nha Teall Abi deal WIA Aaya! Cb Ly OGL shh Olpall aby! Ay Bylj9 2015 Olgr :3y92 SP paledl ygVl& Obert tak gle hat 2305 Ls 03:31 Aibjill aglall cole Glee! sQyagllill Cys gedagall sal Uy Gol editall le JSS) Egagall (Bids 04) :L69) ca pa (K'+Mn0, )setigdl bide, Jglae ye Vi = 50 mL Las gic t= 0 Abell ae meal Uyloe Ge V, = 50 mL legay C= 0,2 mol/L lyall 9:88 Uemenall 2C, = 0,6 mol, Ayal 9S H,C,O, Als! (MnO,,,,,/Mn”,.,) (CO,,.)/ Hs C0) 2UeUall § Asta (Ox/Red) SLAL gs gayalls Spall Se IS aust el“ uc lyyY! sau8Y) Sold Usles gitlals plu Yly SGU Guideeill yibaleall HSI-2 Sell pais Syne ¢ptl-3 $e Will Ay fhe gS fill Lag pall 8 SIG! aapall a4 GA MNO; cilieieyll apts gaall lal 5Syll dds JS DA Jad Jel ppb destid-5 zegltl Jjaall | t(min) 0 [1[2[3/4 1617] [MnO; ](10° mol.L* )/to0 98] 92| 60/30, 2 5|3| sql A HC,O, 5 MnO; 3 SY! gyal! 5S) es! =| [Mn* J) = S-[Mn0; Jf ABLLY ae (t) Ua) se[Mn™ ] peal 582 OI A) Hayy ao GAS Ay fades yy he esl! UVa: [Mn0,] bss ae eu! > > t=2 min Qaalll (3 Wiad Gua! [MnO ](t) Uy Jetiill deaall de pall gle aay} 2 8 oy Liniemeee ae “CH 24s) 7 assuslls CH :43lg) D esetisall tcuns uel jias Ge ie —=£(MeV/nucléon i? val : + abs JS lp Gas heli Do © © m w wo Oper © © 00 20 20 20 : is je 2 4 Casal ciate Sy I3La-3 2 $ 1-82 aac gll Alaa) Abba) Jig ole — Soball Ge Aas al gull sat — es alg By ag i Gaye -4 “Aasgil Phe lial shits) aia gs (CH H) ajell oS of it bile gl olde iba 2 Absa! gle (I) Spaills cheiey }He alll JS I) sayy cleat! Jes sqipjall Lig) Grass (1 -JS2/) Scat) ¢ Le) Je al dq Lecell Alateall Gast -1 Auasall Led Geel A olin ti les Jo liill Ibe ye yall 4aULI ajo bel -—G MeV 3b ~Fe(:ite)=7.1Mevincléon = uiH)=2 8MeVinucléon FH) a1 IMeV/nucléon ? gle" «-m(3He)=4,00150u , m(}H)=3.01550u , m(jN)=1,00866u © 1u=931,5MeV/¢? m({H)=2,0135Su 7 (218 04): 28) sy itl REVO Q Sus 2- SSI dant yall AilygSli ApS ju) Gh. : ay, - E Asks Smalls Sag Cul ad | Bae Apalis Lime oy}0 gli Del Skea ew dss AES AI Aybe Coe Galaall cilayeSll sill uejll he 8 pinenian chad deli dhe tls, K Gblil Gls t= 0 Saal se Gall 8 48 aac! S78 Gf oad us F(t) Shall gael Gyula 3-usa t(ms) a 10 20 30. 40. SAastill deny Lill eels! Saal! usd) slgall ya Le spulall Sle ole (a -1 Fe ap Aelia aly ileal a Janes Ziggh ale (ay fa) Labs my sel -2 te (1) ges =U. (t) SlygSiI sall Yaa, coll AsLeolal Asta! aah ss sll ees Ggild Gules -3 AGLI Ali) Usleall Ja yo u.(t)=E(I-e*') nyu >RC sill geil ul ge “TSE US Aad Lhe ois 3 cu, (1)=0.63E : (SUG 04): cath co pact! a Gell gt Saal Joe Baal SSI Se les as Baal AES Ja cus 1 Util Ghat, O lyse sige 5 esaall é x My Selly gut Fe Sol Adal sal pL le ing «4 SAI) any el =] eda Be Am, GS 5 SIS sal gle Guat Gb ws Aiea! Ages Qo sical aillbe Gass EME) y rem, My «(sss Gila St) Gye ds ava F ‘Al A oil Guubiny FL ayall Ld gat ts Ms 6G AS A pega) 8 SSI) Sa smell Iya ie dash 8 3 inde gill gta ye fe -2 I Eyed le say US ib Jlal -3 Bt ole aI # :WY bs5 5 Goal Gal OSS Oa US gu gyal ts asl 5 USUI Gly la 5 te{Pao"s) SIS US sae phi nas Cad, 1 Po] Shs eat estat a hall Gilg da I ie ieee tol ci oll Jl Gs ws eam dag a 7 =3,0x10-°(8.1) o4f—_| en ee : 024 aa OS eatery re FLO’) ree C0 se aes as - G=6,67x10"" (S.1): tow 5 ~ Usail “Sm a9 Led an 1,50.10"lm ya Guat Gal Ls Ge ha all sel gf Lue -6 somal Jn Ga (BU 04) cea al) cy atl Cy yall S38 C,H,CO,H sagt Gaal gil Jglae GeV, = 20 mL lage C, =10" molL* Ayall 355 (Naj,, +HOZ, ) assay oe ae OLN pee AV, Cos (6-H) pH=E(V,) cla) a Ge cae gle uaa ital QaSeuall Solel! gyledll Jeli Usles Cas] +E silsal) 4L5 laa) Lily oka -2 yall CO, lyall 5S il ua !-3 ASL pK, 4g Lie ye -4 -(C,H,CO,H/C,H,CO;) eb baalstall Atheasl IAN S18 Gual—$ Aslaall oe 14mL (Su aie Jylaat 7, Aled pall Aes Lad an uN /,(mL) + 25°C Mayall aie Cad Sule! gf Lule 8 dni,ciiRz 1 BAcz 01 § A Wi TNA cgi) Equa yal) (bts 04) 28) co paill C= 107 mol/L lyall Sits V dens HCOOH opt! Uneal (pls Yylae pan “I -25°C Aaya sic pH =2,9 4 Syst G3y oLall 8 Ashe) Gunes as! Hales Gas! =] deli pai yan Get ~ Ste Whe Jel 7, eal) pall Lad na — eSe li) i lb lall (uaan/elel) wee -HCOOH/HCOO™ 4st pK, J) dag Geel “4 ye JS gh auns C Sill Aitide CoHsCOOH stasjill amen D+ clas the east “Il [C,H,Coo"] y [C.H,COO™ | dual! A-dSab = o ‘ 1-JSML Gell pH = f (log [cLCOor} ) oll oF eH coor] pH Eevenip-veapveel meres) Ky she Gis! -] -(C.H,COOH/C,H.COO- ) Asli pK, Aa Usleall pH Wile a9) -2 [EHCOO) as, (C.H,COOH/C,H,COO™ \ [C.H.COOH] ~ “ os } | pK, cwtill a8 ital colull gle late! \ ) = C,H,COOH/C,H,COO™ wSiulal shy Sly 5S ai Lagl Uf cide 13] CH,COOH. al HCOOH us (ueaall gid (dts 04) + ei) Gu il asin! pay M Sle qeey -2- USL all Hall OS! ABSA yb oy GlyxSll ssl (4- Sa) 5 B-USA) «dilly atl lef uan() Seal) 485A) gad oy Leas) § AL! Os beste JE AalygSll Spall 8 Cul sill aye Ubaulse oe Sal! ay Sy Ges t= 0 Abell 42 Cas! col ALU UB Gy LiL ABSA Gat oe RI = 500. Adeslie gash Jit © M_Sleall aust Ley (Gat ol Cm) ilyall Salah inte dS Gall -1 Bp Sidei Aghealisl Aabeal) CSS) sll gam ld Gut —2 -ayill Aye DE Ugg (t) Aa Hla JSAM) Ge Saboliall Ubud! Ua gl ye Gia -3 = cally Ca A Cus Ugg () = Ave FC 0 100 5 hey AGIA! dog pill Ge Ale aasd api EAI) SlyeSl! Slall sab ole US) 4 ml all Gajll UG TT hed Lily 38 -5 tall de Quills Fajlie Und R 5 48S! dee C Aad ul -6 ant) ages) la (BU 04) NE cy pat) =6,02x107 mol : sale sil Cutiy M = 131 g/mol 2131 ssall 4yill yall AES sobbed! HAtbeSI jolie!) jaca lll Jsiell oe [ eee ee ee Sal so | te | I 7 Xe Cs eter a a 35 ines Spay (BT) Csbeag ASStiy pres gill y lll lal) GB hall 131 apd Sale Lanta sta ee caval fd ghd 131 sell oe AnS hall sll Gays Ge Sal (Bq Gaas) eles) butt Sly A ys SISA 8 In(A) = f(t) satel bes i : A(t) Used 5 gina | 131 asa als GS beel -1 © 131 agll SSG DA Conall paul ge Le f-2 cold 983 ee 131 apll uASGG Males GS) Alesis Blin) tours) Es + In(Ag) 9 tig «t Aa In(A) ce se -3 8 6 bbeoui Me Kall Ay ISN! ey Lua ag qin 2 (pineal isles) Asal ‘yhall CoS) -4 2131 ogall typ peed Ged ye) ads t= 0 Abadi Aida) 8 Alecia! 13] ogllmy ABQ! Ab Gaal -5 (U5 04) :gatal cpa sAB=2m « a@=30° « g=10ms7 the -(6- Jil) ABCD jluall gle cm = 100g ii «bis opted gill « (S) auoll dat -1 Ags) dep G52 A eaapall Gs (8) aol! Slay 6 Vp =2 MS eye B evazall ll deal Node C geayall ll ob F altsia! 55) (6) aucall weedy AS pall Aga] AuSlesy Sa.dll UL «leuall day le TS od Jagd AB jbeall le LAB jhuall gle Spall ghd le ang ecigal tll osilill Gubis -i JF Sta) 58 58 gil & gyLaill [ke Aad on wcll! le $ BC jludl le 48 pal) duh Le ma Say gl BN Geshaeall Ye = 0,8 m ELL) le abe gl C Quagall (S) pall jake, -2 + Vp deny D Adadill I) Sees elggll gi ibaa D5 O costal daily SLaales (t= 0) Aue tare C aragall ol) (S) peo! Ged Gee: (ill Aba Sle velgell Aaslbey ated re (Osi k) led! 8S) pall lke JS Glas Uses of ok -I g z=-~8 x?th oe (OD Aue!) O Abaill 4e D Abaaill a2} Sta Vp Ac paall Legh Gaal a 8 oy Tinie(hi 04) sual a ALLY! Cuan Gy Bia gad Mahar WOU Ge Gd pl yada! lac dae i +C,HOH Ist 5 CH,COOH ASE Gaaen Gye 1,40mo! Ge sSs Lage Casall US Gl Ipaeangy JUGS! nl 8 dial Sai ples pb HUN Coes 0d Spall CoyysSlI vases Gye Glad eaten csi! Gs 140mol 5 of = 04a 8 alSaly eae ae 64, =190°C Aiea dap tle Aa dylacy paall Lal) 98 devogy Hb! onl ch dle Qed Lb = 60min Ball 28 HE Ble es Aaland adi yp Ss ob spgedprall Ss pe plane daly pitall uoeall ag del h Bisaall eu CalSS Hats Hin} Ciba! é 1(min) Jo 60 120 | 180 | 240 | 300 | 360 | 420 | [ena 140 | ogo | os9 | 052 | 048 | 047 | 046 | 046 | rast | | | Stal) Bu) gary isla wen yal g Lal etd Alakes Gast T=! $ Ayeill sha Gd Cay SII aaa yd Le Gs ss = FO) $e Nag Stal) Stl Sake Sy yh Say gill lal) aly tall Sas ALY Alyy es GEG Ay sales Ayy Ue ep ot 3809) Iya of ow B Je lil asl Yoon ctl -3 eli Gast Ga} Lily cle 4 100°C Stall glaatl he day dal Ge emu, = eC) iniell LES Tie “5 8 Bide