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FIITJEE

ALL INDIA TEST SERIES


FULL TEST – III

JEE (Advanced)-2020
PAPER – 2

Time Allotted: 3 Hours Maximum Marks: 183

General Instructions:

 The test consists of total 54 questions.

 Each subject (PCM) has 18 questions.

 This question paper contains Three Parts.

 Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.

 Each Part is further divided into One Section: Section-A.

1. Section–A (01 – 07, 19 – 25, 37 – 43) contains 21 multiple choice questions which have only one
correct answer. Each question carries +3 marks for correct answer and –1 mark for wrong
answer.

Section-A (08– 14, 26 – 32, 44 – 50) contains 21 multiple choice questions which have one or
more than one correct answer. Each question carries +4 marks for correct answer and –2 marks
for wrong answer
Partial Marks +1 for each correct option provided no incorrect option is selected.

Section–A (15 – 18, 33 – 36, 51 – 54) contains 6 paragraphs. Each paragraph is having 2 multiple
choice questions having 4 options with only one correct answer. Each question carries +3 marks
for correct answer. There is no negative marking.

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Physics PART – I

SECTION – A
(One Options Correct Type)

This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.

1. In the Young’s double slit experiment using a monochromatic light of wavelength , the
path difference (in terms of an integer n) corresponding to any point having half the peak
intensity is
 
(A) (2n  1) (B) (2n  1)
2 4
 
(C) (2n  1) (D) (2n  1)
8 16

2. The speed of a wave on a string is 150 m/s when the tension is 120 N. The percentage
increase in the tension in order to raise the wave speed by 20% is:
(A) 44% (B) 40%
(C) 20% (D) 10%
R
3. A frictionless tunnel is dug along a chord of the earth at a perpendicular distance
2
from the centre of earth (where R is radius of earth). An object is released from one end
of the tunnel. The correct graph, showing the variation of acceleration of particle with its
distance r from centre of earth is
a a

(A) (B)

r r
R R R R
2 2
a a

(C) (D)

r r
R R R R
2 2
Space for Rough work

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4. A closed organ pipe of length L is vibrating in its first overtone. There is a point Q inside
the pipe at a distance 7L/9 from the open end. The ratio of pressure amplitude at Q to
the maximum pressure amplitude in the pipe is
(A) 1 : 2 (B) 2 : 1
(C) 1 : 1 (D) 2 : 3

5. A charge particle q of mass m is placed at a v0 v0 -2q


distance d from another charge particle – 2q of q
mass 2m in a uniform magnetic field B as shown. XB
If particles are projected towards each other with
equal speed v0, so that the two particles touches
each other without collision during its motion.
(Assume only force due to magnetic field acts on
the particle)
qBd qBd
(A) (B)
m 2m
2qBd 3qBd
(C) (D)
m 2m

6. When the electron in a hydrogen atom jumps from the second orbit to the first orbit, the
wavelength of the radiation emitted is . When the electron jumps from the third to the
first orbit, the wavelength of the radiation emitted as
9 4
(A)  (B) 
4 9
27 32
(C)  (D) 
32 27

7. The image of an object, formed by a plano-convex lens at a distance of 8 m behind the


lens, is real and is one-third the size of the object. The wavelength of light inside the lens
2
is times the wavelength in free space. The radius of the curved surface of the lens is
3
(A) 1 m (B) 2 m
(C) 3 m (D) 6 m
Space for Rough work

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(One or More than one correct type)


This section contains 07 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.

8. A bimetallic strip is formed by two identical strips, one of copper and the other of brass.
The coefficients of linear expansion of the two metals are C and B . On heating, the
temperature of the strip goes up by T and the strip bends to from an arc of radius of
curvature R. Then R is
(A) proportional to T (B) inversely proportional to T
(C) proportional to B   C (D) inversely proportional to B   C

9. Two parallel long straight conductors lie on a smooth horizontal surface. Two other
parallel conductors rest on them at right angles so as to form a square of side a initially.
A uniform magnetic field B exists in vertical direction. Now all the four conductors start
moving outwards with a constant velocity v. The induced e.m.f. e and induced current i
will vary with time t as
e
e

(A) (B)
t
t

i i

(C) (D)
t t

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10. Consider the decay 238 Pu  234 U  4 He


The atomic masses are given as
238 234 4
238.04955 u Pu 234.04095 u U 4.002633 u He
Neglecting the recoil of the residual nucleus
(A) the kinetic energy of the  particle emitted is 5.58 MeV
(B) the kinetic energy of the  particle emitted is 5.58 eV
(C) conservation of electric charge is valid for the given reaction
(D) conservation of electric charge is not valid for the given reaction

11. In a thermodynamic process Helium gas obeys the law TP2/5 constant. If temperature of
2 moles of the gas is raised from T to 3T, then
(A) Heat given to the gas is 9 RT
(B) Heat given t the gas zero
(C) Work done by the gas is 6RT
(D)  VdP for the process in the given temperature range is 10RT
12. Sounds from two identical sources S1 and S2 reach a point P. when the sounds reach
directly and in the same phase the intensity at P is l0. The power of S1 is now reduced by
64% and the phase difference between S1 and S2 is varied continuously the maximum
and minimum intensities recorded at P are now lmax and lmin
(A) lmax  0.64 l0 (B) lmin  0.36 l0
(C) lmax / lmin  16 (D) lmax / lmin  1.64 / 0.36

13. A wave disturbance in a medium is described by


y(x, t) = 0.02 cos (50 t + /2) cos (10 x),
where ‘x’ and ‘y’ are in metre and ‘t’ in seconds.
(A) A node occurs at x = 0.15 m
(B) An antinode occurs at x = 0.3 m
(C) The speed of the component wave is 5.0 m/s
(D) The wavelength is 0.2 m.

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14. A cannon shell is fired to hit a target at a horizontal distance R, however it breaks into
two equal parts at its highest point, one part returns to the cannon. The other part
(A) will fall at a distance R beyond target (B) will fall at a distance 3R beyond target
(C) will hit the target (D) have nine times kinetic energy of first

Paragraph Type (One Option Correct)

This section contains 02 paragraph each describing theory, experiment, data etc. Four questions relate
to the paragraph. Each question of a paragraph has Only One correct answer among the four choices
(A), (B), (C) and (D).

Paragraph for Question Nos. 15 and 16

In a photoelectric effect, a point source of green light of power 40 W emits mono-energetic


photons that can just emit photoelectrons from an isolated metallic sphere of radius r = 1 cm,
placed at a distance of 1m from the light source. Now, four other separate sources of violet,
blue, red and yellow light emitting same number of photons as that of green light are brought
near the source of green light.
Assume one photoelectron is emitted out of every 106 incident photons on sphere.
(Take violet = 4136 Å, blue = 5000 Å, red = 7200 Å, green = 4963 Å, hc = 12408 eV Å)

15. No. of photoelectrons emitted from the sphere per second is


(A) 2.5 × 109 (B) 2.5 × 108
7
(C) 2.5 × 10 (D) 2.5 × 106

16. The potential of the sphere when emission of photoelectrons will stop is
(A) 0.7 V (B) 0.5 V
(C) 0.6 V (D) 0.8 V

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Paragraph for Question Nos. 17 and 18

One mole of a monatomic gas undergoes the cycle shown in the


diagram: The pressure, volume and temperature at A are P0, V0 2P0 B
and T0 respectively; the pressure at B is 2P0 and the volume at D
is 2V0. The processes AB and CD are isochoric. During BC DA, C
the gas undergoes the processes such that during an infinitesimal A
contraction or expansion, the heat absorbed dQ, the change in P0
internal energy dU and dW, the work done satisfy the relation: D
1 2
dQ  dU  dW
2 3
For the process BC, DA, we can write V0 2V0
1 2
dQ = dU  dW  dU  dW
2 3
1 1 1 3 1
or,  dU   dW ; or,  RdT   dW
2 3 2 2 3
13
pdV + Vdp  RdT ; or, pdV + Vdp = 0
9
13
or, pV 9 = constant

17. Find the temperature at C


(A) 2T0 (B) 3T0
(C) 25/9 T0 (D) 3 5/9 T0

18. What is the efficiency of the cycle? Assume 25 / 9  1.5,24 / 9  4 / 3 approximately


(A) 24% (B) 30%
(C) 36% (D) 42%
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Chemistry PART – II

SECTION – A
(One Options Correct Type)

This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.

19. O
i SOCl
 2
 Product Major  is
OH  2 2
ii CH N
Ph Me  iii Ag2O
 iv  EtOH
O
OEt
(A) (B)
OEt Ph Me
Ph Me
OEt OH
(C) Ph Me (D) Ph Me
O O

20. Which one of the following reagent can be used for differentiating the Cu2+ and Bi3+?
(A) H2S gas in presence of dil HCl (B) NH4OH(excess)
(C) K4[Fe(CN)6] (D) (B) and (C) both

O
HCl Cat.
21.   X
The compound[X] is
O O

(A) (B)

O
(C) (D)

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22. The compound formed by dissolving gold and platinum in aqua-regia is


(A) [AuCl4]3– and [PtCl6]2– (B) [AuCl4]– and [PtCl6]4–
– 2–
(C) [AuCl4] and [PtCl6] (D) [AuCl4]– and [PtCl6]2–

23. The pair of compounds having the same hybridization for the central atom is
(A) [Cu(NH3)4]2+ and [Ni(NH3)4]2+ (B) [NiCl4]2– and [PtCl4]2–
2+ 2+
(C) [Cu(NH3)4] and [Zn(NH3)4] (D) [Co(NH3)6]3+ and [Co(H2O)6]3+

24. The major products M and N formed in the following reactions are:–

M
OH
H 3
I/Na
C

N OH
CH
2N N
2

(A) H3C
M= N=

N OH N OCH3
(B)
M= N=

N OCH 3 N O
CH3
(C)

M= N=
N O N OCH3
CH3
(D) H3C
M= N=
N O N OH
CH3

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25. The highest occupied MO in N2 and O 2 respectively are (take x-axis as inter nuclear
axis)
(A) 2px, 2py (B) 2py, 2pz
(C) 2px, 2px (D) 2py, 2pz

(One or More than one correct type)


This section contains 07 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.

26. Which of the following statement(s) are correct?


(A) CH3 – Cl > CH3 – F > CH3 – Br > CH3 – I (Order of dipole moment)
(B) Cl2 > F2 > Br2 > I2 (Order of bond energy)
(C) S 2O32 ,S 2O24 ,S 2O52 (All have S – S linkage)
(D) PCl5 > SiCl4 > AlCl3 > MgCl2 (Order of hydrolysis)

27. Which of the following statements is/are true about the transition metal alkene
complexes?
K [Pt Cl3C2H4]
(A) Back bonding weakens the double bond of the alkene
(B)  bonding and back-bonding synergistically strengthen metal alkene interaction
(C) Electron withdrawing substituents on alkene reduce back bonding
(D) –acidic co-ligands on metal strengthen back bonding

28. On electrolysis, in which of the following, O2 would be liberated at the anode?


(A) dil H2SO4 with Pt electrode (B) aq. AgNO3 with Pt electrode
(C) dil H2SO4 with Cu electrode (D) aq. NaOH with Pt electrode

29. Which of them can act as oxidizing agent in acidic as well as in alkaline medium?
(A) KMnO4 (B) K2Cr2O7
(C) H2O2 (D) Cl2
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30. In which of the following reactions benzaldehyde will form in final product.
CN CH3

(A) (B)
SnCl  HCl CrO Cl /CS

2
 
2 2
H O
2
H O 3 3

OH

CO  HCl
(C) 
Anhyd.AlCl /CuCl
 (D)
3 KOH/ 
 CCl4 
H

31. A dilute solution contains ‘t’ moles of solute X in 1 kg of solvent with molal elevation
constant Kb. The solute dimerises in the solution according to the following equation. The
degree of association is .

2X   X2
2 K b t  Tb 
(A) The degree of association  
KbT
(B) The molecular mass observed will be lesser than actual molecular mass
(C) The colligative properties observed will be Tb obs < Tb theoretical ; Tf obs < Tf theoretical;
P obs < Ptheoretical
K K t  Tb 
(D) The equilibrium constant for the process can be expressed as: K  b b 2
 2Tb  K b t 
32. The correct statements about the following reaction are

CH3


 2 6 1B H CH3 COCl/Pyridine H3 O

2 H O /OH
  X     Y     Z   Acetic acid
  2 2

(A) (X) is transisomer of 2-Methylcyclopentan-1-ol


(B) (Y) is Cis isomer of ester
(C) (Z) is geometrical isomers of (X)
(D) (X) and (Z) have identical boiling point

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Paragraph Type (One Option Correct)

This section contains 02 paragraph each describing theory, experiment, data etc. Four questions relate
to the paragraph. Each question of a paragraph has Only One correct answer among the four choices
(A), (B), (C) and (D).

Paragraph for Question Nos. 33 and 34

MnO2 is the most important oxide of manganese. MnO2 occurs naturally as the black coloured
mineral pyrolusite. It is an oxidizing agent and decomposes to Mn3O4 on heating to 530oC. It is
used in the preparation of potassium permanganate and in the production of Cl2 gas. Over half
a million tons per year of MnO2 is used in dry batteries.

33. In the laboratory, MnO2 is made by


(A) Heating Mn in O2
(B) Oxidizing Mn2+ in air
(C) Electrolytic oxidation of MnSO4
(D) Precipitating MnO2 from solution when performing titration of KMnO4 in alkaline
medium

34. In which of the following species, the colour is due to charge transfer.
(I) [Mn(OH)4]2– (ii) MnO24 (iii) MnO2 (iv) KMnO4
(A) I, II, III correct (B) II, IV are correct
(C) I, III are correct (D) only IV is correct

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Paragraph for Question Nos. 35 and 36

Acid-base indicators are either weak organic acids or weak organic bases. Indicators change
colour in dilute solution when the hydronium ion concentration reaches a particular value. For
example, phenolphthalein is a colourless substance in any aqueous solution with pH less than
8.3. In between the pH range 8.3 to 10, transition of colour(colourless to pink) takes place and if
pH of solution is greater than 10 solution is dark pink. Considering an acid indicator HIn, the
equilibrium involving it and it’s conjugate base(In–) can be represented as:
HIn  
 H  In

acidic form basic form

In 
pH of solution can be computed as: pH  pK In  log  
HIn
In general, transition of colour takes place in between the pH range, pKIn  1.

35. An indicator is a weak acid and pH range is 4.0 to 6.0. If indicator in 50% ionized in a
given solution, then what is the ionization constant of the acid?
(A) 10–4 (B) 10–5
–6
(C) 10 (D) None of these

36. Select the correct statement(s)


(A) at midway in the transition of an acidic indicator pH = pKIn
(B) Methyl orange(3.1 to 4.4) is suitable indicator for titration of weak acid and strong
base
(C) Bromothymol blue(6.0 to 7.6) is not a good indicator for titration of HCl and NaOH
(D) Thymol blue(1.2 to 2.8) is a very good indicator for titration of 100 mL of 0.1 M
NH4OH (pKb = 1.74) and 0.1 M HCl

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Mathematics PART – III

SECTION – A
(One Options Correct Type)

This section contains 07 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.

37.  
If roots of quadratic equation x 2  a2  7 x  15a  0 lie on either side of 2, then
complete set of values of a is:
 9
(A) (–2, 4) (B)  2, 
 2
 9  3 
(C)   , 2 (D)  , 6 
 2  2 

38. Consider a triangle ABC and let a, b and c denote the lengths of the sides opposite to
vertices A, B and C respectively. If a  1,b  3 and C  60o , then sin2 B is equal to:
27 3
(A) (B)
28 28
81 1
(C) (D)
28 3

39. 18 points are indicated on the perimeter of a triangle A


ABC (see figure). How many triangles are there with
vertices at these points?
(A) 331 (B) 408
(C) 710 (D) 711

B C

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40. If the mapping f  x   mx  c, m  0 maps [–1, 1] onto [0, 2] then


 1 
tan  tan1  cot 1 8  cot 1 18  is equal to:
 7 
2  1
(A) f   (B) f  
3 3
 1  2 
(C) f   (D) f  
3  3 

nxn1   n  1 xn  1
41. lim where n  100 is equal to:
x 1
e x

 e sin  x
5050 100
(A) (B)
e e
5050 4950
(C)  (D) 
e e

 x 3/5 if x 1
42. Let f  x    3
then the number of critical points on the graph of the
   x  2  if x 1
function is:
(A) 1 (B) 2
(C) 3 (D) 4

43. The equation to the orthogonal trajectories of the system of parabolas y  ax2 is:
x2 y2
(A)  y2  c (B) x 2  c
2 2
x2 y2
(C)  y2  c (D) x 2  c
2 2
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(One or More than one correct type)


This section contains 07 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.

44. If 2cos   sin   1 , then the value of 4 cos   3 sin  is equal to:
(A) 3 (B) –5
7
(C) (D) –4
5

x dx
45. x 4
equals:
 x2  1
2  2x 2  1  1  1  2x  1  1  2x  1  
(A) tan1  C (B)  tan    tan    C
3  3  3  3   3 
1  2x 2  1  1  1  2x  1  1  2x  1  
(C) tan1  C (D)  tan    tan    C
3  3  3  3   3 
Where C is an arbitrary constant.

x 3 5x 2
46. The co – ordinates of the point (s) on the graph of the function, f  x  
  7x  4
3 2
where the tangent drawn cut off intercepts from the co – ordinate axes which are equal
in magnitude but opposite in sign, is:
 8  7
(A)  2,  (B)  3, 
 3  2
 5
(C)  1,  (D) none of these
 6

x 1
47. Let f  x   then which of the following is correct?
x2
(A) f  x  has minima but no maxima.
(B) f  x  increases in the interval (0, 2) and decreases in the interval  ,0    2,   .
(C) f  x  is concave down in  ,0    0,3 
(D) x = 3 is point of inflection

Space for Rough work

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17 AITS-FT-III (Paper-2)-PCM-JEE(Advanced)/20

48.  
If 2xy dy  x 2  y 2  1 dx, y 1  0 and y  x 0   3, then x 0 can be:
(A) 2 (B) –2
(C) 3 (D) –3

49. A line L passing through the point P (1, 4, 3), is perpendicular to both the lines
x 1 y  3 z2 x  2 y  4 z 1
  and   .
2 1 4 3 2 2
2
If the position vector of point Q on L is  a1,a2 ,a3  such that PQ  357, then
a  a 2  a3  can be:
(A) 16 (B) 15
(C) 2 (D) 1

50. Solutions of the differential equation 1  x 2   dy


dx
 xy  ax where a  R, is:
(A) a conic which is an ellipse or a hyperbola with principal axes parallel to coordinates
axes.
(B) centre of the conic is (0, a).
(C) length of one of the principal axes is 1
(D) length of one of the principal axes is equal to 2.

Paragraph Type (One Option Correct)

This section contains 02 paragraph each describing theory, experiment, data etc. Four questions relate
to the paragraph. Each question of a paragraph has Only One correct answer among the four choices
(A), (B), (C) and (D).

Paragraph for Question Nos. 51 and 52

Let f  x   x 2   a  2  x  a2  a  2 . Given a, ,       be real numbers and ,  are the roots


of the equation f  x   0 .

51. If   2   , then a lies in the interval:


(A) (0, 1) (B) (1, 2)
(C) (2, 3) (D) (3, 4)
Space for Rough work

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website: www.fiitjee.com
AITS-FT-III (Paper-2)-PCM-JEE(Advanced)/20 18

52. If both roots of the equation f  x   0 lies in interval  0,  , then range of a, is :
2 
(A)  , 2  (B)  ,  2 
3 
(C)  0,  (D) 

Paragraph for Question Nos. 53 and 54

  6x 2  13  
Let f be an even function satisfying f  x  2   f  x   2    x  R and

  x  2 
 3x, 0  x  1
f x  
 4  x, 1  x  4
[Note: [y] denotes greatest integer function of y.]

53. The area bounded by the graph of f  x  and the x – axis from x = –1 to x = 9 is:
31
(A) (B) 15
2
15
(C) 12 (D)
2

54. The value of f  89   f  67   f  46  is equal to :


(A) 4 (B) 5
(C) 6 (D) 7
Space for Rough work

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website: www.fiitjee.com

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