Professional Documents
Culture Documents
Nescaum PDF
Nescaum PDF
September 1990
Prepared by:
James W. Peeler
CEM/Engineering Division
Entropy Environmentalists, Inc.
Research Triangle Park, North Carolina 27709
Prepared for:
Nancy Seidman
Northeast States for Coordinated Air Use Management
By agreement with:
Page
Section 1 SUMMARY 1
4. Linearity Test
A new performance specification and test procedure should be
added to require a four-point cylinder gas audit to demonstrate the
linearity of each pollutant and diluent monitoring channel. The
linearity specification and test procedure applies to the entire
monitoring channel, including the data acquisition system, as
installed and operated at the MWC facility. (A non-linear analyzer
used in conjunction with appropriate adjustments by the data
acquisition system is acceptable.) Source owners and operators are
encouraged, but not required, to have equipment vendors demonstrate
conformance with the linearity specification prior to shipment of
the CEMS to the subject facility. However, the linearity test is
required to be conducted for each CEMS after installation.
The linearity test should use the zero and upscale
calibration values used for the daily calibration checks and the
two audit points specified for cylinder gas audits by Appendix F,
Procedure 1. If the high range audit point (i.e., 50 to 60 percent
of the pollutant monitor span) of Procedure 1 is used for the daily
upscale checks, an audit gas of 80 to 90 percent of span should be
substituted for the high range audit point. Protocol 1 gases, CRMS
or SRMS should be used for the two audit points that supplement the
daily calibration checks. Three non-consecutive measurements
should be made for each of the calibration gases (e.g., zero, low,
mid, high, zero, low, mid, high, etc.)
The linearity specification should require that the mean
difference between the calibration gas value and the monitor
responses at each of the four points be calculated from the three
measurements. The mean difference at all four test points must be
less than 5 percent of span for SO2 and NOx monitors and 0.5
percent O2 or CO2 for diluent monitors.
The linearity test should be performed as soon as practical
before or after the relative accuracy test. Only the routine
calibration drift adjustments are allowed between the two tests.
Other adjustments or repairs to the monitoring system would
necessitate repeating the linearity and the accuracy test. (During
subsequent quarterly audits, only calibration drift adjustments
according to the written procedure contained in an approved QA plan
are allowed prior to the linearity test or the relative accuracy
test.)
4. Linearity Test
A new performance specification and test procedure should be
added to require a four-point cylinder gas audit to demonstrate the
linearity of CO monitors. The linearity specification and test
procedures apply to the entire monitoring channel, including the
data acquisition system, as installed and operated at the MWC
facility. (A non-linear analyzer used in conjunction with
appropriate adjustments by the data acquisition system is
acceptable.) Source owners and operators are encouraged, but not
required, to have equipment vendors demonstrate conformance with
the linearity specification prior to shipment of the CEMS to the
facility. However, the linearity test is required to be conducted
for each CEMS after installation.
The requirements for the selection of the audit points for
the linearity test and the test procedures for CO monitors are the
same as described in Section 2 for SO2 CEMS. The linearity
specification should require that the mean difference between the
calibration gas value and the monitor responses at each of the four
points be calculated from the three measurements. The mean
difference at all four test points must be less than 5 percent of
span for CO monitors.
The linearity test should be performed as soon as practical
before or after the relative accuracy test. Only the routine
calibration drift adjustments are allowed between the two tests.
Other adjustments or repairs to the monitoring system would
necessitate repeating the linearity and the accuracy test. (During
subsequent quarterly audits, only calibration drift adjustments
according to the written procedure contained in an approved QA plan
are allowed prior to the linearity test or the relative accuracy
test.)
4. Linearity Test
A performance specification and test procedure should be added
to require a three-point cylinder gas audit to demonstrate the
linearity of each HCl monitor. The linearity specification and
test procedure apply to the entire monitoring channel, including
the data acquisition system, as installed and operated at the
particular facility. (A non-linear analyzer used in conjunction
with appropriate adjustments by the data acquisition system is
acceptable.) This test should use the zero and upscale calibration
gas used for the daily calibration checks and an additional audit
point at 20 to 30 percent of span. The recommended procedures for
performing the test are the same as described above for SO2 CEMS
except that Protocol 1 gases are not available for HCl. Therefore,
the concentration value of all three calibration gases should be
determined as described above in Item 3. The linearity
specification should require that the mean difference between the
calibration gas value and the monitor responses at each of the
three points be calculated from the three measurements. The mean
difference at all three test points must be less than 5 percent of
span for HCl monitors.
7. Out-of-Control Periods
Criteria for "out-of-control" periods are similar to those
defined in Appendix F, Procedure 1. Specifically, the monitor is
out-of-control if (a) the calibration drift exceeds two times the
performance specification drift limit for five consecutive days,
(b)=the calibration drift exceeds five times the performance
specification limit on any day, (c) the system fails a relative
accuracy test, or (d) the monitor fails a cylinder gas audit
described above in Item 5. Data collected during out-of-control
periods cannot be used to satisfy minimum data availability
requirements.
The plan should very briefly set forth the basic approach that
will be used to comply with the applicable monitoring requirements.
It should include:
a. The identification, location, and description of the specific
combustor unit(s) (e.g., plant name, unit number, unit size or
capacity, general type of control system, etc.)
b. Identification of the applicable regulations and continuous
monitoring requirements (e.g., EPA NSPS, state regulations, permit
requirements, etc.)
c. Identification of the CEMS manufacturer or vendor, the model
number or other identifying feature of the equipment to be
installed
d. Identification of the proposed monitoring location(s) (i.e.,
position along the effluent path), description of the
transmissometer measurement path orientation at each monitoring
location, measurement path length, and stack exit diameter
e. Discussion of procedures and equipment that will be used to
calculate the opacity of emissions discharged to the atmosphere
where two or more transmissometers are installed in multiple ducts
for a single unit or where emissions from multiple units are
exhausted through a common stack
f. Description of any automatic procedures that will be used to
correct or adjust opacity measurement results for calibration drift
g. Description of the data recording devices that will be used
h. Identification of any exceptions to the performance
specifications or other applicable monitoring requirements and any
alternate procedures that may require the approval of the agency
5. Performance Audit
A performance audit of each opacity CEMS should be performed
each calendar quarter according to the procedures contained in
"Performance Audit Procedures for Opacity Monitors"
EPA-600/8-87-025, April 1987, or equivalent procedures subject to
the approval of the agency. The criteria contained in the
referenced document for stack exit correlation error, system
faults, zero and span errors, monitor alignment, dust accumulation,
and calibration error should be used to determine acceptable
performance. The results of the performance audit should be
reported to the agency with the emissions report for the period
during which the audit is conducted.
The values of the optical filters used in performance audits
should be checked at least once per year according to the
procedures in Performance Specification 1.
6. Zero Alignment
A zero alignment should be performed at least once per year
unless a particular facility can submit data showing that a
different frequency is appropriate. The zero alignment procedure
involves adjustment of the monitor so that the response to the
simulated zero device coincides with the monitor response to clear
path conditions. The check may be accomplished if clear path
conditions are present during a source outage or by removing the
transmissometer from the stack and setting up the instrument at the
operating pathlength in a clean environment. (General procedures
for performing zero alignment checks are described in Section 9 of
"Performance Audit Procedures for Opacity Monitors.") The amount
of adjustment necessary to accomplish the zero alignment (expressed
as percent opacity) should be reported to the agency with the
emissions report for the period during which the procedure is
conducted.
An external, removable, zero-jig may be used as an alternate
procedure to the zero alignment provided that (1) the zero-jig
setting is established for the specific monitor by comparison of
monitor responses to the zero-jig and to the clear path condition,
(2) the zero-jig is demonstrated to be capable of producing a
consistent zero response when it is repeatedly reinstalled on the
monitor, and (3) the zero-jig is protected when not in use to
ensure that the setting equivalent to the zero condition does not
change. Source owners or operators that use a zero-jig should
perform a zero alignment and check of the zero-jig at least once
every three years.
7. Out-of-Control Periods
Criteria for "out-of-control" periods are similar to those
defined for gas CEMS. Specifically, an opacity monitor should be
considered out-of-control if (a) the calibration drift exceeds the
performance specification drift limit (i.e., 2 percent opacity) for
five consecutive days, (b) the calibration drift exceeds five
percent opacity on any day, or (c) the opacity monitoring system
fails a performance audit. Data collected during out-of-control
periods cannot be used to satisfy minimum data availability
requirements.
110
100
90
80
70
60
50
40
30
20
10
10 20 30 40 50 60 70 80 90 100
ACTUAL EMISSIONS
(Percent of Standard)
70
50 ppm
STD
60
50 ppm STD
Transition
50
10 % of 50 ppm STD
(i.e. +5 ppm)
-
40
30
30 ppm
STD
20
Equivalent 5 +
ppm
- Mean Difference Accuracy Criterion
(assumes 2.5 ppm confidence coefficient)
10
30 ppm STD
Transition
+ +
- 10% of 30 ppm STD (i.e. 3 ppm)-
10 20 30 40 50 60 70 80
ACTUAL EMISSIONS
(ppm)
Figure 2. Example Accuracy Specifications for 30 ppm and 50 ppm Standards