72525 /°T0524 CHEMICAL ENGG. THERMODYNAMICS Il cnen Te SEMT | casas) mry peers Tamms asco am (3 Hours ) [ Total Marks : 80 N.B. : (1) Question no.1 is compulsory. (2) Attempt any THREE of the remaining questions. (3) Figure to the right indicates full marks. (4) Assume suitable data wherever necessary: f O 1, a) What are the desirable properties of the refrigerant? ® b) Discuss chemical potential as criteria of phase equilibri c) Estimate the entropy change of mixing. when 2.8L nand.19.6 L of hydrogen at 1 atm are mixed to prepare 2 gas mix! Explain in brief boiling point diagram. 5 aan d 2, a) Discuss in brief phase equilibria in Single it system. 10 b) Inthe synthesis of'methanol from CO an 00K and Sbar, estimate the 19 degree of conyérsion of co if the reas with mixture of CO and H, and methanol in the mole ratio of 1 2. Given: K= 4.973 x10. 3. a) What are the different types of fegigetation? Explain any one in detail. 10 b) From VLE measurement x1 Benzene system at 318 K and 40.25 10 KPa, it is found that wilibrium with liquid containing 38.9% be benzene: The con ¢nzene in vapor is 56.6%. The system forms an azeotroy . At this temperature the vapor pressure of ethanol and bt .9 KPa and 29.6 KPa respectively. Determine position and total pressure of Azeotrope. The system is non ideal; It cansbe .d that the activity of the system can be expressed el. techniques forthe estimation of critical parameters. Explain ‘i 10 Itaneols reaction occur in the reactor, b) 10 5 the equimolar mixture of A and Bare fed to the reactor for producing D, ® Estimate equilibrium conversion at 1 bar. The reaction mixture is assumed tobe an ideal gas mixture. ‘a) Explain in brief UNIQUAC equation and NRTL equation, 10 | TURN OVER]6. b) a) b) stems. Discuss the phase rule for non reacting and ee ane number of degrees of freedom for the system CO,CO,,H,,H,O, and CH, in chemical equilibrium. Explain heat of reaction in detail. cay hey The vapour pressures of acetone (1) and acetonitrile by the Antoine equations :- ® In P;’ = 14.5463 - 2940.46AT - 35.93) InP,’ = 14.2724 - 2945.47. Le 49. oe where T is in K and P is in unde pluton enmby these are ideal, calculate :- i) x, andy, at 327K and 65 kPa, ii) Tandy, #63 Weand x, =),