INNER ‘US 2016037652681 cu») United States 2) Patent Application Publication co) Pub. No.: US 2016/0376526 Al Smith (43) Pub. Date: Dec. 29, 2016 (54) POTASSIUM SOAPS THAT CAN BE A619 19/10 (200501) THICKENED WITH CHLORIDE SALTS cub 10 (2006.01), C1OM 16904 (200501), (71) Applicant: Vanguaed Soap LLC, Memphis, IN (42) US. € « ) ce CHE 1925 2013.01; CHD 970 (2013.01): CHD 17/049 (2013.01), COM 10524 (2013.01); C1OM 169/04 2013.01) 7 s AGIK 8/36 (2013.01); ABIK 8/20 (2013.01), (73) Assignee: Vanguard Soap LLC, Memphis, TN arg son Guisoly arg fae calsole (ws) CHC 1000 (2013.01, C1OM 2207/1203 (2013.01); C1OM 2201/08) (2013.01); 461K ‘280088 (2013.01) (72) Inventor: Scott A. Smith, Memphis, TN (US 21) Appl. Now 15/197,486 (22) Filed: Jun. 29, 2016 “ny ABSTRACT Related U.S. Application Data ‘Natural quid potassium soap compositions and methods of smantfacturing and using the same are provided with thick- ening by the addition of chloride salts, such as sodinm chloride and potassium chloride. The natural liquid potas- sium soap compositions may contain one or more fatty acids ‘with carbon length ranging Irom four (C4) to twenty-two (60) Provisional application No, 62/186,099, filed on Jun. 29, 2015 Publication Classification (1) Inc. (€22) oF natural fatty acd mixtures with eoconut oi, olive cuic im (2006.01) oil, tallow, sunflower ol, sallower oil andor tll oil fay cup 1704 (2005.01) acids which are saponified with lye. The saponification lye cioM 105724 (2005.01) is preferably potassium hydroxide. Prefered embodiments cic 1m (2006.01), contain potassium salts of fatty acids comprising at least AGIK 836 (2006.01) oleic acid (C18:1 cis-), olive ols, coconut oils or mixtures 461K 8720 (2006.01) thereol. The chloride satis added in ether solid oliguid A610 502 (2006.01) form following saponification and neutralizationUS 2016/0376526 Al POTASSIUM SOAPS THAT CAN BE ‘THICKENED WITH CHLORIDE SALTS CROSS-REFERENCE TO RELATED 'APPLICATIONS| 10001] This application claims priority to U.S. Provisional Application No. 62/186,099 to Scott A. Smith fled on Jun. 20, 2015, the contents of which are incorporated here by reference in its entety FIELD OF THE INVENTION 10002] The present invention is generally dirvcted towards natural Higuid soap compositions that can be thickened with chloride salts and methods for manufacturing thickened natural soap compositions made from various earbon ehain Jength fatty acids BACKGROUND OF THE INVENTION 0003} | Soap can be defined asa salt of one or more of the higher fany acids with an alkali oe metal. Most soaps are made by the action of potassium or sodium hydroxide on ‘animal Tals and vegetable ols (or faty acids), Tae prepa ration of soap directly from the raw fatty acids by the use of ‘lye ether potassium of sodium hydroxide) is refered 10 fs saponification, which is well known in the art of soap manufacture 10004) Commercial potassium soaps generally have low Viseosites, a hash afterfeel, and are not able to achieve viscosity build characteristics with the addition of chloride falls, Poduets curently sold inthe market place are pi cally thickened with cellulosic (such as hydroxyethyl cel Iulose or HEC) or polymeric thickeners if not just left in their natural law viscosity Cwatery”) state. Such thickened ‘commercial potassium soaps are found in numerous prod ucts used as general cleaning soaps. shampoos, body washes, et 10005)" There is a need for soap made with all natural products that ean maintain a luxurious Feel through peopee Tilly acid and natura oil seletion as well a thee ability 10 be thickened with chloride salts without separating, losing their raised viscosity, and clarity SUMMARY OF THE INVENTION 10006] _ Accordingly, tis an object of the present invention to provide novel natal liquid soap compositions and meth- ‘ods that overcome these and other problems of the prio at by providing natural liquid soap compositions thickened wth chloride salts that ean maintain a luxurious fee through proper fay acid and natural ol selection as well as tei bility to not lose their raised viseosity and elaity In one aspect, the preseat invention provides @ method of manu facturing of & natural liquid soap composition comprising the step of saponifying one or more fatty acids ranging in ‘carbon length from four (C8) to twenty-two (C22). In some nboiments, the Faty acids comprise a mixture of Tatty ids ranging in carbon length from four (C4) to twenty-two. (C22), In some embodiments, natural fatty acid mixtures ‘with coconut oil, ove ol, tallow, sunflosser ol, sallower oil, and/or tall oil fatty ackls are used. In some preferred ‘embodiments, the fatty acids comprise at least oleic acid (CI8:1 cis-9). In other preferred embodiments, the fatty ids comprise at leat olive oils. In ther preferred embod ments, the fatty acids comprise at least coconut oils. Instill Dee. 29, 2016 other preferred embodiments, the faty acids comprise at least oleic acid (C18:1 cis-9}, olive oils, coconut oils or mixtures thereof, The step of saponification may be per formed by adding Iye in some embodiments. In preferred embodiments, the Iye is potassium hydroxide. For thieken- ing, chloride salts are added following saponification and neutralization and may be added to the reaction vessel in solid or solution form. Preferably. the chloride salts are Selected from either sodium chloride or potassium chloride fr combinations thereof [0007] In another aspect, the present invention provides @ ‘atural_tiquid soap composition comprising one or more ssponified fatty acids ranging in carbon length from four (C4) to twenty-two (C22). In some embodiments, the fry acids comprise a mixture of fatty acids ranging in earbon Teng from four (4) to twenty-two (C22). In some embed cals, natural ety acid mixtures with coconut ol, ove oi tallow, sunflower ol, slower el, andor tal ol fatty acids fare used, In some preferred embodiments, the faty acids comprise at least oleic aid (C18: cis). In other preferred embodiments, the fatty acids comprise at last olive ols. In other preferred embodiments, the faty acids comprise at Teast coconut oils. In stil other preferred embodiments, the fatty acids comprise atleast oleic acid (C18:1 cis), olive oils, coconut oils or mixtures thereof, In preferred embod ‘ments, the saponified fatty acids are prepared with potas- sium hydroxide. The natural liquid soap composition is thickened with a chloride salt, which may be added to the reaction vessel in solid or solution form. Preferably, the chloride salt is selected from either sodium chloride or potassium chloride or combinations thereof. [0008] In another aspect, the present invention provides 2 ‘aural figuid soap composition in vatiows administration forms, such as soaps (iguid or foaming cleansers), wipes shampoos, lotions, body’bath soap gels, exfoliate cleansers ‘nd industrial soaps and lubricants comprising one or more Ssponified fatty acids ranging in carbon length from four (C4) to twenty-two (C22). In some embodiments, the fatty acids comprise @ mixture of fatty acids ranging in earbon Jenuth from four (C4) to twenty-two (C22). In some embod ‘ments, natural fatty eid mixtures with coconut ol, olive o} ‘allo, sunflower oi, sflower oil, andor tal ol fatty acids fre used. In some preferred embodiments, the fatty ‘comprise at least oleic acid (C18: cis). In other preferred embodiments, the fatty acids comprise at least olive ols. in other preferred embodiments, the fit acids comprise at Teast eocontt ols In still other preferred embodiments, the fatty acids comprise atleast oleic acid (C18:1 eis), olive oils, coconut oils or mixtures thereof, In preferred embodi- ‘meats, the saponified faty acids axe prepared with potas- sium hydroxide. The natural liquid soap composition is ‘hickened with a chloride salt, which may bo added to the reaction vessel in solid or solution form. Preferably, the chloride salt is selected from either sodium chloride oF potassium chloride oF combinations thercof, DETAILED DESCRIPTION [0009] The following detailed description is presented to tenable any person skilled in the art to make and use the invention. For purposes of explanation, specific details are set forth to provide thorough understanding of the present invention, However, it will be apparent to one skilled in the these specific details are ot required to practice the nti, Descriptions of specitie applications are providedUS 2016/0376526 Al conly as representative examples. Various modifications t0 the prefered embodiments will he readily apparent to one shilled in che ar, and the general principles defined herein may be applied to other embodiments and applications ‘without departing from the scope of the invention. The present invention i no intended wo be limited wo the embodi- ‘ments shown, bu isto be accorded the widest possible seape ‘consistent with the principles and features disclosed herein, [0010] ‘The present invention provides a series of novel natural Higuid potassium soap compositions thickened with ‘chloride salts and methods making the same that overeome the problems of the prior art discussed above, as well as other problems. While the embodiments are discussed herein as being directed toward natural liguid potassium soap compositions and related methods, a pe the art would appreciate thatthe present inv liquid potassium soep compositions and elated methods can be used or as a base of a soap composition (© treat and prevent a variety of microbial infections (or, for example prevention of microbial contamination) by cleansing oF treating the skin andr har of a subject in need thereof, Por ‘example, a subject in need thereof ean be an animal with ‘exposure fo oF susceptibility to a microbial infection oF transfer on or from its skin and/or hair (fur). In preferred ‘embodiments, a subject in nced thereof is @ person with a ‘exposure to or suscepibilty to mierobial infection on the skin or a general need to cleanse the subject's skin of microbial flora, Furthermore, @ person of skill in the art ‘Would appreciate that the present inveation’s natal liquid potassium soap compositions and related methaxls ean be used alone or asa base ofa soap composition eomprising an industria/commereial cleaning agent, an anti-microbial su Jace cleanser, a bath or hand soap(gel, ashampoo, and skin ‘are tions andl creams. [0011] Thus, in one aspect, the present invention provides 8 method of manufacturing a natural liquid potassim soap ‘composition comprising the step of siponifying one or more {itty acids ranging in carbo length fom four (C4) to twenty-two (C22), In some embodiments, the fatty acids ‘comprise a mixture of fatty acids ranging in carbon length Jom four (C4) to twenty-two (C22). In some embodiments, natural ity acid mixtures with coconut ol, live ol, allow. sunflower oil, saflower oil, andor tall ol fay acids are used. In some preferred embodiments the fatty acids com- prise at Teast oleic acid (C18:1 cis-9). In other preferred ‘embosdiments, the fatty acids eoraprise at Teast olive oils, In ‘other preferred embodiments, the fatty acids comprise at least coconut ils. In still other preferred embodiments, dhe fatty acids comprise atleast oleic acd (C181 eis), olive cis, coconut oils or mixtures thereol. The step of supor ‘eation may be performed by adding Iye. Any saponifying ‘counterion ean be used in some embodiments. In preferred ‘embodiments, the lye is potassium hyronide. thickening sep is then performed by adding an appropriate amount of chloride salt, which may be aed tothe reaction vessel in Solid or solution form. Preferably, the ehloride salt is selected from either sodium chloride or potassium chloride ‘or combinations thereof. An appropriate amount is sueh an mount that results in thickening of the natural liquid potassium soap composition without affecting clarity, color, ‘or cause the soap composition to separate or become less viscous afler step completion. The saponified fatty acids (Goap) ate generally foaming water soluble natural liquid potassium soap compositions that are mild tothe skin and Dee. 29, 2016 Ihave excellent color, clarity, and odor. The natural liquid potassium soap compositions exemplified herein are par- ticularly suited for personal care applications like hand ‘washes, body washes, shampoos, and bubble baths. They are also excellent additives for pet care products, hard surface cleaners, and industrial lubrication applications. They may then be processed with other soaps, pigments, detergents, andlor adjuvants/ragrances that are well known in the field or otler processing for preparing commercial soaps, sham- poos, wipes, lotions, hody/hath soap gels, exfoliate eleans- ers, or ereams for use by a subject in need thereof ro ereste 1 further natural Tiguid potassium soap composition of the invention another aspect, the present invention provides a iquid potassium soap composition comprising ome ‘or more saponified fatty acids ranging in carbon length rom four (C4) to twenty-two (C22). In some embodiments, the Tiny acids comprise @ mixture of Fatty acids ranging in carbon length frm for (C4) to twenty-two (C22), In some embodiments, natural fatty acd mixtires with coon 0} olive ol, tallow, sunflower ol, sallower oi, andr tal il fatty acids are used. In some preferred embodiment, the fatty acids comprise atleast oleic acid (C181 cis-D). Inther preferred embodiments, the fatty acids comprise at least olive oils. In other preferred embodiments, the Tay acids comprise at least coconot oils, In still other preferred embodiments, the fatty acids comprise at least oleic acid (C18:1 cis), olive oils, coconut oils, oF mixtures thereof. ‘The fatty acs ranging in carbon length from four (C4) 10 swenty-two (C22) or natural fatty acid mixtures with eoeo- ut oil, olive ol, tallow, sunflower cil, salllower oil, andior tal ol fatty acids are saponified by addition of a lye or other ‘appropriate potassium counterion to create the saponified fatty acids, in some preferred embodiment, the saponifisd {amy acids are prepared with potassium hydroxide as the ye In some preferred embodiments the fatty acide comprise at Teast olete acid (C181 cis-9) In other preferred embodi- ments, the fatty acids comprise at least olive oils. In other preferred embodiments, the fatty acids comprise at least ‘coconut oils. In still other prefered embodiments the fatty acids comprise atleast oleic acid (C1831 cis 9), olive oil, coconut ols, or mixtures thereof. In my practice, the type And source of olive oil has eased no signifieant difference (other than color) in a process batch [0013] 1 have surprisingly found dat substituting at least 4 portion of coconut oil in process batches with natural ‘unsaturated fatty acids, sueh a, but not limited to, oleic acid ricinoleie fatty acid, eurucc fatty ace, olive ols, sunflower oils, andr sallower oils allows fora lower requirement for percent solids in a potassium fatty acid soap while main- ‘aining efetive cleaning ability, However, Thave also found high saturated fatty acid components, such as eocomt oil, is needed to efficiently complete saponification eaetions that also contain oleic acid (inning unsaturated fatty acids and oils, suc as, but not limited to, olive ol). Heving oo ‘much olee acd (unsaturated fatty acidsois) in the reaction ‘ean force the retin to break and resort in high residual oils ‘due to incomplete saponification. A person of skill in the at ‘ean follow the diselosuze herein to determine the best ratio of coconut oils (saturated) to oleic acid (unsaturated) that ‘maintains efficient completion of saponification and main- tains the texture and viscosity required for the intended applicationUS 2016/0376526 Al 10014] |The natural iquid potassium soap compositions are thickened with an appropriate amount of ehlorde,suel as @ chloride salt, which may be added to the reaction vessel in solid or solution form. Preferably, the chloride salt is selected from sodium chloride and potassium chloride, or ‘combinations thersaf. An appropriste amount is such an amount that results in thickening of the soap composition without affecting clarity, color, oF eause the soap composi tion to separate or become less viscous after step comple- tion. The reaction ean be monitored by a person of skill in the art to achieve this, T have surprisingly found that the thickening of the seap compositions with chloride allows for lower percent solids while maintaining cleaning effective- ness and desirable viscosity in abroad range of liquid soap applications, Ihave also supprisingly found that combining the chloride additive with a substitution of cocontt oil (predominantly saturated fatty acids) with oleic acid (pre- ‘dominantly unsaturated fatty acid) has a synergistic effect on the requirements for percent solid ina liquid soap compo- sition while maintaining cleaning effectiveness and desir able viscosity in a broad range of liquid soap applications. For example, as litle as 4.7% (weight) of added sodium chloride to reaction batch will achieve high viscosity in ‘many natural fatty aid or combination natural fatty acids soap compositions 10015] A person of skill in the aet will be able to monitor ‘batch resction during the addition of ehloride to achieve the desired viseosity forthe intended application of that soup ‘composition batch It is also understood that depending om the intended final application forthe natural potassium soup ‘composition, the desired viscosity will vary. Por example, some liquid saponified fatty acids (soap) described herein fare generally foaming water soluble natural soap composi tions that are mild to the skin and have excellent color, clarity, and odor. A viscosity value of about 2,000 cPs at room temperature is generally acceptable for @ hand soap. However, a body wash may be desired to be around 12,000 ‘Ps at room temperature Tor customer acceptance. Also, body wash gels and shampoos may similarly need to be within 12,000 and 40,000 Ps at room temperature. An abrasive or exfoliate liquid soap product will be more “desirable tthe consuming public if thas the consistency of a gel, which is about 40,000 ePs_at room temperature Decreased percent solids in the final consumer product allows for processing batches as liquid soap concentrates that can be further diluted by water to achieve the desired final viscosity for different applications. This discovery has Jed to decreased processing time and wear on reaction vessels, as well at decreased costs per unit of final soup product, among other benefits over the prior ar. {0016} ‘The natural liquid potassium soap compositions ‘exemplified herein are particularly suited for personal eare pplication like hand washes, body washes, shampoos, and bubble baths. They are also excelent additives for pet care products, hard surfice cleaners, and industcial lubrication applications. They may then be processed with other soaps, detergents, pigments, and/or adjuvants/fragrances that are ‘well know in the fick! or other processing for preparing ‘commercial scaps, shampoos, wipes, lotions, bodybath soap gels, exfoliate cleansers, or ereams for use by a subject jin need thereof to crete a further natural lsu potassinm soap composition ofthe invention. Dee. 29, 2016 Example 1 Method of Manufacture [0017] Manufacturing natural liquid potassium soap com- positions that are thickened With ebloride salts has proven {ifcult to achieve in a consistent clear particulate free form. Most commercial produets are therefore thickened with HEC (hydroxyethyl cellulose) or polymeric compounds The following example provides the general procedure sed {o achieve consistent clear particulate freeform for natural Tiquid potssium soap compositions that are thickened with chloride salts. To a reaction flask equipped with agitation, Doeat, thermometer, and nitrogen sparge is added the spe fied amount of fatty acid and or natural ills). Next the specified mas (eg, number of grams) of potessium hy rox- ‘de reactant is added under good agitation with and without ‘nitrogen sparge. Sodium hydroxide ean be used in lew of ‘or in mixtures with potassium hydroxide, which wil quire ferent specified mass bused on the mass difference between sodium and potassium, However, potassinm hydroxide is preferred for Tiguid soap concentrates and ‘applications, Next i added enough water lo make the final product havea solids content af 30-60% by weight, depend Jing on the application or concentrate being prepared. This can be determined by monitoring the reaction as water is added. Nitrogen sparge, whea utilized, is simply nitrogen ‘3 bubbled through the liguid contents ofthe flask ata rate Tow enough aot to produce too muck Foam and arate high enough t0 Keep the color light by minimizing oxidation. While nitrogen spurge is not required in the method, iis advantageous to use in reactions containing base oils or fatty acids of carbon chain length having a susceptibility 10 ‘oxidation in order to prevent color bodies from buildin, The reaction mass i heated to 90-105" C, and i held for 255 hours. [0018] Testing for the itis alkali fllows the reaction progress, Once the theoretical value is reached, the reaction ‘s teminated, When the reaction is terminated, the free alkalinity is then neutralized to an acceptable pH andior alkalinity range with an aceeptable neutralizing agent. For the purpose of dese examples hydrochloric acid andor citric acid were uilized for neutralization: however, those stalled in the art may use other neutralizing agents without Sparing from the spirit and seope of the invention. A person of ordinary skill in the art will understand that an acceptable pH and/or alkalinity range may depend on the intended use ofthe final product (et, hand soap, antiseptic cleaning soap, shampoo, bath gel, et) with most having an alkaline pH. All simple and blended sample compositions Were tested over a range of pH from 8.8 to 13.5, with the ‘optimum range being. from 5 t0 10.2 for liquid soap applications. Upon neutralization to an aceepiable pH andior alkalinity, an appropriate amount of a chloride sal is added {o thicken the compenition. The chloride salt may be added to the reaction vessel in solid or solution form. Preferably, the chloride salt is selected from either sodium chloride or potassium chloride or combinations thereo Preferably, the product is used without adlitional purification or processing. With each Sample (see TABLE. 1), multiple simple and blended compositions of the fatty acidsoils Below were assembled to achieve optimization for different applications. ‘The perwent solids were tested ata range of 18.0% (weight) to 75% (weight), with the optimum being inthe range of ‘38.59% (weight) fo 41.5% (weight) or liquid soap applica-US 2016/0376526 Al tions, As described further below, the batches (especially those with # range around 40% solids, but ot limited 40 these) may be produced as a liquid soap concentrate that may be flsther diluted with water to achieve a final con- sumer quid soap product having 20% or less percent solids Altematively, the concentrated formulations may be pack- ‘age and sold to consumers as eoncenteated potassium soap ‘compositions, which also” generates costs savings in ‘decreased packaging and shipping costs, as well as ‘decreased shelving/somage needed by rl TABLE 1 Sample Fay Asia or OL Nave Cabon Chin 1 Buyroca cace 2 Capote a 3 cape cho 4 Cipgtociee Sten 6 Myre cm 7 Laie eines Fase cle 3 See cit 0 Ome cit Te Ranateis crE0% 2 BewsBunse ence 1 acon Of Wiste OM Dstt 1 lneo Wisi OM Detbton 1S TAO Fay Acid Whe OM Datta Example 2 Butyrie and Caproie Acid: 10019] A sample composition including both butyric faty acid (C4) and caproie fatty acid (C6) according to the teachings above was prepared. The composition comprised about 12.6% (‘seight) butyric fatty acid and about 17.9% (vcight) caproie faty acid. Potassium hydroxide was ‘nchided a about 10.4% (weight). The remaining material in the batch was mostly water, Sulicent citric acid (citrate) was add 10 neuirlize the pH to an acceptable Jevel as discussed above. Also, less than 4% (weight) of sodium chloride was arided to increase the viscosity to a desired evel. Compositions following this general formulation (sth and without modifications) can be used in applications ‘of deodorizing and disinfecting hard surfaces, skin, and b (fur) with low foam, Also, heavy duty cleaning applications Tor metal srfces and other industrial surfaces, Example 3 ‘Caprylic andlor Capric Acid Sample Formulation 1 10020] A sample composition including either or both ‘caprlie fatty acid (C8) and capri fatty acid (C10) accord ing to the teachings above was prepared. The composition ‘comprised about 30.5% (weight) total of eaprylie fatty acid ‘and/or capric Falty acid, Potasim hydroxide was included atabout 10.4% (weight) The remaining material in the batch ‘was mostly water. Silicent cite aed eiteate) was added 10 neutralize the pH to an acceptable level as discussed above. Also, less than 49% (weight) of sodium chloride was added to increase the viscosity to a desired fevel. Compositions ‘ollowing this general formulation (with and without modi fications) can be used in applications of deodorizing and disinfecting hard surfaces, skin, and baie (ur) with low Dee. 29, 2016 foam. Also, heavy duty cleaning applications for n surlaces and other industrial surfaces Example CCaprylie and Caprie Acid Sample Formutation 2 [0021] _A sample composition inch acid (C8) and capric fatty aeid (C10) accor teachings above was prepared. The composition comprised about 12% to about 15% (weight) of eapryie fatty aed and about 12% 10 about 15% (weight) of capeic fatty acid. Pevassium hydroxide was included at about 10.4% (weight). ‘The remaining material in the hatch was mostly water Suliient citi acd (citrate) was added to neutralize the pH toan acceptable level as discussed above. Iso less than 4% (veight) of sodium ebloride was added to increase the viscosity to a desired level. Compositions following this tener Fomulation (with and without modifications) can be ‘sed in applications of deodorizing and disinfecting ard surfaces, skin, and baie (Fur) with low foam, Also, eavy duty cleaning applications for metal surfaces and other industrial surfaces. Pxample 5 Laurie Acid Sample Formation 0022] A sample composition including laurie fatty acid (C12) according to the leachings above was prepared. The ‘composition comprised about 28.8% (sight of laurie fatty acid. Potassium hydroxide was included at about 11 2% (Gveight). The remaining material in the batch was mostly ater, Sullicient cite acid (citrate) was added to neutralize the pil to an acceptable level ax discussed above, Also, less ‘than 4% (weight) of sodium chloride was added o increase the viscosity o a desired level, Compositions following this general formulation (with and without modifications) can be ‘used in applications of general cleansing and washing where high foam is desirable. Example 6 Laurie Acid und Myristc Acid Sample Formulation [0023] A sample composition ineluding both laurie fatty acid (C12) and myristic fay acid (C14) according to the teachings above was prepared. The composition comprised about 20% (weight) of laurie fatty acid and about 8 8% (Gseight) of myristic fatty acid. Potassium hydroxide was ‘included at about 11.4% (weight), The remaining material in the hatch was mostly water. Sufficient citric acd (citrate) vas added 10 neutralize the pH to an acceptable level as discussed above, Also, less than 4% (weight) of sodinm chloride was added to increae the viscosity to a desired level. Compositions following this general formulation (vith and without modifications) ean be used in applications fof general cleansing and washing where high foam is esirable Example 7 Myrisic Acid Sample Formulation [0024] A sample composition including mystic fy acid (C14) according to the teachings above was prepared. The ‘composition comprised about 30% (weight) of mystic fattyUS 2016/0376526 Al id, Potassium hydroxide was included at about 11.4% (Gveight). The remaining material in the batch was mostiy ater, Sullicient ite acid (citrate) was added to neutralize the pll to an acceptable level at discussed above, Also, less than 4% (weight) of sodium chloride was added 10 inerease the viseosty to a desired level. Compositions following this general formulation (with and without modifications) can be ‘sed in applications of general cleansing and washing where high foam is desirable. Example § Palmitie Acid Sample Formulation 10025] A sample composition including palmitie fay acid (C16) aeconting to the teachings above was prepared. The ‘composition comprised about 30.2% (weight) of palmitic fatty acid. Potassium hydroxide was included at about 10.4% (weight). The remaining material in the bateh was mostly water. Sullcient citric acid (citrate) was added neutralize the pH o an acceptable level as discussed above. Also, loss than 4% (weight) of sodium chloride was added to increase the viscosity o a desired level. Compositions following this general formulation (with and without modi fcations) can be used in applications of general cleansing and washing where high foam is desirable Example 9 Palimitic Acid and Stearic Acid Sample Formulation 10026] sample composition including both palmitic fatty cid (C16) and stearic fatty acid (C18) according to the teachings above was prepared, The composition comprised about 20.5% (weight) of palmitic fatty acid and about 10% (oseight) of stearic funy" acid. Potassium hydroxide was ‘included at about 108% (weight) The remaining material in the batch was mostly water. Suficient citric aid (citrate) was adkled to neutralize the pH] to an acceptable level as discussed above. Also, less than 4% (Weight) of sodium ‘chloride was aded to increase the viseosly to a desired Tevel. Compositions following this general formation (sth and without modifications) canbe use in applications ‘of general cleansing. and washing. where high foam is desirable, Example 10 oO [0027] _A sample composition including both oleie fatty ‘acid (C181; omega-9) and stearic fatty acid (C18) according to the teachings above was prepared. The composition ‘comprised about 20% (weight of oleic fatty acid and about 11% (weight) of stearic fatty acid, Potassium hydroxide was included at about 11% (weight). The remaining material i the batch was mostly water. Suficent citric acid (citrate) was added 10 neutralize the pH to an acceptable level as discussed above. Also, less than 4% (weight) of sodium chloride was axided to increase the viscosity to a desired level Compositions following this general formulation (sth and without modifications) canbe use in applications ‘of general cleansing and washing where high foam is desirable, c Acid snd Stearic Acid Sample Fortnlatos Dee. 29, 2016 Oleic Acid and Olive Oil Sample Formulation [0028] _\ sample composition including both oleic fay acid (C18:1; omega-9) and olive oil (ole ol distribution ‘of constituent ils, which will naturally vary by lot and source) according to the teachings above was prepared, The composition comprised about 24% (weight) of oleic fatty acid and about 4% (weight) of olive oil. Potassium hydrox- jde was included at about 9:8% (weight). The remaining ‘material inthe batch was mostly water. Sullcient citric acid (citrate) was added to neutralize the pH 10 an acceptable level as discussed above, Also, less than 49% (weight) of sodium chloride was added to increase the visoosity to a desired level. Compositions following this general foenm- lation (ith and without modifications) ean be used in applications of general cleansing and washing where hiph {eam is desimble. Example 12 Coconut Oi, Oleic Acid, sod Olive Oil Sa Fomulation le [0029] A. sample composition including cocomt oil (shole oil distribution of constituent oils, which will natw- rally vaty by lot and source), oleie fatty acid (C181; ‘omegi-9), and olive vil (shoe ol distribution of constituent oils, which will naturally vary by Jot and source) according {o the teachings above was prepared, The composition comprised about 14% (weight) of eoeonst oil, about 10% (eight) of ole fatty acid, and about 2% (weight of olive oil Potassium hydroxide’ was included at about 98% (weight), The remaining material in the batch was mostly ‘water. Sulicient citric acid (citrate) was added to neutralize the pH to an acceptable level as discussed above, Also, less than 4% (weight) of sodium chloride was added to increase the viscosity to a desired level, Compositions following this gener formulation (with and without modifications) ean be ‘used in applications of general cleansing and washing where high foam is desimble. For some applications, batches following this general formula of Example 12 (or modified versions that comprise less coconut ol and more oli fa acid) can be processed as a concentrated liquid soap com- position while mainisining desired viscosity (controled by percent weight of chloride addition) forthe final product ‘pplication. The concentrates can be diluted with Water to about 20% (weight) solids with no appreciable loss in cleaning effectiveness or packaged as “green” concentrate products Example 13 Myristic Acid and Coconut Oil Sample Fomulation [0030] A sample composition including both myristi fatty acid (C14) and coconut oil (whole oil distibution of eon- stituent ols, which will naturally vary by lot and source) ‘cording 1 the teachings above was prepazed. The com- Position comprised about 20% (weight) of myristic fatty acid and about 12% (weight) of coconut i Potassium hydroxide was included at about 11.8% (weight). The remaining material a the batch was mosly water, Sulicent citric acid (citrate) was added to neutralize the pH to an acceptable level as discussed above, Also, less than 4%US 2016/0376526 Al chloride was added to increase the level. Compositions following this tener formulation (with and without modifications) can be ‘sed in applications of general cleansing and washing where high foam is desirable. For some applications, batches following this general formula of Example 13 (or modified versions that substitute at Teast some coconut il far oleic fatty acd) can be processed as a concentrated liquid soap ‘composition while msintaining desired viscosity (controlled by percent weight of chloride addition) forthe final product application. The conceniates can be diluted with water 10 about 20% (weight) solids with no appreciable loss in ‘leaning effectiveness or packaged as “green” concentrate products Example 14 Coconut Oil and Ricinoleie Acid Sample Formulation 10031] A sample composition including both coconut oil (shole ol distnbation of constitient oils, which will nati- rally vary by lot and souree) and rcinoleie fatty acid (C18:1, ‘Ol omega-9) according to the teachings above was pre pared The composition comprised about 19% (weigh) of ‘coconut ol and about 14% (weight) of ricinolee fatty avi, Potassium hydroxide was included at about 9.8% (weigh. “The remaining material ia the batch was mosly water Sullieient cir acd (citrate) was ade to neutralize the pET to an acceptable level as discussed above. Also less than 4% (Gveight) of sodium chloride was added to increase the Viseosty to a desired level. Compositions following this ‘ener formulation (with and without modifications) can be ‘sed in applications of yeneral cleansing and washing where high foam is desirable. For some applications, batches following this general formula of Example 14 (or modified versions that comprise less encom oil and! more ricinoleie Zany acid or substituted with atleast some oleic Fatty acid) ‘cane processed asa concentrated liquid soap composition While maintaining desired viscosity (contalled hy percent ‘eight of chloride adlitinn) fr the final product application, The concentrates ean be diluted with water to about 20% (seight) solids with no appreciable loss in cleaning ellee- liveness or packaged as “green” concentrate products Example 15 Coconut Oil, Ricinoleie Acid, and Beheni/Purucie Fatty Acids Sample Formulation {0032} A. sample composition including coconut oil (shole oil distribution of constituent oils, which will natu- rally vary by lot and soure),riinoleie fay acid (C181, ‘OF, omega-9), and behenic (C22) andlor eurucicterucie (C22:1; omegs-9) faty acids according to the tea above was prepared. The choice of individual or ratio of behonic fatty acid to eurvce fatty acid will depend on the Jnended final product application or desired viscosity. The ‘composition comprised about 10% (weight) of coconut oi, about 10% (weight) of rcinolee fay aed, and about 8% (Gvcight) total of behene andlor eurucie/ercic fatty acids Potassium hydroxide was ineluded at about 109% (eight. ‘The remaining material in the batch was mostly wate Sullicient citi acd (irate) was added to neutralize the pF to an acceptable level as discussed above. Also less than 4% (eight) of sodium chloride was added (0 inerease the Dee. 29, 2016 viscosity to a desired level. Compositions following this general formulation (with and without modifications) can be ‘used in applications of general cleansing and washing where low to moderate foam is desirable, as wel a skin care and concitioning. applications. For some applications, batches following this general formula of Example 15 (or modified versions that comprise ess coconut oil and! more riinoleie fatty acid and/or enrucie fatty acid) can be processed as a concentrated liquid soap composition while maintaining esired viscosity (controlled by percent weight of chloride sadition) forthe final product application. The concentrates fan be diluted with Water to about 20% (weight) solids with ‘ho appreciable oss in cleaning effectiveness or packaged as “green” concentrate products Example 16 Coconut Oil and Olive Oil Sample Formulation [0033] sample composition including both coconut oil (shoe oil distibution of constituent oils, which will nam rally vary by lot and source) and olive oil (whole oil istrbution of constiruent ois, which will natwally vary by Jot and source) according to the teachings above was pre- pared. The composition comprised about 24% (wejaht) of coconut oil and about 5% (weight) of olive ol. Potassium hhydroxide was included at out 11% (weight). The remain- ing material inthe bateh was mostly water, Suicient cite ‘acid (citrate) was added to neutralize the pH to an acceptable level as discussed above, Also, less than 4% (weight) of sodium chloride was added to increase the viscosity to a Sesired level. Compositions following this general fornn- Jation (vith and without modifications) ean be sed in applications of general cleansing and washing where high eam is desirable. For some applications, batches following this general formula of Example 16 (or modified versions that substitute atleast some eocontt oil for oleiefaty acid andor more olive oil, which typically contains oleic and Tinoleie fatty acids as a majority fraction) can be processed ‘asa concentrated liquid soap composition while maintaining ‘sired viscosity (controlled hy percent weight of chloride addition) for the final product application. The concentrates ‘an be diluted with water to about 20% (weight) solids with no appreciable loss in cleaning elfectiveness or packaged as “green” concentrate products Example 17 ‘Coconut Oil and Tall Oil Fatty Acids Sample Fonmulation [034] sample composition including both coconut oil (stole ol distribution of constituent oils, which will natu- rally vary by lot and source) and tall ol fatty acids (whole oil distribution of eonstitaet oils, which will naturally vary by lot and source) according to the teachings above was prepared. The composition comprised about 24% (weight) fof coconut oil and about 5% (weight) of tal el fatty aids Potassium hydroxide was included at about 11% (weigh). ‘The remaining material in the batch was mostly water Suliient citric ace (itate) was added to neutralize the pH toan acceptable level as discussed above. Iso, less than 4% hn) of sodium chloride was added to’ increase the viseosty to a desired level. Compositions following this general formulation (with and without modifications) can be ‘used in applications of general cleansing and washing whereUS 2016/0376526 Al high foam is desirable, For some applications, batches following this general formula of Example 17 (or modified versions that substitute at Teast some coconut il far oleic Titty ack) can be processed as « concentrated liquid soup ‘composition while maintaining desired viscosity (controlled by percent weight of ebloride addition) forthe final product application, The concentrates can be diluted with water to about 20% (eight) solids with no appreciable loss in ‘leaning effectiveness or packaged as “green” concentrate products, Example 18 Coconut Oil and Tallow: Sample Formulation 1 10035] A sample composition including both coconut oil (shole oil distribution of constituent oils, which will natu- rally vary by lot and source) and tallow (whole oil distri- bution of constituent oils, which will narraly vary by lot ‘and Source) aecoring othe teachings above Was prepared, ‘The composition comprised about 24% (weight) of coconut oil and about $% (weight) of tallow: Potassium hydroxide ‘as included at about 11% (eight), The remaining material inthe batch was mostly water Suficient etic acid (citrate) ‘was added to neutralize the pil to an acceptable level as discussed ahove. Also, less than 4% (weight) of sodium chloride was auided to increase the viseosty to a desired level. Compositions following this general formulation (vith and without modifications) can be use in applications ‘of general cleansing and washing where high foam is desirable, For some applications, batches following this eneral formula of Example 18 (or modified versions that Substitute atleast some coconut oil for oleic fatty) ean be processed as a concentrated lguid soap composition while ‘maintaining desired viseosity (controled by percent weight ‘of chloride addition) for the final product application. The ‘concentrates can be diluted with water to about 20% (Gscight) solids with no appreciable los in cleaning ellee- tiveness or packaged as “green” concentrate products Example 19 Coconut Oil and Tallow Sample Formulation 2 10036] _A sample composition including both coconut oil (sbole oil distribution of constimint oils, whiel will nate rally vary by lot and souree) and tallow (whole oil distr- bution of constituent oils, which will nanrally vary by lot and source) according to the teachings above was prepare. ‘The composition comprised about 20% (weight of coconut cil and about 9% (weight) of tallow: Potassium hydroxide Was included at about 11% (Weight). The remaining material inthe batch was mostly water. Sufiient citric acid (citrate) was added to neutralize the pH to an acceptable level as discussed above. Also, less than 4% (weight) of sodium ‘chloride was axlded to increase the viseosty to a desired Jevel. Compositions following this general formation (sth and without modifications) canbe use in applications ‘of general cleansing and washing where high foam. is desirable. For some applications, batches following this ‘general formula of Example 19 (or modified versions that Substitue at last some eaconurt ol for olee fatty acid) can be processed as a concentrated liguid soap composition while maintaining desired viscosity (contalled hy percent ‘eight of chloride adlitinn) fr the final product application, The concentrates ean be diluted with water 10 about 20% Dee. 29, 2016 (vcight) solids wit tiveness or package tno appreciable loss in cleaning effee- ‘a “green” concentrate products, Example 20 Coconut Oil Sample Formulation 0037] A sample composition including coconut il only (shole ol distribution of eonstituent oils, which will nat rally vary by lot and souree) according to the teachings above was prepared. The composition comprised about 29% (vcight) of coconut ol, Potassium hydroxide was included at about 19% (weight). The remaining material in the bateh ‘was mostly water. Sufficient citi ac citrate) was aed to neutralize the pH to an acceptable level as discussed above Abo, less than 4% (weight) of sodium chloride was added to increase the viscosity to a desired level. Composito following this general omulation (with and without modi- fications) can be used in applications of yeneral cleansing ‘and washing where high foam is desirable. For some eppl cations, bates following this general formula of Fxample 20 (or preferably, modified versions that substitute at least some coconut ol for oleic fety acid) can be processed as 3 concentrated liquid soap composition while. maintaining desired viscosity (controled by percent weight of chloride addition) for the final product application. The concentrates fan be diluted with water to about 20% (weight) solids with ‘ho appreciable loss in cleaning elfestiveness or packaged as “on” concentrate proiets Example 21 ‘Sunflower Oil and Coconnt Oil Sample Fomulation [0038] A sample composition including both sunflower oil (sole ol distribution of constituent oils, which will natu- rally vary by lot and source) and coconut oil (whole oil distribution of constituent ois, which will naturally vary by Jot and source) according to the teachings above was pre- pated. The composition comprised about 24% (weight) oF sunflower oil and about 5% (weight) of eoconut oil. Potss- sum hydroxide was inckuded at about 12% (ocight). The remaining material i the batch was mosily water, Sulice citric acid (citrate) was added to neutralize the pH to an acceptable level as discussed above, Aso, less than 42% (eight) of sodium chloride was added to increase the viscosity to a desired level. Compositions following this general formulation (with and without modifications) can be ‘used in applications of general cleansing and washing where high foam is desimble. For some applications, batches following this general formula of Example 21 (or modified versions that substitute at least some coconut cil far oleic faty acid or more sunflower oil) can be processed as concentrated liquid soap composition while maintaining Gesired viscosity (controlled by percent weight of chloride dition) forthe final product application. The concentrates ‘ean be diluted with water to abont 20% (weight) soids with ‘0 appreciable loss in cleaning effectiveness or packaged as “geen” concentrate products Example 22 Satllower Oil sad Coconut Oil Sample Formulation 0039] sample composition including both saflower oil (shole oil distribution of eonstituent oils, which will nateUS 2016/0376526 Al rally vary by lot and souree) and coconut oil (whole oil lisiribution of constituent oils, which will naturally vary by Jot and source) according tote teachings above was pre- pared, The composition comprised about 249% (weight) of salllower oil and about 5% (weight) of eoeontt oil, Potas- um hydroxide was included at about 12% (eight). The remaining material in the bateh was mostly water. Suficient citric acid (citrate) was added to neutralize the pH to an acceptable level as discussed above. Also, less than 4% (Gveight) of sodium chloride was added to increase the viscosity to a desired level. Compositions following this ener formulation (with and without modifications) ean be ‘sed in applications of general cleansing and washing where high foam is desirable. For some applications, batches following this general formula of Example 22 (or modified Versions that substitute at Teast some eXeonnt il for oleic fatty acid or mote safflower oil) can be processed 3s ‘concentrated liquid soap composition while maintaining desired viscosity (controlled by pereent weight of chloride ‘dkition) forthe final produet application. The concentrates, ‘canbe diluted with wster to about 20% (weight) solids with no upprecable lost in cleaning ellectiveness or packaged as “green” concentrate products Example 23 Sunflower Oil, Coconut Oil, and Olive Oil Sample Formulation [0040] A sample composition including sunflower oil (oshole oil distribution of constiment oils, whieh will nati- rally vary by lot and source), caconnt oil (whole oil distri- bution of constituent oils, which will naaraly vary by lot and source), and olive oil (whole oil distribution of stituent oils, which will naturally vary by lot and source) ‘acconling to the leacings above was prepared. The com- Position comprised about 20% (weight) af sunflower oi, about 5% (weight) of coconut oi and about 4% (weight) of ‘olive oil. Potassium hydroxide was inclided a about 12% (eight) The remuining material in the batch was mostly ‘water. Suficent etic acid (citrate) was added to neutralize the pli to an acceptable level ak discussed above, Also, less than 4% (weight) of sodium chloride was added to inerease the viscosity to desired level. Compositions following this ‘general formulation (with and withou modifications) can be ‘sed in applications of general cleansing and washing where high foam is desirable. For some applications, batches following this general formula of Example 23 (or modified versions that substitute st least some coconut oil for oleic fatty acid or more olive andor sunflower oi) can be pro- ccetsed as a concentrated liguid soap composition while ‘maintaining desired viscosity (controled by percent weight ‘of chloride addition) for the final product application. The ‘concentrates can be diftted with water to about 20% (Gvcight) solids with no appreciable loss in cleaning effee- tiveness or packaged as “green” eoneentate products, ample 24 ‘Salllower Oil, Coconut Oil, snd Olive Oil Saaple Formulation {0041} A sample composition including safflower oil (sbole oil distribution of constimint oils whi will nata- rally vary by lot and source), caconut oil (whole oil distri- bution of constituent oils, which will naturally vary by lot Dee. 29, 2016 and source), and olive oil (whole oil distribution of eon- Stituent oils which will naturally vary by lot and source) according 10 the teachings above was prepared. The €0 position comprised about 20% (weight) of salllower ol, about 5% (weight) of coconut ol, and about 4% (weight) of olive oil. Potassium hydroxide was included at about 12 (eight), The remaining material in the batch was mostly ‘ater. Sulicient citric acid (citrate) was added to new the pH to an acceptable level as ciscussod above. Also, less than 4% (eight) of sodium chloride was added o increase the viscosity o a desired level. Compositions following this gener formulation (with and without modifications) ean be ‘sed in applications of general cleansing and washing where high foam is desimble. For some applications, batches following this general formula of Example 24 (or modifiod versions that substitute atleast some esconut cil for ol fatty acid or more olive andr saflower eil) can be py cessed as a concentrated liquid soap composition whi ‘maintaining desired visosity (controled by percent weight of chloride addition) for the final produet application. The foncentrates can be diluted with water f0 about 20% (veight) solids with no appreciable loss in cleaning elec tiveness or packaged as “reen” concentrate products. [0042] The terms “comprising.” “including,” and “tav- ng,” as used inthe claims and specification herein, shall be considered as indicating an open group tat may inelude other clements not specified. The terms ana the Singular forms of words shall be taken to include the plural {orm ofthe state word, sich that the terms mean that one fo more of something is provided. The term “one” or “single” may be used to indicate that one and only one of sontething is intended. Similarly, other specie things is intended. The terms “prefered “prefer,” “optionally.” “may.” and similar terms are used to indicate that an item, condition or stp being refered t0 is ‘an optional (not required) feature of the invention [0043] ‘The invention has been described with reference to various specific and prefered embodiments and techniques However it should be understood that many variations and ‘modifications may be made while remaining within the spitit and scope of the invention. It will be apparent to one of ordinary skil in dhe at that methods, devices, device ele- ‘ments, materials, procedures and techniques other than those specially described herein ean be applied wo the practice of the invention as broadly disclosed herein withoot resort t0 ‘undue experimentation. All ar-known functional equiva. lents of methods, devices, device elements, materials, pro- cedures and techniques deseribed herein are intended 0 be fencompassed by this invention, Whenever @ range is dis- closed, al subranges and individual valves are intended 10 be encompassed, This ivention is not to be limited by the embodiments disclosed, inluding any shown in the draw- ‘ngs or exemplified inthe specification, which are given by way of example and not of limitation, [0044] While the invention has been deseribed with respect to limited number of embodiments, those skilled in the art, having benefit of this disclosure, will appreciate that other embodiments can be devised which do not depart rom the scope ofthe invention as disclosed herein, Accordingly, the scope of the invention should be limited only by the attached claims. [0045] AIL references throughout this application. for ‘example patent documents including issued or granted pateUS 2016/0376526 Al is or equivalents, patent application publications, and w-pateat literature documents or other source material re hereby incorporated by reference herein in their entireties, as though individually incorporated by reference, to the extent ‘each reference is atleast partially not inconsistent with the ‘disclosure in the present application (Tor example, a refer- ‘ence that is partially inconsistent is incorporated by refer fence except fr the partially inconsistent portion of the reference). Tela: 1A soap composition comprising saponifiod fatty acids with a carbon chain length of C4 to C22 or mixtures thereat and added chloride 2, The soap composition of claim 1, wherein the sapon- fied fatty acids comprise natural oils selected from the group ‘consisting of coconut ol, eve oil tallow, tall fatty acids, sunflower oil sallower oil, and combinations thereof. 3. The soap composition of claim 1, wherein the saponi- fled fatty acids comprise omepa-9 unsaturated fatty acids scleted from the group of oleic acid, ricinaleie acid, and ‘eurcie seid, snd combinations thereot. 4, The soap composition of claim 1, wherein the saponi- fled faty acids were saponified with a lye comprising potassiuin hydroxide and the added chloride was added 10 the saponified fatty aids afer a neutralizing process 8, The soap composition of claim 1, wherein the soap ‘composition with added chloride is more viscous than & similar soap composition only lacking inthe added chloride ‘component 6, The soap composition of claim 1, wherein the soap ‘composition is a hund soup, 1 liguid hand soap, a foaming Tiguid hand soap, bath gt, an exfoliate cleanser, cleaning wipe, a shampoo, a lotion, 2 cream, an industrial soap, or a lubricant, 7. The soap composition of claim 1, wherein the soap ‘composition asa percent solid fom about 18.0% (weight) to about 75% (weigh) 8, The soap composition of claim 7, wherein the soap ‘composition fas a percent solids from about 30% (weight) to about 60% (weight 9, Tho soap composition of claim 8, wherein the soap ‘composition has a percent solid from about 38.5% (weight) to 41.5% (weight, 10. The soup composition of ela 1, wherein the soup ‘composition his a percent solids of 208% (weight) or less. 11, The sogp composition of elaim 1, wherein the added chloride does not affect clarity or color, or eause the soap ‘composition to separate oF become less viscous, Dee. 29, 2016 12. The soap composition of ea fone or more additives from the ar seteruent a soap, a pigment, an adjnvant ‘combinations thereof. 13, The scap composition of claim 1, wherein the added chloride comprises om 4% (Weight) to 7% (weight). 14, The soap composition of claim 1, wherein tae added chloride comprises less than 4% (weight), 15, The soup composition of claim 1, wherein the soap ‘composition iss & viscosity of about 3,000 ePs to about 50,000 oPs. 16, A method of manufacturing a soap composition com prising saponifying fatty acids with «carbon chain length of C410 C22 or mixtures thereof, neutralizing the saponifica- tion reaction to an acceptable level of pH, and adding chloride 17. The method of claim 16, wherein the fatty acids comprise natural oils selected fiom the group consisting of cont ol, olive ol, tally, tall il fatty acid, sunflower oil, salllower ol, and combinations there 18, The method of cluim 16, wherein the fatty acids comprise omega-9 unsaturated fatty acids selected from the aroup of oleic acid, ricinoleic ack, and eurueie acid, and combinations thereof, 19. The method of claim 16, wherein the fatty acids comprise coconut ol and oleic acid 20, The method of claim 16, wherein the fany comprise coconut oil and olive © 21, The method of claim 16, wherein the stop of saponi- fication comprises reacting the fatty acids with Ie. 722. The method of claim 21, wherein the ie i potassium hydroxide 23, The method of claim 16, wherein the soceptable level of pil is between about 8.8 and about 13.5 24, The metho of claim 23, wherein the aoceptabe level ‘of pi is between about 9.5 and about 10.2. 25, The method of claim 16, wherein the chloride is a chloride salt selected from the group consisting of dry sodium chloride, aqueous sodium chloride solution, dry potasium chloride, aquoous potassium chloride solution, ‘and combinations thereot. 26, The method of clsim 16 further comprising diluting the soap composition with water. 27. The method of claim 16 further comprising adding fone or more additives fom the group consisting of 3 etorgent, a soap, a pigment, an adjuvant, a fragrance, and combinations thereof, 28. The method of claim 16, wherein the step of neutral- ination comprises adding a neutralizing agent comprising hydrochloric acid, citric ace, or combinations thereat 1 father comprising ‘consisting of ia fagrance, and fds