+ 100 W= WAS tl Te OAK oath will 2 in gusca state Pe* 80.0% y ~ ehone™ weather oy since Te Te ond °4Pe, omume, Te* G00.04 Pee 88.99b0r 2 1. Estimate the fugacity of (i) (pure) ethane and (ji) (pure) ethanol at 300 K and 50 bar. (You may want to use the generalized correlation for this calculation.) Fugacity is a — “> measure of “escaping tendency” of the substance at a given temperature and pressur Do your numbers make sense? That is, which of the two substances has higher a fugacity? Why? Molecular arguments are appropriate here. ee AJ cae a i, Figura 3.15 2 2-Ferm Viriol oko? he BMA {20 pts} te ao 9: "lo = exp BES AGE B+O'+20" wr=0089-BE Ot: 19g, HH > ere 6: cet DeNWODMH B> 088 B= -2510 B= one HL ¢ 2 eFH00(50 bor) = 33.74 bor Ti. B=% seep OrSRE B-Brrwe Se -aisH 9 B* 985 Be-gat\ > -1. RBA = 1956 (So bor) = &.FFbar “> Bthane has the higher Agacity, whieh dee male Seoe because ronal nos © hydrogen bond | do interMdeculor oftradkiens ane Increaged . Recavee oi othaest mcs «ald hve \ese oF an toning tardency and a ommller Raggcity. Ethane , withast the hydrogen lend Loud ove a.grearer Agpeity = 1.510 We Vgs saee ca $= exo fz} ee Zl - at 2-128 D rex (Rd Oe SSS2. The molar enthalpy of a particular binary liquid mixture at T and P is given by: H = Hix, + Hoxa + A x17 (b) Verify that your results for part (a) satisfy the summability relation, AA (©) Check your results for limiting cases. (a) Write down an expression for the molar excess enthalpy, H®. if the parameter A is wae positive, at what composition does the molar excess enthalpy attain its maximum SS (a) Determine the implied expressions for partial molar enthalpies of species 1 and 2, ( , value? : A hen, doo, vying 24 Bt] ne Hime bint Anetcy Be, OF Hat Ane (a - OMe Hi rang ACE)my Te She, Ane (1 De) EM 0+ An, (28- Fy Hye Acs? (1-242) a He 2A x, (40> x4) We eHie 2Ang, (lex) ATH 2A? to = boHE XH # x A, Mix Haat 2 + Hixab axa x(t dea) BEML Bt DDK HARE = LASEK WE xy rake tA OO & Tiny HCHO ACNE MAE relies pence tat Hoth uhen it. 10 foking inte ace nt only ig, Ha + Ha ALO} (1-20) = Hy” Hes pore opecies i” DHFS HAH Abmig 20 (\-2m rae) Gat Haas Hane Anan SHE Ha Hak, t Amt AR? og Hy Hingt Hata t Amin 2AM + Ax? PIF xP HE would become negative because x? qrare faster than Xx” e its ) Bot IE PL HE Wold Otay postive becowse and couse HE to reach ao ae " wring Onli apee fren tron 2) ie &® xe! s nok hue, HEL AH: Hey. A= Outta) = AK a6 3. A liquid mixture of ‘cyclohexanone(1)/phenol(2) for which x; = 0.5 is in equilibrium with its vepor at 144 °C, Determine the equilibrium pressure P and vapor composition y, from the following information: e * Excess Gibbs energy is given by the Porter equation: GF/RT = Axixa po) * At l44 °C, Py**= 75.20 kPa and Pp" = 31.66 kPa + The infinite dilution activity coefficient of cyclohexanone, 71°, is equal to 0.0821 Se Aan [23 pts} BE axon, > Ar %n) dott fi I= Sm *Am(k- Ha) Wn YZ Ax (ex) 2 Ax? 1 ta= Any Me) e Ag (Ima) Axe In 0821 = AUN)* (x0) x,‘ At-24N998 ~~ KV, 9,0% = y.? xaVePater sya? pe x Kor + x tee KEM (48.20 hPa) + @7 24°55") (31. viokPa)) 5 (ARN G.I0 yy Hee ed2M he wacko, —b MK Lo Chae mixture, Hp rene —> 8 4, Two (2) kmol/hr of liquid n-octane (species 1) are continuously mixed with four (4) kmol/hr of liquid iso-octane (species 2). The mixing process occurs at constant T and P; mechanical power requirements are negligible (A) Use an energy balance to determine the rate of heat transfer. (B) Use entropy balance to determine the rate of entropy generation, in WiK. Please state carefully and justify any assumptions you make. G since n-octane and iso-octane are 2 dimilar, we can as3ume [23 pts] frat Yay will enix ideally G Qu: AlaW)es WO Wecause mm mechanical work ‘s ~is Z twin =O because it's ideal & AlAt|e, =o 1:0] zero hoot transter o, be bot AlnDles B= BING Tet, one = @000"™/ne = N(Admix) ASmix=-AE xiln x, ASmix® “ACE In B+ Sin 4) = 8.2929 enol 96 + (6.2929) (000 Yor )(!™/uen s) > 8.8206 Thy )10 5. Species | and 2 are chemically similar and form an ideal mixture. What is the partial molar entropy of species 1 in the binary mixture at a given composition {x1,x2}? (Derive an expression.) Is the partial molar entropy of 1, 5} in the mixture higher or lower than the pure componeat entropy, S}, at the same T and P? Comments? 5 . feed. - 3 P len, Sere ne m0 {10 pts} \ 7) / & . Phyo ina PS) in the misture should elvan) tron the pure comomnant 5, because 0 derivative ‘io covallly gmallar then its ariginol valve ps is.