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In a galvanic (voltaic) cell, the anode is considered negative and the cathode is considered
positive. This seems reasonable as the anode is the source of electrons and cathode is where
the electrons flow.
Reactions in which electrons are transferred are called oxidation-reduction (or "redox")
reactions. There are two parts to these changes: one atom must lose electrons and
another atom must gain them. These two parts are described by the terms "oxidation"
and "reduction".
Originally, a substance was said to be oxidized when it reacted with oxygen. Today, the
word "oxidized" is still used for those situations, but now we have a much broader
second meaning for these words. Today, the broader sense of the word oxidation is
defined as losing electrons. When a substance loses electrons, its charge will increase.
This may feel a bit backwards, but remember that electrons are negative. If an atom
loses electrons, it is losing negative particles so its charge will increase.
The other half of this process, the gaining of electrons, also needs a name. When an
atom or an ion gains electrons, the charge on the particle goes down. For example, if a
sulfur atom whose charge is zero (0)(0) gains two electrons, its charge becomes (−2)
(−2) and if an Fe3+Fe3+ ion gains an electron, its charge changes from +3+3 to +2+2.
In both cases the charge on the particle is reduced by the gain of electrons. Remember
that electrons have a negative charge, so gaining electrons will result in the charge
decreasing. The word reduction is defined to mean gaining electrons and the reduction
of charge.
actually it is not best cathode the best cathode is KrF2 because of its high +ve SRP
value . though graphite is widely used because it is also a good cathode , cheap , can be
found in adequate quantity , has a large surface area .
Magnesium metal is an ideal rechargeable battery anode material because of its high
volumetric energy density, high negative reduction potential and natural abundance.
Similar products
Dating back to the 19th century, metal-air batteries are old technology. Commercially,
they have been in production for almost a hundred years.
Products like toys and other lamps similar to SALt that use similar technology are
already on the market. In the United States, a company called MetAir markets a
“personal portable power system” with the same core technology, using zinc-air
batteries as its energy source.
The MetAir power system is designed for emergency and off-grid power supply, with
accessories such as waterproof LED lamp, AC power inverter, multiport USB charger
and cigarette-lighter adapter.
Some toys using saltwater for metal-air batteries are even sold on Alibaba, an e-
commerce company founded by Chinese businessman Jack Ma, who was onstage with
Mijeno and Obama at the Apec meeting.
“(It’s) not for everyday lighting, but for emergencies … It’s a fancy product,” he said,
adding that it is still expensive compared with other sustainable technologies, such as
solar power.
“Ecologically designed is questionable when your target is daily lighting,” he said.
“It’s very convenient for emergencies … (when) the goal is for the lamp to last a
couple of days.”