ey UY SY6YI INEOS Oxide Product Name GASSPEC" TS-10* Solvent Revision Date: Api 29, 2010 Page 1 of7 SAFETY DATA SHEET Section 1: Product and Company Identification Product Name: Product Code: Product Use: Manufacturer Phone Number: 24-hour Emergency: ‘GAS/SPEC* 16-10" Solvent 34342 Gas condtioning solvent INEOS Oxide Block 5501 21255 A Louisiana Huy. 1 South Praquerine, LA 70764 i neosenide.com (008) 268.4767 (CHEMTREC: (809) 424.9300 Indicates a Trademark of INEOS Oxide, Section 2: Hazards Identification GHS Pictogram: Hazard statements: Precautionary statements: USA: Canada: Warning. Causes serious eye ination \Wash hands thoroughly ater handling. Wear protective gloves / protective clothing J eye protection / face protection IF IN-EVES: Rinse cautiously with water for several minutes, Remove contact lenses, if present and ‘easy odo. Continue rinsing. If eye inilation persists: Get medical advice/attention, USA: This material is considered hazardous by the OSHA Hazard Communication Standard (28 GFR 1910.1200) This is @ controlled product under WHMIS. Classification D2B [Section 3: Composition / Information on. Ingredients ] larardous ‘Chemical Name ‘Common name GAS No, wee 2.2methyimine)a.etnanot MDEAMothyldiehanolemine | 105-599 | 00-97 Non-Hazardous Ingredients: So me ‘Chemical Name “GAS No. Water ‘Water 7732485 | 1-10 Trade Secret Addie L Proprietary Proprietary | 05-1INEOS Oxide Product Name GASISPEG* T-10" Solvent Revision Date: Apri 2, 2010 Page 2017 SAFETY DATA SHEET Section 4: First Aid Measures Inhalation: Eye Contact: ‘Skin Contact: gestion: ‘Symptoms of exposure to vapors or mists may include coughing, wheezing, sore throat, nausea ‘and difficult breathing. if symptoms are experienced, remove source of contamination of move victim to fresh air. Obtain medical advice. Direct contact with liquid or vapor wil eause serious eye iitation Immediately fush the contaminated eye(S) with lukewarm, gerily flowing water for several ‘minutes, while holding the eyeli(s) oper. Neutral saline solution may be used as soon as tis available. Take care not to nse contaminated water ino the unaffected eye or onto face, If inttation persists, ablain medical attention. Direct contact with the liquid may cause ination with local ciscomfor or pain, redness and ‘swelling, particularly on cut or abraded skin, ‘As quickly as possible, remove contaminated clothing, shoes and leather goods (0.9. watchbands, belts). Immediately wash with plenty of soap and water. Discard contaminated clothing, shoes and leather goods. Ifinitaion persists, obtain medical advice. ‘Swallowing can causé itation of the digestive tract with abdominal and chest palh, nausea, ‘vomiting and diarrhea. Never give anything by mouth if vitim is rapicly losing consciousness, or is unconscious or ‘convulsing. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Have Viti inse ‘mouth wth water again. immediately obtain medical advice. Section 5:__ Fire Fighting Measures Flammable Properties: Suitable extinguishing Media: Unsuitable extinguishing Media: Explosion Data: ‘Speciic Hazards arising from 'e Chemical: Protective Equipment and precautions for firefighters: NFPA Hazard rating: Product may bum if strongly Neated or involved in@ fie. [Flash point > 181°C (> 975°F) PMCC)] Water fog or fine spray, foam, alcohobresistant foam, dry powder. Use water spray to cool fre- exposed containers Violent steam generation or eruption may occur upon application of direct water stream to het product High pressure water streams may scatter hot liquid ‘Sensitivity to Mechanical Impact: Not applicable Sensitivity o Static Discharge: Not applicable During a fre, the chemical components may vaporize; these components can be severely inftating to eyes and respiratory tract. Hazardous combustion products may include and are not limited fo: nitrogen oxides, hycrogen cyanide, carbon monoxide, and carbon dioxide. Evacuate the area and fight fie from a safe distance or a protected location, Approach the fre from upwind to avoid hazardous vapors. Burning liquids may be extingulshed by dition wih water. Water spray may be used fo flush spils avay fram ignition sources. Avo ail contact with this material curing fire fighting operations. Wear chemical resistant ‘Clothing (chemical splash suit) and positive-pressure self-contained breathing apparatus, Contain water un-off if possible, HoINEOS Oxide Pee Page Sot SAFETY DATA SHEET Section 6:__ Accidental Release Measures Personat Precautions: {solate the area: keep ail unprotected paople away from the spill area. Vertilate the area. Wear all proper personal protective equipment as indicated in Section 8, Prevent inhalation exposures, sn ‘contact and possible eye contact. Ensure clear-up is conducted by trained personnel only. Do rot touch or watk through the spied material. Exiinguish or remove all ignition Sources. Spied matatial ‘may pose a sipping hazard. nmental Precautions: Prevent material from contaminating soll and fiom entering sewers or waterways, Methods for Containment: Isolate the spill aroa. Stop the spl iit is'safe to do so. Contain the spi with earth, sand or othe: suitable non-combustible absorbent. Keep materials which can burn away from spilled product. Do ot absorb with sawdust, woodchips or other cellulose materials. Mothods for Clean-up: Clean up spils immediately. Scoop up spilled product and any contaminated absorbents into _sppropriate labeled containers. Contaminated absorbent may pose the same hazards as the splled product. Flush the area with water. [Section 7: Handling and Storage ] Handling ‘Avoid contact with eyes, skin and clothing. Avoid generating mists and vapors. Avoid breathing vapors. Ensure that engineering contro are operating and that protective equipment requirements are being followed. Inspect containers for leaks before handling. Prevent damage to containers, Keep containers closed When notin use. Assume that empty containers contain residues which are hazardous, Discard all contaminated leather items such as watchbands, shoes and belts, Never perform any welding, cutting, soldering, diting or othr tot work on an empty vessel, Container or piping until al iqua and vapors have baen cleared Storage: ‘Store in a cool, cry, well-ventilated area away from sunlight, heat and ignition sources. Keep storage area away fiom work areas. Store away from strong acids and other Incompatible materials (see Section 10). Keep containers tightly cased. Section 8:__ Exposure Controls/Personal Protection sure 6 onsul local authors for acceptable exposure tints ‘Chemical Name ACK WV US_OSHA PEL Russia (s-. TWA} ‘e-ne. WAl ir MAC) (mgim’ (mginn’ (mgier 2,2'-(methylimino)di-ethanol, avec Notestabishea | Not estanisned 5 Not establched Exposure Contr! Engineering Controls: Good general ventilation is normaly sufcen. In places where vapors or mists ofthis material ate ‘teated, local exhaust ventilation Is recommended, Ventiation system should be made of eoroson- resistant mater Personal Protection EyolFace Protection: Wear chemical safety goggles. If splashing is possible wear a face shied ‘Skin Protection: Wear chemical protective gloves made of buty rubber, neoprene, nile or Viton ™. Wear clean, ody-covering coverals. If skin is soralched or cut, impervious gioves andior clothing must be worn ‘oven for brief exposures. Where prolonged or frequently repeated contact could occur, wear impervious body-covering clothing and chemical protective boots,INEOS Oxide Product Name GASASPEC* TS-10" Solvent Revision Date Api 23, 2070 Page dot SAFETY DATA SHEET Section 8: Exposure Controls/Personal Protection, continued Respiratory Protection: Other Protective Equipment: General Hygiene Moasures Raspiratory protection should not be newessary uniess the prequel Is heated ta ralaARa vapors ara mist is craated. If airborne vapor or mist exposure is ikely wear an approved ful-face mask, sef- ‘contained breathing apparatus. if respiratory protection is required, instute @ complete respiracry protection program including selection, i testing, training, maintenance and inspection A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANS! 288.2 requirenents ‘or Canadian Slandards Association (CSA) Standars 294.4-02 must be followed whenever workslace conditions warrant a respirator’ use. Have a safety shower and eye-wash fountain readily avalable for emergency use. Remove contaminated clothing prompily Keep contaminated clothing in closed containers; dieeard ‘oF launder before rewearing. Do not eat, drink or smoke in work areas, Wash hands thoroughy and ‘promptly after hancling this material. Maintain good housekeeping. Inform laundry personnel o! contaminant's hazards, [Section 9: Physical and Chemical Properties ] Physical State: Liqui, viscous Flash Point & method: =191°C (-375°F) PMCO, ASTM D83 ‘Ropearance, Colorand Odor; Pale yelow, faivike amine odor | Autoignition Temperature: Not availabe Odor Threshold Not avaiable Flarimabity Lit in Airs Wot avaiable Fe ~~ Sirona base = Vapor Pressure: BO TIG GAC Relative density THES BT Vapor Density: 7 {water= 1) (air= 4) Parton cooficient: “108 a1 25°C Kaw for MEA) | Evaporation Rat Tot avalabie (n-octanotivater) {(e-Butyl Acotate = 1) Solabity wa water: Boiliig Point: aS BOTY Viscosity: = Freezing Point: Not available fe Decomposition Teimperature: Not avaiable ~ 7 ‘Section 10: _ Stability and Reactivity ‘Chemical Stitt: ‘Stable under normal temperature and pressure. Conditions to Avoid: Incompatible Materials: Hazardous Decomposition Products: Possibility of Hazardous Reactions: Avoid high temperatures and contact with sources of ignition. Avoid direct sunlight ‘Avoid contact with strong acids, strong oxidizing agents, halogenated hydrocarbons and nitrating ‘agents. Decomposition products may include nitrogen oxides, ammonia, itating aldehydes and Ketones. Hazardous decomposition products depend upon temperature, air supply and the presence of other materials ‘Contact with nitrosating agents, under acidic conditions such as nitrous acid, nitrite or nitrogen ‘oxides, can form nitrosamines Some of which are potent carcinogens, Alkanolamine substances are oxidized by air slowly with evolution of heat, This reaction may lead, ‘to spontaneous combustion # the substance is on an adsorbent or on a high surface area material (eg. absorbent material or thermal insulation).INEOS Oxide Product Name GAS/SPEC* T&-10* Solvent Revision Date: Ap 23, 2070 Page Sof 7 SAFETY DATA SHEET Section 11: Toxicological information ‘Acute Health Effects: Inbaletion: Ingestion: ‘Skin: Bye: Chronic Heath Entects: Medical Conditions ‘Aggravated by Exposure: Interactions With Other Chemicals: Relevant Roule(s) of Exposure: Inhelation, ingestion, Skin contact, Eye contact. ‘At oom temperature, exposures to vapors are minimal due to the physical properties. When heated, vapor concentrations may be generated that can cause adverse effects, A harmful concentration of airborne particles can be reached quickly on spraying, Overexposure to alroorne vapors or mists can Cause initation to the respiratory tract. Symptoms of exposure may Include coughing, wheezing and shortness of breath, Component substances have low oral toxicity, bul swallowing large amounts can cause initaion of the digestive tract with abdominal and chest pain, nausea, vomiting and diarrhea, Direct contact with the product may cause skin initation particulary on cut or abraded skin Prolonged skin contact may result in severe ination and the substance being absorbed trough the skin Direct contact withthe product causes serious eye initation. Airbome vapors or mists may cause eye ination. Protonged or repeated overexposure to mists or vapors may result in damage to the respiratory tract, Prolonged or repeated contact with concentrated MDEA may cause severe skin initation and possibly second-degree burns. Repeated skin contact may aggravate an existing dermatitis. Repeated inhalation may aggravate respiratory concitions, such as asthma and bronchitis ‘Amino alcohol ingrecients in this product may react with nities, under acid conditions to form ritrosamines some of which are potent carcinogens, ‘Acute Toxicity Data ‘Shomical Name EDs Decmal ‘LCsinhalation lf = (mg/kg) (4 brs.) MOEA 1 946 (asp ___ 6250 (abe) Not availabe hronie Toxicity Data Carcinogenicity: Sensitization: Neurological Effects: Genetic Effects: Reproductive Effect Developmental Effects: Target Organ Effects: ‘This product does not contain any component that is considered a human carcinogen by IARC {Intemational Agency for Research on Garicer), ACGIH (American Conference of Gavernmental Industrial Hypienists, OSHA or NTP (National Toxcology Program), Not avaiable Not available Not available Not available Not available Not available tion 12; Ecological Information ‘Data for MOEA: ‘Ngee: 72 Hr ECs Desmodesmus subspicatus: 37 mal. 96 Hr ECaa Desmodesmus subspicatus: 20 mal Freshwater ish: ‘96 Hr LCxo Leusciscus ius: 1000-2200 mg [satc) 86 He LCae Fimephales promelas:>1000 mai. 481 EC Daphnia magna: 230 mah.INEOS Oxide Product Name GASISPEC* 76-10" Solvent Revision Date: Apr 20, 2010, Page 6 of 7 SAFETY DATA SHEET ‘Section 12: _ Ecological Information, continued. PersistencelDegradabiity: Bioaccumulation/Accumulation: Mobility: German Water Hazard Classes: ther: Product is expected to biodegrade ready under aerobic conditions, Data foc MDE A ‘Theoretical Oxygen Demand (TOD) is calculates to be 2.29 pip. 28-Day Biochemical Oxygen Demand (80028) is 30-69% of TROD, 5:Day Biochemical Oxygen Demand (BODS) is below detectable limits. Biodegradation reached in Closed Bottle test (OECD Test No. 301 D) after 28 days is 0% Biodegradation rate may increase in soil and/or water with acclimation, ‘Beta for MDEA: Bioconcentration potential is low {BEF <100; and tog Pox <3). Log Pow fs ‘estimated using the Pomona-MedChem structural fragment method fo be -1.202. Data for MDEA: Henry's Law Constant (H) is estimated to be 8.38E-19 alim mimale at 25°C, Potential for mobilty in sol is very high (Koc between 0 and 50), Log sof! organic carbon parttion coefficient (log Kec) is estimated to be 0.48, MDEA isin Hazard class 1, low hazard to waters; #1588. For detailed Ecological data, wite to the address in Section 1 or call INEOS Oxide's Customer Information Center at (866) 865-4767. ‘Waste Disposal Method: usa: canada: Sect ‘DO NOT aischarge into any sewers, on the ground or into any body of water. Store materia for disposal as indicated in Section 7 Handing and Storage. For unused, uncontaminated product, the preferred options include sending toa licensed, permitted recycler, reclaimer incinerator or other thesmal destruction device. Under RCRA, it isthe responsibilty of the user ofthe product to determine, atthe time of disposal, whether the product meets RCRA criteria for hazardous waste. Dispose of in accordance with focal, state and federal laws and regulations. Dispose of in accordance with local, provincial and federal laws and regulations. ‘Waste characterizations and compliance with applicable laws are the responsibilty solely ofthe waste generator. INEOS Oxide HAS NO CONTROL OVER THE MANAGEMENT PRACTICES. OR MANUFACTURING PROCESSES OF PARTIES HANDLING OR USING THIS MATERIAL, ‘THE INFORMATION PRESENTED HERE PERTAINS ONLY TO THE PRODUCT AS SHIPPED INTTS INTENDED CONDITION AS DESCRIBED IN SDS SECTION 2, ‘As a sence to its customers, INEOS Oxide can provide names of information resources to help identity waste management companies and other facities which recycle, process or manage: chemicals or plastics, and that manage used drums. Telephone INEOS Oxide's Customer Information Center af (885) 865-4767 n 14: Transport Information: U.S Hazardous Materiats Regulation (DOT 4SCFR}: Not Regulated Canada Transportation of Dangerous Goods (TDG): Not Regulated wpe: Marine Pollutants: ICAOMATA: Not Regulated Not applicable Not Regulated Other: For regulatory information regarding transport, i required, consult product shipping papers, or your INCOS Oxide representativeINEOS Oxide ‘TSCA Status: SARA Title I! See, 302/304: Sec: 311/312: See. 313: CERCLA RO: WHMIS Classification: SNR Stat NPRI Substances: tional inventories European Union Inventory ‘Australia: New Zealand: Philippine: Product Name GASISPEC* TG-10" soWvent vision Date: Apri 2, 2010, Page? of 7 SAFETY DATA SHEET Section 15:_ Regulatory information USA ‘All component substances are sted in the TSCA laventory "None of the chemicals in this product nave a TPa, Acute Not applicable "Not appiicabie ‘This product has been classified in accordance with the hazard erteria of the Controled Products Regulations and the SDS contains all the information requited by the Controlled Products Regulations, 28 ~ Material Causing Other Toxic Effects ~ due to eye initation. ‘All component substances are listed on Canada's Domestic Substances List (OSL). ‘Not applicable MDEA is listed in EINECS 4208-3127. MDEA is present on the Inventory of Chemical Substances (AICS). "MOEA is present on the Chinese inventory MDEA is present on ENCS; Methyldlethanolamine (2)-300 MDEA is present on the Inventory of Existing and Evaluated Chemical Substances; Methyldiethanclamine KE-24304 MDEA is present on the Inventory MOEA is present on the Inventory of Chemicals and Chemical Substances (PICS). Section 16: _ Other Information Revision date: evision summary: Manufacturer Disclaimer: Prepared by: ‘Apri 20, 2010 ‘October 4, 2008:, Section 1; updated Manufacturer address, Section 4; updated first aid information, Section 6; updated spit information Apiil20, 2010: Update SDS format. Revised Section 8: Exposure Limits. Section 11, acute toxeity data ‘The information provided on this SDS is correct tothe best of our knowledge, information and belief atthe date of ts publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, cisposal and release and is not to be considered as a ‘warranty or quality specification. The information relates only to the spetifie material designated ‘and may not be valid for such material used in combination with any other material or in any process, unless specified in the tex. LEHDER Environmental Services Limited (619) 336-4101 While LEHDER Environmental Services Limited believes thatthe data set forth herein is accural, 25 ofthe date hereof, LEHDER makes no warranty with respect thereto and expressly disclaims ail liability for reliance thereon. Such data is offered solely for your consideration, investigation and veritication.