wae 7204 sree [1] [A] 2019 () wart fart ae Reh trea gar er efter fre re wt Ate (20 wea + 40 wD Hts CO wre Cage Fete net (MCQ) FRC aTe i are TH A: HH afl 15 ste aT ‘BHR 38 ma mr CR 25 west sere BA Hi aRe Rafer fing weit ser ey ears area rere 1S, ry Aa gH 35 aT (CH Ee 25 ert fare ort Se ae sere aw te Pear ar Bh ser he eae ate ar are rt 8 we ae arts aft, fe aren ges ge ate wet & me wt aea a Hi ae fr Ba a sfhttec 3 sft ats afer eer ar ter ae wee Ai ot ae A ate are. sere Tweet at ats oa afer ee re aor Fr ae es wer 3. sare sere ware es 1 3 cae et a fet ere a me ew ft FET sara: Ferg, are ee gear ota 4 are arch at. cprare Sere wre H Rha ea, Ree she, gfe he ate exe Beene saghter gait mt ate tet eee TA! wear BH aa re 2 ste wr CH ee eR 4 ate RT RL NTA! TTB HE aes TT SORE NE MTR ATT 0.50. st aa TTC | ate FT TT 6. wet rer Ata are fore Recor 8 aH Ser rer edt rma wettar Zor ret rete er a at sree rate et deat 7. area wee Bre ar sah eh a at eC aM aE aT aT Tete Ra er atte aa sar erat fe sritea aera ar ma 8. ftom at zeae ore ar ew eat fate mgt ate ge af ft Pre fem 9. Rargter ar arith A aga ot A 10. efter anf re fine Fg Fre era # Sree core ore A Pf eh eee Sagat fat a Le feettmeamtereer ser tat Brae ae aft ateew mrfire a 12, Ren afer ft raft om ok ort feb a At her aera oR are ath agate ft arch vba ere ft orate amet. sProtttec gee ‘S106 CRIEM9—1AH—1A,2019 (1) : CHEMICAL SCIENCES Time: 3:00 Hours TEST BOOKLET Maximum Marks: 200 INSTRUCTIONS, “This Test Booklet contains one hundred and twenty (20 Part‘A”+40 Part B' + 60 Part °C’) ‘Muitiple Choice Questions (MCQs). You are required to answer a maximum of 15, 35 and 25 questions ftom part “A” “B° and °C’ respectively. If more than required number of {questions are: answered, only first 15, 35 and 25 questions in Parts *A’ ‘Band ‘C° respectively, will be taken up for evaluation. OMR answer sheet has been provided separately. Before you start filling up your particulars, please ensure thatthe booklet contains requisite number of pages and that these {re not tor or mutilated, If tis so, you may request the Invigiator to change the booklet of the same code. Likewise, check the OMR answer sheet also. Sheets for rough work have been appended tothe test booklet. Write your Roll No,, Name and Serial Number of this Test Booklet on the OMR answer sheet in the space provided. Also put your signatures inthe space earmarked. You must_darken the appropriate circles with a black ball pen related to Roll Number, Subject Code, Booklet Code and Centre Code on the OMR answer shes. It is the sole responsibilty of the candidate (0 meticulously follow the instruetions given on the Answer Sheet, failing which, the computer shal able to decipher the ‘correct details which may ultim ult in loss, including rejection of answer sheet Each question in Part ‘A’ and ‘BY carry 2 marks and Part “C° questions carry 4 marks each, marking @ 0.50 mark for each wrong answer in Part A’ and *B" and @ | mark for Part °C’. Below each question in Par: A’, "BY and ‘C” four alternatives or responses are given. Only ‘one ofthese alternatives isthe “correct” option to the question. You have to find, for each ‘question, the corrector the best answer. Candidates found copying or resorting to any unfair means are liable to be disqualified from this and future examinations Candidate should not write anything anywhere except on answer sheet or sheets for rough work. Use of calculator is NOT permitted ‘Alter the testis over, at the perforation point, tear the OMR answer sheet, hand over inal OMR answer shect to the invigilator and retain the carbouless co ‘Candidates who sit for the entire duration ofthe exam will only be permitted to carry their “Fest booklet. LAH $106 CRIE9—1AH—1BATTI/PART- A TS 1 (rem Tes a ares we Pet Gee aft pet ve qs ater rat 8 a 2019 abe fread ed &i eae Ht Peat ge? 1. 609 2. 610 3. 709 4. 710 ‘The number of digits you have to type to write all the page numbers of a book starting from 1 (first page) is 2019. What is the ‘number of pages in that book? L609 2. 610 3. 709 4,710 uw Rraré ta: a vis creme # 91, 86, 81, 79 THT 92 ate stot EOI VaR ‘ramwnt areaiat ar sta 85 #1 wd far Hat at ote free 1 83 2. 85 3. 81 4, 88 A student received the following marks in the five of the six courses: 91, 86, 81, 79 and 92. Average of his marks in six subjects is 85. How many marks did he receive in the sixth subject? 1. 83 2. 85 3. 81 4. 88 Paikat +a’ a at aq afi yee Rs, 5 oH a ote emit sa Pama ger oe 5% oT setter From ga Pe “Be 8 elt & ae aftr ger 2 Rs. 15 wr Tea i wa ee ETT 15% after Fan aE A war B att eof H arr oP ett et a ae aT aftr yea aa 2? 1 10 2.20 3 2s 4. 30 Salesperson ‘A’ sells an object at a price Rs. 5 less than the marked price, receiving a commission of 5% on the selling price. The same object is sold by person ‘B” at a price LAH Rs.15 less than the marked price, ea commission of 15% on the selling price. If both A and B receive the same amount in commission, then what is the marked price of the object? L 10 2. 20 3 ms 4.30 oe er gota aft dhe A xe 8 at eT areca 1 fee fig 0 xe PER afopaT sitters oRtem mate ( 0), Te Hae oftarita wea A B Raina (0) 19, 19, 20. are B Pe te ae eT 1. 3. 2, x? 4. xy Graphs A and B define the same relation- ship between y and x for x, y>0. A B eat a ? ° is 0 5 ‘The variable on the ordinate of graph B is L 2 3. foxy vor stfire oft mT art 3.4587 + 0.0022 are srar Bi gfe at ot dar a 88 ge Pet Ha ate ar ao at ager eae zeta e 1. 3.4567 3. 346 2. 3.487 4.35 ‘The value of « physical quantity is measured to be 3.4587 + 0.0022. Which one of the following is the appropriate representation of the result taking the errors in account? 1. 3.4567 2, 3.457 3. 3.46 435 at cee dana aeit Reema # ge ate aq ages ofteae waa: gt oer a A eat 1. Peeraty 3. watac area The cross-section along two mutually perpendicular axes of a solid object are a circle and a square, respectively. The object is 1. truncated cone 2. acylinder 3." arhomboid 4, a cube 2, dat 4 4tAT/PART- B 21, refer tof aeitte qae at itr ez, Fe(Il) #1 K:CnO, # areata FHP, Frafiert 1. Fe(lt) fuer ateattareer a area 2. Fe! Fe” witeite faa at wzat 3. Bee ero 4, KC, 9 Fer 21. The role of HsPO, in the estimation of Fe(II) with K:Cr,0; using diphenylamine sulpho- hate as indicator is to 1. avoid aerial oxidation of Fe(tl) 2. reduce the electrode potential of Fee" 3. stabilize the indicator 4, stabilize K,C1,0, 2. 2 |, Wet 0-0 ara aaré o, fatter ret att 2 2. On ft atte ze we sae ater wate fi 3. IR afr eh 4. gia oat & ster A gee wet # ar #1 22. O;"is 1. having a shorter -O bond length than that in Os 2. a stronger oxidizing agent than O} 3. IR active 4. unable to abstract proton from weak acids 23, Fagrt afro Pec # ghia Phar art aret fafror 1. area 2. B Feat 3. Prot 4. X- Fircit 23. In neutron activation analysis the radi commonly detected is 1, aerays 3. yerays 2. Berays 4, Xerays LAH 24, 24, 2s, 25. 26. 26. 27. 27, Rete er irre aediftanrieare ara eavarrafer arg & 1, Mo 2. Cu 3. Fe 4 zn The metal transferred by bacteria and fungi using siderophores/siderochromes is 1. Mo 2. Cu 3. Fe 4. Zn am: fat gagia errr et fram 8, 7e% 1. [Ru(NHs)6)?°°" 2. [Co(NH3\ f°" 3. [CrOH,)6}°">" 4, [Fe(OH,).)°* Selfeexchange electron transfer is fastest in 1, [Ru(NHy))?"2" 2. [Co(NHy))"”" 3. [CrOH,).)°" 4. [Fe(OH,),)""* Ite Free wr creat wer aT [CpNiQue PPh.) BH, 3 Ni-Ni sre ater Lo 21 3.2 43 ‘The number of Ni-Ni bonds in. [CpNiQi- PPh,)Js complex obeying the 18 electron rule Lo 32 trans-[IX(COXPPhs)o] (X = F, Cl, Br, 1) O;, & after & fire, = a XH are ftafita att ar at rt 1, Br>1>F>Cl 2. F>Cl>Br>1 3. F=Cl=Br=1 4. 1>Br>Cl>F For the reaction of ‘rans-{IrX(CO)(PPhs)s} (X =F, Cl, Br, 1) with Os, correct order of variation of rate with X is 1, Br>I>F>cL 2. F>Cl>Br>1 3. FSCI=Br= 4. [>Br>CI>F28. 28, 29. 29. 30. a at. “STRETHTEATES [AL,(OH);Si,Oue] H StaTE Si(IV) FT AIM) & aeAA TE (KC) are arte iq] sort BA aah efter 1. wea 2, wetter 3, abentfteiiaree 4. or ‘The species that results by replacing one quarter of Si(IV) in _pyrophyllite [AL(OH);Si,O\o] with AICI) [charge balance by K(1)] is, 1, muscovite 2. phlogopite 3. montmorillonite 4. tale loy # r @ orfte anet PARerrr Fafa afta 1 hwaTH,0 2. hTATH,O; 3. 10a HO 4. 10 War HO, ‘The reaction of 10s" with I” in aqueous acidic medium results in 1. and HO 2. Taand HO, 3. 10 and H30 4. 10° and H,0; [Fe(CO) PPh.) & aresitetae rere aida t 1. CH” 2. cH 3. CH, 4. CH The organic species isolobal to [Fe(CO),(PPh)T is 1. CH 2. cH 3. CH 4. CH srearatre car srearatfte area # aoe A atefrerm wae}, we: 1. 44,46 2. 44,45 3. 43,45 4. 43,46 ‘The oxidation state of sulphur in the jonous and dithionic acids, respectively, are: LAH 10 322, 32, 33. 33. 1. 44,46 2. 44,45 3. 43,45 4, 43,46 ‘faftafifirs after vx fare ffm: He¥(aq) + X° (aq) = [HaX]'(aq). [Hex] (aq) ® fora, aft x =F, Cl rat Br é, at efter flr err agen ct bee L Fy NW SOR 39. The major product formed in the following 40 The major product formed in the following ae reaction is reaction is on Dem a mea 7 Ape yikes 1 Ph aes : xa “Br Br 41. AWB R Herat ‘ ‘ Ra FR iy ‘ Ho GH 8 1, dite (ren) 2, aes 3. faint Pate aera 4, eft 41. The relationship between A and B is . ‘ H H H CHs Z : Homomers (identical) Enantiomers Diastereomers Conformers 42. Reafafer any erate eat der cc LAH 3 42. a] pM wh i Me 4 Me Me h ‘The mast stable conformation of the follow- ing molecule is Me H Me 2 Yyeme Me Paredes a #110, % 2 era & sftfear averse ofits set car wrtedtgres St 21 a Ot ere14 44.0 Preafefas afifiear # ser yer sere £ ol PL-Pt (undivided cell) ‘OH electrolysis CF; Meo 9 OMeO Meo" “0 “Troe MeO M 2 NL ote Meo CFs i, ia Fac" "OH MeO © 4 F3C" S "OH 44. ‘The major product formed in the following reaction is ion of deoxymonosaccharide A with 2 Meo PL-Pt (undivided cet) equivalents of HIO, affords propanedial, Meo” formic acid and formaldehyde. The structure CFs Cage of Ais Toh we 2 hse am ee = > Fac hon Med : FC ‘OH 3, 48, BL ara Pree m/z 120.90 oi aie amare frre afar 8, 4g & 4. 7 Sy OH a OMe LAH49. st si. 1. p= (e77/40 4 ert/e) 2. Wa (eles — e-ralas) 3. p= emilee 4. pa etl ‘The lowest energy unnormalized wave function of Hf molecule is (r, andr; are the distances between the electron and nuclei | and 2, respectively) 1. b= (e774 @-r/te) 2. Wa (e-7/te —e-r/es) 3. b= entilae a he eles are oar a & fire ue fee fare Frwen aftittt aft 8, ag Rrare t 1 weer 2. era fra or 3. Preraarer 4. aren rr Nearest neighbour distance in a crystal system of side length a is in 1, Face-centered cube 2 Body-centered cube 3. Trigonal primitive 4, Primitive cube 2 sank % 0pm Atte ate H AA, m aight op wre Pen = 8 Rata wat are t cr nm + ami Bn? ta ant 3 * mi For a particle of mass m in a one-dimensional box of length 22, the energy of the level corresponding ton = Bis a a "Smit 2 Sami ae 2a 34 4 Prafafia # % Hcl var pei ® fare at ware LAH 16 1 HCL AY ater DCI A ger fig =at ser at 2. DOL#t atten Hel Ar arg rt ate 3. HCL ater er at Frame &, DCI art wr aren eer & 4. HCL # ater Del er aarti zener rer eae ‘The correct statement about HCI and DCI, among the following, is 2. 3 4 DCI has a smaller zero-point eneray than HCI HCI has a smaller vibration frequency than DCI ‘The force constant k of the HCI bond is half that of DCI ‘The reduced mass of DCI is smaller than that of HCL vert eam ft aed tet F300 K aa 2 atm 3.600 K =ar 4 atm 3 Peat Frey ara 2, ve ome A grt afta e 1 3. $Rin2 2. RIn2 z trina 4. 5 ERInz One mole of. a mono-atomic ideal gas is transformed from 300 K and 2 atm to 600 K and 4 atm. The entropy change for this process is 1. 3Rinz 2. tRin2 3. 2RIn2 4. 2RIn2 em afters Rarer arr sinrm # 2. 3 4. 3K, > 5D; 3h > 1D; 3h > 3P, 3 3Dp The allowed transition in an atomic system is 1 > 3D, 2 'Ds tH 1, ">= = MeO" = Cr ' Cx ‘The compound that will show a base peak at ‘m/z 120 in its El mass spectrum is CO OMe = | oho! is CO;Me CO Cy. co ‘OMe frefittre afitirar # seer ger seme 2; 3.\F Br ‘The major product formed in the following reaction is LAH as, 47. 47. 48. 49. Her feddw ener foo after Bx 10-8 me v-tst Bara AT rare from & Gr A erm = 1 ch; 1.6 x 107?9C) 1. 106 pm 2. 212 pm 3. 424 pm 4. 318 pm ‘The mobility of a divalent cation in water is 8x 10-%m?V-#s~, ‘The effective radius of the ion is (viscosity of water = | cP; €=1.6 x 10°C) 1.106 pm 3. 424 pm 2. 212 pm 4. 318 pm Prafafir # & ay age fee are arr re Fee er fra ee Set ah, ae z 1. Romgieer 2, ate 3. at 4 tatgea ‘The electrical double layer model among the following that consists of both fixed and diffuse layers is |. Helmoltz, 2. Gouy 3. Stem 4, Debye-Hickel Hg amy Pie Presa oat ar anette ae era &1 (wage aa eaPret| ar 2 Seer A ght wae 7, WaT Te #58. 87, s7. 59. ered sing a seat At ga sie La 24 3.6 4.8 The total number of symmetry elements in diborane molecule is 2 2. 3.6 4.8 ve affte se ger ty, Peron snfitear e120 Free Bar Bh ‘x! ar aera art 2 23 4,12 ‘A physical observable, ‘x’, appears with the Probability distribution e!*-120, The average of x’ would be Lo 2:3 3.6 Prefefir a fer ay rq wie rare wart wait ox atfre &, ae 2 LH 2 3M 4 The rotational partition function is expected * to be the smallest for the molecule, among, the following, 1 Hy 2 ty, 3..Ny 4.F aft us afin A pfarq afreste Bina & af & eqamarqart &, at aftfear Hates Lo 24 3.2 4.3 If the half-life of a reaction is inversely Proportional to the square of the concentration of the reactant, the order of the reaction is Lo 21 3 4.3 we agettrce afiiea # agetteeor At feat CN) a earra segee stat (P) ewe ware LAH ‘S106 CRIE19—1AH—2A 7 39. fraction of monomer consumed (P) for a polymerization reaction are related as. t LE 1 2. y= 1 3. (ND 4. (=z sateen 132 fit ast wr ec IL ee nna Rare fire : wierd a ‘The correct match for the compounds Column I withthe property in Colum 11 ‘Column T Column Tt] P | Dichlorodifiuoro-| 7 methane Sulfadiazine Q R | Cortisone s Hexachioroben- | iv | Ozone layer zene depletion6 61. a. ATT/PART- C [RUC(CO)s) FTTH re Praha wait a a ad fi (a) 1a 86 TAIT FART (b) aA CAAT closo TATE AE (oy cert arpa ter ara art Pere & (ore krh Ru waa Cae 1 abemard 2. award Far 3, a bTaTC 4. baat ‘The correct statements about [RucC(CO)] cluster from the following {@) itis an 86 electron cluster (b)it is a closo structure type (©) its shape is capped square pyramid (@) carbon interacts with all the Ru centers in the cluster are 1. abcandd 2. aand b only 3. a, bande 4. abandd ‘freafatiarn, afitiiear & aeferr wa aftr wena Ht fac & [Fe(?-CsH5CH;)(CO)a] + PAs — [Feln®-C)(C(-O}CH3)(COKPP)} LAH 18 oo Wen, 62. A plausible structure of the intermediate involved in the following reaction [Petn’-CsHls)(CHs)(CO)s] + PPhy —> [Fe(n'-CsHs(C(70)CH5)(COMPPhS)] 63, orftereaPraftats % ate fae Pacer, arsine car sare ate 8, rer 1, MeySiCl, MeSiCl 74 MeSiCl, 2. MesSiCls, MeSiCl 74T Me:SiCl 8/06 CRIE9—1AH—2863. 68, 65. as 3. MeSiCl,, MesSiCl; 41 Me)SiCI 4. MesSiCls, MeSiCl; TT Me,Si In the synthesis of polydimethylsiloxane, the chain forming, branching and terminating agents respectively, are L. Me,SiCl, MesSiCt and MeSiCl, MeSiCl; and Me,SiCl 3. MeSiCl;, Me,SiCl, and Me,SiCi 4, Me,SiCls, MeSiCl, and MeiSi freafafer 4% ae Reet aft emit vafiersiat ot Afien teat 8, ae 1. 20, 28, soar 126 2. 24,28, 8241 126 3. 20, 50, 80 aT 184 4. 28, 50, 82741 180 The set among the following in wl ‘numbers are magic numbers of nucleons is, 1, 20, 28, 50 and 126 2. 24, 28, 82 and 126 3. 20, 50, 80 and 184 4, 28, 50, 82 and 180 all sare agra for sree pert & 1, ag Pereer arer are ee senha 2. waft amfear, Segre aecara ater war soaaz aE 3. Bae fry are: qre At areca mE 67 art 4, Seabees rer att & Incorrect statement for amperometric titra- tion is 1. itis based on measurement of diffusion current 2, its sensitivity is always higher than those of spectrophotometrictitrat 3. itdoes not generally require an indicator 4, itrequires inert atmosphere (N3/Ar) areata ps0 % stank # fey gait a faare far, A. ait ed, aaa oer tates Bg fit ger op ones HEE TAH 67. C. ert Fe(il) ae cares Per ¢ sewer ie wet wat UE LAB 2AC 3. B,C 4. art A Consider the following statements with respect to Cytochrome P-450 A. Ithas histidine coordinated to ironcentre - B. It is@ membrane bound metalloenzyme C. Ithas Fe(III) ion in the resting state of the enzyme ‘The correct statement(s) is/are 1 AB 2A,C 3. BC 4. Nonly ‘Preaferftrs eater afatirarsit 1 TAMER By BoE a Rear AAT AL 1,226 are, B. CO, 1 Hatt C, aeefte & terrae D. erate genres & erate Tea ARATE By: ¥ fore at war Be 1LAGD 2. A,B, 3a 3. B,C at 4. Aart Consider the following transformation reactions in the context of co-enzyme By A. 1,2-Carbon shift B, Hydration of CO; C. Benzene to phenol D. Dimethyl sulfide to dimethyl sulfoxide ‘The correct statement(s) for co-enzyme Byz is/are 1 AGD 3. B,Conly 2. A,B, only 4. Aonly ‘Bete Ratatat tat ere ©) a Batter a ft rater er afre ate Gi) Bora CH ord A eet RE Ree panera ar rage sae fe cae afte age aire & i69. 20 (iv) *B? gare efter NaOH & afta se NaBOH), PeATT 10. ‘The correct statements regarding B among the following (i) Nuclear spin of 'B is greater than that of "8 Gi). The polarities of B-H bond and C-H1 bonds are opposite ii) Cross-section of neutron absorption 0, for "B is much more than that of "B (iv) B reacts with boiling aq. NaOH solution 10 form NaB(OH), Freaferting & & adh seareeet at ahr: @ Liclo, # str Lit wr # afte tres mL. (i) Na # gaat # Li ae eet fara (2°) afire aemrare Gil) Nag) # ate Li'@) # wert won afire et 1 @anGi) 2. rar Gili) 3. (i) ar Gi) 4. Gi) Fr ‘Choose’the correct statement/s among the n. following: (LiF is more soluble than LiClO, in water. (Gi)_‘The standard reduetion potential [E"] of Li is more negative than that of Na. ii) The heat of hydration of Li"(g) is greater than that of Na'(g) L. (and (i) 2. (and (iii) AH 3. (ii) and (iii) only Preafafira # & aft wart At ghte: (i) OnF. fara FT Oe Gi), or: wera Ar A ag 2%) PT NaOH Pactra & arfirfieay we OF, FT Pra ete Gi) HS 8 OP, fatto arate et ae 1. @ ary Fat 2. (, (i) TT (i) 3. Gi) 7 (iii) Fat 4, (i) ert Choose the correct statement(s) among the following: i) The diheciral angle in O;F: is 0°. OF is generally prepared by reacting fluorine gas with dilute (2%) ag, NaOH solution. ‘re rere ret gaa 2, ae e Le [Min(Hs0)5)" Hotiewet = Hans (COLO): ATTA 2. [Mn(H:O)e)*: tare Hagns [Co(H;O)4)” Has’ [CoC 4, [Mn(#.0)] Hotenet > Hans [Co(HO),]: EAP The correct set of information is 1, [Mn(H1:0)4)": tates = Halas [Co(H20).}"": Paramagnetic 2. [Mn(H20)<}™: Hotuea > Hei [CoCH,O)s}”: Diamagnetie 3. [Mn(H:O)": Hagin [Co(H,0).] iamagnetic A. [Mn(H20)6P": Hobserved > [Co(H,0),]"*: Paramagneticn. 2B. 2. 2 33 fora sige Bagi reat i iat 3 Refers site Rare fifi ACT 3 ger ue te fe Pah 8. Co® wat Ce Raige atare re Rear C. Mn aga aft gfe ati a dat anit zat D. NEF ige Ata are ae aa § at wa 1. AmaC 2. A,CaarD 3. cmap. 4. B,CmarD. 74, 74. Consider the following statements regarding electronic spectra of high spin complexes A. TH” complexes exhibit one sharp band. B. Co™ and Cr* complexes exhibit two broad bands. C. Mn" complexes exhibi Weak and sharp bands. D. Ni complexes exhibit three broad bands. ‘The correct statements are: 1. Aandc 2, A, Cand D 3. Cand D. 4. B,Cand D, aif ste feet were efter fare afett vem faeft sea ter oarfttt a Aim: (A) FXeO(0S0,F)_ (i) Hw (B) FXeN(SO;F), (ii) FAR (©) Xe0; i) Tarp (D) XcOF: (iv) art 1. AMG), (B)-G), (Ci), (OMG) 2. (AMG), (B)(), CHL). (Div) 3. (AMI), (BC), (CC), OP) 4. (AMI), BHiv), (CHAD, (D)Lii) series of very Match the appropriate geometry on the right with each of the species on the left: (A) FXeO(0SO;F) (i) linear 16. (B)FXeN(SO;F): (ii) pyramidal (C) Xe0s (ii) T-shaped (D) XeOF, (iv) bent 1. (A), (B)4), ©), (DH(iii) 2. (AH, BM), (CH), (OMiv) LAH 78, 75. 3. (AMV), (B)-(), OH 4. (AMA), (BYiv), (Ci (yi) (Oil) trans-{CoLC\(en);]' (L= NO} , NCS , OH, C1) ore serena qftorr we SeMTz (A) BUST FATE (A) ¥ cise eT Prog Preran ar age woe are 1. L= NO, on? 92. freafafirn after ar wer sears t 93. 1. LIHMDS, TMSCI 9 ok then A ew 2. PhSeCl 3. HaOp, A Q L Pho |. 4 Ph Q, eS lee | : 29 93. Sesion Ase =e ren oe ‘The major products A and B in the following reactions are whe LUDA. THR, -78"6 eeHO ‘The major product formed in the following oe reaction is bcd Bom Punmgs, msc 1 © on Pho then A aloo 9 ea Er et io 2. Phseci io 3. H;02.A = 2 © On S| Sea esos ccreab er fe a he oD] [a a + hh L Ph Sh 7 7 eafa tre afhinat apse see A aa es wh oe eh Be c io TAHOH > ‘NH YS is N L ra 1 © 1. 4 2 4 ms ceyick | lec H\ HAN CN ail J ofa 95, ‘The major product formed in the following reaction is ae atin 4, NOC!, pyridine 2h 3. H2SO, 94, The major product formed in the following reaction is L = - ae \ N J - 1 L a 2. th ch flea] N 2 nN fa a _ oS (J l J 4 3 4 / Cee WwW Wn = ! ! 96, Fafa afitfvar sige Reefer eo 9s, Prenat fer ar ou sere & 1, NOCI, pyridine _ od” 2.hv 3.H804 ‘OH © NH LAH31 3 ra OU a ee reaction is 96. ‘The major products A and B formed in the SO.et NeBHACN eco : 1.8 PH~4 "= he Os a. : NaBH3CN pH~4 1 HO. 44 ‘CHO I 98. The structure of product B formed in the following reaction sequence is eS, crpcreno 8 omen ig oS Z 2 ‘CHO A 3 Ss OH CHO LAH 32 rae zi aes 1 ‘The major products A and B in the following reaction sequence are oe "0 > Ho1e>0,) ‘ear $44 (T>>0,) ater Sart re arr eT oar et, TER Laskin 2 dad 1 4 east For a linear molecuile the mean energies for translation, rotation (T>>0x) and vibration (1>>0,) follow ratio: Lasdea ae ed 4 3.1: AH ‘8/06 CRIE19—1AH—3A, 104, 104. 10s. 105. aftr Pret fe seer sah we safer safer Lou tint his 2 en Be 3. daa Fete + Gs 4.3% -in- Zu ‘The highest energy 1 — molecular orbital for the allyl system is l gu tiat ae 2a aa ene 3. gmat Bu jta-Fyts oe regis Terry & Pere avant rin wer 8, r2e-5(3.cos? @ — 1) 1 afer 8 titer Ate warren sear 1, wat m 8 ara: 1, 2,20 2 ind 3. 3,2,0 3 ‘An unnormalized wave function of the hydro {gen atom is given by r2e~3(3 cos? @ ~ 1). ‘The three quantum numbers, nl, and m, associated with this orbital are, respectively 2.211 aan cisssyererter ar -anffes py, + pa — pa iy fer setae Pre sede cor, ae @ GolETG lo] At tft A, [I [1 =l}-1 B [t f-1 jt f-i B [ei LAr 2. Ae 3. By 4. By106, ‘The m-orbital p, + P2 ~ Ps — Pa of cise butadiene belongs to the irreducible repre- sentation a = 2. Ay 4. By 107, Cop PS ET AA Ree Pew HA, recor fara are waz dra @, seh Heat & Cw [EG [% lo» rit ft [3 1 22 3.3 44 107, ‘The number of times the A representation appears in the representation T of the Cay point group given below is oD ! 3 3.3 Ls Taar 7.07% gait oat ww aT Br cat ve sat Hert Peat At sere Sat wat aaftat maa: N TaN a In care Bh (yoke, Tore: Tera aT et eb aan ag ar art & are aifire PH AT frarat Pravat were $1 afer Perr ‘saat 2) 1. SSyh/kT Ce [5 1 i Ea 2.2 44 . eyh/kT 3. Bynjer 4. BSyh/kT LAH 34 108, The populations of proton spins in the highest energy level of a sample in magnetic fields of 1.5 T and 7.0 T are N’ and N, respectively. The value of In" is (y,h,k,T are gyromagnetic ratio of the proton, Planck’s constant, Boltzmann constant and temperature of the sample, respectively; assume that the partition functions for both systems can be approximated as 1) 1, S.Syh/kr 2. Synper a 3. Fyaper * 4, BSyh/kT 109. 2 teesrcrny fet A car B At Tre Free grat 5 HET HTT (Sq ~ Shy) PT arya 8 (fear ef AA tae elt BAT airae eft A ater THE ) 1. $RIn2 2. Rind 3. Sainz 4, SR nz 109, ‘The difference between standard molar entropies of two mono-atomic gases A and 8 (52.4—S8,n) at a given temperature is (Given that the molar mass of A is twice the molar mass of B) 1. 3Rin2 2. Rin2 SR in2 4. ER inz 110, p= 2+) sat B tear are ar wae Bh ore te aioe aH rere, U — Uideat RT, me sr Gy 2 SEG, 32s 4 8/06 CRIE/19—1AH—3B110. A non-ideal gas follows the equation = Eee! PoE hee Where 8 is a function of temperature only, ‘The deviation in internal energy from that of an ideal gas, U — Uigeas is given by 2 EG), ea 111, 1000K Fe A ar Aafia sraear a Perirocr ay fracas ar argon car rate rer A>B+C A>P+Q @ @ 1000K 9% Pp ft afireae dain after afer s 1, 625 2 3. 166 4, ss 5 111. ‘The gas phase decomposition of A at 1000K follows two decomposition paths Blementary | Rate process | constant @ [aserc| 3st @[A>P+o] Ss The maximum theoretical percentage yield of Prat 1000K is 1. 25 2. 60 3. 166 4.375 112, fear sit se MR weer cH eT aia te, wet rate sat = a M+hvoM | Tobe i) | Me +Q>M+Q | koleliM) MoM+hvy | 0.2[M"] APRA Ate SE (IVs slQ] * aT [Q]=0-TC ae: HE 4B Japs BITTE TAH 35 112, 113. 113. 14 3.20 2, 0.25 4.08 Photochemistry of a molecule, M. is described as by the mechanism Elementary process | Rate M+ hv Tee | M+Q>M+Q | kglQIM] G MM +hve | 02(M"] ‘The intercept at (Q] = 0 is 4 for the inverse of Muorescence intensity (1/,)xs{Q] plot. ‘The value of laps is 4 3. 20 2. 0.25 4.08 Wan gefa ack: %, wifte Pee araar (CMC) & Sue Ht aizat %, aehe faerrr ft iter areca Hf nize azt e ara ar ara afta ay at fase adh er Amine 2, see 1. rae area tian a andl 8, vee Preraa Hares vat cea 81 2. tere area fixer at wedt 3, vey freer sraradt cect 2 3. Hae arene ataar a aedt &, war conerat Ht farren oft far ata 4. crerft # seafire aft ara atax area dtaar & aged 2 Above the critical micelle concentration (CMC), the option which correctly describes the variation of molar conductivity. with increase in concentration of sodium dodecylsulphate in aqueous solution is |. molar conductivity increases sharply, but the solution does not remain colloidal 2. molar conductivity decreases sharply, but the solution remains colloidal 3. molar conductivity decreases sharply and dissociation into monomers also ‘occurs sharply 4, molar conductivity increases sharply with large loss of entropy114, FAA % St tei at oa BZ ata T 300K art aR were Pert A oft Frere fier sat -15kjmol? @ cea arr Pa wer A fet gat (ks 2) Brae Precan @, 388 (R= 8.3) K*mol) 1, -129 2. -6.0 3-15 4-09 114, When two moles of liquid’A are mixed with two moles of liquid B at 300 K, the excess molar Gibbs energy of the solution is 15k] mol“, The corresponding value of Gibbs energy of mixing (in kJ) is closest to (R=835K"'mor') 1, -12.9 2 -60 3. -15. 4. -0.9 118, 2.0 Ata 02(g) ¥ a AR (are ATED) FT SOO K ACS LY 50 L ae watt wT sortie areas rafter frat wat atafer Saf (ks 8) aaa Beth Pree amet 5 = Raf KR mor; 5 (e = 83K! mol"; Cyy 3%) 1, =225 2, =125 3. -19.1 4-75 11S. A sample of 2.0 moles of O2(g) (assumed ideal) at 500 K is expanded from 5 1. to $0 L = under adiabatic and reversible conditions. ‘The change in its internal energy (in Kl) is close to 5 re hr etgers (r 3) Kt mot + Gym =3R) 1, 225 2, 125 19.1 4-75 36 116, 117, 117. op eascitta ateftrretiacen Rafer a (Brafinar ac at car were wea ra ariire sizer #, at ager aftr AN) HH Ree B, TEE 1. WN) = 2M Bk 2. (Ny? = 2M eke 3. (N)? = 2IMIgke +1 4. (NY? = Moke +1 ‘The reaction rate of a self- polyesterification reaction is given as — Siegott — k{cooH#[OH). If [Mly is the concentration of hydroxy! and ‘carboxyl monomers, then the degree of polymerization, (N) is given by 1. (N) = 2[M1gkt 2. (NY? = 2[M]gke 3. (N)? = 2[MIRke +1 4. (N)? = 2[M]okt +1 ue farrerarer free fart (a= b + lyzed initial Ga= 90°) & farm freatatera ot ete ae a, TER 1, sinta = 2 fet? +42) +0244] 2, sinto = Ea fc2(h? +k) + a2") 3. sinto = [a2(h? + k2) + c2e2] 4. sin? = ne +24 2) ‘The correct relationship among the following, for a tetragonal (a= b # cia = 90°) crystal system, is 1, sinto = 2 [c?(h? +k?) + ae} 2. sinto = alee? +k) +0227] . sin? = 2 fa? (h? + k2) + c2e2] 4, sinto = Zn? +k? + 2]tis, af us faa arsed ® Pe afters 05 V Faz ac06 Va arare, tt ge ener fire wer src sr acy (Inlet) res at ater ag & (fear & sae yi B= 0.5) e rf 105% 2, 005 = 3. 015 4. 001¢ 118, Ifthe overpotential of an electrolysis process is increased from 0.5 V to 0.6 V, then the ratio of curent densities (InJ¢#)of the electrolysis will be equal to (given transfer co-efficient = 0.5) jose 3. 04 ale 119, 2 stare Na,SO, Pera cravat Pore (a) Stren araftee afierar Tre (74) ah Pra ware citar at 8 wee . w+ SRTIn2 + 3RTInyy yO + 3RTIn2 + 3RTIn yy w+ RTI ¥y uO + ARTI Yg 119, The chemical potential (x) of a 2 molar Na,SO, solution is expressed in terms of ‘mean ionic activity co-efficient (y.) as 1. 9+ SRTIn2 + 3RTInys 2. w+ 3RTIn2 + 3RTIn ys 3. w9 + 3RTIn ys 4, 49 + 4RTIn 74 37 120, CO FRAG, = (Eyer — &) (+) men were ace oe ahh tar 2, fare at —14em™? gar ates 2170 cm 1 CO Retort Saf (em! #) aT art amet cra fife, PCO mm sorta dif @, fect sat ft arftreaft & = (v+})o-(v+3) x0iD=2) 1, 42044 2, 34088 3. 168175 4, 336350 120, The Birge-Sponer plot between AG,,,: (Gve1— &y) and (v+ 1) for CO is a straight line with slope of —14 cm~tand intercept of 2170 cm™! . The approximate value of dissociation energy of CO (in cm') is (Assume CO as an anharmonicoscillater with the energy expression eo= (ot 3)a~(v43) xD 2) 1. 42044 2. 4088 3. 168175, 4, 336350,