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Chemistry XII PDF
Chemistry XII PDF
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CHEMISTRY CLASS-12th Chapter 1
Bksl voLFkk (Solid State)
lgh fodYi pqfu;sA
Choose and the correct answer :
$ &
1- CsCl esa ;fn Cs dh dksvkfMZus’ku la[;k 8 gks rks Cl vk;u dh dksvkfMZus’ku la[;k
gksxhA
(a) 8 (b) 4 (c) 6 (d) 12
If coordination number of Cs+ is 8 in CsCl then coordination number of Cl– on is.
(a) 8 (b) 4 (c) 6 (d) 12
2- Ýsady nks"k ugha n’kkZ;k tkrkA
(a). AgBr (b). AgCl (c). KBr (d). ZnS
(a) Mol L Sec (b) Mol-1 L-1 Sec (c) Mol L-1 Sec-1 (d) Mol-1 L Sec-1
2- jklk;fud vfHkfØ;k dh nj fuHkZj djrh gSA
¼v½ lfØ; nzO;eku ij ¼c½ ijek.kq nzO;eku ij
¼l½ rqY;kadh Hkkj ij ¼n½ vkf.od nzO;eku ij
The rate of chemical reaction depends Upon.
(A) Active mass (B) Atomic mass (C) Equivalent weight
(D)Molecular mass
Prove that the half life period of the zero order reaction is proportional to the
initial concentration of reactants?
7- vkghZfu;l lehdj.k D;k gS\ bldh mi;ksfxrk D;k gS\
What is arheneius equation give its importance.
8- v)Zvk;qdky ls vki D;k le>rs gksA fl) djks fd izFke dksfV vfHkfØ;k dk
v)Zvk;qdky inkFkZ dh izkjfEHkd lkUnzrk ij fuHkZj ugh djrk gSA
What do you understand by half life period? Prove that half life period of first
order reaction is does not depend upon Initial concentration of element?
9- vfHkfØ;k dh nj dks izHkkfor djus okys pkj dkjdks dks le>kbZ;sA
Describe four factors offecting rate of reaction.
10- vk.kfodrk vkSj vfHkfØ;k dh dksfV esa dksbZ pkj vUrj fyf[k,A
Write any four differences between molecularity and order of reaction.
Chapter-5
lrg jklk;u (Surface Chemistry)
iz-1 lgh fodYi pqfu, &
1- Lo & mRizsjd &
(a) LVkpZ (b) gkbiks (c) QhukYQFksyhu (d) KMnO4
Auto Catalyst is -
(a) Starch (b) Hypo (c) Phenolphthalein (d) KMnO 4
2- vf/k’kks"k.k fØ;k gSA
¼v½ m"ek{ksih ¼c½ m"ek’kks"kh ¼l½ m"ek ifjorZu ugh+ ¼n½ dksbZ ugh
Adsorption process is.
(A) Exothermic (B) Endothermic (C) No heat change (D) None of these
3- dksykbZMh fofy;u dh Ldanu {kerk -------------------------------- fu;e ls fu/kkZfjr gksrh gSA
The Coaglution power of colloidial is determine by …………………….. law
4- dksykbMh d.kksa dk vkdkj ehVj esa fyf[k,A
Write the size of colloidal particle in meter?
5- ftl inkFkZ dh lrg ij vf/k’kks"k.k gksrk gSA mls -------------------------- dgrs gSA
The substance on whose surface adsorption takes place is called ……………………….
6- fdlh vo{ksi dk dksykbMh d.kksa esa cnyuk D;k dgykrk gS\
What is the process known for the conversion of precipitated into colloidal solution?
7- Lo.kZ la[;k D;k gS\
What is gold number?
8- ik;l D;k gS\
What is emulsion?
11- fV.My izHkko dks le>kbZ;sA
Explain Tyndall effect.
12- gkMh+Z 'kqYts dk fu;e fyf[k;sA
Write Hardy-schluze law
Chapter-6
rRoksa ds izFFkdj.k ds lkekU; fl)kar o izfØ;k¡, (General Principle &
Process of Isolation of elements)
1- dksjksflo lCyhesV dk jklk;fud lw= ---------------------- gSA
Chemical formula of corrosive sublimate is ………………………..
2- dSyksey dk lgh lw= ------------------------------- gSA
The Correct formula of calomal is …………………….
3- eSykdkbV ------------------------------dk v;Ld gSA
The are malachite is for ....................
4- ywuj dkfLVd fdls dgrs gS\
What is lunar caustic?
5- >kx Iyou fof/k --------------------- v;Ldks ds fy;s iz;qDr gksrh gSA
Froath floatation is mainly used in ………………… types ores
6- ,Y;qfefu;e dk eq[; v;Ld gS &
¼v½ dksj.Me ¼c½ QsYlikj ¼l½ Øk;ksykbV ¼n½ ckDlkbV
Main one of aluminium is -
(A) Corundum (B) Felspar (C) Cryolite (D) Bauxite
7- izxyu esa dkSu lh HkV~Vh dk iz;ksx gksrk gS \
Which furnace is used for smelting ?
13- uhys FkksFksa dk lw= fyf[k;sA
Write chemical formula of blue vitriol
14- lgh tksM+h cukbZ;s %
dkWye ¼d½ dkWye ¼[k½
1- [kiZj.k fo/kh & Pk¡knh
2- e.Mfof/k & K2HgI4$NaOH
3- usLYkj vfHkdjd & fufdy
4- veyxe & ejdjh
Chapter-7
"P" CykWd ds rRo ('P' Block Elements)
1- bysDVªkWu cU/kqrk vf/kdre gSA
¼v½ F ¼c½ Cl ¼l½ Br ¼n½ I
Which has maximum electron affinity.
(a) F (b) Cl (c) Br (d) I
2- fuEufyf[kr es ls dkSu ugha ik;k tkrk gS\
(a) XeOF4 (b) NeF2 (c) XeF2 (d) XeF6
Which are is not found -
(a) XeOF4 (b) NeF2 (c) XeF2 (d) XeF6
3- lokZf/kd fØ;k'khy gSykstu vEy dk uke fyf[k,\
Write the name of most reactive hallogen acid?
4- vkxZu dk ,d mi;ksx fyf[k,A
Write one use of Argon.
5- mRd`"V xSlks dk pqEcdh; xq.k ---------------------------- gSA
Magnetic Property of noble gases is ………………………...
6- dkSu lk gSykstu rRo m/oZikfrr gSA
Which halogen element is sublimes.
7- dkj.k crkb, &
1- gSykstu jaxhu gksrs gS] D;ks\
2- ¶yksjhu dh bys-ca/kqrk]Dyksjhu ls de gksrh gS] D;ksa\
3- mRd`"V xSls jklk;fud :Ik ls vfØ; gksrh gS] D;ks\
Give reasons –
a) Halogens are colorful. Why?
b) The election affinity of fluorine is less than chlorine. Why?
c) The noble gases are chemically incest. Why?
8- ukbfVªd vEy ds fuekZ.k dh vksLVokYM fof/k dk ukekafdr fp= ,oa iz;qDr
vfHkfØ;k dk lehdj.k nhft,\
Give the labelled diagram for the Ostwald method of preparation of nitric acid.
Write the chemical equation for the reaction involved also?
9- vUrjk gSykstu ;ksfxdks dks le>kb;s\
Explain Inter halogen compounds.
10- QkWLQksl ds ik¡p vkWDlh vEyks ds uke o lajpuk lw= fy[kks\
Write five oxyacids names and structure of phosphorous.
Chapter-8
d & f ds rRo ('d' & 'f' Block Elements)
1. f CykWd ds rRo dgykrs gSA
f block elements are called.
2. EDTA fdl izdkj dk layXuh gS\
Which type of ligand is E.D.T.A?
3- d rFkk f CykWd ds rRoksa eas izeq[k pkj varj fyf[k,\
Write the four main difference between d and f block?
4- ySaFksukbM ladqpu D;k gS\ bldk rRoksa ij izHkko le>kb,\
What is lanthanide contraction? Write its effect on elements?
5- fuEu ds IUPAC uke fy[kksA
¼d½ [Ni(CO)4] ¼[k½ [K2(Hg I4)]
Write IUPAC name of following.
¼a½ [Ni(CO)4] ¼b½ [K2(Hg I4)]
6- dkcZ/kkfRd ;kSfxdksa ds nks mi;ksx fyf[k;sA
Write two uses of Organo metallic Compounds.
7- ySUFksukbZM ladqpu ls vki D;k le>rs gks rFkk blds ifj.kke dks crkb;s \
What do you understand by Lanthanide contraction and write its results also.
8- laØe.k rRoksa dh ifjHkk"kk fyf[k;s ,oa izFke laØe.k Js.kh ds rRoksa ds uke] ladsr o
bysDVªkfud foU;kl fyf[k;sA
Define Transition and elements and write name, symbol and electronic
configuration of first Transition Series.
Chapter-9
milgla;ksth ;kSfxd (Coordination Compound)
fjDr LFkkuksa dh iwfrZ dhft;s &
1- VsVwfbZFkkby ySM ------------------------------ jks/kh gSA
Tetraethyl lead is …………………………. Knock.
2. DMG ,d ----------------------------- ;kSfxd gSA
DMG is a ………………… Compound.
3. K [ Co (CO)4 ] esa dksckYV dh vkDlhdj.k la[;k gS &
(a) +1 (b) +3 (c) -1 (d) -3
The oxidation number of Cobalt in K [ Co (CO)4 ] -
(a) +1 (b) +3 (c) -1 (d) -3
4- izHkkodkjh ijek.kq la[;k dks le>kb,\
Explain EAN?
5- dhysV D;k gksrk gS\
What are Chelates?
6- fuEu ds IUPAC uke fy[kksA
¼d½ [Ni(CO)4] ¼[k½ [K2(Hg I4)]
Write IUPAC name of following.
¼a½ [Ni(CO)4] ¼b½ [K2(Hg I4)]
7- dkcZ/kkfRd ;kSfxdksa ds nks mi;ksx fyf[k;sA
Write two uses of Organo metallic Compounds.
Chapter-10
gSyks,Ydsu ,oa gSyks,jhu (Haloalkane & Haloarenes)
1- fuEufyf[kr vfHkfØ;kvksa dks le>kb,\
¼v½ ÝhMy Øk¶V vfHkfØ;k ¼c½ gSyksQkeZ vfHkfØ;k
Explain the following reaction?
(a) Friedal Craft Reaction (b) Haloform reaction
2- DyksjksQkeZ dh fuEufyf[kr ds lkFk jklk;fud vfHkfØ;k nhft,\
¼v½ ,lhVksu ¼c½ QhukWy dk {kkjh; foy;u
Give the reaction of Chloroform with the following?
(a) Acetone (b) Alkaline solution of phenol
3- Mh-Mh-Vh- ,oa vk;MksQkWeZ cukus dh fo/kh fy[kksA
Write method of Preparation, D.D.T. and Iodoform.
4- DyksjksQkWeZ ls fuEu ;ksfxd dSls izkIr djksxs lehdj.k Hkh fyf[k;sA
¼d½ QkWLthu ¼[k½ Dyksjksfidfju ¼x½ ,flVhyhu ¼l½ QSfuy vkblks
lk;ukbZM
How will you get following compound from chloroform? Write equation also.
(a) Phosgene (b) Chloropicrin (c) Acetylene (d) Phenyl isocyanides
1- izkFkfed] f}rh;d ,oa r`rh;d ,Ydksgy ds foHksn dh foDVj es;j fof/k dks
lehdj.k lfgr nhft,\
Give the victor mayors method for the differentiation among primary,
secondary of tertiary alcohols?
2- ,slh nks vfHkfØ;k,¡ nhft, ftuls fQukWy dh vEyh; izd`fr iznf'kZr gks\
Name the reactions in which the acidic nature of phenols is exhibited?
3- 'khjs ls bZFkkby ,sYdksgy dk fuekZ.k fdl izdkj fd;k tkrk gS] vko’;d lehdj.k
Hkh nhft;sA
How Ethyl alcohol is manufactured by molasses write essential equation also?
4- fuEu vfHkfØ;kvks dks le>kbZ;sA
¼d½ jhej Vhej vfHkfØ;k ¼[k½ dksYcs vfHkfØ;k
¼x½ fofy;elu la’ys"k.k ¼l½ ÝhMy ØkW¶V vfHkfØ;k
Explain following reactions.
(a) Reimer Tiemiann reaction (b) Kolbe reaction
(c) Williamson synthesis (d) Friedal craft reaction
5- D;k gksrk gS tc&
,fYdy esXuhf'k;e gsykbM fØ;k djrk gSA
1- HCHO ls 2- CH3CHO ls
jklk;fud lehdj.k ,oa mRikn dk uke fyf[k;sA
What happned when alky magnesium halide reacts with
1- HCHO 2- CH3CHO
Write chemical equation and name of the product.
6- izkFkfed] f}rh;d o r`rh;d ,Ydksgyksa ds vkDlhdj.k dks jklk;fud lehdj.k
lfgr le>kb,A
Explain the oxidation of primary, secondary and tertiary alcohols with chemical
equations.
7- QhukWy ls fuEufyf[kr dks izkIr djus ds fy, jklk;fud lehdj.k fyf[k, &
i. fidfjd vEy
ii. lSfyflfyd vEy
iii. csUthu
iv. 2]4]6 VªkbczksuksQhuky
Write the chemical reaction to obtain following from phenol –
i. Picnic acid
ii. salicylic acid
iii. Benzene
iv. 2,4,6 tri-bromo phenol
Chapter-12
,YMhgkbZM] fdVksu ,oa dkZcksfDlfyd vEy (Aldehyde, Ketone, Carboxylic acids)
1- fuEufyf[kr dks le>kb,\
¼v½ Dystu la/kuu ¼c½ jkstueq.M vip;u
Explain the following?
(a) Claisen condensation (b) Rosenmunds Reduction
2- Vksysu vfHkdeZd D;k gS\ bldh ,flVfYMgkbM ds lkFk D;k vfHkfØ;k gksrh gS\
What is Tollens reagent? What reaction takes place between it &
acetaldehyde?
3- ;wjksVªksihu cukus dh fof/k o blds mi;ksx fyf[k,\
Write the method of preparation of urotropin and its uses.
4- fuEu vfHkfØ;kvks dks le>kbZ;sA
¼d½ dsfutkjks vfHkfØ;k ¼[k½ ,YMksy la?kuu
¼x½ jkslsueq.M vfHkfØ;k ¼l½ xV~Vjesu dksp la’ys"k.k
Explain following reaction.
(a) Canizaro reaction (b) Aldol condensation
(c) Rosenmunds reaction (d) Gatterman koch synthesis
5- D;k gksrk gS tc dsoy jklk;fud lehdj.k fyf[k;sA
¼d½ ,lhVyfMgkbZM] QkLQksjl iS.VkDyksjkbZM ls fØ;k djrk gSSA
¼[k½ ,lhfVd vEy] veksfu;k ls fØ;k djrk gSA
¼x½ ,lhfVd vEy] bFkkby ,sYdksgy ls fØ;k djrk gSA
¼l½ ,lhVykbZgkbZM] VkWysu vfHkdeZd ls fØ;k djrk gSA
What happens when give chemical equation only.
(a) Acetaldehyde reacts with Phosphorous penta chloride.
(b) Acetic acid reacts with Ammonia
(c) Acetic acid reacts with Ethyl alcohol
(d) Acetaldehyde reacts with Tollen’s reagent.
6- fuEu vfHkfØ;kvksa dks le>kb,A
¼v½ bVkMZ vfHkfØ;k
¼c½ ,YMkWy la?kuu
Explain following reaction -
(a) Etard Reaction
(b) Aldol Condensation
7- fuEu vfHkfØ;k dks le>kb;s \
¼v½ ,LVjhdj.k
¼c½ gsy&cksYgkMZ&tsfyaLdh vfHkfØ;k
Explain the following reaction –
(a) Esterification
(b) Hell-Volhard-Zelinsky Reaction
Chapter-13
ukbVªkstu ;qDr dkcZfud ;kSfxd (Organic Compound Containing Nitrogen)