sm* -87714484.968
HR/RT -736.55738 SR -0.855627201
HM -87942454 SM -87714485.823
HR -4592804 SR -7.1136845488

LNΦ Φ fi^ 0 0 dB2ij/dt dBij/dt

-0.0090636 0.9909774 1.4864661 0.3504765 0.16978608329 -0.0221209 0.4346927
-0.0118656 0.98820451 7.4115339 0.3541778 0.17545750807 -0.022683 0.5768872
-0.0236079 0.97666855 4.3950085 0.3458771 0.16286202651 0.012143 0.7221449
-0.0128688 0.98721363 1.4808204 0.502692 0.47721710223 -0.0110355 0.2474232

0 0 0 0.3496765 0.16857193051 -0.021776 0.500543

0 0 0 0.3411598 0.15590247518 -0.0042847 0.561025
0 0 0 0.3489006 0.16739814906 -0.0043973 0.6464375
0 0 0 0.4039497 0.26036459526 -0.0227105 0.3254612
0 0 0 0.3900394 0.23501024795 -0.0199624 0.3756791
0 0 0 0.3725689 0.20495451266 0.0051268 0.4199767

fm 79.8149719
Combinacion Suma dB/dt 0.5629588
1,1 = 0.0043469
1,2 2,1 = 0.0500543
1,3 3,1 = 0.0336615
1,4 4,1 = 0.0065092

2,2 = 0.1442218
2,3 3,2 = 0.1939312
3,3 = 0.064993
2,4 4,2 = 0.0375679
3,4 4,3 = 0.0251986
4,4 = 0.0024742
*****