Laws - Ideal and Combined sample problems part | Nam jnors Chemistry se the Ideal gas law, “PerV-nRT”, and the universal gas constant: BLMBEL L*atm to solve the following problems: ReD.2O% K*mol PV=nRT 1) flhave 4.00 moles of a gas at a pre: temperature? aa re of 5.60 atm and a volume of 12.0 liters, what is the (1 00¥AY(o.o¥200)T * : 3 2) Hf haye an unknown quantity of gas at a pressure of 1.2 atm, a volume of 31 liters, and a temperature of 87 °C, how many moles of gas do | have? Ke 3} +193 Cratm\n)-nfeaadGuox} He 360 3) If contain 3.0 motes of gas in a container with a volume of 60. liters and at d temperature of 400. K, what is the pressure inside the container? oO P(e. 15.0 mal)(o.o%806}(100. 4) (P= atm 4) If have 7.70 moles of gas at a pressure of 0.0900 atm and at a temperature of 56,0 °c, what is the volume of the container that the gasis in? St.0+7?3= 324 K f 4.40 mmol dt. 092003025 x) (V=2.34 x10? L ideal and Combined Gas Laws. Use your knowledge of the ideal and combined gas lows to solve the following problems. (If it involves moles or grams, it must be PV = nT) PV=RRT or PiV;=P2V> hot A toy balloon filed with air has an internal pressure of 1.25 atm and a volume of 2.50 L. If take the balloon to the bottom of the ocean where the pressure is 95 atmospheres, what will the new volume of the balloon be? How many moles of gas does the balloon hold? (Assume T = 285 K) G.2 at) (280) = @5 atm)Y, | ‘© ian = OS atnii(o.033 L) A Gone fiz. 13 motHonors Chemistry Name. JAS Law Mixed review Part! KS ‘Answer the following concept questions: ‘1, What is the ideal gas equation? PvenRT 2, Identify the variables in the ideal gas law equation. af Pepressure Ge gas conttant > 0.08200 Fol Vevelume Te leomperathare Ga telum oely) newot moks 3. Which value of R should you use in a problem? 0.08200 ner 4. Which volume unit must be used in ideal gas law problems? liters Q) 5. How do you convert from mL to L? “4000 mL= 1 L. 6. If given cm3, what should you do? dem?=4 ml 1) FO moles of a gas at a pressure of 5.4 atmospheres have a volume of 120 liters, what is the temperature? (report answer to4sigfigs) 5 - © GG atwi20 L) = (4-0 mol XO os26dt 2) Mycar hasan internal volume of 2600 liters. If the sun heats a car from a temperature of 20° Ctoa temperature of 55° C, what will the pressure inside my.car be? Assume the pressure was initially 760 mm Hg, 20%273= 243K SST S BLE Simm 3) How many moles of gas are in the car in problem #2? ‘Ql atmd@u00 L)= vi(0.08206) (528 K) 4), fthave 17 moles of gas at a temperature of 67 °c, and a volume of 88.89 liters, what is the pressure of the gas? CAT = OL Fest Oe: sot Xoi0x206YGHOY) 95) 6) 7 9) 10) pvenkT If have an unknown quantity of gas at a pressure of 0.5 atm, a volume of 25 liters, and a temperature of 300 K, how many moles of gas do | have? @satm)(as L)= 0 (.07206)(300 %) If thave 21 moles of gas held at a pressure of 78 atm and a temperature of 900 K, what is the volume of the gas? Gatm)V = G1 mot)(o.0x200)(400 K) IF Ihave 1.9 moles of gas held at a pressure of 5.0 atm and in a container with a volume of 50. liters, what is the temperature of the gas? Gorabei GOL) = 0.4 mei looree yy If Ihave 2.4 moles of gas held at a temperature of 97 °C and in a container with a volume of 45 liters, what is the pressure of the gas? 97+473=340N. PUSL)= 4 mel)to.o7 204 )(570.K) P=1.Gahm if |have an unknown quantity of gas held at a temperature of 1195 K in a container with a volume of 25.0 liters and a pressure of 560. atm, how many moles of gas do I have? GOO. sr(25.0 L) = (0.082000) (2145 ¥) If Ihave 0.275 moles of gas at a temperature of 75 K and a pressure of 1.75-atmospheres, what is the volume of the gas? 45 atmyV = 0-275 eel }(o.082 06) IC) If Ihave 72 liters of gas held at a pressure of 3.4 atm and a terhiperatiire of 225 K, how many moles of gas do | have? G4 ate) G2 L) =n (0.08206) (115 &)Gas Laws - Dalton’s Law of partial pressure ~ sample problems part! Y Honors Chemistry __ Name ere Pyar = Pa # Pa + Pat ow | O ee é eae | | Partial pressure of gaé'x: moles of gas-x | moles oF 8% xp, word hike fon, = | ple aston 5 = ee % | i Gas Mixtures and Partial Pressures + Since gas molecules are so far apart, we can assume they behave independently. « The total pressure of a mixture of gases equals the sum of the pressures that each would exert if present alone, « Partial pressure is the pressure exerted by a particular component of a gas mixture, + Dalton's law of partial pressures: In a gas mixture the total pressure is given by the sum of partial pressures of each component: Pt= Pl + P2.+ P3 +. Partial Pressures and Mole Fractions _mole fraction of gas A= moles gas A total # moles of gas Since partial pressures of gases reflect the quantity of @ particular gas, comparing partial pressure with total pressure will give you mole fraction. Note: Mole fraction has NO units 41, carbon dioxide, nitrogen, and oxygen are in a container and exert a pressure of 760 torr, and the partial pressure ‘of carbon dioxide is 0.285 torr, the partial pressure of nitrogen is 593 torr, what is the partial pressure of oxygen? 700 Gagne + Por 2. Mixtures ornate and ton “re used in scuba diving tanks to help prevent "the bends". For a particular dive, 46 O Lof helium at 25.0 C and 1.0 atm, and 12 L of oxygen gas at 25.0 C and 1.0 atm were pumped into a tank with a volume of 5.00 L at 25.0C. Calculate the partial pressure of each gas and the total pressure in the tank at 25 C. (Oa) =CPue(5L) C0 ated (11.1) = (PNEEL) Pue=4 atm Poo® 2 atm Pratat= Sat 3. The partial pressure of oxygen was observed to be 156 torr in air with a total atmospheric pressure of 743 torr. Calculate the mole fraction of 02 present. (Beteer) G43 aeer) 4. Agaseous mixture containing 1.5 mol of Ar and 3.5 mol COs has.a total pressure of 7.5 atm. What is the partial pressure of CO,? "GSpot __ Ths pats 35 ona * OD tN) =| 5, The valve between a 5-L tank containing a gas at 9 atm and a 10 L tank containing a gas at 6 atm is opened. Calculate the final pressure in the tanks. (atm) LY =RGSie). = Pe © Go atm)(401)= Pp, (ISL) Pere 4 atmY Gas law mixed review_Part I! Name. Honors Chemistry ¢ ‘A metal'tank contains three gases: oxygen, helium, and nitrogen. If the partial pressures of the three gases in oe the tank are 35 atm of O,, 5 atm of Ns, and 25 atm of He, what is the total pressure inside of the tank? Pata = 23atmiS ate 2S ate Peoral = 5 abn, 2) Blast furnaces give off many unpleasant and unhealthy gases. Ifthe total air pressure is 0.99 atm, the partial pressure of carbon dioxide is 0.05 atm, and the partial pressure of hydrogen sulfide is 0.02 atm, what is the partial pressure of the remaining air? a. = 0.05 ata + 0.02 atm Pair 3) __ Ifthe airfrom problem 2 contains 22% oxygen, what is the partial pressure of oxygen near a blast furnace? @.220(0.92 atm)= (0.20 abn) 4) Mixtures of helium and oxygen are used in scuba diving tanks to help prevent "the bends". Fora particular dive, 48.9 LLof oxygen gas at 25.0°C and 1.57 atm, and 7.49 L of helium gas at 25.0°C and 1.85 atm were pumped into a tank with a /-Yolume of 600 st 25 orc. Se (S 292 K G.4 at) V= 4x10" mol )o.0r20te) (292 6) V= 0.0030 L. 0030 411000 mL osanenjatoat, 11) The gas pressure in a n aerosol can is 2.5 atm at 25C. Assuming that the gas inside obeys the ideal gas law equation, what would the pressure if the can were heated to 450 C? Bara DAF N5O2TS=IB KR 5 avo). Pe GR GIB) 12) Adeep breath of air has a volume of 1.05 L at a pressure of 720 torr and a body temperature of 37 C. Calculate the number of moles of gas in one breath. Po twer|t a0 _ IRB2 ‘0 tear ste = 0.95 aten BER EHOK (0.96 atm X(4.05 LJ = n fe.08200) (310 O