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Natural gas is considered to be a prormsmg alternative fuel for passenger cars, truck
transportation and stationary engines providing positive effects both on the environment and
energy security. However, since the composition of natural gas fuel varies with location, climate
and other factors, it is anticipated that such changes in fuel properties will affect emission
characteristics and performance ofCNG (Compressed Natural Gas) engines. The purpose of the
present study is to investigate the effects of the difference in gas composition on the engine
performance and emission characteristics. The results show that THC (Total Hydrocarbon)
decreases with increasing WI (Wobbe Index) and MCP (Maximum Combustion Potential). On
the other hand, it is observed that NOx slightly increases as WI and MCP increase. The TLHV
(Total Lower Heating Value of Intake) is proposed in this study as a potential index for
compatibility of gas fuels in a CNG engine. There is a variation in power up to 20% depending
on the composition of gas when the A/F ratio and spark timing are fixed for a specific gas fuel.
Key Words: CNG (Compressed Natural Gas), Emission, Gas Composition, MCP (Maximum
Combustion Potential), Total Lower Heating Value of Intake (TLHV), WI
(Wobbe Index).
13000
different kinds of test gas fuels were chosen to
consider the composition of gases from various WI
regions. The MBT conditions were obtained with 12000
t
Russia(Batuobian)
changing A/F ratio and spark timing for each test
gas. Emission tests were carried out for the MBT 11000
,nand
condition at 1800rpm, bmep of 2.0 bars and at
2400 rpm, bmep of 2.5 bars. ioooo
3Z 34 36 38 40 4Z 44 46
Mep
2. Experimental Apparatus and Fig. 1 Property variation of natural gases
Procedure
which is known to be an indicator of the com-
2.1 Selection of test gas fuels bustion characteristics in engines, is an index for
Over 30 types of natural gases around the world combustion speed and defined as Eq. (1).
are listed with respect to Wobbe Index twn and I.OHz+O.6(CO+ CmHn) +O.3CH4 (I)
MCP ,;cr
Maximum combustion potential (MCP) in Fig. I.
The WI, which is related with the heating value of Hz, CO, CmHn and CH4 are volumetric fractions
gas fuels, is defined as the caloric value divided by of Hz, CO, Csdi« and CH4 in gas fuels, respec-
a square root of the specific gravity. The MCP, tively and d represents specific gravity of the fuel.
Effects of Gas Composition on the Performance and Emissions of Compressed Natural Gas Engines 221
L-
has WI and MCP values similar to those of Gas
B, but have a different gas composition. Note that
nitrogen, carbon dioxide and hydrogen are used
as inert gases for Gas C, E, F, G and H.
N2 All" HZ
40
.
GasH
•
o
3500rpm
2000rpm
u
c ••
~35 GasG
>- U
..
Jl1
'-
Cl
f-
c;;.F
.5
§
>-
3S
'!a- 30
~
-;;30
c
E
i=
GasH
Ga\EG!sD~C .
GasB GasA
U>
t: 25
0
GasF GasG
0
'"
a.
rJ) ~EcisD~B
GOSC GasA
20
34 36 38 40 42 44 46
MCP
(a) 2000rpm (h) 3500rom
Fig. 5 Variation of MBT with respect to MCP
Fig.4 Contours of the engine torque (WOT, Gas B)
has the smallest MCP among HC species, is the
ance contours with a variation of the A/F ratio
main species in natural gas.
and the spark timing for 2000 rpm and 3500 rpm
Effects of TLHV on Engine Power - The WI is
when Gas B is used. The values in the figure
a standard to determine gas compatibility for
indicate the torque (Kg-m) at each operating
general gas appliances regarding the amount of
point and the solid line represents MBT points at
heat. It is not applicable for gas compatibility in
each A(relative A/F ratio) value. At 2000 rpm
engines since WI is defined based on the HHV
unstable combustion phenomena such as
(higher heating value) for the same volume flow
knocking do not occur up to 50° BTDC of spark
rate of gases. In internal combustion engines, the
timing for all cases. In general, power shows the
volume of the gas fuel entering a cylinder is
maximum value near A=0.95, then reduces grad-
different for each gas since the theoretical A/F
ually towards both lean and rich regions. The
ratio is different for each gas even though the size
engine shows stable operation even in the fuel
of the cylinder is the same. Moreover, the LHV
condition as lean as A= 1.25, as observed in pre-
(lower heating value) is appropriate for
vious studies (Ishii et aI., 1994, Turns, 1996). It is
calculating the amount of heat generated in
also observed that power decreases gradually as
engines. Figure 6 indicates the variation of engine
the spark timing advances after the MBT condi-
power with respect to the WI. The power is
tion. This trend is similar at a higher engine speed
generally proportional to the WI, but Gas D,
of 3500 rpm, while power is more sensitive to
which is 100% methane, has quite a low value.
change of A than to change of the spark timing.
This is probably because Gas D has a relatively
Effects of MCP on Spark Timing - The MBT
large difference between HHV and LHV, and its
condition varies with composition of gas since
smaller A/F ratio indicates a smaller volume of
each gas has a different MCP value. Figure 5
gas burning in the engine. In order to confirm
shows variation of the MBT with respect to the
this, the TLHV (total lower heating value of
MCP. The MBT is inversely proportional to the
intake) is proposed for the standard index to
combustion potential, indicating that the gas with
determine gas compatibility for natural gas
a smaller MCP should be ignited earlier since it
engines. This value is defined as an actual amount
requires more time for an initial flame to develop
of the gas entering an engine multiplied by the
sufficiently. The spark timing for Gases E, F and
LHV of the gas. Figure 7 shows the relationship
G needs to be advanced because nitrogen retards
between the engine power and the value nor-
development of the flame. It is also observed that
malized by that of Gas B. Gases D and G move
the amount of methane in fuels plays an impor-
far to the left so that power appears to be pro-
tant role to determine the spark timing for fuels
portional to the TLHV of intake. Therefore, the
without inert gases. It is because methane, which
Effects of Gas Composition on the Performance and Emissions of Compressed Natural Gas Engines 223
,'"
..
r.
. 0 Spark Timing FLXed._
"2
'96
59.
• Fuel Duration Fixed;
592 O_~I Fixed_
"0
sa.
'85
en
'84
sa2
580
.. c~j~
~
,
~ 2000rpm 342
,i ,!.
".0
~ '38
a. 1~::
j 33.2
1.32.8
33 0
i ! 1-
~ 326 ! :
32'
... 322 , l,
o GaoH Gp~
O.:SO 0.82 O.:W o.:.s o.:m o_~ 0.92 0.94 0,96 o.~ 1_~ 1.~2
1320
1.04 1.00 1-\
'NoRelativeto GasB
GaoA ,,",c ",",0 ",",E G¥F GuG GasH
60.'
602
60.0
59.'
Gao'
. condition (2000 rpm)
Gaa H
~ ~:~ GasG:
~-'-
~.
--- -- ----------,
i c "
~
Gao.
se
I.!'
, -
. ---
~
.,
f-~- ----
~
---,
a. o 0
o
GaB GasC
<J. .. .. - I' --
GaoF
o GooE
f
i
_. - ,~ f
u .l
"
92 .- - --
, n~ t.. ~
o
Goo 0
.,
,;
so "
0.970 0,975 0.980 0.985 0,990 0.995 '.000 UlOS 1010 I".~
- - ", .. ~ "
~t
Total Lower Heal Value.Relative 10GasB
"
.. ~i
t .,
f- -- ,il h ~
:
-
Fig.7 Variation of the power with respect to the
Total Lower Heating Value of Intake
" 'i
~1 >
, !i I ~; I- ~ I
L-~~-------;:::====:::;l
I
1.25
6.00
1.20
5.75 l. 1800 rpm
2400 rpm
.. 1.15
! 5.50
~
o
9
...J:
1.10
1.05
1800 rpm
bmep Z.Obar
MBT.~::II1
c:
~ 5.25
.. ..
~ '00 "
"0 5 00
'.; ~.
0.95
i! ill 4.75
0.90
:5
4.50
0.85
0.75 0,80 0.85 0.90 0.95 1 00 1.05 10000 10500 11000 11500 12000 12500 13000 13500 14000
relative WI to Gas B WI
Fig. 10 Variation of the relative amount of THC Fig. 11 Variation of the injection duration with re-
with relative WI to Gas B (1800 rpm) spect to WI
1.25
Variation of THC with the gas compo-
3.2
120
sition
Variation with respect to WI - Figure 10 shows . 1.15
1.05
.. 1800 rpm
bmep 2.0 bar
to Gas B at the engine speed of 1800 rpm. As WI ~
... MBT,).::I1
1.00
~
increases, the amount of THC in the exhaust gas '"
~ 0.95
0.85
.. -,
to be supplied to the cylinder in a larger amount 0.80 0.85 090 0.95 100 1.05 1.10
than that with higher WI in order to obtain the relative MeP to Gas B
same bmep of the test condition. This point is Fig. 12 Variation of the relative amount of THC
confirmed in Fig. II, which shows that the with relative MCP to Gas B (1800 rpm)
amount of supplied gas fuel is inversely propor-
tional to WI. If the amount of supplied gas tion gas temperature. Therefore, the amount of
increases, the unburned hydrocarbon captured in THC for the gas with larger MCP decreases in the
the crevice increases so that the THC in the emission of natural gases.
exhaust gas increases (Matthews, et al., 1996). In Variation of NMHC - For eight kinds of test
the cases of Gas F and G which have lower WI gases, it was observed that the main species in
values, the amount ofTHC does not increase even NMHC (non-methane hydrocarbon) is C2 spec-
though the amount of fuel increases. The reason is ies, especially ethane. Figure 13 shows the varia-
that the HC in the gases does not increase tion of the volume fraction of NMHC with the
proportionally to the amount of fuel compared fraction of CH 4 in HC of gas fuel. Gas A and Gas
with Gas E since these two gases contain large C show relatively larger value since the emission
amount of nitrogen. A similar trend was shown in for two gases has relatively large portion of C2
the result for 2400 rpm. species. Gas B shows the next large value because
Variation with respect to MCP - The effect of it contains larger portions of C3 and C4 species in
the MCP of natural gas fuels on THC of the raw the emission than any other gases. Gas D gives the
emission is shown in Fig. 12. The THC, which is smallest amount of NMHC since the main
normalized by that of Gas B, decreases as the fraction in THC for this gas is methane.
combustion potential of natural gas increases. As Relative Ozone Reactivity - Table 2 shows the
MCP increases, the combustion pressure in the ozone forming potential for each HC species. In
cylinder increases resulting in a higher combus- this study, the hydrocarbon emissions are report-
Effects of Gas Composition on the Performance and Emissions of Compressed Natural Gas Engines 225
~
gO,/
~\
Molecular g03! Molar reI.
• . .. I 4 E"'YlE.,j
weight s He mole He Reactivity
I 1800 rpm
Methane 16.04 0.0148 i 0.137 1.00
-,
bmep 2.0 ba r
MBT,A"1
Acetylene
Ethylene
16.04
18.05
0.50
7.19
13.0
105
54.8
861 . ~=~\
Ethane
Propyne
30.07
40.07
0.15
4.10
,
7.51
164
31.7
691
:.
Propylene 41.08 9.40 I 396 I 1670 75 80 6S 90 95 '00
CH/HC in fuel (%)
Propane 44.10 0.48 I 11.1 89.1
Iso-butane 58.11 1.11 70.3 196
Fig. 14 Variation of the equivalent CH 4 reactivity
n-butane 58.11 1.02 59.3 150
for the ozone formation with the fraction of
methane in fuel (1800 rpm)
Iso-butene 56.11 531 I 198 1150
I. 3-butadiene 54.09 10.9 589 1480
gas fuels. Since ethylene has a large reactivity
value, the gases with a large ethylene fraction in
200 Gas A
the emission such as Gas A appear to form a large
'"0 ~·.,Gas C
amount of ozone. Since the relative reactivity of
'"0
1800 rpm methane is I, there is no difference between the
_ 140 bmop 2.0 bilr
[ ... Gas 8 MBT,l."1
values for THC and NMHC even though the
E: !20
(J
:I:
Gas F .., Gas E amount of methane is dominant in the emission.
::l; '00
z '·"Gas H Furthermore, it is observed that the formation of
.0
GasG ",.
ozone of natural gas emission is inversely pro-
eo
Gas 0 ~
portional to the amount of methane in gas fuels.
40
75 eo ~ ~ " 100
cHiHe In Fue. (%) 3.3 Variation of NOx with the gas composi-
Fig. 13 Variation of NMHC with CH 4/HC in gas tion
fuels (1800 rpm) Variation with respect to WI - Figure 15 shows
variation of NOx with a change of the relative WI
ed on a volume fraction basis. Therefore, the last to Gas B at 1800 rpm. As the WI increases, the
column represents the relative ozone reactivities amount of NOx in the exhaust gas increases. The
of the hydrocarbons on a molar basis, which are higher the burned gas temperature is, the higher
normalized by the value of methane. It is. noted the rate of formation of NOx is. Since WI
that the ethylene, which was observed to be the indicates the heating value for unit volume, the
third major species after methane and ethane in higher WI gives the higher temperature of gas in
the emission for natural gases, has the value as cylinder. But, the curve has a gentle slope. It is
large as 861 (Paulsen and Wallace, 1994). The also possible that the inert gas contained in gas
equivalent CH 4 reactivity of the THC for ozone fuels of lower WI reduces the combustion gas
formation can be calculated by Eq. (2) using temperature.
values in Table 2. Variation with respect to Mep - The effect of
Equivalent CH4 reactivitvw Et.uolume the MCP of natural gas fuels on NOx of emission
fraction) HC X (molar re l, reactioitvise is shown in Fig. 16. NOx, which is normalized by
+ volume fraction of CH4 X I (2) that of Gas B, increases as the MCP of natural gas
increases. As MCP increases, the combustion gas
Figure 14 represents variations of the equiva-
temperature increases. Therefore, the amount of
lent CH 4 reactivities for ozone of THC, NMHC
NOx for fuel with larger MCP increases in the
and ethylene with the methane fraction in HC of
emission even though the change is not dramatic.
226 Byung Hyouk Min, lin Taek Chung, Ho Young Kim and Simsoo Park
2.0
(3) The MBT for natural gas is inversely pro-
1.8
portional to the combustion potential (MCP) of
1.6
the fuel.
1.4
(4) Engine power is shown to be proportional
1.2
E
~ 1.0
... ~---:-------_.!.-.- '--'-~---- .._,-_. to the total heating value of the actual amount of
0" 0.8 ..-~ gas entering a cylinder. The value of TLHV is
Z
0.6 proposed as a potential index for compatibility of
0.4 gas fuels for natural gas engines.
0.2 (5) The THC in the emission of natural gas
0.0
0.75
fuels increases as WI and MCP decrease.
0.60 0.85 0.90 0.95 1.00 1.05 1.10
WI (6) The equivalent methane reactivity for
Fig. 15 Variation of NOx with respect to WI (1800 ozone decreases as the fraction of methane in gas
rpm) fuel increases.
(7) The amount of NOx of CNG engines
2.0 , - - - - ~
increases slightly as the WI and MCP increase.
1.8
1.8
References
1.4
1.2
E _-.!.--a-.---~-- Ishii, M., Ishizawa, S. and Inada, E., 1994,
8: 1.0
II
_ _ _ _ - - - II II ----.