a8 de of C, Hand N contains 20% 2a es eae WEEN o (3 10 @ 6 (WB JEE 2009) > 1 atne (= 127 coisas 254 grams of fone and 8 30. Any ts formula coud be (@) 0s © 10 © 10s @ 10 sn, eget ound to have the formu (CO), ts WD. i 70. The value of must @? mn as 6 32, The percentage of Se in peroxidase anhydrous enzyme is 05% by sreight (atomic weight = 78:4) Then minimum molecular weight of peroxidase anhydrous enzyme is (a) 1-568 x 108 (B) 1-568 x 10° (©) 1568 @ 3136 x 104 1.10 STOICHIOMETRY AND STOICHIOMETRIC CALCULATIONS 1.10.1. Involving mass-mass_ relationship 1. A metal oxide withthe formula M,O, is reduced by H to give Aeatata and wate, 0-1596 g ofthe oxide required 6 mg of Hy fer complete reduction. The atomic mass ofthe metal is @ 79 © 558 © 87 @ 116 2. IAL, Zn and Fe scraps had the same rate per kg then forthe Treatcton of Hy by ation of dilute H,S0, {@ Fe wil be cheapest and Al wil be costliest {@) Alwill be cheapest and Zn will be costliest (© Fe will be cheapest and Za will be costliest {@ Za will be cheapest and AL wil be costliest 1, intone of Nal and NaCl on reaction with H,SO, gave N0S0s ae weight of eignal mintre taken. The preemies Nat inthe inte is (@ 9238 @ 2638 (@ 6238 (@ 2838 on 1 oeee mantre of elem carbonate and magnesium eo 26 ga a mins Conant eign of 13g, Te atomic ee is rong Neate gees are 40 and 24 TC of alee owing weights expresses te Weil win tein de original mixtre? (@) 980 me (oy 400 mg © 1758 @ m8 ea me ad isobutane hen 5. 1PLPG eylinder contains a mintre of bay rane, en TELPG calinder sen that would be required for combusion Teg ott wil be @ 18k 27% 45K i 338K «6. St posse eniorate i 80% pure, then 48 & oa atomic mass of R= 39): wanna KIO, @) 1225 eof KCIOs Oe patKClO,—@) 980806 KCIO, 1 a ee mana nlp eset (0 he po- What quan, of amrirtent fo ewe solatonconsining action of NE Reo 3681 (80, = 12 Ny = 17) OSES 4. —_ ‘oxygen would be dhe aha Sa Id 1b (@ 22 ow, (©) 5288 @ 1056 g 8. 30 g of Magnesium an o rebel alte omy 8 Ea (a) 60 g of Magnesium oxide only (D) 40 g of Magnesium oxide and 20 g of Oxygen (©) 45 g of Magnesium oxide and 15 g of Oxygen (d) 50 g of Magnesium oxide and 10 g of Oxygen (Karnataka 9, Alumina (AI,03) is converted to aluminium inte Aly heating with carbon in the atmosphere of Np. How many grams of ‘carbon is required to convert 23 g of Al,O3 to AIN ? (@ 8g © Re © 15k @ 1028 10, 50:0 kg of No (g) and 100 kg of H (g) are mixed to produce NH, (g). The mass of NH formed willbe close to (a) 50 kg S2kg (©) S4kg @ 56 kg (NCERT Based) 11. The amount of copper that can be obtained from 100 g of copper Feacted, then the sulphate (CuSO,) is (Atomic mass of Cu = 63:5 amu) (@ 3788 (@) 3988 © 4128 (d) 424g (NCERT Based) 42. Chlorine is prepared in the laboratory by treating manganese Gioxide (Mn0;) with aqueous hydrochloric acid. How many grams of HCI react with 50 g of manganese dioxide (Atomic mass of Mn = 55 u) (@ 4208 © 6408 (© 8408 (@) 200g — (NCERT Based) 13. A 582 g silver coin is dissolved in nitric acid. When sodium Ehloride is added t0 the solution, all the silver is precipitated a ‘AgCL The AgCl precipitate weighs 720 g. The percentage of silver in the coin is (@) 603% © 80% (©) 931% (@ 70% — (AMU Engg. 2014), 14, 30 g of Magnesium and 30 g of oxygen are reacted, then the residual mixture contains (a) 60 g of Magnesium oxide only (©) 40 g of Magnesium oxide and 20 g of oxygen (©) 45 g of Magnesium oxide and 15 g of oxygen (@) 50 g of Magnesium oxide and 10 g of oxygen 15. The weigh of iron which will be converted int its oxide (Fe302) by the action of 18 g of steam on it will be (at. wt. of Fe = 56) @ 168g © Be ©) 28 (@) 21g (AIMS 2011) 16. The mass of CaO that shall be obtained by heating 20 kg of pure lime-stone (CaCOs) is @ N2kg © Bag (©) 1008 kg @ 168kg 17, 200 g of magnesium carbonate sample decomposes on sive carbon dioxide and 8: g magnesium oxide. What Percentage purity of magnesium carbonate in the @) 60 @® 84 © 15 @) 96 (At. wt of Mg = 24) (Res 18, ‘The mass of carbon anode consumed (giving only in the production of 270 kg of aluminium metal the Hall process is Lb 2b he the ad ad aa 15.e() se (o 180kg (Atomic mass: Al = 27) (AIPMT 2005) 1.x g of Ag was dissolved in HNO, and the solution was treated with excess of NaCl when 2.87 g of AgCI was precipitated. The tales of 8 a) 1088 ©) 2168 (2708 ( 1628 p77 gof Al (at mass = 27) will react completely with oxygen equal » @ Me Oss © 08 (@ Wg 1, What mass of calcium chloride in grams would be enough to produce 14-35 g of AgCl (At mass Ca = 40; Ag = 108) (a) S858 @) 8295 ¢ (16598 @ 1198 b. The weight of slaked lime necessary to decompose completely 107 fof ammonium chloride is () 1485 (@) 0378 3. The mass of oxygen that would be required to produce enough CO which completely reduces 1-6 kg FeO, (at macs Fe = 86) 8 (a) 40x () 480g © 5 (2) 960g M. What is the weight of oxygen required for the complete combustion of 2 kg of ethylene ? ) 28kg () 64kg ©) 96kg (2) kg S. The weight of calcium oxide formed by burning 20 g of calcium in excess of oxygen ts (a) Me " () 40 kg (@) 270kg (a) O74 8 @) $8 me 728 (kvPY 2012) %4. The amount of metallic zinc (Atomic weight = 65-4) required to react with aqueous sodium hydroxide to produce 1 g of Ht is (a) 275 () 981g (0 645 (163% (KvPY 2013) 2. The molar mass of CaCO, is 100 g. The maximum amount of carton dione that can be liberated on beating 25 g of CaCO, is (We () S56 @ 228 M.S of CaCO, completely reacts wi (2) 365 g of HCI (8) 365 g of HC (6) 0368 g of HCI () 730g of HC. (COMED K-UGET 2007) 20 mi. of acetic acid reacts with 20 mL. of ethyl alcohol to form fiiyl acetate. The density of acid and alcohol are 1 g/ml. and (07 pimL. respectively. The limiting reagent in this reaction is 2g (KVPY 2010) (a) acetic acid (b) ethyl alcohol (6) acetic acid and ethyl alcohol 4) exer (COMED K-UGET 2015) 1027 g of water ie formed daring complete combustion of pure Fepene (CH) the mass of propene barat is oor oe bie Me d) S65 (0) 0g (Kerala PET 2016) We me a Me a ar NOMS yes MIDUAU CAMERA 31. LAOH reacts with CO, to form LigCO, (atomic mass of Li = 7). The amount of CO; (in g) consumed by 1g of LIOH is closest to ©) 0916 ) 1832 (©) 0544 1088 (KvPY 2016) 1.10.2. Involving mass-volume relationship 32. What volume of hydrogen gas, at 273 K and 1 atm pressure will be consumed in obtaining 216 g of elemental boron (atomic mass = 108) from the reduction of boron trichloride by hydrogen ? (@) 7.2L ©) 448 (© 4b @) 896 (AIEEE 2003) 33. The decomposition of a certain mass of CaCO, gave 11-2 dmv of COz gas at STP. The mass of KOH required to completely Deutralize the gas is @) S68 () 288 © 25 (@) 20g (Karnataka CET 2006) 3M. The drain cleaner Drainex contains small bits of Al which react With caustic soda to produce H;, What volume of hydrogen at 20°C and one bar will be released when 0-15 g of Al reacts? (2) 606 mL. (&) 2030 mL () 1015 mb. (@) 502 mL 38. What volume of oxygen at 18°C and 750 torr can be obtained from NO g of KCIO, ? (@) 2.6L 277 (©) 326L (d) 427 (AMU Engg, 2013) 136. For the formation of 365 g of hydrogen chloride gas, what volumes of hydrogen gas and chlorine gas are required at NTP. conditions ? (a) 112 i 12 tt (©) 365 tit, 183 tit (@) Vit, it (Kerala CEE 2005) 37. 10g of a piece of marble was pot into excess of dilute HCI acid. ‘When the reaction was complete, 1120 em? of CO; was obtained at STP. The percentage of CaCO, in the marble is (a) 25% () 50% (©) 78% (@) 10% 38. H evolved at STP on complete reaction of 27 g of Aluminium swith excess of aqueous NaOH would be : : (@ 24 ) 48 (©) 672 (336 titres 39, The amount of zinc required to produce 224 ml of Hy at STP on treatment with dil, H3SO, will be (a) 065¢ (6) 65% (©) 68 (d) 0065 g 40, Assuming fully decomposed, the volume of CO, released at STP ‘on heating 985 of BaCO, (Atomic mass, Ba = 137) will be (a) O84L (6) 224 (©) 4061 @ aL 41, When 1.0 g of zine is treated separately with excess of H,S0, and ‘excess of NaOH, the ratio of volumes of H, evolved is @ it 1:2 zt ac4 42. The volume of Cl, at STP obtained on reacting 4-35 g MnO) with cone. HCI (at. wt of Mn = $5) is (a) 448 litre () 228 tite (6) 112 tite (4) 0-86 lite we Be ha Ba Ma Ta 2b ven z3. The volume of ox; Ss Te rue of apg ST ei ha 24 of om to aa 0) 8964 % Wass a dd) 448L (KVPY 2014) When 224 Lf Calg SP comity 196 of COs sat STP and 73 gk water we pou Mhe wie of oyee6 gas at STP consumed in the reaction is closest to 2 ome (a) 89-6 L (6) 2b (c) I344L (d) 224L (KVPY 2015) 12 g of Mg with excess of HCL at NTP gives (@) 11-2 dm? of Hy (b) 22-4 dm? of Hy (©) 5-6 dm? of H (d) 15-6 dm? of H (COMED K-UGET 2011) ts with required amount of meth! of methane gas at STP is. 46. 375 mg of an alcohol reac ‘magnesium bromide and relases 140 The alcohol is (@) ethanol (®) butanol (©) methanol (a) n-propanol (©) phenol (Kerala PET 2016) 10.3. Involving volume-volume relationship 10 litres of dihydrogen and 30 litres of for reaction which yielded only 50% of the qaeeSred product. What will be the composition of the Exscous oxPrcre under the aforesaid condition ia the end ? {@) 20 lies ammonia, 20 litres nitrogen, 20 lies RyaroEe® () 10 litres ammonia, 25 litres nitrogen. 1% Hes hydrogen (©) 20 litres ammonia, 10 litres nitrogen. 49 Hees hydrogen smnmonia, 25 litres nitrogen, 15 litres hydrogen on heating forms P and Hp, The volume change ia the reaction is = (a) an increase of 50 ml (© an increase of 150 ml 10 litres of O2 gas is react totes of each gas present atthe 10 litres, COz = 20 litres 0 litres, CO = 30 litres = 20 litres, CO; = 10 litres = 10 titres, COz = 20 litres 0 litres, CO = 10 litres onygen by volume, The volume of air ins nearly 20% eat combustion of 100 cx of acetylene will be (8) 100.ce fe) 250¢€ (a) 1250.ce ne of oxygen gas (Oy) measured at °C and T atm is ‘completely 1 L Of propane gas (C3Hy) measured conditions ? 47. In Haber process. 3 dinitrogen were taken (b) an increase of 100 ml (d) a decrease of 50 ml fed with 30 litres of CO at STP. The a. ind of the reaction are 51. 3 @ gp. so ee of COs Pst ve fd tek, The volume of CO evolved is (@ Wee © 306 @ We eet tty and 112 L of Chy are mixed and ex 1 o eectnimtes nent me ) Wee ee ee a OSL Hy, 224LHCI ld) 24LHCL . Bd Me a a pam i ss os ots 4, In Haber process. 8: ‘ammonia whose volume ‘would be (a) one fourth fe) the same (d) three fourth 155, 100 mL of PH, when decomposed produces hydrogen. The change in volume is Phospbonss ang (a) 50 mL increase (&) 500 mL decrease (c) 900 mL decrease (A sil 16, What willbe te volume of the mixture after the reaction? GNU (11) + (@) HEL (1S L) ——> NACI) (@) 15L @ OSL jib (ol cous nitrogen and hydrogen rac yy 78 see compared to that of reactants 6y°2% Ot (b) one ball (PMT 2003) srs he nacions:C0+ 1 0; C03 304 Ns +0}—280, sninng CO ond roped wl 0; nse 10 mL of mixture con Ao ind NO on combustion. The volume of Nin de mire will be @ 72a @ 172 mL © 4m (@ Tm_ = (EAMCET 2014) le relationship (0:2 mol of NasPO,, the that can be formed is 1.10.4. Involving mole-mol ‘58, If 0-5 mol of BaCl, is mixed with maximum number of moles of Ba;(PO.)2 (@) 07 (©) 05 (©) 030 @ 010 159, Inthe reaction, 4 NH + 5 > 4 NO + 6 HO, when one ole of ammonia and one mole of oxygen are made to react completion, then (@) 1-0 mole of H,0 is produced (B) all the oxygen is consumed (©) 1S mole of NO is formed (@) all the ammonia is consumed (DCE 2006) lowed to react to fora 60, 4 moles each of SO, and O, gases are all 50, in a closed vessel. At equilibrium 25% of O2 is wed TH total number of moles ofall the gases at equilibrium is () 65 () 70 70% (@ 20 (Karnataka CET 2000) |. How many moles of KI are required to produce O- moles of KyHsl,? o (a) 04 ©) 08 © 32 @ 16 62. One mole of magnesium nitride on reaction with an excest of water gives (@) 1 mole of siti acid (@) 2molesofamnonit aay (AFMC (9. One mote of calcium phorpide oa reeon with exis of wate (@) one mote of phosphine (©) 0 moles of phosphoric acid (©) 10 moles of phosphine (2) one mole of phosphorus pentoxide Ba 59.5 (a) 1 mole of ammonia (©) 2 moles of nitric acid oa 0.5 50d O15 She adSg enon nth 30110 ml sm 64 Crpydrogen gas produces {@ one moe of ammonia ; © Jo 10 molecules of ammonia (0) 2mokes of ammonia (a 301108 mca of emia (&vPY 2009) jum reduces manganese dioxide to manganese at hi 65 Alumina moun of aluminium required o reduce one “pole of manganese dioxide is (@ 12 gram mole (@) 3/4 gram mole (©) 1 gram mole (@ 48 gram mole (KVPY 2009) so na closed vessel, 5 moles of Ax (g) and 7 moles of By (g) are ‘Bed inthe following manner A, (g) + 3 B, (g)—> 2 AB (g) ‘Wat isthe total number of moles of the gases present in the UMiner atthe end of the reaction ? @ 28 © 73 © 143 @ 8&3 (EAMCET 2014) 1, inthe reaction 4A + 2B +3 C—» AgB,C,, what will be the aber of moles of product formed, starting from one mole of A, 06 mole of B and 0-72 mole of C ? (@ 025 @ 030 (9 024 @ 232 95. Involving mole-mass relationship . Consider the following data : (EAMCET 2014) Atomic weight Element A 2 B 355 ‘A and B combine to form a new substance X. If four moles of B combine with one mole of A to give one mole of X, then the weight of one mole of X is @ 4758 © Bs © 14g @ 1668 How many molecules of CO, are formed when one milligram of 100% pure CaCO; is treated ‘with excess of hydrochloric acid ? (a) 602 x 107! (®) 6.02 x 10 (©) 602 x 10” (@) 602 x 108 (Kerala PET 2013) ‘The molecular formula 6f a commercial resin used for exchanging fons in water softening is CgH,SO3Na (mol. wt. 206). What Would be the maximum uptake of Ca* ions by the resin when expressed in mole per gram resin ? 1 1 @ 95 © 506 2 L © a5 Om GEE Main 2015) 06 g of carbon was bumt in the air to form CO,. The number of molecules of CO, introduced into the air will be a) 6.02 x 10 @® 3.01 x 10 6) 602 x 1022 (@ 301 x 102 How many moles of lead (I1) chloride will be formed from a raction between 6-5 g of PbO and 3-2 g of HCI? a) 0044 @ 0333 ¢) 0011 @ 0-029 (AIPMT 2008) 0 8 of hydrogen and 64 g of oxygen were filled in a steel vessel ae ‘Amount of water produced in this reaction will be : 2) 3 mol ) met {EIDE |BNCO = DU SeRG (Se 74. The moles of O, required for reacting with 6-8 g of ammonia @ 05 7. 10 g of MgCO, decomposes on heating to give 0-1 mole of COz and 4 g of MgO. The per cent purity of MgCOs is ©. @ 24% ) 44% © 54% @ 18% © %4% (Kerala 2017) 1 76. IF 15 moles of oxygen combine with Al to form AljOs, the ‘weight of Al used inthe reaction is (AI = 27) @ 278 © 54g © 4058 @ 8g 77. When 262 g of xenon (atomic mass = 131) reacted completely with 152 g of fluorine (atomic mass = 19), a mixture of XeF, and KeF, was produced. The molar ratio XeP; : XeF is (@ 1:2 @ 1:4 () Lil @ 1:3 (KVPY 2015) 78. One mole of one of the sodium salts listed below, having carbon content close to 14:3%, produces 1 mole of carbon dioxide upon heating (atomic mass Na= 23, H = 1, C= 12, O= 16). The salt is (@) CH,COONa (@) NaHCO} (© HCOONa (@ CH;COONa —(KVPY 2016) 1.10.6. Involving mole-volume relationship 79, When 1 L of CO, is heated with graphite, the volume of gases collected is 1-5 L. Calculate the number of moles of CO produced at STP 1 28 © T3 © 1 ob CET © a @ (EAMCET 2014) 1.10.7. Involving pressure-pressure relationship 80, A 100 mL vessel contains hydrogen at a partial pressure of 600 torr and oxygen at a partial pressure of 400 tort. An electrical spark causes the gases to react as L Hyg) + 509 (8) —>H,0 (@) Which of the following statements is correct, ifthe reaction goes to the end? (a) Partial pressure of Oy is 100 torr at the end. (&) Oxygen is the limiting reagent. (©) Partial pressure of steam is 900 torr. (@) Total pressure at the end of the reaction is 1000 torr. 1.10.8. Involving more than two quantities 81. In the reaction, 2 Al (s) + 6 HCI (ag) —> 2 Al (ag) + 6 CI" (ag) + 3 Ha (8) (a) 112 L Hy () at STP is produced for every mole HC! ( consumed (®) 6 L-HCI (ag) is consumed for every 3 LH, (g) produced = (©) 336 L Hy (g) is produced regardless of temperature pressure for every mole of Al that reacts (@) 67-2.L Hy (g) is at STP is produced for every mole of Al