wv INFORMATION AND COMMUNICATIONS UNIVERSITY END OF SEMESTER EXAMINATION ADVANCED CHEMISTRY TIME: 3HRS DATE OF EXAMINATION! DECEMBER 2019 INSTRUCTIONS 1. Answer ONE COMPULS RY Question in Section A 2. Answer any FOUR (4) Qui \ in Section B. 3. ALL Questions carry (Lomarks) 4. Please write as clearly as possible as ilegible handwriting cannot be marked 5, Number the answers to the questions clearly before answering 6. IMusrate your answers were possible 1. Non-programmable scientific calculators are allowed DO NOT TURN THIS PAGE UNTIL YOU ARE TOLD TO DO so.‘SECTION A: ANSWER ALL QUESTIONS IN THIS SECTION. EACH QUESTION CARRIES 2 MaiRKS L 4+ Wat your understanding of Lewis str and what is signifies 5 om sma i. Draw the Lewis stitute lloving [2 mar NOs = » coc 2 RSE masresiam has thre ble stpes withflowing masses and abundances. [ees | Maxam) * Mg 133.9880 Mg 249858 “ue 259826 Caletate the eave atoms mass af magnon 3. CD __* Gretna. se sybase ison oie by ec te ut 2 quantum numbers (4 marks <+ i Amelement 7 telongs othe thd prod and ih group ofthe pride Table ee 28) Whats its atomic number? iWI1O ') Give the name and symbol of sn element which shares the same period bo and another element which shares the same group wth element Z [marks SECTION B: ANSWER ANY FOUR (4) QUESTIONS OF YOUR CHOICE. EACH QUESTION CARRIES 10 MARKS fOr Gg yl State the Heisenberg uncertainty principle. | 1 mark] 'b. Determine the frequency of light with awave length of 4257 = 10cm, o [A mark] List down the order in which orbitals generally fil, rom the 1s tothe 7p orbital. [2 marks} Given that the electron configuration for phosphorous is 122¢2ph3s25p, answer the following questions: [ 6 marks] oO {ime Cl=C-=0 : li cliil, What is its orbital notation? 5. How many unpaired electrons does an som of phosphorous have? ‘What ists highest occupied energy level? Vi. How many inner shell electrons does the atom contain? 2 a Balance the following chemical reactions [4 marks} © 1 KNOs +4005 —>4:C05+ HNOs S ii, So0r + Hh > Sn + HO iv. BasNs +Hs0—5B4OH) +NHs b. What mass of CO is reyuired to react with 25.13mg of FexOs according to the chemical reaction below? 5 > FQ; + cq fe fo: (2 marks} How many molecules of NH; are produced by the rection of 7 Mols of Ca(OH)? aecording to the following [4 marks} he (Q\HIn$04 + CalOHT, > NHs+ CaSO, + HO ery 1 ce 5 Vr eo tiy Bt wo 241g pee Aad I tO Ae 1. Define the following terms: i, Electropositivity ii, Bond polarity iii, Tonization energy +) Whats the difference benseen onic bonds, covalent bonds anc polar covalent bonds? Give two examples of each ©) Draw Lewis structures foreach ofthe following: [4 marks] LBS BR ii, XeFe iv Ps 4. Artange each othe following inthe order of increasing electronegativity ‘Seypen Nog, Lion, Fancum [3 mari] Te a tations were observed the Haber proces a 127%C NH =3.1 «10? mol/L Te=81 10" mol3.1 * 10° mol 4) State the reaction conditions and the catalyst needed fortis reason to take place [Smarks} by Hence, allt he egitiam constant forth Habe roses a 127 mart ©) Predict the shift, whether Ie rght or no change that would occur if i) Temperature is increased ii) Pressure increased iii) Volume reduced [Smarks] Caleulte the concentration of Hydrogen ifthe concentration of sarcoma is reduced to 2.0 10'ma/L while the otber conditions are kept the same [2marks} a Seton sas [3 maha i Gate's i Avopado'sLaw 6° ii Boyes soownasinesne canbe eed roe 'b. Caleium Carbonate CaCO also chemical with wide variety of uses. The calcium oxide (lime), an industri ‘balanced equation forthe reaction follows. [3 marks) cacox(s) ——— C2018) + COX) How many grams of calcium carbonate must be decompose to produce 5.00 ‘of carbon dioxide gas at STP? GCS ae | )) {| 14 ! 14 , ae i SpCpatle —t & TAHe fae ) ot : 2 g | ao 6 2