390°C, c kapOoHaTOM KasIMa — 9BTeKTHKy C TeMMepaTypo naBleHHA 360° C; 22% no macce K,CQ3. Tugpoxcua Kanus nony4awrT: 1) anexrponw30M Ro- THEIX pacTRONOR xTOpuyA uNY KaphonaTa Kanus c xKenewrmM (quadhbnar- MeHHBIM MeTOM) Huu PTYTHBIM KaTOJ{OM, C HCNOML30BaHHeM HOHOOOMeH- HEIX McMOpaH; 2) B3aHMoyelicTBHemM BoqHoro pacrBopa Kap6oHatTa Kalba M THApOKcHfa KawbUMA MM peakuMe KOHUCHTpHpoBaHHoro pactTBopa cysbibata Kanua c rMapoKcuyom Gapua mo cxeme K,CO; + Ca(OH), = 2KOH + CaCO, OOpasyroumiica unetpaT (pacTBop rHqpoKcuya Kalua) nocme oTTe- JeHHA CooTBeTCTBeHHO CaCO; umH BaSO, ynapHpaloT B HHKeNeBBIX pe- akTopax Mo, BaKyYMOM, JIA yaneHuaA cneyoB Bard THApOKcHA Kanna BblepKuBaoT npH 360—400° C B BakyyMe; 3) bumbTpoBaHHeM BOQHOTO pacTBopa cynbdara Kana Yepe3 aHMoHHT B OH -cbopme. Tuapoxcng KasIHa MpHMCHAIOT B MpOH3BOACTBE X%KHAKOTO MBIJIa, Mep- CepH30BaHHOTO XJIONKa, coeqHHeHHit KaslHA, B UICIOYHBIX AKKYMYJIATOpAX. Ox apaaetca abcopOeHTom cymEuya BOMOpOma, AHOKCHOB Cepbl KH yriie- poda, OCYIMaIOIWMM areHTOM JIA AMMHMaKa, TEMHOKCHa a30Ta, cbocuna M Apyrux He pearupyiouvx ¢ HM ra3oB. 2.3. XJIOPH KAMA @u3nKo-xumuyeckHe cBOiicTBa, mpHMeHeHHe. XnopHyz Kanna KCl, GecubeTHble Kpucramibl C KyOH4ecKoOH pemerKoH (a = 0,629 um, z = 4, kyOuyeckant Mogu@ukauaa Tuna CsCl. Temneparypa Kumenna 1500° C; moTHocts 1,989 r/cm’; Cp = 51,30 Dpk/(Mone'K); AH}, = 26,32 K]bk/mMonb, AH: op = —436,49 Kbk/monb; Sioa = 82,57 [I>x/(mone:K). Temneparypa napie- Hua 776° C. PactsopuMoctb KCI B Boge (r B 100 r): 28,1(0°C), 34,3(20° C), 40,3(40° C), 56,2(100° C). Tlonutepmuueckas muarpamma pacrRopumocTu B cucteme KCI—NaCI—H,0 npupegena ua puc. 2.3. Temneparypa naB- nenua oprexruxn (24,6 r KCl 8 100 r Bogut) -10,7°C. Temnepatypa KH- NeHHA HaCbIWeHHOrO BogHOro pactBopa (58,4 r KCI B 100 r H20) 108,59° C. Thioxo pactBopuM B aMMHake HM MeTaHOlIe. XNOpHy KanHaA ABIACTCA OCHOBHBIM MpOMyKTOM KaIM#HOH MpOMBIL- NewHoctu. Oxono 95% xnopHya kava MpHMeHseTcA B KayecTBe yoOpe- HMA, @ OCTANbHOe KONMYECTBO MepepaOaTEIBalOT B COeIHHEHHA KasA, 1088 & 8 NaCl, %(macc.) 5 10 15 20 25 30 35 40 45 50 55 KCl, %(macc.) Puc. 2.3, Tlonntepmweckas oMarpamma pacTaopuMoctu B cucreme KCI—NaCI—H,0 TIpMeHseMbIe B pa3NW4HEIX OTpacnax HapoyHoro xo3aiicrka (KOH, K,CO3, KNO3, K2SQ4, KCN, KCIO; u ap.). Cornacno tpeSosannii gefictyrouero TOCT 4568—83 (ra6m. 2.3), TipewycmarpuBaerca MpousBoscTBo xNopuza kanua Mapok K (kpucramnu3za- uxeii H3 pacTBopos), ® (roTayHoHHEm oboramjenHeM KaTHHHEIX pyf) Wt TeXHMYeCKHX WeneH HM rpaHyNHpoBaHHOTO HAM KpyNHOKpHcTanmH4ecKoro MIpogykta Ja cenbcKoro xo3aiicTBa. XOpHa KATA, BEIMTyCKaeMbI DA CENbCKOTO XO3AHCTBA C WCNIbIO HCKIOYEHHA C/IEKHBAeMOCTH, OOpabarbiBacTCA amm¢paraveckHMu aMHHaMi WK JpyrHMi KOHJMIMORMpyIOWIMMH 206aBKaMH. Ta6nnua 2.3, Tpe6opanua K KaiecrBy xnopHaa Kaus Codepowanue @ nepecieme Ha cyxoe setyecmso, %: KCl, ne Menee NaCl, we Gonee Baru, He Gonee He pacTsopuMoro B none ocTaTxa, He Gonee Tpanyst pasmepom 4 ma, ue Gonee or 1 go 4 MM, He MeHee Mexee 1 MM, He Gomee 98 | 9st | 95t1 | gitt | 95e1 | oit1 14 | ast | 4st1 | 741 [He Hopmmpyerca 10 1,0 1,0 1,0 10 | 10 0,2 [He Hopmupyetcsa He Hopmupyetca Tpanynamempurecruit cocmas, %: He nopmupyerex 5 5 » 90 | 90 » 5 5 109Cc Cnoco6n1 nonyyenna X10- puaa Kanna. Xnopuy Kanna TIpOW3BOLAT B OCHOBHOM BYMA croco6amu: 1) ramypra4eckHm S75 4 2) dnorauvoHHEiM. Tanypruyecku cno- co6 (pacrBopenvem u pa3- TenbHott KpHcTasn3alHeii) OCHOBaH Ha CBONCTBaX CHCTeMBI KCI—NaCl—H,0 (om. puc. 2.3), a HMeHHO Ha pa3- AW4HOH pacTBOpHMOCTH B Boye xJOpHyoB Kana H HaTpua. H3 WaHHEIx prc. 2.4 BARHO, 4TO B SBIOHMYECKOM pacTBope mpi NOHWKeHHH TeMMepatypb! co- epxkanve XjIOpHya HaTpHa Puc. 2.4, Pacrnopumocts m cucteme ysenmuupactca. DuryparnsHaa KCI—NaCl-H,0 npu 25 n 100°C TOuKA CHCTeMBI, COOTBETCT- BytOlleli COCTaBy 9BTOHHYeCKO- To pactBopa Ejo9 mpu 100°C, B npouecce oxnakqeHHa pacTBopa, Hacsl- uenHoro KCl u NaCl, B ocagox BEIMaqaeT B OCHOBHOM XOpHy, KaIHA, B PpacTBope ocTaeTca xNopHy HaTpus. B mpouecce oxnaxkjeHia sBTOHMYeCKOrO pacTBopa Ejo9 ot 100 go 25°C B pesynbrare OcwKIeHHA XOpHa KAMA COCTaB pacTBopa OyneT MeHATECA — ero HrypaTHBHad TO¥Ka MepeMeCcTHTCA BAONb My4Ya Kpuc- TammM3ayHH C, oT Ejoo WO n. Ecnu nocne oTgenenua KCI B Bugle ocanka pacTBop cHoBa Harpetb yo 100°C, To on GyneT CHNbHO HeHAaCBILeHHEIM KCl 4 mHuIb HeMHoro HefOHacEIMeHHBIM NaCl. Ecau 2ke 3THM pacTBO- pom o6pabotaTs wcxOgHEI CHIERHHUT, TO B HeM GyyeT pacTBOpsTECA mipeumywecrseHHo KCl. Mocne orgenenus TBepgoro octarka NaCl BHoBB 6yner o6pazopEiBareca ropsuHii sBTOHHYeCKHH pactBOp Ejo9, H3 KOTOporo B Mpouecce oxnaxgenua BEIjenaetca KCl. TIpumensa taxoi uHMKnuue- ckMM Mporecc, OcyujeCcTBAAIOT B MpOM3BOACTBe pasqeneHMe CHIBBAHUTA wa KCI n NaCl. TlomHoe BbyjeneHHe XNOpHza KaHA H3 CHIBBHHHTa oOecneyMBaeTCA IIpH YCHOBMM COOTBETCTBHA KONMYeCTBA BBOMMOFO B CHCTeMy XJOpHaa kal“ KONMYeCTBY UMpkynMpyroulero pacrsopa. Ecnv mpHHATb oKpyrieH- HO COCTaB MCXOqHOFO CHIbBHHHTa 25% KCl u 75% NaCl (TouKa S), To TouKa cMeceii ero C MaTOYHBIM paCTBOPOM mn pacnonoxkaTcA Ha MHHMH nS. Heo6xonuma Takai CMeCb, KOTOpad MONHOCTEO pazyensmach Obr Ha pactBop Ejo 4 Teepe NaCl. Stomy ycnosmio coorsercTByet cMecb coctapa K, nesxatmero Ha nepeceyenun nunnn 7S u EjoB. Cnegoparens- HO, A MOMHOrO pacTBOpeHHA xXNOpHya KAA M NOMyYeHHA NpH 9TOM 103BTOHHYECKOFO pacTBopa Ej99 HeoOxoquMo ObpabaTbiBaTb CHABAHUT Ta- KHM KOJMYECTBOM MaTOYHOTO pacTBOpa cocTaBa n, YTOOLI OTHOLIeHHe KO- aM4eCTB 1:5 PaBHANOCh OTHOLMeHHIO oTpesKoB SK:Kn. Tipu paGore ¢ CHIbBHHHTOM, 3arpa3HeHHBIM KaDHaJWIHTOM, B Mpouecce peulMpKY/AWMM pacTBOpa B HEM NOCTOAHHO HakalWIMBaeTcA XNOpHA MarHHa. B mpucyTcrBHM B CHCTeMe XNOpHya MarHHa pacTBOPHMOCTb xXNOpua Ha- TpHa CHWKaeTCS, B pe3yNETaTe yero B Mpolecce 3arpx3HeHua pacTBopa XOPHOM MarHHst CBepx OMpey{emeHHoro mpeyena B WeneBo nponykKT Ha- 4HHAcT MepexouTL 3HaqHTeNBHOe KOMMYCCTBO XMOpHa Harpua. Ito npu- BOAHT K CHHDKCHHIO COfepxkaHHa XOpHya KasA B WeNeBOM npogy«te. Ilo- 3TOMY 110 Mepe HaKOMJIeHHA B CHCTeMe XJOpHa MarHHA pacTBOP BBIBOLAT 43 npouecca. C yembio OOHOBMEHMA pacTBOpa NpOBOART ABYXCTyNeHYAaTy!O ynapky. pw 3ToM nocite nepBot cTaquM ynapku OTAeNAOT XIOpHA HaTpHA NMUeBOH KOHAMIMH, a Nocne BTOpoM cTaqMH — CHIBHHHTOBy!0 CycrieH- 3H10, KOTOpyio MocHe cryWeHuA BO3BpalllaloT B TexHONOrH4ecKHH WK, a XJOPH, MarHHA BBIBOMAT H3 CHCTEMBI. TIpoyecc nonyyeHua xnopuya KaslMa paccMaTpHBaeMbIM ciocobom BKHOUaeT CIENYIOUMe OCHOBHBIC CTaHH: 1) W3MenBYeHHe CHIEBAHMTOROM pydEI; 2) BomHoe BEIenayHBaHHe (pacTBopeHve) XMOpHya KAMA H3 CHIEBK- HHTa TIpH TemMepatype 90—98° C matouHEIM pacTBopom. IIpH sTom co- OTHOWICHHE MO@KZY KOJIMYCCTBAMH HCXOQHOrO CHJILBHHHTa H MaTOUHOrO pacTBopa NopyepkHBaroT TakHM, ¥TOOBI pacTBopsica mum KCl, a NaCl ocTaBasica B OcanKe; 3) orgeneHue pactBopa or uliama, cocTosujero 43 NaCl nu mmHn- CTBIX BeLI€CTB; MPOMBIBKa IlaMa HM MIMHMCTBIX BeLIeCTB; 4) KpucTannm3alua xnopuga Kanna; 5) orqeneHwe KpucTanoB OT MaTO4HOrO pacTBOpa HM HX CyLIka; 6) HarpeBaHve MaTo¥HOro pacTBopa yo 99°C H Bo3BpallleHHe ero B Mpouecc pacTBOpeHHA MCXOMHOTO CbIPbA-CHIbBAHUTA. CornacHo cxeme nonyyeHHa xnopuya kanusa (pwc. 2.5), w3MenEHeHHaa CHIBBHHUTORAA pyfa u3 GyHKepa J Yepe3 JO3aTOpsI 3 NeHTOUHEIM TpaHc- Nloprepom 3arpyxkaeTca B UIHeKoBLIt pacraoputens 5. B 9ToM pacTBopu- Tene pymy BBILeNaiHBaloT MaTOUHLIM pacTBOpOM, NOCTyMaIoWlMM 13 WIHeKOBOTO cMecHTenA 6. PacTBopEl Mocne cMecHTeIA, NpoxogA uepe3 Tpy6uatbiii nogorpepatenb 7, HarpeBatotca no 105—115°C. Pacrpopute- jm 4 a 5 He oi jar peBaICAbHbIMM YCTpOMCIBaMH, OSTOMY TOTE- PM TenioTs! B pacTBOpHTeNAX KOMMeHCHpyloTca nMogateH B alnaparst ocrporo napa. B wHeKoBoM pacTBopuTene 4 pacTsop wm pysa nepemeuya- 1OTCA NO NPHHIMNy MpAMOTOKAa, a B IHEKOBOM pacTBoOpuTene 5 — npoTu- BoToKom. IIpHHUMN NpoTHBoTOKa He MpHMeHAeTCA BO H30exKaHHE O6pa30- BaHWA MeNKMX KpucTanoB NaCl, BbICaMBaeMBIX M3 pacTBOpa mMocie PactBopeuna B HeM KCl. LlInam, BbIxXoqsuMi M3 WIHeKOBOrO pacTBopHTe- Jia 5, © WeNbkO MOBBILNEHHA CTeNeHH H3BMeYeHHA XNOpHa KaNMA WH OA 11LJenox Ha pacrsopenne Cynbennur | 30 KCI HacKnag Bosayx & Puc 2.5. Cxema nponspogcTBa xiopHma KasA TanyprHteckHM MeTOOM: 1 —6yuxep c mrarenen; 2— newrouii tpaicnoprep; 3— nosarop; 4,5— wexonbte pacrnoprrenn; 6— umnexossiii cmecuTens; 7 —TpyOuaretii nonorpesatens; 8— oTctokmMk-cryctuTens, 9 — cMecHTens; 10—uewrrpobexusie Hacockr, J —cGopHk wwama; /2—saxyym-punetp; /3—paxyym-Koten; 14, 16 —cGopHuxw 214 mpoMBIBHOH Bonb, 75 — Gapomerpuyecknii cOopHux, 17 — GapomeTpHiecKHii KOH- aencaTop cmewenns, 18— 6psraroynosurens; 19, 2/ — paxyym-nacockt, 20—nopepxHoctHbie KOHeH- cavopsi, 22—jononnwrensubie voHeHcatopsr, 23—napocrpyiiusie axeKTopsi, 24 — xoHNeHCaTOpET cmetienua, 25—GapomerpHyecknii cOopaux, 26—ropwsoHTaNbHBle BakKyYM-KpHCTanMHsaTopHl, 27, 30—cmecirenn, 28 —uenrpubyra, 29— crycratens, 31, 32, 35—cOopuuxn, 33— GapaGannan cy- munxa; 74—tuxnon, 76 — neprucansnniit RaKyyM-knucranmearop (I ctynewn): 37— resrunstonpekynepalMH TeIMIOTbI NOMONHHTebHO obpabaTEIBaloT pacTBOpOM MpH 70° C B UIHeKOBOM cMecuTene 6. OOpa3yloulniica pH 3TOM Lam Mpo- MbIBaIOT FOps4eli BOAO Ha HeNpepbIBHO AelicTByIOWeM FOPH30HTAabHOM rakyyM-@uitpe 12. TIpompiretii wnamM comepxuT 5—6% Boul H 10 2,5% xnopuaa Kama. HacpuyenHbii ropsunit (97—107° C) pactBop, momyyeHHEI B UIHeKO- BBIX pacTBopuTensx 4, 5 H CMecHTeme 6, HanpaBMAIOT Ha OCBeTMeHHe B wecTHKOHyCHEIN oTcTolinux-crycrutenb 8. B mepBbrx AByx KOHycax mpo- HCXOQMT BbIenNeHHe ConeBoro uaMa, KOTOpEI LeHTpobe:kHIM HacocoM 10 Bo3ppallaioT B UIHeKOBBI pacTBopuTemb J, a B OCTANBHBIX KOHYcax ocakyalorca MIMHMCTEIe yacrnubl. MMHvcrsii uiaM MepHoOAM4ecKH BbI- BOAAT B EMKOCTb C MeWlanko 9, re ero OOpaOarbIBaloT rops4el BOZOK (TOK = 4:1) mw mepenator WeHTpoGexHbIM HacocoM 10 Ha MpoTHBOTOY- Hy!0 MIpOMBIBKy B UIHekOBbIM pacrsopuTemb 5. TIpombitii riMHMcTHIi uaM WeHTpoOexKHbIM HacocoM JO BBIBOJAT B LIWaMOKONHTesIb, a Mpo- MBIBHBIe BOI WeHTpOOexKHBIM HacocoM /0 BO3BpaillaioT Ha pacTBOpH- TeNb B UIHEKOBEIH CMecHTeNb 6. C WembIO YCKOpeHHA Mpouecca ocakye- HHA TIMHMCTOrO WWaMa MpHMeHAIOT KOaryJAHTSI — UleMoyHOH pacTBop KpaxMasla, BOAHbI€ pacTBOpbI THIO3bI HIM MomMakpHnamMHa. Dddexrus- HOCTb MOMHaKpHaMHda MpHMeHHTeMbHO K TIHHKCTOMy ullamy B 20 pa3 BIMe MO CpaBHeHMio c Kpaxmasiom. Paspa6oraH HOBBIii BEICOKO3>pipeK- THBHLIK KOaryAHT — CONONHMep aKpHaMHya Cc aKpHOBO KHCNOTOH. TIpouecc kpuctanau3zaumu KCl “3 ocpeTneHHoro HacbillleHHoro pac- TBOpa MpOM3BOUAT B MHOFOKOPMYCHBIX BaKYYM-KPHCTAsIM3al\HOHHDIX ycraHoBkax 36, 26. [IpuMenatorca 14-crynenyatsie (Kopnycubie) BKY. B Tipouecce 14-cTyneHyaToro OxN@KeHHA CKOPOCTS OXN@KeHHA PacTBOpOB coctapaaeT oxono 2°C B | MHH, Mepenay TemMepatyp B Kako cTyne- HH He MpespiaeT 4—5°C. Sro obecneymBaeT nonyyenve KpHCTamOB KCI pasmepamu He MeHee 0,15 mM. C wenbIO yKpyMHeHHa KPHCTaIIOB KCl B kayecTBe perynaTOpoB B pacTBOPEI BBOAAT COMM CBHHIa, NeKTHH, NepBHYHble amMarHyeckve aMHHbI HW Ip. B neppom kpucrannu3atope 36 paspexenne coctannset S9—64 «Ila, a B nocneqHem 26— 98—100 xIla. Baxyym B cucTeme co3faeTca napo- CTpyHHEIMH 9:KeKTOpaMH 23, OTCACEIBaIOWMMH 3 KPHCTasIM3aTOpoR Ma- POBO3yUIHY!O CMeCh. S%KeKTOPbI YCTAHOBNeEH’I Ha MOBEPXHOCTHEIX KOH- aencaTopax 20, B KOTOpEIe mofaroT Nap napicHHem 600—700 Ila. Coxopbili nap Ha TepBbIX AeBATH CTYT PYHOTCA B MOBEPXHOCTHBIX KOHJIeHCaTOpax C MOMOIIbIO MaTO4HBIX pac- tsopos. Tipu stom pacrBop Harpepaetca 3a cyeT Tens00GMeHa Cc COKO- BbIM TlapoM 0 65—75°C. Pacrsop mepeyq mogaye Ha pacTBOpeHHe CHIBBHHHTa MoforpeBaloT NOMONHHTeTbHO WO 113—115°C B TpyOuaTom nlogorpeparene 7, o6orpeBaeMoM MapoM Noy AaBneHuem 200—300 xIla. Coxosbiii nap 43 mocnenyroulMx MATH cTyneHelt BKY KonyeHcupyetca B KOHJeHCaTopax CMelleHHA 24, OpOUlaeMbIX BOLO H CHAO>KeHHBIX 3KeK- 113Topamu 23. O6e NHHHH KOHJeHCaTopoB OOpeqMHeHI JONOAHHTeABHBIMK KOHJeHCaTopamu cMeuleHHa 22, oOopynoBaHHBIMM MapocTpyHHBIMH 3KeK- Topamu 23 4 COeIMHeEHHBIMH C BakyyM-Hacocom 2]. Kon yeHCcaT 43 KOHJeH- HMeHCATOPOR Y: AM MIPOMbIBKH OTBalla H3 pacTBopHTeneli H TMMHMCTOrO UImaMa. Cycnen3ua 43 MocneaHero Kopmyca BakyyM-kKpuctammu3satopa 26 no 6apometpw4eckoi tpy6e HenpepbiBHo BBOZMTCA B BakyyM-cOopHHk 3/, OTkKy#a NepekayvBaeTcaA B LUECTHKOHYCHbIM crycruTenb 29. OcBeTneHHBIi MaTOYHBI PaCTBOp BO3BpallaioT B CHCTeMy pacTBopeHHs. CrylleHHy1o cycnew3mi0 xmopuya Kawa (K:T = 1:2) m3 KoHycoB cryctuTena 29 ne- PekauHBaloT B EMKOCTE C Melllankoii 27, OTKyqa OHA CaMOTeKOM MOCTyMa- eT Ha WeHTpHdyry 28. B npowspogcTBe XiOpHta KasA NPHMeHAIOT LeHTPHOyrH MomyHenpe- pbiBHoro Zelctaua Tuna OF-1800 umm Gonee npov3BomMTeMbHble WeHT- pudyru Henpepsranoro jefictaux 2@TTI-2K-1200H. 7aa cumxenus cnexupaemocta KCl npu xpavenmu nu mepepo3Kax B CYCICH3HIO Tepes, UeHTpHdyrHpoBaHHem jOOaBiAIOT KOHAMUHOHMpytOLly10 goGaBKy — 1%-Hblii BogHbI pacTBOp rHApOXOpHAOB NepBU4HbIX 2MPHBIX aMHHOB C}¢— Cy u3 pacueta 180—200 r/T weneBoro mpogykta. Kpucrannbi weneporo mpofykta cyllaT B MpsMOTOUHBIX GapabaHHBIx cymmikax 33 40 octaroyHon Bnara 0,5—1,0%. Temnepatypa Tono4HBIx ra- 30B Ha Bxoge B cymMky — 800—900° C, a Ha BbIxone — 140—160°C. Buarocbem B TakHX CyuIMkax CoctaBiaeT 35—45 xr/(m?-u). TIpumenenue B TIpow3BorcTBe B3aMeH GOapaGaHHBIX cyLIHNOK afmapaToB KHMAllero cnon (puc. 2.6) NO3BONAeT NOBBICHTS YACbHBIM BarOCbeM 40 160—260 xr(m? 4). CornacHo MmpakTH4eCKHX JaHHBIX, B HaCTOAUee BPeMa TO paccMoT- peHHomy ciocoby Ha nomyyeHue | T WeneBoro mpomykta— xnopuya ka- mua (95% KCl) — pacxogytoT ooo 5 T cunbBHHHTa. Konmuectso ranH- TOBBIX OTXONOB Ha | T mpomyKTa coctapnaeT 2,5—3,5 1. OTxogbI conepxaT 91—95% NaCl, qo 0,2% MgCh, 1,2—3,5% KCl, 0,6—2% CaSO., 40 4% HepactBopumoro ocTarka u ~6% H,0. @noTauywonuHHw cnoco6 nonyyeHus xnopugna kamnusa. Cnoco6 nexHoi dnorauu, ocHoBaHHEI Ha pa3eneHHM xi0- PHA0B Kanva M HaTpHs, ComepxKaLyMxca B MCXONHOM pyne c npegBapuTe- JIbHIM BEIeeHHeM PIMHHCTOTO WWIaMa, LIMpoKO MpHMeHseTca B KamHii- wot mpompmunennocts. Bapnaurst cyurecrsyioninx TexHono HOH MpombinincnHccTH. Bapuanrsi cyuicoTsyiomix TCKHOROTH' ix CX€M OTMHYAIOTCA Apyr OT Apyra B 3aBHCHMOCTH OT COepxKaHHa MpHMe- ce B MCXO{HBIX pyax M OT CTeNeHH HX NpeqBapHTebHOrO H3Me/bYe- HMA, a TalOKe TeMMepatypbl mpouecca. @noTauMoHHoOe pa3yeneHHe MMHEepanoB OCHOBaHO Ha CIOcoOHOCTH CM@4HBaeMOCTH e€fO COCTABIAIOWMX, B JaHHOM Mpowyecce XMOpHJOB Ka- Ma WM HaTpus. B npowecce moran m10xX0 CMayMBaeMBIe YaCTHIbI BbI- HOCATCA H@ MOBEPXHOCTb 2KHJKOCTH BMeCTe C MY3bIPbKaMH BO3YXxa. 114 EQY!OTHuxe1s yrmbodnodes — gf ‘oarsyodiok somoshdieed — 6 ‘extomad wenaraumavadnsedose: — g smurfs tdonex—z :sdenoh yrsusranmioas0—9 ‘owxats sovodiona—¢ ‘aratearsedoced —y ‘MemeWx yrmonoL%ed —¢ ‘exmo1—z -eanfodo—| met evadorx mmko KIT WOLD OIOMIIHX EMIHMIAD °9°Z “Bd osmuuoy ROM ROOIIpuiunmanve TBepfow YacTHUbI K Ny3bIpbky Bo3qyxa— Mpouecc ca- MONPOH3BONbHBIM, MpoTeKaiouyHii C yMeHbuleHHeM 9HepruK T'uO6ca no- BepxHocTu. Jia ycnosuli neHHOM dboTauMH mpouecc NoqYHMHAeTCA MpH- 61WKeHHOMy yDaBHeHHIO: AG = o,.,(1-cos8), Tae Ox,—oneprua Tw66ca 1 cm’ mopepxHocra pasqena >xKHa- KocTs — ras; © — Kpaepoii yron (yrom cMayMBaHMa). PaOora, KOTOpyi0 MOKeT COBEpIIMTb CHcTemMa B Npolecce BbITeCHe- HM BO3ZYXOM 2KHZKOCTH c 1 cM’ TBepgoro Tena Ha cTaqMH Mpwnunanus yacTHI, K My3bipbkam, papHa AG. IIpa ycnospua nonHoro cMa4yHBaHHA TBEpIbIX YaCTHL XMOpHaa Kanua Bono @ = 0 u, cnenoBatenbHo, AG = 0. TIpouecc npwnunaHHsa BO3MOxKeH NHUIb Mpw 6>0. Uem rumpotobuee yac- THUBI, TeM Gonbule 3HateHHe 6 u Tem OxIcTpee HM MpoyHee OHM Mpunnma- for K fy3bippKam. Kpaeso# yron @ 3aBucuT or crpykrypbl TBepgoro Be- WecTBa, KOTOpad onpegenser xapakrep cease, oOHa@KaIOWIMxXCA Ha TBepyoH noBepxHOcTH, oOpazyloulelica B npouecce ApoOnenua. Ecnu Ha MOBepXHOCTH 4YAaCTHI[bI HMeIOTCA HEKOMIeCHCHPOBaHHBIe CHIbHbIe (HOH- HBI€, KOBAICHTHbIe, MeTA/IMYECKHe) CBA3H, TO OHA XOPOLIO CMayHBaeTCA Bonoii. Ecn xe cpa3u cnaObie (MOneKyNApHBle) WIM KOMMeCHCHPOBaHHEIe CHJIbHbIe — NoBepxHocTb rHzpodobua. B mpouecce cnunania TBepqoH YaCTHUbI C NY3bIPbKOM BO3ZyXa NpOuc- XOUMT pa3pyleHHe ruipaTHBIX COeB Ha HX MOBEPXHOCTAX B TOUKe Kaca- Hus. Ha 370 3aTpayMraetca KMHETHYECKad SHEPrvsa FRWKYIAXCA YACTHIbI 4 ny3bIpska. U3menenve 3Hayenus sHepruu T'u66ca npu yMeHBieHHM ToN- UHH! 6 *KHAKOH NpocnoiikH Mexkay YacrHyei H NY3bIPbKOM pH Hx cOnH- 2KEHHM MOKa3aHO Ha pc. 2.7. [lo Mepe yMeHbuleHHa 3Ha4eHua 6, Bola 43 %UDKOW MpocmoiiK ynansaetca MerKo (y4¥acToK KpuBol i—Z). Tiocne npo- uecca CMelIeHHA rMapaTHEIX OOom04eK 4YacTH- G, bl C My3bIPbKaMH pacxog 9HeprHu Ha ysane- 5 HH BOZbI pe3KO BO3pacTaeT HM 3HayeHHe oHepruu T'v66ca G mpocnolikn yBenmunBaetca (yyactok 2—3). B mpouecce ambHeiturero COnMKeHHA YaCTHIBI C MYy3bIpbKOM (yYacTOK 3-4) G peaxo yu pesKo 4TO THpaTHad Mpocnolika craHoBHTcA Heyc- TOHYHBOM, paspbiBaeTcA H B pe3ybTaTe yacTu- Wa mpwnunaet kK ny3bIpbKy. Tlockombky Ha n0- Puc. 2.7. Viaweneune saves P°PXHOCTH —4ACTHUBL = OcTaeTCA ~—_ po4HO aueprum Tu66ca B mpouecce CBAS@HHIM C Heli OYeHb TOHKHH COM BO- COMMKEHHA 4ACTHUBI c bl — MOMeKyNAPHEIX pasMepoB, yAaneHHe KO- TIYSBIPbKOM BO3YXa Toporo moTpeGopao Obl 3HayHTebHO GonE- aetca, ro novazmaer,wo 3aTpaTbl BHeLIHeH 9SHepruv, ConpoBoxkganoch Obl 3HaYHTebHEIM poctom G (y4actox 4—5). C wenbio HHTeHCHHKaUHH Mpouecca guotauMH MpHMeHstoT duoTa- MMOHHBIe PeareHTEI. B COOTBeTCTBMH C MX Ha3Ha4eHHeM peareHTb! DenAT Ha co6upatenu, oGecneynBalouMe MpHnunaHve (NoTupyeMbIxX 4YacTHU K ny3bIpbkaM, Ha mMeHooOpa3opaTemu wM Ha MOmMpUKaTOpE (peryssTOpEl), co3qaioulve ONTHMANbHBIe ycnopua BemeHua Mpouecca. TIpumMensloT TaK- *%Ke peareHTsl, ycunHBaloume xelicraue coOupareneii (akTupaTopsl) 4 YxyAMIaIoUe WH MONHOCTEIO HcKMOYAaOMIMe dmoTauuio (Zempeccopst WM MozaBuTenH). B npouecce baoraumu kanMiineix conelt HanOomee oddexTHBHBI Ka- THOHHbBIC coOuparesnmu — Ne pBAYHbIE anndarnueckne @MHHbI, MOsJY4aeMbie 43 aMMHaka H HedTenmpofykros (napadHHos Hi Ap.). OGp4HO MpHMeHsIOT HX COMM, Oomee pacTBOpHMBle B BOAe (alleTaTLI H XNOpHAbI), HanpamMep alleTaT OkTajjeluMaMHH, TH{poxnopHy aMHHa H Jp. B npouecce dnorayuu pearents! alcopOupyloTca Ha MoBepxHocTH CHIBBHHA, Jelad ee HeCMayuBaemoii. Ha KpHcTammax rata aMHHBI aicop- OupyioTca MeHee MpO4HO, 4M B CHIBBHHe, MOSTOMY MOBepXHOCTS ocTaeT- ca ruapodunsHo. Benencrave 3Toro Take KPHCTamel He MpwnunaioT K Tly3bIPBkaM BO3yXxa MW BbIMaaloT B OCaNOK, OOpa3ys ranMTOBLIe XBOCTEI. Shdbexrusnocrs mpouecca hrotrayHu 3aBHCHT OT TeMMepaTypsi, onpe- Hemsemoii coctaBoM KomnekTopa (coOupatena). CaepxonTHManbHaa TeM- Nlepatypa yBenH4HBaeT ancopOunio coOvparena Ha raslHTe, 4TO HapyilaeT CeNeKTHBHOCTS mpoyecca drotaumu. [Ipaxrmuecku yctaHopneHo, 4TO MaKCHMalIbHaa CKOPOCTb Mpoyecca @uoTalMM CHIBBMHa pH MCrOMb30Ba- HMM OKTagelMNaMuHa JocTuraetca mpu 30—35°C. SddexruBHocts xe pasqeneHua MHHepanos oOecneynpaetca mp pH cpembI S—6. TIpouecc dbaorayHu cunbBHHa OcyulecTBMAOT 6e3 BBexeHHA MeHOO6- pa3oBaTenei, MOCKOMbKy pacTBOpsI, HacbileHHbie KCI u NaCl, cnoco6upt Nerko BcneHMBaTbca npu GapSoraxe Bo3qyxa, OcobeHHO pH yyacTHH B Hem coOupateneii. OnHako JOMONHHTeMbHOe BBeLeHHe B CHCTeMy COOKpa- Tene (cocHoBoro Maca MM CIMpTOB WMOKCaHOBOrO, NMpaHoBoro paqa W Mp.) cnoco6crayeT MOBBIMeHHIO AUCMepCHOCTH My3bIPsKOB BO3yxXa H ycTowumBocTa neHEl, rHapodobusayHH moBepxHocTu dmoTupyeMBIX 4ac- TH MuHepasa, Tannctsie uiaMet notupyror aHHOHHEIM cobupatenem ®P-2 (npo- AYRT onvcicHA yaliT~ M KepOcHia Ana yay *iiie- HMA TeXHOMOPHYeCKHX CBOHCTB MeHbI M pacTBOpa MomMaKpHnaMusa, B MpHcyTCTBHM KOTOpOrO MpPOMCXOAHT KOaryJIAHA Llama, 4TO CHMKaeT Pacxog, peareHTos. CxembI (oral CHIbBHHUTOBEIX PY OTIM4AIOTCA MeTOROM O6pa- OOTKH TIMHMCTEIX WlaMoB: OOoralleHHe c MpeyBapuTenbHoOw dmoTayveit TNMHHCTEIX UWlaMoB M OOorallleHve C enpeccveli PMMHUCTBIX WWIaMOB, a Taloke CTeMeHBIO HX H3Me/bYeHHA. 117@notTauMoHHoe OGoralleHHe CHMbBHHHTOBLIX py COCTOHT M3 cyeny- OUHX onepaynii: 1) ApoOneHve H H3MeNBYeHHe HCXORHOM pyZbI WO pas- Mepos YacTHu, oOecneyHBaloMHx O6pa30BaHHe MeXaHH4eCcKOH CMeCH BXO- AaWMX B COCTaB pybl MHHepanoB,; 2) mMpelBapvtembHoe yyaneHHe TMMHMCTOrO WWiaMa W3 pyibI HW ero NMomaBeHHe (nenpeccua) B npouecce ocHoRHOH dnotauHn; 3) ocHoRHas dhnoTauMa c REIMeneHWeM tWeneRoro mponykta (KCI) 8 newHbiit mponykr uw nocnexyiomel mepeyncTKo momy- yeHHOTO KOHWeHTpata; 4) NepeuncTka rMMHUCTOTO UMaMa C LeMbIO CHH- 2KeHHA MOTepb WeneBoro npomykra; 5) o6esBox%KHBaHHe XBOCTOB, WaMa H KOHUCHTpaTa MeTOJOM cryuleHHa H buNLTpoBanua, MepepaboTKa BaxKHO- TO KOHUeHTpara B ueneBso mpomykT (cylIKa H Qa MeNKHX (ppaK- uuii — rpanynmpopanue). BosspaT B CHCTeMy MaTOYHBIX pacTBOpoB. Menxozepnucman gnomayui — oGoraenve MenKO3epHuCTOK dpak- uum (0,8 MM)— BKMIOYaeT TpexcTaquiiHoe OOecHINaMMMBaHHe B rHApo- WMKNOHaX, CMeLIeHHe C jempeccopom — KapOoKcHMeTHAenMON03;0H H gnorauuio c coOuparenem—rMapoxnopHyoM aMHHa H BCIeHHBaTe- lem — COCHOBBIM MacnoM. [locne ocHoBHow (motauHH Hu mepeyHcToK KOHIeHTpaT O6e3BOxKMBAIOT Ha WeHTpHdyre M CyllaT B annapate KuNale- To culos. B npoyecce dnorayun KpymHo3epHHcTEx KanniHEX pyq monyyaror KOHIeHTpaT c comep»xkaHvem 93% OcHOBHOrO BelljecTBa NpH CTefleHH H3BIe- yenun 90—92% KCl. Ha monyyenne 1 t 95%-Horo KCI pacxogyror: 5,0—5,2 t (B mepecuere na 22%) KCl; 0,520—0,780 xr rugpoxnopuza amuua; 1,040 kr cmMecH MasyTa H conapoBoro Macua (2:1); 2,6—2,8 Kr To- nowHoro Masyta; 60—70 KBT-4 snexrposHeprun 1 4—5 mM’ cBexeit BOUEI. OcHoBHEIMH anmaparaMu B Mpolecce NomyyeHuA xnOpHya KamHA AB- UAOTCA CNOTAMOHHEIe MalIMHBI HW AyroBoe CHTO. @romayuonnan Mawuna MexaHMyeckoro Tuna «MexaHobp-7BM» ama MeJIKO3epHHCTOO THNa droTauMM (pc. 2.8) cocTOHT H3 HECKONBKHX (JO 20) MeTamM4ecKHX KaMep, COCQHHEHHEIX Upyr c opyrom. CycneH3ua B anmapaT noctynaet B KamepsI no Tpy6e /, Yepe3 KoTOPy!0 Non Bo3zeiicT- BHeM Bpalljaouleroca HMMenNepa 6 3acacbiBaeTca Bo3yx Gnarogaps HH- TeHCHBHOMY MeXaHu4ecKoMy MepeMellluBaHMto. Menkve ny3bIpbKM BO3Iy- xa BMecTe Cc cycrieH3Helt sBbIGpacbiBaloTca B KaMepy, Te K HAM HipunumaioT rugpooOuble yacTHULI CHIEBHHa, H BCIILIBaIOT Ha MOBepx- HocTL, o6pa3ya cnoi MuHepamH3oBaHHol mens. O6pa3zyroulaica neHa m0- NacTaMu meHoronos 4 crpeGactca B oOmmit xen06 5. Octasumeca B CYCHeH3HH THAPOHIbHBIe YaCTHUBI pyAbl (raIMTOBbIe XBOCTHI) MocsAeEZO- BAICIDHO LIPOXOAAT BCE KAMEpbI HM BEIBOAATCA YEPE3 CAMBHOE OTBEPCTHE Ha JambHeliuy1 nepepaGorky. @norauMoHHad MallMHa C KHMALIHM cioeM (puc. 2.9) cocTOHT 3 6—12 kamep. Yucno kamep 3aBMCHT OT Hx OObeMa. CycneH3Ha nofaetca B HAKJIOHHy!0 peliletky /, HMeIOUIy10 2%KHBOe CeyeHHe 25—30%, paBHOMepHO pacnpeyensetca No Bceii LIMpHHe KaMepsI 3 M MOCTyMaeT B 30HY NOBbILeH- 18109 8 Pue. 2.8. OnoraumonHsii annapar Puc. 2.9. [lnesmomexaHHueckat «MexaHo6p-7BM»: quiorauMoHHaa MallIvHa C KHMAIUMM cj0eM: 1—scacisaiouas tpy6a; 2—wnGep; 3—npy- /—waxionnar pewerxa, 2—nombih wan; bon uMnennepa; 4—nenoromu: 5—xeno6; 3—xamepa; 4, 5—umyuepsr, 6 — ropwsourans- 6—wunennep; 7— crarop naa pewerka, 7—narpy60x, 8—nonacta crato- pa; 9— qucneprupyiomtee yctpolicteo; 10 — cra top, 11 —wmneniep; 12 — asponnpt Hoi a9paluu, cozqaBaemyto asponudrom 12. Uacts cunbeana dborapyetca B neHHEI nponyKt. HectnorHpopaHHble YacTHUEI MepeqBUraloTcA 0 Ha- KOHHOK GecnpoBanbHol peuterke J, mepHoAM4eCKH MepeMelIHBaloTcA BOC- XOJALJHMH aSPHPOBAHHBIMH MOTOKAMH CyCHeH3HH, obecne4dHBarolHMH AOnoAHHTeNbHy!O aoTauMO cHIbBMHa. YacTb HecOTHpoBaHHoro MaTe- pana nocrynaetT Ha Topw30HTambHyo pelletky 6 (kMBOe ceyeHHe 15—20%), Ha KoTOpoii nog AeiicTBHeM a3pHpoBaHHEIX MOTOKOB, moyaBae- MBIX HMMenepoM J/, Co3qaeTCA KMNALYAA CHO, M3 KOTOporo AopAoTHpy- JOTCA 4aCTHIIbI MoNe3HOrO MHHepasa. XsocrTsl @uotalvu BbIBOZATCA Yepe3s naTpy6ok 7. B drorauMoHHoOi MaLIHHe KHMALero CNOA MMEIOTCA 1Ba KOHTypa UMPKyAWMM MH a3pupoBa- HMA cycneH3HH. Onn cozfaetca paboTow asponndra nog Bo3feicTBHeM cxaToro Bo3yyxa, pyroi—vmnennepom J] w jKcneprapyromluM yenpotictsoM 9 B Buse MoMOrO yceyeHHOrO KoHyca c pHdeHo roppu- HOBepxHOCTEIO. B ‘nponteccax (OcHOBHOM HM KOHTpoNbHOM) quoTauMH KpynHosepHH- CToro CHNbBHHa MIpHMeHAIOT TaioKe H MaLIMHbI nmeHHOH cenapanun PTIC-16. Menno protauvet naspiparor mporecc mogayn o6paboTaHHok PearevTaMM cyCneH3HM cBepxy Ha neHHbI col. TIpx stom ragpoo6- Hble YaCTHYbI MHHepalla 3alepKHBaIOTCA MeHoli, a rMqpoduNbHBIe yBNe- KalOTCA 2KHAKOCTBIO, MOCTyNatoulel Cc cycneH3Heii cBepxy HM C BO3AYyLIHbI- MH Ty3bIpbKaMH CHH3y. 119Maumua PIIC-16 (puc. 2.10) mpeacrapiaet co6of nupaMHyanbuy1o kamepy / c BepmIMHO B HMDKHeH 4acTH. CycneH3Ha MocTynaeT Ha MeH- HBIM cool, oOpasyembiii B pesyibTaTe NOMa4H cxkaTOrO BO3LYXa Yepe3 pe- 3MHOBBIe TpyOyaTble a3paTOpbI. KOTOPbIe pacnoMoxKeHbI B OBA PAA Ha pacctosHuy 18—20 MM apyr na ce Uncno nepopauni B tpy- Sax — qo 60 orsepcTui Ha w3O6EITOUHOe aBeHHe BO3LyXa 1,18-10° Ta, pacxon Syne te o “cM /MnH. TIpu 2Tom rugpodoburre YaCTHILI OCTAIOTCA B MeHHOM Coe H yfansloTCA Yepe3 CHMBHOM mopor 6, a Hednorupopanibie yacTHULI onyckaloTca BHW3 HM BbIrpy2kaloTca 4e- Ppe3 pasrpy3ouHoe ycrpolicrao 8, oGopygoBaHHoe WNaHTOBLIM 3aTBOpOM B BHC _HCPHOBEIX XBOCTOB, KOTOPBIC MOMBepraloTca Hanbueiiumeli o6pa6ot- ke. TipowsBOqHTeAbHOCTS AByXCEKUMOHHOM MalinHbl DIIC-i6 upu Kpyu- HOCTH KyCKOB 4o 3 MM cocrapaser 100 1/4 KanmiHOw pygpl. Tyropoe (BorHyToe) cuTo (puc. 2.11) mpHMeHsOT B Mponeccax o6e3- BOKMBAHHA WH KTACCHPHKANMH MeNKHX YacTH. BorHyTat NOBepxXHOCTb cuTa C paqMycoM KpHBH3HEI 1,50 u 0,55 M (cooTBeTCTBeHHO muollaqb Cycnensus Puc. 2.10. TInesmarmiecaa quoraunonnas Pye, 2,11. [Ayrosoe (801 ) enro: MammaHa 19 TeHHoi cenapaunu: 1, 2—xpouuny, 3— wopuye, wre) nochnnosa pemterka cura; 5—npwxumnoli cerwenr, 6 — un- Gep; R-pannyc KpHBHaHBt 1 —vanepa: 2—rpytrarsie anparopet aa; 4—sarpysostoe yctpolictao; nopor; 7 — e106; 8 — paarpy204ioe ycrporicTBo 120npocenBanna 2,0 nu 0,95 M’) oOpasyeTca MeTaJUIM4eCKHMH KONOCHHKaMH 4, MOCTaBeHHEIMH Ha peOpo. PasMep wlenH perymHpyeTca paccToaHHeM MexKIY KOsIOCHHKaMH. TIpoceupaembii MarepHan mBM>KeTCA NOMepeK ycTa- HOBNEHHBIX KOIOCHHKOB CO cKopocTHO 0 3 m/c. IIpx Gonsmoi cKopo- cTH JRWKeHUa R nk MpoxonsT num. yactuner pawenom Rr 1,5—2 na- 3a MeHbUIe WMpuHsI WenH. YgenbHaa npowspommtemsuocTs cut Ha 1 M* pa6oueli nopepxnoctu cocrapnaer 200—250 w/a cycnensuu. 2.4. CYIb@AT KAJIMA @u3Hko-xHMBYeCKHe cBOicTBa, MpHMeHeHHe. Cynbibar Kama K2SO,, GecupeTHsle KpucTamib! pomOuyeckoli cuHronuu (a = 0,742 uM, b = 1,001 HM, ¢ = 0,573 HM, 2 = 4, mpoctpaHcTBeHHas rpynma Pnam; nnoTHocTs 2,66 r/em®). Bene 584° C ycrotiumpa rexcaronanbHaa MogHouKauna (a = 0,5947 HM, ¢ = 0,8375 HM, z = 2, npoctpancrsenHaa rpynma P6;/mmc; nnOTHOCTE 2,26 r/em’), AP nepexoya 8,0 KJbx/mMonb; Temneparypa miapienua 1074° C, Temneparypa kunenua ~2000°C; C? = 131,4 [px/(monsK); AH? = = 36,3 KJbk/Momb; AH xp =-1437,7 KJbx/Mone; Sop = 175,56 Dk/(Momb'K). PacrBopHMocTs cynbdata Kalua B Boge (r B 100 r): 7,35(0°C), 11,1(20° C), 14,8(40°C), 24,2(100° C). Temnepatypa nnapienva osprextuxu (7,1 r K2SO, B 100 r H,O0) — 1,51°C. Tinoraocts 5%- 4 10%-HEIX RONHEIX pacTROpOR cooT- BetcTBeHHo 1,0393 u 1,0817. Cynpdar Kanua o6pasyeT BolHBIe cONH, B TOM 4HCMe KBaCUBI. Conmu 2K ,SO4-Na,SO, (rmaseput), K2SO4-MgSO,4-6H,0 (uexnt), K,SO4° MgSO4: 4H,O (teonut), K,SO4: 2MgSO, (nanrGeiinut), K2SO,4- - MgSO, - 2CaSO,4: 2H2O (nonurannt), K,SO,4CaSO,H2O (cunrennt), a TawKe K2SO, (apkaHHT) BCTpeyaloTca B MpHpowe B MeCTOPOXKeHHAX KasMHHbIX cone. Cynbar kanHa CoepxKHTCA TaloKe B BOyaxX cone- HBIX o3ep. Tuapocynpdar xanua KHSO,—6ecypetutie Kpuctaib pomOvye- cKo cuHronuu (a = 0,840 uM, b = 0,979 uM, c = 1,893 HM, z = 16, TipoctpancTBeHHast mia Pbca). Temnepatypa nannenua — 222°C; nnotuoct, 2,4 rem’; AHO =-1163,3 uJIu/mom; S09, = 142,2 Upx/(Mont‘K). Benue Temneparypst Timapnenua o6pasyeT emecs K,SO, « K,S.0;. Tarpockonu4er, pacTBopsetca B Bose. Cyabar Kama IpHmMermor B KasecrBe yAvOpennxa, B UpoUeccax 110- JYYeHHA KBACIIOB HM Apyrax coeqMHeHHK Kala. ABNAeTCH KOMMOHEHTOM WMXTEI B MpOH3BOCTBe cTeKIa. Tuapocynptbar kanua NpHMeHSIOT B Ka¥eCTBe KOMMOHeHTAa dioca B Me- Tasypruu HM cynbHpyioujero areHTa B MpOH3BOACTBe KpacuTeneli, B Npo- Weccax NOMyYeHHs CHOKHBIX yROOpeHHi, a TakoxKe B aHaNMTMYeCKON XHMHK Aa Mepewoga TpyHOpacTBOpHMBIX COeAHHeHHH B NerkopacTBOpHMbie. 121