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VIBRATIONAL SPECTROSCOPY
S. SANKARARAMAN
DEPARTMENT OF CHEMISTRY
INDIAN INSTITUTE OF TECHNOLOGY MADRAS
CHENNAI 600036
sanka@iitm.ac.in
O H OH
NaBH4
O O
OC2H5 OC2H5
SnCl2
NO2 NH2
Absorption due to vibrational transitions of each bond type is different and they are
confined to a small portion of the IR region.
For example CO2 molecule has 4 degrees of vibrational freedom corresponding to two
Stretching mode and two bending modes of vibration.
C C C C C C 1 K
C-C 2150 1650 1200 cm-1
2 c
m1m2
C C H C C H C C H
= m +m
1 2
C-H 3300 3100 2900 cm-1
C H C C C O C Cl C Br C I
C-X 3000 1200 1100 750 600 500 cm-1
For a particular vibration to be infrared active there must be a change in the dipole
moment of the molecule during the vibration.
Difference bands: Similar to combination bands. The observed frequency is the difference
between the two interacting frequencies.
interferogram
Peaks at 1603 and 3062 cm-1 are used to calibrate the spectrum
Sampling techniques for IR spectroscopy