Use the result of Problem P3.10 to show that (AC /a¥’)y forthe van der Waals gas is zero. (, Weuse the relationshipP3.10 Derive the follo (0Cy fay = 1g expression for calculating the isothermal change in the constant volume heat capacity (2), -GH)) Ge), ‘The order of differentiation can be reversed because (/s a state function, w) _ (ae Using the equation (22) = 722) - p tecomion (=f), (©), -4(@),-7)) (2, (2]P312 Calculate w,q, A/T, and AU for the process in which 1.75 mol of water undergoes the transition H0(/, 373 K) HO(g, 610.K) at 1 bar of pressure. The volume of liquid water at 373 K is 1.89% 10-* m’ mol! and the molar ‘volume of steam at 373 and 610.K i 3.03 and 5.06 x 10"? m° mot", respectively. For steam, C),,, can be consid- cred constant over the temperature interval oF interest at 33.58.) mol! K! aH WAH ypportcaion + ACESS AT 1.75 mol x 40656 J + 1.75 mol x 33.58 mot" Kt x (610,K ~ 373 K) = 8.5110" J ~Pasernat dV = -108 Pa x (1.75 x 5.06 x 107? m? — 1.75 «1.89% 10% m?) 8.85% 10° 8.85% 10° 1 48.51% 108 J = 7.62% 104 AU =wegP3.26 Fora gas that obeys the equation of state iz Rr = Aly ar) pt BAe) derive the result Equation (3.44) states thatBry-T APs mry-7 ABT ar ar ABT) 2, 7-2-7 BO et BD) P ar