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    8 views2 pages

    File 307

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    shekharc

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    1196 PROPS oF PYSCal iewsii ae ofc because the ected eletons ca, in prieil, be excited to infin vlctics. However, in a metal crys, the seaterng of electrons (rom Ge vibrating atoms produzes fcion wih restricts the mobility of he eletons Electial conde is given by ae were Is he suber of electrons per unit volume, ete electron charge and the elesron sebiiy. The fee lecton model of metals discussed above i oly a special cate ofthe more geerl sodel, viz, be band model of meal. The Fern encgy is nathemaaly given by the expression, = Him, (3 IVP? 43) where Mis the numberof valence electrons per ole of the meal and Vis the molar volume of he tel At temperature above O K, the elestonie kinetic ergy per mole i given by os ‘The eestonecoutribton to thermal energy ste by Feernat ™ &~ & = NET PAGE (45) eee «ste internal energy ofthe meta at some tengeratureT and oi the ineaal energy of fe meal 0K. 5 «tug ‘We may mention here tat depe iasight ino the metalic ste bas been provided by-L. Pauling. NB. Mot, PW. Andenon and Al. Cotrell, The geat indian chemist CNR. Rao, win has conibied to several areas of structural chemistry, is anther pioneer here. Mot and’ Anderson lave given sew theoretical isighis on meas. Mot i text krown fe the meti-insaltor transition and AH, Cael is oe ofthe founding fathers of modem metal. nome 1, Cleat he Ferm eer som tal, iret he dent of the mt O97 co nade aon wane pmo sonia: p= 091 gon? The la tne V of Netley a, Besoin F097 ge Sic sm of a oso vale ects, hoe, te mae f alee eo eal vasomie® Ta, Bw? tel) gente ihf ect eB suas grew 89-107 = 10 ‘a wok) ‘ sample 2. Calelte the electrooi contribution fo the thermal energy at 25°C fa soiam metal, given hat the Frm eoergy af Na b 5:00<10° J. 7108 kg 237xio$ wat 4.4) Satniod + Eaems = PMOTE . we, c i Bona 10? maya. 38510°? FAP asd)? a Serr qx" ead THE SOUND stare 1197 x, anole 23. Cle the ewes, slver mt, gv tthe ste mas of ser ie 174 int the ty te meal 105 7 co ee caameee Sotatin = 105 gon = 105 X10 ky y 2M = 17858 10° gmt : POTOSI = TIOXIO met! Sion wm of gc one vile esr, er, he ate of ee des pe mole of seal nhceea ha : ene ANY? (6:66 x10 597 346.02 «10 wot) F _ scien) Homing starnoae] sommes and Thery of Sls, The bad theory of sls sine a xing vas iereaces ine conti oft wich e mae mechan es eeton hey aed ae Nee Ca Faron! by F. Bloch (of NMR fame, best known for the Bloch ‘equations in NMR), begins wih te Siriper wae equton aod lcoiprts te prods pocatal Seep et ce ons. The eq ths otind, cle he Bloch equatin, watca ase 7 “, Since the potential energy is periodic, Mx) = Mx+na) whee a is the repeat distance along the + dreton ia the lati and i an integer. Bloc gave the solution of Ea. eg “ 12) = wn) exp (ie)

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