2012 (D war fst We Wa ayee sah Reeth wih ers gr ar er Rear Hart dort (20 ar “ANH + 50 aI! +75. oC) age ae mer (CQ) My #1 areal mm "Ka oobi 1S he arr "BNF 35. rest oer arr CF 25 sent ob ete BPE Ue Prater st aifier wet ab care Rey are aber ect ae 'A' 15, ara Bad 35 er aor 'C! #ISwany a ower a oe | eee OF atone a4 ara sh eRe he Bae aT rd ae Te ae ig Ae gear pes ge ad set rer wa aE we—o2 el | ate om et so aPbistee & often weer) ar Pte we ered & | Ee ue et ere OF BT oP Ge B/E Gra ae amr aes oe ia we Be | Waa er a pe LA RU ve FF area a IR ML OT aT aT Fw MT par 1 wes SEY | ame eT A orwP Bf ‘amr sh eae Bere WP] HAT TH, ARTY BH, Pray kate Boe sd weer apf To ah eae are eS | Te Ow ar eel Krstere) 8 ae aree gfttor 9 ay my Arde wy ya woaTa domo we per aed OME Rerco ar exept & arafar st ee rom, Kare) ee amok aT, FT aaehh rae rar 1 age Hees, ah anf ® 1 Smr'Al ge ap7'B! mar wes BD. ser, oC met ord ale ar ap gate err eer CHIEN HHS 25 Me alba HF bar TET | soko mes a ab aye Seer Ree BF seh hace os Roo ah ar eral cer er ant weahar ger ar weet ower wabeeT Ber Gor BY ee ay angio ited any rahe oe 5g coy amt ore sees or er ate Sng opera @ fre seh owen tr wT SY i ‘Snare BY Te OT WH at MRR wel che A et Ree UR | 9. eign arma et aR oy gar ttn Gar ate ree ort mb BAAR BY ore aT Ben 10, ergater ar evar wet of sept nF 2 1 LL, vet er ab armed atl serecer wat art TOT eseesnengeeestnceee aap rer Tf career eh A eee onan & 1 SPPRD/-IAB—1A5/7 RD/2-1AH—1Big ama « Ww ann srirh enye Reis enw aoe ake fata cds ox recat feet sare ir Levene Ler 10 ke 667 10 NaPkye? eae fer: arate 8.854 10° Fie a 10° Hn? Tier a Feria USEFUL FUNDAMENTAL Mass of electron Planck's comstant ‘Charge oP etectron Boltzmann constant ‘Yeloctyof Light 16x10") 167107 667 I Nike Rydberg, constant Avogadre number 885410" Fan! a 107 Eine Molar Gas constants CONSTANTS S11 10K 883 10 Save Low mnee 1381020 3.0% wormsec 1.097% 10? wt 6.023% 10" mole! 8314) Kanne 9.110 Ka 6.63 10sec seine 138 PK 3.0 Lh ice 1,099 20" 6.023» 10" mole" 831K anole‘ LIST OF THE ATOMIC WEIGHTS OF THE ELEMENTS ire ie = ‘Weight ‘Symbol Atomie - uminiur a Gar} Mereun poate ight Americium as 26, x Hig oe ae Eory ce ao Melybdenuin we we 200.59 Acton ab 5 (242) Neopian i. s 35.94 Argon ae BAITS eon ia wo teeas rsenie . 93.988 ig : en AS : i Neptuniucn x, Ba 20483 pela At ie 92 Mickel * (237) lium ak 13734 itrogon, i. at Borylium a # (243) i or Boe Be < La, Robetirn ae ain 14.007 eee a a ga) Serine os i (285) ies ir alladl ue 4 15.9994 Cadmium eae 3 pe SoS ba 6 z Caleium ck ae fae pees P iat Califeraium ia aoe Baca Pt Pe fey Carbon a a ea! BE Pu u Por sate ¢ 3 (281 Balonarn i a (244) one. Ge sii Potassium we (219) a Gs MOIz pra 8 ering a bed s3291 seine! GF ate Chromium Ge a Bat) roman Pe fe bene Shove se a sH—protactovum Pa e (sar) Coapee = ” ae Rogum a eS (231) carium en ba five, patel Rn be (228) Dysprosium by ag ‘aga, Coote Re (ea) oe 56 Rhos Lie stein ium ey " 162.50 ie Rh a Aapaers rela ae * asa) Rubia ia 2 tori Sern x: verze fun ‘ai ui 37 Permit oa s gis. See ge & 101.4 Fane 4 ae. seandlun ae 5 150.35 pescie eh s teon | Seleniuey ae x age agoliniyen 6a (ay —Sieon g Ey 7o98 Galtium ™ ‘Sih bad ad ee # eae Stantivm oe it rasen8 aon i s gusor Sue a a. rae ‘elu nga! Faetalare a azoss Holmium: Hf 2 me Tech bs 7 He toss Termlum tb e 2750 i 49 snasz—_‘Thallum ss an te s dasao Thorium th # ao0a7 He fe tap Thulium ae a are ot ies be sas Tia 5 8 16683 tsainanun oe % fren Titanium " a 889 Javeransiiim x 1 Tungsten i 2 . i " 2 aay vansctom y e ates ur ce wate Xonon = Magnesium é e p.30 nag te e qruat Yuerblum +8 st 198.90, Maneanene a6 £ zamz Yttrium @ To aries ms felevium Wa ae sao Zing 5 » nat jased on mass of C™ (296) Zisconi : w S natural isoto of Ana The ia a = set BSE eaten Aree eee euch cram Etante known isotopes.)recs ey 2 orth Be core A pH Doe IR) TOR) ee) ee oot oe ec foe ann 1 ge gran a gee mer Qo gran & er aver 7 3. ope gran cars HF $0 gear Gree a ee oma fer 8 Rah ant 7 19 2 1d 3.15 0 SIGH Rar os eT aU ar ent Her 2 ae afer om 8 / 90 wand a ober mame mm Bare PF hod 2 3 ism< v3 4. (13) sm = (1/2) anayem 2d a cod 13, There are two points £ and a’ on the equatorat longitudes O* and 90*E, and two other points 8 and Bon the same longitudes, respectively, but at latitude 60°S, The distances (along the latitudes) Detveeen the points 4, A’and #, Ware related by 1 Ad BR 2 sao 2.BB ra 3, Ad'=(13)BB 4. Ad"= (02) BB — — M4. Se) euler war & er tefl # Ur ae Ger 2 1A) Waioris flowing through a tubeas shown, ‘The 3 _ Ca saquier sues wr, 7 BB aH) cross sectional areas aA and Cane equal, and digwa afte & J aw awa ayer @ 7B ot] greater than the cross-sectional arca a, Ifthe ct oF osme cere flow is steady, then the pressure on the walls at B is 1 AgC# yen tome) 1. less than that at A and that at © 2 ABC gen toate ep 2. more than that at A and that at. 3. A 50 Serre endl dare ey 3. tame as that at A nd that at C 4. ALD germ ater oe Cot greet Heo | 4. more than that at A but Jes than that atC. 1S, tah ght or eh ster wa 1S. Match the two lists (ae ar ‘Ravi daieriat Product 1 (Roger ae | [A Limestone [ar Pores B. ras | — |b. Gass ©. Rfer ag |e. emeralds || seer ot Fas D._afre Ta. fete ~ A Bec D A Bc D oa boc a Loa boo 4 2 doc ba 2 doe ba 3a ce db 3 a © db 4d a cb 4 do a eba 16. wee ~60,000 era a geet ater ocreat a {i6. The “C dating method is not usually used for dating organic substances older than ~60,000 years, because i 2 3 4, ong Prufeor a MC meme or mar ae) Arar or, as 1, eh rei at rte Af er ora 2, Fat weet sant ae @ veer “Car wert are Ey 3. ser were MC a ceares sella er | 4, a wr air SC Rufea et gor chor 1 17. 0 aarendt P er ot ada aed #6) Hae ag § aes wh ila axes dy ane P aS ca} af mie? weet 7 Ren ao uP to 7 6 fo te sito dar gore a okra ew Get 1, 252080 2. 42 fan ms 3, 7070 Ae iy 4, 72 Ry fe 18, Wiel soreete Boot Rees at Rac gf aerentha D aad) & (at ony sb are PD a oe eden ar arpa ah 11 2 33 42 73 ard Rowe A a ge a Pr 19, zt rae oar a Hyatt rd 1 Ped ¥ nian & pat a rae ee 2 fe per 4 Ramm bP wh F oredt amma @ sted afte LL Per ferz 2 ier faz: 3 fers fora areal sider acc Rae ie weietar waver afteter seh eurnlar ae oe aie ener a ona fe ey mene afer ORI 4, fer 1 > anor meri ae RCE firs 25 area meetin a res fel 20. oar Gar Bae ce cat A ma CO, a mer fenior @ er Grr at omken Tee as we Ga ont ard sree ot rar wselaor nf ih rod ed orct & Pr 1. querer se coner oP aren ara 2. ae fe A cnr wo ae 81 3. agers oe argomsten are sie) A, eae a opin nda er & | tn ‘such objects rely contain carbon. such objects accumplated "C after their formation, in those times there was no produetion of “C. ‘most of the “C in the sample would have decayed, ismograph reccives a Sewave 60s after it receives the Pavave, I the velocities of P- and S-waves are 7 kms and 6 kaw's respectively, then the distance of the Seismic focus from the seism0 graph is 1, 2520km 7070 ka 2 42km 4 2km 18. The decay ofa radioactive isotope P produces a Stable dauphter isotope D. The ratio of the number of ‘atoms of P10 the number af atoms of Pati 2 halt lives would be Loa 33 2 34 4 2, 19. The scatter plots represent the values measured by: wa similar instruments, Point A in the figures ‘represents the true wslue. Which of the following is a commect description of the quality of these measurements? Ca Vee NB A 1 Fig Fig. 2 2 Bgl Fig. 2 3. ied : Fig. 2 4. Biel Fig. 2: good accuracy, good precision ood accuracy, good precision poor accursey, poor precision ‘good accuracy, poor precision poor accuracy, pood precision poor sccuracy, poor precision. [poor accuracy, poor precision oor accuracy, good precision 10, Even though the concentration of CO: isthe same at sea level and al high altitude, the photosynthetic rate is higher in a plant grown at sea level then in # plant (of the same species) grown at high aliitade, The reason for this is light intensity ix more at sea level. : temperature is lower at higher atte. atmospheric pressure is higher at sca level. relating humidity is higher a sea level,21, ooh (a) rr (8), a+ CI — [CIH:Op] 6H,O + Mg — (Mg(@l,O)6)” (Ay ~@) ser a sree aah (A) er (B) Pa aT 2. (ADF ee wer ar ar (B) ow are aL 3. (A) go ere a re (8) ew are 4, emt (A) men (B) Heme oF / BE, Si, PLS aRaC] A at epeant ar Rerme fret ar sige amend Bae By asi Cle Pes >si Pesesie Cl Si>P>S>Cl 23, eat aia amege 8 wath Gera A 24 3. 4. oot 25, Fe(CO), a7 ateaie sigs at a gaais ae wt UT ther ue ag aP at twat wr ge aes wea a oer 2 oe 8 Shae ret Aa tort AE 1 aie Seay eh & vie ted ah F tart at #1 10 PARTB 21. In the reactions (A) and {B), nH 4 Cl [CIH.O}T GHLO+ Mg" [Mgt ONT” -a ~1By water behaves as Lange in both (A) ana (B) 2 on acid in (A)and a base in (B) 3. abbase in(A) and am acid in (B) 4. alhase in both (A) ond (B) 22. The sive of the of unbitals in Si, PS. follows the order 1 Cl>sa resi 2, CL>P2S>5i 3, BD S>Si>CI 4 Si>P>S>CI 23, The cargeet structure of basic beryllium nitrate fs ISS As, fac kcal Reger \S 5a4 es 24, The total number of Jone pairs of electrons in Ly> Lee 2 3. six A nine 25. If Mésshauee spectrum of Fe(CO), is eeanded in the presence of a magnetic field, te original spectnim sith fvo lines changes into the one wth 1 three lines 2. fourlines 3. five Lines 4 sbelines26. aa Cut oral at Pree at ETA th sepaite ach ar Pre seeyiviethy spear wos hth @ 1 aber #1 1 erent ab [Fe] wer omer ed [Gu] 2. erat ab = [Cu™] aur omar od re) 3. arm ab = [Fe] war anmerr od = sity EDTA, 4, ommet al = [Cu] an ore ed = set EDTA, 21, fed were SCA etd aria Protea wala, ere char b= peers G- wat arf optiibent ory cifares arf 28.DNA vt fe gat riren fmt Gere (CA), caaetis (T), aagedette (C) ards (G), 9 ont cane ee goa 1 AG war CT AC aw GT AG fer AC . AT a7 GC see 29. ormet ot metestabotitr & aneetrem sere & 1 qacg 1 [26 The spcciruphotometie response forthe Ktcation ofa mixture of Fe” and Qu" ions against EDTA | | The corect lemeat is 1. volume ab = [Fe] and volume ed = cu") 2, volume ab = [Cu"} and volume ed = fFe"] 3. volume ab = [Fe] and volume c oxeess EDTA. 4, -yolume ab = [Cu] and volume ed © excess EDTA [27. ls tearbon-dsting” application of radioisotopes, Cemits 1. Bepaetiele 2 aputicle 3. pradiation 4. positron [28. The actual base paics present in the double helical simeture of DNA conlaiing adenine (A, thymine (T), eytosine (C) and guanine (G), are lL. AGand CT 2 ACand Gt 3. AGand AC 4 ATand GC [29,The oxidation state of roa in weet-hemoglebin is 1 three 2 two 3. four 4, eta30, NICO) #t RARE L (L = PMes a POMc)))9 Fe efiiraT NICOL at # ae after 1, Brew woe a # y 2, Reet non we | 3. fire (L,) mere a | 4, RR aa (layer a Ey 31. ime ob ew CD 1 gero-emré 2. ahen-gor # / 3. o-mer n-anm eT E | 4, Wor our an meh tt) 32 a d-gdaery Reary i) Reese or ah ener 2m 2) ngbegt use? 440 tyghe,” Jet ty! &! 33, ae flow (RL) starter at rare raph ob re ot airs Le fe ot aati 1 2. aga pager ope on omer we BT ey 3. arias ot omfierisy voor oe seh Pe eh 4, ieee ay of ya in Rent of elias chen B 1 34. BT vans. (IeCl(COMPPAy}] + Cle + tras[liCl(COMPPhy), ed set retary & veol re) > veo (aierrn Veo (FATE) < veo (sre) Veo (TRIE) = Veg (asec) ool BR) = veo (77 CO} sien 12 30,The reactions of Ni(CO) with the igand L_ (L= PMes of P{OMe},) yields Ni(CO)}L. The reaetion associative dissociative interchange (1) Imterchanye (40) BU.Asa ligand CF Is 1. anlyae-danor 2. aalyandoner 3. both ag-donorsnda m-donor 4. acdonor and a m-aceeptor 32. The correct d-electron configuration showing spin-orbit coupling is Ly gfe De tpt e 3. testa tee? 33.The comect statement for the aggregating nature of alkyl thin (R11 reagent is 1, the carbanion nucleophilivity increases with agercgation, 2, the observed agercgation arises from its electron deficient nature, 3. carbanion nueloophicity does wot depend on aggregation. 4. the extent of aggregation is maximum in polar dative solvents 34 Tor the reaction, mane [EACHOOMPPI;}:] +Ch rane {leCh{COMPPA;), the correct observation Veo¢product) > Wee (reactant) Veo (broduct) < veo (reactant) Soo(Produet) = veo (Tesetant) Voatproduet) = (free C0)35. silted oe gar aera Lar amor str 2. abated ve ager htt omer ot ont ser wear tr @ 3. etRrT hh siketbtta? we enras ator 4. fag og ere wrecriaion ant atior avrag 2) 36, Peeve # arora sraettorees aie & [cru [Reo.y" 1. pWoy 2 3. [MoOJ” 4. 37, faeateater # eh ager emer 1. AKON; 2. 3. CeO, 4. La(OH)s Luton) 38. ce Were A mer pat wae Als fa sme mare | LAAt wf 1 2 AAT AIA ge) 3. A+Al ehh 2 | 4 Anal ama 1 39, arial sinter 2, ab angghas cory at Rg, or srcer te tn! wat sates # rot re weet or sega arch & aa Es 1 Bewe 2, 3 Be 4 40, aagtoer vomg ole srry F Frou er Ri AP B (ao @ te Area / 1 2 20% m 4, 15 a9 OS a0 13 35, The mueclophilic attack on olefins under mild conditions Li alorays facile 2. ismore facile than electrophilic attack on olefins 3. is facile for electron-rich olefins 4. requires activation by coordination to metal 36. Among the following the strongest oxidizing agent is 1. pwo,* 2 [€r0.)* 3. [Mo0g) 4, [Reo] 37. The least basic among te following is LAOH = 2. 2. COM, 4. La(OH)s LOH), 38, For any operator A. and ity adjoint AY, the INCORRECT statement is 1, AAishermitian 2. AAM AlAishermitian 3, A +Atishermitian 4. A-Alicherwitian 39. Por hydeogen-tive atom with a nuclear charge Z, the energy of aubital with principal quantum number “n' follows the elation Lo fan? 2. Banke 7 2 Aeneas 40, The average value of the eadius P—0rS-O>cLO 2. POF SI-O>S—O>CL-O 3, $-O>C-0>P_0>30 4, €-0>8-0>P_O>Si-0 “The strength of pred, Bonding in E— 0 (E = Si, P, $ uid Ci) follows tie onder LL Si-OsP-0>$_0-c1-0 2 PO>s-0>8 020.0 3. 8-0>¢l-aaP_o>8i-0 4. Cl0>S-0>P_O>8i-0 ‘state air ob me Ney # fee dntNt [zat +2 NI — KelengNais) Hah] 2NHNO, —+ Zn(Sb) =2 KN, 4 NE ANIL: He NHINOs wil we # re | 1, REBT ene Marca area ars 2, weet ape: ce Ara 91 3. agri cree oe age ee om igi ee aoa pnt erp) Inthe following resetions earried out in Hiquid NH, Za(Nth)s-t 2 KNHy —> K:{enONH K,2e(NHd + 2NILNO, — 2a 1) I-42. KNO, +4 Ni, KNIleand NHjNO} act respectively ae 1. solvo-asid andl golve-base 2, solvo-base-end solwo-neld 3, canjugate acid and conjugate base 4. conlgate hase sm cunjuste acid stares ger Reerah gata somere seat writin aS bo BuGd 2 wy 3 Dy. Yb % Lm Ye ‘The pair of laniBaniles with the highest third-lonization encray is 1 Emad 2 Euke 3% Dy Yb 4 La Vecn M. 15. 15. 6. 1% nh 1, 22 tebe IN) sre Ree ren eT ren tae HINO, # ea Ree gee wan Bae Lee 2 Kutt 3 Nd) 4 hadith “The lanthanide) ton having the highest partition coefficient between tin-bulylphosphete and -goncontrated HNO is Ll kaan) 2 Bud) 3 Naty «Lut NoHy 1 K10s st ara arma HQUCCL, st Perm Per gor at onreter tr # NGM KIO) + ANC) =) Ny KCL ICL+ SHO gr iia of Veg oh ote oe 1, Nibkateerat ot dy 2 Ile Away 3. CCL a ore CL a wpe ger 4. Ch a garth; & az 2 Oe tra arats ey ag Pr a aig tt 8 | ‘The quantitative deternsination of NH, with KLQ, proceeds in a mixtuce of H{ONCC} as follows NiHle* KIO) + HC] — Sy FRCL + ICE 3H,0 The end point for the titrimetric reaction is consumption of Nati 1 2. ICL formation 3, disappemance ofthe yellow color due to Cl: in CCl, layer 4. disappearance of the Fed color due to Ty in CCI, layer BaTRENCI, (A), PCI (B) mer ASCH (©), #8 aR we rer nem ae we Gt Rr ores ara amet Be EY Lo AmB Amc Bm AB ‘Among the halides, NCI (4), PCL (B) and AsC (C), hose which produce two diferent acids pea etobpinins 1 AmdB 8 Amma Bande ABindc ant & Bye anpt wet or ae L. NES NEVSH,0 2. NHS NF,> HO 3. ThO>NIR> NF 4. hO>NR> NH “The decreasing order of dipale moment of molecules it l. NFx> NH > HO 2. NHS NE > HO 3. O>NH\> NF, 48, n, 79, a. 8 23 FRET fae arachna sore wee mee 1. [Os(COnd 2 [Os(CO)n] 3 [IeaCOe] 4 {Rh{CO)ie) The cluster having araehne ype stnectare is 1. fOsCOhd 2 FOsx(CO}2} 3. GedCOhad 4. [Rh(CO}e] [O-CHORKCO), (RH, sae Rar 1 = 4, 100%) FM CNM ehacw 7 eter were 05°C er ee ob ay Reed weft are weft oben Be Ler CO 2 CO. 3 CO 4 W-Calle “The carbonyl resonance in °C NMR spectrum of f(n'-sHsIRb(CO)], ("Rh muctear spin, | 100%) shows a triplet at -85°C owing to the presence of 1s tetminal CO ueCO 3. we6O a Cay ge eran Bg ore etter tht ag Re ar eee aN RE Le. ag arrest wt he rer fever 2 age wer ae toc aah #1 3. ag cy a ae ne a #1 Sera seer # we wear & pals O30 0 2 07 LO star rg # HY Serer we Low oxidation state complexes are often at-sensitive, but ar rarely water sensitive because 1. Airis reducing in nature while water i inert 2. both airand water re oxidizing innate 3. both airand water are not x-acceptors 4. complexes with low oxidation states will easly lose electrons io Oz but wal not bind (oa donor molecule lke H:0 ny Bays GP REP NMRA Fe aor eer aE 1. mer-{LrCly(PPhs)s) 2, trane-[UCKCOKPF}:) 3. fac {leC] PPh] 4. fimeP HT ‘The metal complox that exhibits triplet as well asa doublet ints "PNMR spestcum is 1, mer-[LeCh(PPA] 2. erane-{eCKCO)FPh):} 3, fac IrCh(PPhs)s) 4 [Pd82, 43 8 Ba. aA 24 age fre 10 ecg om aon ae ir ae 1. {v-C-tgaecKCOyPPR) 2. (W(COMCSIMe NCDONCME),] 3. (LCHCPPas (APT 4. (Ost yBr(PDfayONME)] The complex that BO 2 obey 18 election rules 1. feu Ce) RUCKCOKPP HI] 2. DW(CO),(SiMeNCHNCME);] 3. (ErO(PPnaACASPha}) 4. (Ostan(eMe)NMesIT arate NICU) ages Riana) Misia saan °A,, @ a Be Mar aigaa err a aera at cea Mo & 2 ite 3 awe = rarer of spin-alowed ligand eld onstos for othr NI comple wil Ay acdsee is Lame 2 three 385. 6, 86. m a a8 8, 80 25 se [Ma(CO}! + MeL lw ae #1 1, [MnfCO))"Me- 2... [Mn(CO}sMe} 3 [MCR 4. [(MeCO)MagCO}] ‘The final product of the reaction [Mn(COL) + MeLi-+ is 1 [MnCO)Me 2, [MnfCO}Me} 3. [MaCOR} 4 [(MéeCOyMACO\s) er font La ANH) wr eter 8 ee | 1, HCHeieese) “ANCL LI 2 BSAR LS 3, LiH (exeess) + AICL 4, LiH (exeess) Al > “Phe nesotion thet yoldeFi[ AIH is 1. HEI (excess) + AIC + Li 2 Eat APPLE 3. L3H (eseess) HAC 4 LU (eveets) + AL of chagre Ararar # Bre mame a viet 1 xe 2 Mx 3 1x6 4. BRE The nimbérof microstates fort electron configuration is Lo tee 2 leet a hee ae 228K? ee aah oh ph ae aN iy 14 die gritins ming HP hE) AA Ce a sep) a ag) anda. ebcer 15.3 dist ig! eb al: gol se) at wap) a uote ng (anced & Se 1, =5730 29) 8 1 5000 dow Ta a eit ‘The earbor-14 activity of ar old wood sample ie found to be 14.2 dismewrations min 'y Calculated age of old wood sample, if for 2 Gesh wood sample earbonel@ activity $515.3 isintegrations min" (tn carbon-l+ is $730 sean), ie 1 S00 yea) 2 4.000years 3B yems aS Fyears se8fier FIRAACO) 5] + 21RN(COe] +4C0 [25 °C, $00 atm CO} pre ae ara fla agg soe we re pier tte ete age & Prd AG <0 chm surndaee apie #2 s(AG>0)®. 50, 20, 3 ot 26 ‘Ths ieaetion 3{Rh{CO).3} + 2U4(CO)a] + 460 (25°C, S60 atm CO mi as more micial-mistal Bonds ere formed, je a5 sitonger metal carbonyl bonds are cleaved while wealeer metal-metal bonds are formed 3. is entopicatly favorable but exthalpically unfavorable suct that AG=0 4. thermodynanncally unfavorable (4G > 0), io greet SHO.S gmt shee ira Riemer a rH ae FB Hone Red re | Pre eee at 2m em Ser 1.0 NaC Rosa ab ener Prorat ras a) eh wor aE en et Pie O.S MNGOH 8 17 aah WP aeons stat & 9 Mea at see Ree ara # 1 tpomeqe 2 128mg 8 SOmegig TS meal ia HT fora, A1.0M Nach smu nguteal. The collected ‘A ontunin fe packed solutign 8 passed then 8.5 1 of a stromply acldic fo exchange resi ‘salunm unt the cluant coming aut be #15 compl by [7 mfof0.5 M NaOIL, The fon exchange capacity of the resin 1 oo mege TAY SOG TS ml che rin 10! tt mio ema" & jC et pe eee Paver tet can baer te oh 04} aera Praee @ (8 a7 ae (wh) = 180) a orp B a 0.13582 ate oes usta cnt Fe) tL 1038 16 3% 20. 4 Te 180) is x 10° Tit mol ‘em! One iter solution of C, en oF B, shows un absorbance ef 0.441 na Lem ‘The malar evtetion caeiticient af B (MN which comains 0.1388 g pharmaceutical prepar price, The percentage (wiw) ofl ix tho phermaccaricl preparation is e020 2 60 a 20a 4 aoe (0598 eit dew toch ee ath it tke GRR AD ap ar HE A) ar ars wong ones (8) she arena army ane © New D4 Nom de Wo herneeythnin p18 A-D given hot) whol: eacur when ©, as oxidise tah GB} ota the roe atomas are on fC) 9, binds 10 one iron aiom ana is also hydrowen boned @) Oy binds wo 9a and is wiso hydrogen bonded B ante 2 Bap 93, Amp 4 AawiCon 93, a 95. 98, ar ery aah Preah area eb sbctat at aatager sear fer gh) & 9 8 + aged (ey 6) angel yf cig (eye fy arn hechwerthy (BC) s gages zare wr ot 1. PC ey bef 2. eythfe eyed mr PC 3. th oytay— Pe 4, PO oytaf— et In photosynthetic systems the rodon metalloprateins invalved in elactron transfer are cytochrome (est), cytochrome Bf complex (cyt ff and plastocyanin (PC). The pathway of elecizon Now is 1. PO enbeyter 2 qthf opto Pe 3. eye oytafs PC 4. PC eytof—eyt avira Ter dher Minti). wig A er en Ber one aT EPR. teal lore oem (128 May 1 das Sms, mo30 Aer 28 ‘The total numbers of fine and hypetfine EPR tines expe jel for oelakedeal high-spin, Mo(!l) Lo Sand30 3 Sand30 04, tan 26 ah gees aigat toe rhage teh eat ds 8 tree eH () TMOG) Bee ARTe a (I) Ta ii) Je-AATT ST CLD) @ vipat A aur & ane wigs! # aie wh ers # Law ww Barlinds 2 A or Gi) erat 3 Aw Gil) eB or Gi) Py 4 A wr Gi) ew Bar Gi) 27 ‘The Mésebaucr spectra of to iron complexes are shown below. ‘They may atise fram Hhighsspin iran{J10, (i) high-spin iron(I) and (ii}owespin iron(111y “ © 3 eer at Sectr mee)96, 6 eT ca 28 erent teas cf poeta (8) and (B) withthe iron complexes ste Aw) nd B with Gd 2 Adwih Gi) and Bwih G) 3) Aaah if) andl Bowie wht (i) and Bb lh (i) bag BE ot gente ps nied pra gee SE oak meme omen sours ae Bh A sctrow a I 2 rs 2 jon] bow of lengih L ti the region between ssid 2 teria nuoet ! z ae Piha wha ma raat are La 2 B39 a 6 a8 hy ig on Pere ay eae A ota aoa Lede Pe be pee we seer ar 1 BR. Br ar aro ye St can SR gud ar ay war grea we) tern seen aie see | Cretan cn anak ap er are a2 ab gual ar ab are ener et Pee aver ht an ee chain i aha art Awe? 2 came 4 owing are the three sat snicais abaut pesturh ation th A. seo ander perusbation conection to the promnd Sac energy is ALWAYS negative the zevoth onter and rst oder corrections: tthe groan state energy fs ALWAY: than the exact gromd sate nosy99, 100. 100, 104, 101 23 G. sum of the aeroth order aad first onder comeeti¢ns to the ground state energy is tess than the exset ground slate enervy. From the following which one is correct? 1 only Ais rue 2, both and B are iri 3 only Cs true AL both B end Care true Fas an eater se ae ae ce Re lee areca FD | 1 arvip, a-VE6, 2 a+ Bo 3B atB an 8, 4 er IB, as 28, {Using Htickel molecular orbital approximation, the two roots of sccmlar equation of ethene are 1 arsGB, av 2p, a ath ow oath a= bh 4 OB, we OB, arn sorer ih! eps py Fr my Oe Fae SE Ltt) Be) ey 2, fo) BE) BEY e 1 3, a(t) aye 4, fat) BR) BA) a2} #7 For HT, molecule in the excite state a, dhe Spin part ofthe triplet state with proportional to teh) BH) 2, [a(l}8@) = BO) 62) 3. #0) e@) 4. [aC B@) + BC) aH So 2 READ oy MN, Cy eg ea a #1 a ae #2 E Cu Cs CLS) MX asa Fat agers Ber sgt 1, Tet 2g Ten Hie be SLEN9 2 ditt 3 51111 4 41143 [A square pyramidal, MX, molecule belongs to Cx, point group, The symmetry operations ane: Es Cy, Ce, Zar and 2ey, The trace for the reducible representation, when symmetry operations of Ce. applicd to MXx is 1 51213 a reat 3 S1111 441113102. 102. 108. 03. 108 Cy ey ene a a an Cy cy [é a. | a Aft Ve ae ft ot re Bt 1 |x By ltt tty 8 sor a arena a aegis Bren ren A et By BV Ay BT STE SCT 3. ge 4 ager allowed electronic transition from A, t0 By is 1 -Fpoleried «2 y-polarized «3. polaried «=x, plained OLS co tn siaeé gh pe ble or LOAM Rey Bod gor oir tel 50%, ween er gh mer atl me more a age eee ute # / (log. = 0.301) L180080°% ear! 2. 3010 Mer? 3. 5000.0" em” 4. 6020.N ent Using covetes of 0.5 cm path length, 2 10°F solution of a ehtomophore shows 50% tranamitance at certain wave length, The molar extinction coefficient of the chromophore at this wave length is (log? =0201) 1900." ein? 2. 301008" ont 3. $000.M" ex” 4, 620M" en Fret 9 at acpre sageta mam ar wee (A) 23‘ @ to ‘n ) lasia @ n=" (2) "23% L ABE 2 ACE 3. BCD 4 CODE104. 105, 103, 106. 106. 107. 31 The set of allowed electronic transitions aman the following is () &n Asn © Ws O Tom oa 1 ABE 2 AGE 3 BCD 4 ODE BB vgn seg gota ec oh ithe st ea Pt ae wt m= Si2em!, wey = # om Gael oo, Boe AT omits sneha weer a & oe x, araranane Kees A cay wf denen oral (D,) #1 14096 ea 2. 614¢em'" 3, 8192en" 416384 en" ‘The following data were obiained fram the vibrational fine stucture in the vibronie spectrum ofa diatomic molecule: @.= 512 om", wx Bem" where oo, is the energy associated with the natural Requency of vibration and x, is the anharmonicity conslant, The dissociation energy (D,} of the molecule is 1. 4096 cnr! 2, 6iatem* 3) §192-en" 4, 16384 em? ern tr ar aera erat tah ee cere eet iter A aa are ee a eee Rear rar okt Pane) aor aber w Prone ar Pome 0 od dab L wsdq<0 2 w>0,4c0 A w0 A wetq>d ‘An ical gas-was subjosted 10 a reversible, adlabote expansion and then ie inital voleme as restored by a reversible, sochermal compression. If 'q* denotes the heat added ta the systent anid tw the work done by the systent thes Lo wsGqs0 2 w>dq0 4 w>0,q>0 Ae ice # sPret INO; (@) —¥ Ni, (e)vie NP maw | NO, aaTNyO, a wey seer rer Bho NO, wr Fiver iter fe or ver 1 1 mv rae | 2 wat 3. Rey errr oe Pier ite ora ha ere oy Pat he Pre107, 308, 108 109, 10 Ho. 32 “The ge pice resetion 2NOy (g) ~>-N.Oy (a) 38 an exothemice process. fn an equilibrium mixture of NO; and ND, the decomposition of'N,0, can be induced by: L: towering the temperature 2. inereasing the pressuze. 2. ineindueing an iner ges at euewstane volume snladhcing an inex ga af eonstune pressed Ber ee fi aati Pate a a Pee Ey Sar a tre nes ay de, weno SAF =O, Bp. ah aa warn 8 4 & n é af 3 4 oe T ° sa ua Rove ore sen there ara 40,2348 0 wet Cem e | 1 hele alm i siya 4, Yl 720 ip for G idenilsal parictes with ibeir weeypation maniber {01,58} in fo tales is 3 kyl 80 kin 720 1AiH Wm. an, 2, 12. 1B. 3, 33 wee Hee Pe] Ha(p)[ HCKa,), | ABCKS)|Ag Ag |AgCG)| HCICa .), | H, (py Pt Pred rea mat Bw 8d He etre ZRT (a,), RT, (az), 1 Eoin 2, Bene Fes Fa), IAT, (ah a weRE yy Goh F(a), 2F (@), ‘Tae correct Nerust equation for the concentetien cell: Pr{H, (p)| HCKa,), |AgCUS)| AE AB]ABCIG) |HICI(a), [1E(p) [PE widsoat tguid junetion would be 2RT,, ars 2, Fo @s ange ane oh a ot gee. gn whe BE he ret wie er | are etter er See eta hase cosa) eter on aime 123 3k Doak T aT ST RT ae Ui =a OT Hehe 99 oe Mali assuptien(s)favelved ia the derivation of Debye Fhackel equation isfar) the validity of 1, only Paisson equation 2, Poisson equation and Boltzmann distrbation 3, Poisson equstion, Rolizmann distribution aad [$2e0)->La 4. Poisson equation, Bollzmann distribution and [22c6}< EMA) 4 EQ)-5 Buns 5 Balt 2 The rate law fer one ofthe micetsanisins af the pyrolysis of CHCHO a $20 °C and 0.2 bar is ies panenpe, ae | [cn,cHof? (2x, ) ‘Tae overall activation éeegy E, in terms ofthe rate baw ist 1 Ba) HE) 2 2. Bas bH0) +B Ea) 3 Bes dea Ea 4. BQ)-5 BAN orgs Bhar af 9 etre Hoe BoA oP Ry ne ae y wn _ 1oly Lae? - SE {eL{S] {E], 1s; yee tol L"9") gem Komen Fora, mol La ra aor 1 idx 0%, 10 2 Lax 108104 3. 14x 1',10* 4 14108 10% (E)fS} (BE). ‘The vatkes of bs (on mol Ls”) aad K (Michaelis constant, wol L'!), respectively, are Lo 140% 10 2 14x 108 10° 3. La 10", 10° 4 Lx 10% 10" shen ar err aber (or et ree tes cre san we: Lo yfet orate wer ge ware 22, Qa ter evar ore 3, gat Rie mr gor eT 4, tg eet mer stor S/T RD/I2-1AH—3B116, 17. m. 18. 8. 19. 19, 120, 36 ‘The most used acid catalyst in ofl industry and the elevanl process are respectively aluminophosphate and reforming 2. aluminositieate and racking slunninosilieate and reforming 4. aluminophosphate and erucking antearerr & Fe ta (E,= 1.98.0 107%) teers at sera ert & Fe wet cen TOT arifgey aa # [h= 6.626 « 107s, ¢ = 3 «10's Le 1000 nem, UV 2 1000.0, IR, 3. 500m, visible 4, $003%m, FAR IR ‘The wavelength and the speewal region for a single electron teaneler across the and gap in a ‘semivondustor (Ey~ 1.98 x 10°") are [Bh= 6.626 « 10s ¢= 3% 10'ms 1, 1000am, UV 2, 1000om, IR, 3. 500nm, visible 4. 500m, FAR IR {Fa foe ara Aer ees aw RY aa Oapoe 404A. #1 rer ot wemry roar & LL 2868 2 43 3. 429A A SODA The lattice parameter of an element stabilized in a foc structure is 4,044, The atomic radius of the stement is 1 286A 2. 143A 3% 429A 4 S728 ‘ror ager Pere —atevr cfr ies (MA, ) ae ser —oph atta Tier (Ie) ab amor aecth & aren ere snaps ATE at erect) ar Fara Te 4 Bes wen arrarer T f a eer weir anes ‘The number-average molar mass (V,) and weight-average molar muss (My) of polymer are ‘obtained respectively by 1. osmometry and light scattering measarements 2. osmometry and viscosity measurements 3. Tight seatering and sedimentation measurements 4. sibcosity and light scattering measurements srr Atal rear Yo fy acral @ ob Be Pei bd 41 42 43 44 45 46 Yea) 102 106 109 Ls Mg 122 YGaB) 102 106 ILE 113 1B 1221 a1. m. a6 at aor oi: aa ah aR MT (My, Ma) AAT CO, One BAT PAE Fa 2 mye My aPee 4 me Sms casey Tho data sets involving the same variables X and ¥ are given below x 41 420 43 44 45 46 Vier) 102-196 «109 SB 12.2 YiseB) 102 ING LE 3B Ihe slopes and intereepts wf the regression lines fr the to sets are denoted by (ase) and (cp, énhetexpectively, hen i mutes Pes 2 mp = my, eee Rom2ms see 4 meme, chew Shan A ewe BaD ant ome WONMIR, sO 2 a gor rarer & peer vo a a bere 5 Ne oi ne Oey A 1 69 RVRIA TOG WT TTIOR Fp 2 TT WTA hy 62 ewe B ty 3. ED AWIOA HR Lina Boee 4 TT ROLLA wee 69TAIOR Fee Compounds A and B exhibit wo singlets, cach in their 'H NMR spoctza. The expected chemical shifts are até: i 46 ory © we i x: a ee sien open mon ome A me BF ae neo! Her, Ad 0. REOH 0H MO ORE1m. 123, Preah as od attr ch eek er ano ot nae & ara wer) a esc" 1.NBS (2 64), B20. 4 the 2.29, NaOH1, ¢ ; é COD 4 Com 123, The sircture-of the wicyolic compound formed in the following two step sequence is oon 1.NBS (200), 8240.8 “Fanon 124, Tolterend aebateer @ Mest Ds Ren sore Fe sa 4 5 5 SL yt F ee ‘ Boe. , Lhe) der galapheretvas Reece Rev oti mar coy rte (1,7}-44 me 2. wet one scenes: aa side si ra err RI [1 TH 3. rier garter we vito rae ar eh eae guru (17H Ae are goatee Bart hy shor mare uae [1,7]-H. ee 124. The two step conversion of 7-dehyetrocholssteral io vitamin Ids pracceds through: LL photochemical eectrocyeliedisotaory ring opening, and thermal antarafacal(1,7-H shit 2. _photostiemial eleetroeyclir conrotatery ring-opening: and thermal autarefacel (1,7 4 si 1. themual elseteacyli conrotatony sing opening: and photochemioal suprafaial (1.7/-H shal. 4 thenns eleetacyetiedisrotaiony ring opening: and thermal suprafacal [1,7] shift 1S, Rate oPRE a RA aU ge TA ° sy oa & 8 28H, (imermediate)39 2} mE f, 4 = i Gr : e-NH 4 i 4 Aemesme: 6 (OL =o 4 125, The intetmodiate A and the major product I in the following reaction aze 2 Admremeré; 8 3 Adem es B= fj © 4 Aleacyeatian: oi Cr 4 I 2 Aigacleston Bis (|_| =O ° 8 Abaotinon 2 wi fl i 4. Ais acy nitrenc: Bis oO , 4 126, rar 2h Bia crm Be ath a ihe (OF Kobe (oxease) Sy c008 2 KolBu (encesa) e) ars S “COOH26, 12. Aare Bane ; ‘c00K a Anramiese J je) eerme odin Forthe following two reactions A and B, the correst statement is Br 5 ‘ Kote (exooss) “COOH oer KO'jBu (excess) (8) —SSSanr a “e004 40 wait hn ox pS aA 1. Agives Boaives % COOK ~ 9, Asives B gives cook 3. bothAand Bove AI La + rename 7 cong Do Frater stron args a ae or Oe BIR, er LITO car AP arene aise | Acro Bt vem € | oo 9-BBN MsCl, NEt, oy = & B ‘COOMe H2O3.NaOH127, 18, Ae ‘oooNe on 2 A “coon oa aoAe py ad 00M wae DY He ‘coome ‘The major compound B formed in the reaction sequence given below exhibited a carbony ‘absorption band at 1770 em in the TR spectrum. The structures A and B are i 2-08N MzC), NEt ge asp NE coome Fz0=Ne0R com te CL on 2 On, ¥ i © {too Se sam DOS ‘oom ee [DP ud 6 re oe OP Aeneas 5 hese Rae a sera ee soe 18% epinens pinanie acid pinie acid AA Baideate Paneer & Bote argent ser & 4 AW OuReanite ane 2B ane chy aur C arecmalieatee wt | A A Raat Rave eB Bay ater & uC Tew Uy arate wer A Haart Goer & Boma Corba anita oer FJ128. 129. 129, 130, 130, 2 Consider the following eeaction sequence staring with moaoterpene e-pinene, Mt the correct statement, AIK KAO, __NSOHY Bey -c epinene pinonic act pinic acid 1. Ahasadisibstiuted double bond; Band C ate dicarboaylc acid 2; ‘has tisubutiuted double bond: Bs « methy! ketone: and Cis a dcarborylie seid, 3, Ahasadisubstiuted double bond Bisa metiyl Ketone; anl Cis a dicarboxylic ac 4, Arhasan exocysic double bond; Band © are monocarbonylis acids, (3RAS)3A-sr ier dom <1 S. ea at 240 °C ae mF edt at ee sere se A we et 1, (0Z,62)-atre2 6-2 2, QE BE) steer? 6 ae 3. (2EGZ)-steee26-2087 6 (BZSH-oteERS 5 aEET The major produt foamed when (3R48)34-dinethythexa-l S-dione isheated a 240 Cis octar2,6-diene 1. 2x 6ipocta-2 6aciene 2 QE 3. QE BZ) cla? 6-diene 4, GE SE)octa3,S-diene Reni were are attr oar 4 anehr emt Aw eee | » cB 2 ob 4 q 3. acr “OD Stmucture ofthe starting material A in the following photochemical Norrish resetion, fs s : s +0Bi. a. 1m. 132, 4B evr ania Pare we ah ene A ace RR reer coro 85% de (a) arate ge # enantiotopie faces € 1 (0) wages ar oneTT recicial #1 (el) ar (erciastereaslective rua # 4 1. aaH(@) er) 2, -éee(a) mer (0) 3, Sate) #9 (c) A @.0) HH de) (Considering the following teaetion, among ac, the commect staternants are {c) _ itis a diastereoselective reduction. 4. @yand (only 4, (heard (®) CoO 1.mCPBA. 2. BFEL0 . : ; “CO “or The major product formed in the following reaction sequence is (Gr _femsePak 2 BF, ERO133. 133, 134, oH ‘ot eee 4. DIBAL (1 ea) Ph ao 2ee Are 3.POC 2 t. - Aco web aloe NA, 6 ao i ah o 9 3 Chee 4 Cl rs ¥ ao H Al ‘The major product fomsed isthe following reaction sequences At comune Chas Retest of 3Pee H 4 Ho a he Pratt a Bret Ph MIR rae P18 pp) tah ber ses @ 9% () titer ous (ote Gs) 178 (8) nbs Scarabs Gs) 205 1 GG) Coy et) ann 2 @rtid) OED — eM) cavai 138, 135, 45 3. @H) Wii 6) (ogi 4 cid) @)-G) ad (rv) Mateh the flowing: ‘compound ®ONMR chemical shift (6 ppm) fa) acetic acid. wo 95 ib) acetonitrile fa) MS (© aeons i) 178 (@)—cavhonterchloride (i) 208 1. ii) Hii) (Ov) (eG) 2 GH His) (sH4i9 3. @)i) Hii) (iv) a) 1 ot OO OH) OY Pair Ph sre pet ae Ame BEF ‘mBughnlt 08RD ANS. Piovenhnal eat 1 (QEAD = dist! azasicnrowtaty Buys ABN g136, 136. LJ whe rT ak ) © Prose War at ar a are b | 9 oe Note f Jus 4 % oe ‘The major produet farmed in the following reaction is 9 Ce NaOMe Q ‘00te 1 cr 2 ae ai 417. 137 138. 47 ar aro fy eee A oa BE) eae. a oO H A AsCEL, Zn-Cu; A=CHL, Zn-Cu; MesS‘T, NaH MeyS(0) I, abd B= MesS"(O) I, Nati =CH, ZieCu The Feagenls A and B in the folowing reactions are ° Be Me\S'(0) I, Naki =CHib, ZC Prat stale arp Hf art ah yet rere Awe BE Uae NORE 4 Shape posaion A eae amt va138. 139, 48 “The major products A and B formed in the following eaetion sequence are UA, NEOEL _Shaitoss epoxidation Lee a Poh (tsi errata WAR RAL ALO 2a be, *~ ‘oH Tees. 5 s & é 5 eighty anit Papa apo Hh a CIE A a BE | — Oren de eer 4.2 OnLy & OO ©) = j oe V9 - OD ww Be oo 0 4hAH 139, 0, 140, 49 ‘The major products A end B formed in the following reaction sequence are 0, DP Ova cs gs WER Pa{PPhis KPO, ‘i es » OD no © GC, Prk eaten oct Fs wet aoe ar ciabatta seen & 1 0 co’ — o~ 1 (a) Me,SiCHOMe, "BuLi; (b) H,0"s (c) NaBH,. MeOH 2 (a) PhuPCHLOMe Cr, "Bi 2) HO"; (c) NaBH, MeOH 3, (@)NHANHITS; (b) NaOE (€) CICOOEE 4 (a) NELNATe: (6) 209. "BuLis (¢) HCHO ‘The cortect reagent combination / reaction sequence for effecting the following canversion is 0 Ca i. (@) Me,SiCH,OMe, "BuL i; (b) H.G°; (6) NaBH, MeOH 2 (@) PhP'CHLOMe C1’, "BuLi; (b) HzO", (¢) NaBH, MeOH 3. @)NILNHTs; (by NaOEs () CICOOE: 4. @)NHGNHTs; (b) 2.09, "Bula, (c) HCHO: SITRDAD1AH—414 e. rere sir # are gen se | MegCuti ELO The major product formed in the following ceaction is - o Me; Et, Q > , “GO Preatar arzeet ere a Pe aroma ar eh atin CoeTia Pa oy 1 a) (CHLON), TSA. antb) = crebie's fterte (61 HAO" (d) KOH, 2. (aICHIOH), PISA, 4: (6) Phy PeCHy (6) 1,0": Cd) KOH oy Coat Aes 2 &) {Febbe's wits sf) HLO" (6) KOH daa) Ph; b) H,0'x4c) KOH12. 143. 443. a ‘The orrect sequence of reagents for effecting the following conversion is , pAnyot eg f ay Goat (@)(CHOM,, PISA, a: 0) 7 Scr (Tebsbe's reagent): (¢) 10", (d) KOHL 2. (@)(CHOM),, PTSA, 4; (6) PhyPoCl;{@) 10% (4) KOHL KS @ ame (Tebbe's reagent: (6) HAO" (6) KOI 4. @PhP-CHi; (6) 10%") KOH rota sir sepor & or oer Aer BE Me 4 nat, Pro To * Fiske y Bo % WW age 6 x eo ( ont = ony S H ‘ NO # oO Us oH AB Be ‘Tue major products A and B formed in the following reaction sequence are 4 xe, _PrcHo PISA yb144. 1s x y ys 4 2 AF ‘ Be 4 Ph shop 4 co a CF ony oH 2 aon A Pree rar ga ec ones A eum ae) ed eH re BE a A ope ANOS / HO on 1, CH.Bry aur KO'BU Be oe 2 As crbrammKoou ge a. a ou o 8. A=CHBr; mer Kola BS on 4. A= CHB wer KO'u B= } ar ‘The reagent A required, and the major product B formed in the following reaction sequence tre a Oe __AGNOs He th14s, us, 53 2, A= CH,B1, mw KOU on 4 Br 1 AD Oiigrgm Kelby Bs CY oH ‘er oH i or i“ 3. ASCHBY mw KOU A= CHER mr KO'sy Petar Remedi Aw Re at Rese atta a was at er By ie of) 2 ap a 1 Age pea tifeir 2. Ate tie Ber & 3. A ef aso Pits wera ar Boe 4 Att rant or Rar OH ‘Among the choieas, the comect statement for A formed inthe following reaction on -G — 1, Ais asingle enantiomer 2 Aisaracemie mixture 3. Aisamixureoftwodiastereomers 4. Alsamixture of two epimers54 ‘ta ard/ROUGH WORK