Chapter 7+8

Kp = Kc (RT) Δ n in the equation if Δ n<0 then:

Kc = Kc, Kc<Kc, Kc>Kc, Kc<0, 2

Excess of BaSO4 was dissolved in pure water at 25oC. if its Ksp = 1 x 10-10 what is the conc: of BA2+ ions in water?

10-10, 10-20, 10-5, 10-6, 3

Pka values of some acids are given below: choose the weaker acid?

HClO4(-10), HBr (-9), H2SO4(-3), HCl (-7), 3

mole
What is the concentration of nitric acid solution having PH of 4?
liter

4, -4, 10-4, 10-10, 2

Pickup the Arrhenius acid or Base:

BF3, NH3, AlCl3, None of the above, 4

Choose the correct order of decreasing basic strength:

MgO < Na2O>P4O10>Al2O3, Al2O3>Mgo>P4O10>Na2O, Na2>MgO>Al2O3> P4O10, P4O10>Na2O>MgO>Al2O3, 3

NH4OH(aq)⇋ NH4+(aq)+ OH-(aq)

Consider the above ionization , Ammonium chloride is added to the system:

Select the correct statement:

The equilibrium will shift to the right, The equilibrium will shift to the left, The equilibrium will remain
undisturbed, The equilibrium will be attained quickly, 3

Which of the following ions can act as both as Bronsted acid and base in solvent water:

CN-, SO-24, CHO-3, PO4-3, 3

The proton acceptor is:

NH3, BF3, HCl, H*, 2

Which one of the following acids has a strong conjugate base?

CH3COOH, HCl, HNO3, H2SO4, 1

The pH of 0.001 M aqueous solution of NaOH is:

6, 13, 11, 12, 3

The aqueous solution of which one of the following compounds maintain its pH constant?

CH3COOH and (NH4)2SO4, NH4NO3 and KNO3, NH4OH and NH4Cl, NH4 OH and NaCl, 3

When does a chemical reaction attain equilibrium:

When forward and backward reaction taking place at the same rate, Reaction takes place, The forward and
backward, There are two reactions with one faster than the other, 1

For a reversible reaction to reach on equilibrium state the reaction said to be carried out in:

Glass vessel, Iron vessel, Open vessel, Closed vessel, 4

Forces controlling the reactions are proportional to the product of the active masses (concentration) of chemicals:

The above statement is of:

Raoult’s law, Le chatlier’s principle, The law of conservation of energy, The law of mass action, 4

A reaction between CO and H2O is CO(g)+H2O ------- CO2(g) + H2 the unit of equilibrium for this reaction is:

Mol/liter, Liter/mol, Dimensionless, Mil/cm3, 3

If Kc is small it indicates that the equilibrium occurs:

At a low product concentration, Only with the help of catalyst, At a high product concentration, None of these, 1

If Kc of a certain reaction is large it indicates that at equilibrium:

the reactants concentration will be high, The products concentration will be low, The products concentration will
be high, The reactants and products concentration will be equal, 3

The equilibrium constant for a reaction N 2(g)+O2(g)  2NO(g) is 4 x 10-4 at 2000 K. in the presence of catalyst
equilibrium is attained 10 times faster. The equilibrium constant in presence of catalyst at 2000 k is:

10x10-4, 4x10-4, 40x10-4, 4x10-2, 2

Consider the reaction 3H2+N2  2NH3 All of the following will lead in this reaction to the production of more NH 3
except:

A decrease in the volume of container, An increase in pressure by addition of hydrogen, Removal of NH 3, An

increase in pressure by addition of nitrogen, 1

H2 + I2 ⇋ 2H this reaction is not effected by:

Volume, Pressure, Temperature, PH, 2

For reaction 2O2(e)⇋2O3(e) Kc = 10-56 at 25oC one can predict:

More O3 is formed, More reactants are consumed, The forward reaction progresses to a large extent, The backward
reaction goes to near completion, 4
Reactant formation in an endothermic reaction would be favoured by which of the following:

Increase in temperature, Decrease in temperature, Nonchanged in temperature, First increase and then decrease in
temperature , 2

Consider the reaction 2SO2 + O2  2SO3 + Heat The yield of SO3 will be maximum if:

Both pressure and temperature are increased, Both pressure and temperature are decrease, Temperature is
decrease and pressure is increased, Temperature is increased and pressure is decreased, 3

The value of K (equilibrium constant) for a reaction?

Is different, at different temperatures, Is the same at different temperatures, Can be the same at
different temperature, is negligible at room temperature, 1

For the exothermic reaction 2NO(8)⇋N2 +O2(8)

Is independent of temperature, Increases as temperature increases, Decreases as temperature increases, Varies

with addition of N2 and O2, 3

Consider the reaction 2SO2+O22SO3+heat. The yield of SO3 will be maximum if:

Both pressure & temperature are increase, Both pressure and temperature are decrease, Temperature is decreased
and pressure is increased, Temperature is increased and pressure is decreased, 4

In the given Exothermic reaction PC3 +Cl2(g)PCl5(g) and increase in yield will be favored by:

Decrease of temperature, Increase of temperature, Keeping temperature, None of these, 1

According to the Bronsted lowery conscept which of the following species cannot function as an acid?

SO4-2, H3O-, HSO4-, N+H4, 1

Which of the following ions can act as a bronsted acid and base in water?

HCO-, CN-, NO3-, PO3-4, 1

The smaller value of Pka:

The weaker the base, The stronger the base, The stronger the acid, None of the above, 2

The values of ionic product kw are 0,64 x10-14 at 18oC from this may be derived that:

Endothermic process, Exothermic process, Vaporization process, Change of H2O into O2 and H2, 1

Which of the following acids has the higest PH value:

HCl, HNO3, HF, H2SO4, 3

An acid is a substance which accepts

An electron pair, proton, an electron, pair of electron, 1