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MACHINING OF GRAY CAST IRONS AND COMPACTED GRAPHITE IRON

B. Tasdelen1, M. Escursell2, G. Grenmyr 3, L. Nyborg 4

1, 3, 4
Department of Materials and Manufacturing Technology,
Chalmers University of Technology, SE-41296 Gothenburg, Sweden
2
Machining Development Center, SKF, Gothenburg, Sweden

bulent@chalmers.se

Abstract: The aim of this paper is to compare the machinability of gray cast iron and compacted
graphite iron (CGI), in terms of tool life and microstructure. Two gray cast irons with different
graphite morphologies and one CGI were tested. After the tool life tests with carbide and Cubic
Boron Nitride (CBN) inserts, microstructural changes on the machined surfaces was
investigated and SEM analysis of the inserts were performed. The results show that CBN
performed much better than Carbide tools when machining gray cast irons but did not work
when machining CGI due to high diffusional wear. The shorter and thicker graphite flakes for
one of the gray cast iron caused different chip contact and wear mechanism on the inserts. The
comparison of machinability and tool wear gave better understanding of the wear mechanism of
CGI.

Keywords: Compacted graphite iron (CGI), milling, tool wear, surface integrity,
microstructure

1. INTRODUCTION This causes a temporary loss in the contact of the tool


and the work piece, until the next chip forms. As a
New regulations in USA and Europe will decrease consequence, the surface roughness of the machined
the maximum allowed emission level for heavy duty work-piece is increased.
diesel engines. To fulfil the new demands,
combustion pressure in the cylinders must be The vermicular shape of the graphite in CGI creates
significantly increased and therefore new materials stronger bonding between the matrix and the graphite
with higher strength are needed. Compacted graphite than in ordinary gray cast iron and there is hence less
iron (CGI), which has improved mechanical crack propagation for CGI compared to gray cast
properties, is therefore a potential candidate to irons (Cohen, et al., 2000; Dawson, et al., 2001).
substitute the conventional engine material, gray cast Furthermore, CGI is also more ductile then gray cast
iron (Dawson and Schroeder, 2000; Sahm, et al., iron. This entails considerably larger contact with the
2002). On the other hand, CGI has lower cutting insert, resulting in increased temperature and
machinability than conventional gray cast irons longer time for chemical reactions between the
(Sahm, et al. 1998; Mocelin, et al., 2004). cutting tool and the work-piece material (Reuter, U et
al., 1999).
For gray cast iron and ductile iron the chip formation
can be described as follows (Mocelin, et al., 2004). 2. EXPERIMENTS AND ANALYSES
First, the tool starts to compress the material beneath
the flank and creates fracture that propagates ahead 2.1 Work piece materials
and below the cutting edge. The tool proceeds and a
material fragment is completely detached. In some Table 1 presents data for the work piece materials,
cases, especially for gray cast iron, a part of the work including nominal tensile strength values, average
piece material can be torn off in front of the tool. matrix compositions and graphite characteristics. All

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materials have predominately pearlitic matrix.


However, there is a certain content of free ferrite for
CGI. The gray cast irons were sand cast in blocks. Table 2 Cutting data and insert information
The difference between the gray cast irons was the
treatment for gray cast iron 2 to obtain thicker
Insert vc fz ap ae D
graphite flakes. This also induced certain porosity.
Despite this, both gray cast irons have Type 1 shape (m/min) (mm/tooth) (mm) (mm) (mm)
A graphite according to ASTM. The CGI material
was treated specially with Mg in order to get the Carbide (HM) 275-360 0.15 0.5 70 80
vermicular shape of the graphite which has also S-N260.8
resulted in 4% nodularity. A comparison of graphite -1204-W
morphology between the materials is illustrated in
Figure 1. The sulphur content is kept between 0.08 CBN 700-900 0.15 0.5 70 80
wt% and 0.14 wt% for the gray cast irons and it was S-N260.8
0.02 wt% for the CGI material. -1204-F

Table 1 Selected data for the tested materials

Material Tensile Matrix Graphite 2.3 Analyses of work piece materials


Name Strength Morphology
Gray cast 275 MPa Pearlite Type 1, Size 3 After the tool life tests, the microstructural analysis
Iron 1 of the milled surfaces was performed with the optical
Gray cast 300 MPa Pearlite Type 1, Size 4 microscope. Cross sectional samples were cut from
Iron 2 the milled surfaces with water-jet to minimize the
7 % ferrite Interconnected
CGI 515 MPa impact of cutting on residual stresses and effects on
vermicular
work piece microstructure within the surface zone of
the milled surfaces.

2.4 Tool wear analyses

High temperature and stresses are the main causes of


the tool wear. The two basic wear zones on the
inserts namely, seizure region (adhesive wear) and
sliding region (abrasive wear) can easily be
(a) (b) investigated with scanning electron microscopy
(SEM). In this study, the rake face of the inserts was
investigated and different regions of the chip-insert
contact were imaged with secondary electron
imaging in a Leo Gemini 1550 SEM instrument.
Since sliding of the chip causes work hardening and
oxidization of the material with different thickness
depending on temperature, electron dispersive
spectroscopy (EDS) mapping was also used to find
(c) the different elements in the oxidised clad material.
Fig. 1. Graphite morphology: (a) gray cast iron 1,
(b) gray cast iron 2 and (c) CGI. The tests were stopped at equivalent time intervals to
measure the tool wear. The wear characteristics were
pictured with a Nikon optical microscope and the
2.2 Tooling amount of tool wear was measured with a special
programme, Mätmodul. The contact of the insert with
The face milling of the blocks were performed with the work piece is seen in Figure 2 below.
two different inserts and different cutting data in
order to investigate the machinability of the
materials, see Table 2 for cutting data and insert hd ap
information.

In order to make terminology easy the hardmetal Fig. 2. Insert and work piece contact.
insert, S-N260.8-1204-W, will be denoted as HM
and the cubic boron nitride insert, S-N260.8-1204-F
will be denoted as CBN.

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3. RESULTS AND DISCUSSION insert that milled CGI. The fracture is a fatigue
fracture evidenced by the presence of beach marks
on the fracture surface, see arrows in Figure 5 (c).
3.1 Tool life analyses

HM Inserts; The tool life tests at the lower cutting


speed (275 m/min) showed that gray cast iron 1 has
the lowest tool wear for both speeds compared to
gray cast iron 2. The highest wear was observed for
CGI material as seen in Figure 3.

Carbide Insert
0,40
(a) (b)
Grey Iron 1
Grey Iron 2
0,30
CGI
Vb (mm)

0,20

0,10

0,00
(c)
0 10 20 30 40 50 60 70 80
Ts (min) Fig. 5. Crater wear and insert breakage, rake face on
the HM inserts at 275 m/min, (a) gray cast
Fig. 3. Tool life results for HM inserts at 275
iron 1 after 45 min, (b) gray cast iron 2 after
m/min.
45 min and (c) CGI after 49 min.
The higher wear on the inserts when milling gray cast
iron 2 compared to gray cast iron 1 is a result of the CBN Inserts: The flank wear was low for CBN
combination of graphite morphology (increased inserts compared to HM inserts when milling gray
mechanical properties), porosity and a rather higher cast iron 1 and gray cast iron 2 at 900 m/min, see
carbide content that resulted from nitrogen treatment. Figure 6. When machining CGI material even with
the lower speed (700 m/min), the CBN inserts
The higher wear resulted in a crack (see arrow in experienced severe wear and the tests were stopped
Figure 4 a) on the end side of depth of cut for gray after 8 minutes due to high diffusion wear. This high
cast iron 1 and a breakage (see Figure 4 b) for gray diffusion wear resulted in a deep crater, see Figure 7
cast iron 2 at the same place for the higher speed for the side views of the inserts.
tests, see Figure 4.
CBN Insert
0,40

Grey Iron 1
0,30
Grey Iron 2
CGI
Vb (mm)

0,20

(a) (b)
Fig. 4. The edge of the inserts after milling gray 0,10

cast iron 1 (a) and gray cast iron 2 (b).


0,00
When the inserts were examined on the other side of 0 10 20 30 40 50 60 70 80
Ts (min)
depth of cut, SEM images indicated crater wear on
the inserts that milled gray cast iron 1 and gray cast Fig. 6. Tool life results with CBN inserts for gray
iron 2. The insert that milled CGI material broke. cast iron 1 (900 m/min), gray cast iron 2
(900 m/min) and CGI (700 m/min).
The crater wear changed the contact area and
increased the fatigue loading (interrupted
machining). The varying stress level caused a crack
on the insert corner when milling gray cast iron 2,
see arrow on Figure 5 (b), and a fracture for the

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(a) (b)

Fig. 9. Mapping of CBN insert for gray cast iron 1.


(c)
Fig. 7. Crater wear on CBN inserts, side view for Another observation is that a partial layer formation
gray cast iron 1 (900 m/min) after 45 min, occurred very close to cutting edge for gray cast iron
gray cast iron 2 (900 m/min) after 45 min 1, but not for gray cast iron 2 and CGI. This banded
and CGI (700 m/min) after 8 min. layer in the contact is connected to chip formation,
heat distribution in the cutting zones and chemical
When examining the rake face of the CBN inserts interaction between the insert and work piece
with SEM, it was observed that a partial layer material. It was already expected that a layer
formation was seen only for gray cast iron 1 on the formation would be missing when cutting CGI.
seizure region of the chip contact. The seizure region However, the lack of this layer when cutting the gray
had a clad material in the shape of a band for gray cast iron 2 means that either a small variation in the
cast iron 1 but not for gray cast iron 2, see arrow in sulphur content or the graphite morphology
Figure 8. difference is the cause for different contact
topography for the two gray cast irons. It has also
been pointed in literature (Mocelin, et al., 2004) that
the easy cracking leads to short chip formation in
gray cast irons. This is also observed in our case and
supposed to be a result of the decreasing interatomic
locking between insert and chip in the seizure region
(Trent and Wright, 2000). This hypothesis is
supported by following arguments. There is sliding
(a) (b) of the chip in the seizure region for gray cast iron 1
Fig. 8. Rake face of the CBN inserts showing the as evidenced by the partial layer formation.
different chip contact and clad material after However, there is no such layer in the seizure region
45 minutes of cut at 900 m/min for gray cast on the inserts that milled the gray cast iron 2. The
iron 1 (a) and gray cast iron 2 (b). plasticity of manganese sulphide inclusions must be
adequate to act favourably in the secondary shear
The EDS mapping revealed that the banded structure zone, meaning that the characteristics of the sulphide
is the clad material that was oxidized. Besides O, the should not be too fluid (Araki and Yamamato, 1975).
clad material in this seizure region consisted of There is an appropriate temperature range for an
mainly Fe, Mn, S and Si, see Figure 9 for the effective lubricating action of manganese sulphide
example of EDS mapping of the region. The same inclusions, not only in the secondary shear zone but
elements were found in the rest of contact area for also in the primary shear zone (Araki and Yamamato,
both gray cast irons. When it comes to CGI, the clad 1975). Consequently, if there is another temperature
material in the contact area consisted mainly of Fe, isotherm distribution on the rake face when cutting
O, Si and Mg. the gray cast iron 2, there could also be a different
banded layer formation. Another reason may also be
the different graphite morphology of gray cast iron 2
compared to that of gray iron 1, which in turn should
affect the contact area. The combination of these two
effects is of course also possible.

It has been commonly anticipated that MnS layer


formation in the gray cast iron acts as a barrier and

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decreases the chemical affinity between the insert microstructure development within the surface zone
and the chip ( Cohen, et al., 2000; Dawson, et al., of the work piece material during machining.
2001; Gastel, et al., 2000; Abele, et al., 2002).
However, although we observed no layer formation Milling with HM resulted in a plasticized layer below
in the seizure contact zone for either gray iron 2 or the cut surface. This heat and deformation affected
CGI when cutting with CBN, the high diffusion wear layer can be observed the orientation of the matrix
was only observed for CGI as a deep crater. and the graphites along the cutting direction, see
Therefore, the affinity of the CBN insert to the work Figure 10 (a). The effect is almost similar for gray
piece material is another important concern. At cast iron 1 and gray cast iron 2. However, the layer is
temperatures above 700 °C (at high cutting speeds thinner for CGI which means that the flow zone is
for cutting CGI and also gray cast irons), the binder thinner, see Figure 10 (b). On top of the surface, the
phase in the CBN tools are not stable. The CBN itself white layer formed for gray cast iron 1 and gray cast
is also not stable and decomposes forming volatile iron 2 is clearly observable and thicker than that
boron and nitrous oxides (Gastel, et al., 2000). observed for CGI. Microhardness measurements,
Hv0.05 showed that this layer had a hardness of about
The diffusion of Co, C and tungsten to the ferrous 600-800 (kg/mm2). Two alternative explanations
work piece materials have been mentioned in the exist. Either the layer is martensite or it is composed
literature (Pereira, et al., 2006). However, Gimenez of a zone experiencing mechanical grain refinement.
(Gimenez, et al., 2006) has found that WC-Co In both cases, significant hardness increase would
substrate dissolves even under 700 °C when in result. Further studies including detailed X-ray
contact with iron, whereas PCBN composites are diffraction studies and transmissions electron
chemically compatible with iron even up to 1000 °C microscopic studies would be need to clarify the
for 1 hour. Dawson, et al., 2001 has mentioned that issue. However, the change in microstructure in the
small amount of free ferrite in gray cast iron can surface results from the combination of high
reduce PCBN tool life. Nevertheless, they concluded deformation and heat. The thinner white layer for
in their work that small amounts of free ferrite is not CGI is then an evidence of a different chip formation
responsible for high wear rates in CGI machining. mechanism that is connected to different heat
The real mechanisms behind the high diffusion effect distribution between the chip, insert and work piece
in CGI machining with CBN has not been clarified material.
yet.

The chips from the CGI tests are longer and have
different colour than the chips from the two gray cast
irons. This means that the chips are less easily broken
due to the vermicular graphite shape of CGI. As
mentioned before, the flake graphites in conventional
gray cast iron contributes to the easy cracking path
and thereby shorter chips. (a) (b)
Fig. 10. Plasticized zone and microstructural change
It is supposed that the low content of S in CGI at the surfaces of milled at 275 m/min for
resulting in no MnS layer formation is not the only gray cast iron 1(after 30 min.) CGI (after
reason for high diffusional interaction and associated 26.14 min).
tool wear. The observations in terms of cladding on
the tool were similar for the gray cast iron 2 and the The same plasticized region and white band were not
CGI tested, although the former showed much less observed on the surfaces that were cut by CBN
wear. Thus, the short chip formation due to the inserts. This resulted in a better and smoother surface
graphite flakes geometry and distribution is therefore finish for CBN inserts, see Figure 11.
expected to be an important reason for chip-insert
contact time. Longer contact time in this context
means higher temperature in contact zone and then
larger degradation of the insert.

3.2 Surface Integrity of milled work piece materials

Milling with either HM or CBN inserts leads to


(a) (b)
different conditions in the cutting zone. For the same
Fig. 11. Machined surfaces with CBN inserts.
depth of cut, the latter kind of inserts can be run at
900 m/min, 30 minutes of cut for gray cast iron 1
much higher cutting speed closer to adiabatic
(a) and 700 m/min, 8.08 minutes of cut for CGI
conditions in the surface. This is also reflected in the
(b).

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4. CONCLUSIONS Dawson S., Hollinger I., Robbins M., Daeth J.,


Reuter U., Schulz H. (2001), The effect of
The machinability of CGI was evaluated in metallurgical variables on the machinability of
comparison to conventional gray cast irons with compacted graphite Iron, SAE 2001 World
graphite morphology ranging between CGI and Congress Detroit, Michigan March 5-8, 2001.
conventional gray cast iron structure. The summary Gastel M., Konetschuny C., Reuter U., Fasel C.,
of this study can be outlined as follows: Schulz H., Riedel R., Ortner H. M. (2000),
Investigation of the wear mechanism of cubic
Graphite morphology plays a significant role in the boron nitride tools used for the machining of
chip formation mechanism. This is evidenced compacted graphite iron and gray cast iron,
from the banded seizure region (different chip International Journal of Refractory Metals and
contact) of two gray cast irons with different Hard Materials 18, pp 287-296.
graphite characteristics. Gimenez S., Vleugels J., Van der Biest O. (2006),
It is supposed that the formation of MnS layer may Chemical Compatibility of PCD and PCBN
not be the only mechanism behind the difference Superhard Tools with Iron, Euro PM2006,
in machinability between the materials tested. Volume 3, pp 109-114.
The tests showed only possible presence of MnS Mocelin F., Melleras E and Guesser W.L. (2004),
clad on tool inserts for one of the gray cast irons, Study of the machinability of CGI for drilling
while the other gray cast iron as well as the CGI process, Tupy Fundicoes Ltda. Brazilian
produced no such clad and still showed Manufacturing Congress, Vol XXVI, pp 22-27
significantly different machinability. Pereira A. A., Boehs L., Guesser W. L. (2006), The
The thinner flow zone was observed for CGI cutting influence of sulfur on the machinability of gray
compared to the gray cast irons pointing out cast iron FC25, Journal of Materials Processing
different heat distribution between the insert, Technology, 179, pp 165-171.
chip and work piece material. Reuter U., Schulz, H., McDonald, M. (1999)
The CBN inserts are robust and gave a better surface Compact and Bijou - The Problems Associated
finish and lower tool wear for gray cast irons but with CGI Can be Overcome, Engine Technology
did not work for CGI. The affinity between CGI International 12/1999, pp 58-60 , Dorking, GB
and CBN inserts resulted in high diffusion wear. Sahm D., Troschel W., Schulz H., Kalhofer E. and
However, the reason for the high affinity Reuter U. (1998). Machining of CGI. Werkstatt
between CBN and CGI has not yet been und Betrieb (Germany), 131(3), 135-137.
explained. Sahm A., E. Abele, H. Schulz (2002), Machining of
Besides such possible incompatibility, higher wear Compacted Graphite Iron (CGI), Mat. –wiss. U.
was generally experienced also for the carbide Werkstofftech. 33, pp 501-506,
inserts when machining CGI. The vermicular Trent E. M., Wright P. K. (2000), Metal Cutting,
graphite morphology was here identified as an Fourth Edition, Ch 9, Machinability, pp 294-295.
important mechanism, leading to longer chips
and different chip formation mechanism with
potentially different heat impact on inserts.

REFERENCES

Abele E., A. Sahm, H. Schulz (1) (2002), Wear


Mechanism When Machining Compacted
Graphite Iron, Annals of the CIRP Vol.
51/1/2002, pp 53-56.
Araki T., Yamamoto S. (1975), Influence of
Metallurgy on Machinability, Proceedings of the
International Symposium on Influence of
Metallurgy on Machinability, vol 7, pp, 159-173.
Cohen, P. H. ; Voigt, R. C. and Marvanga, R. O.
(2000), Influence of graphite morphology and
matrix structure on chip formation during
machining of ductile irons. AFS Casting
Congress, American Foundrymen`s Society,
Pittsburg. pp 651-661.
Dawson, S., and Schroeder, T. (2000). Compacted
graphite iron offers a viable design alternative.
Engineered Casting Solutions (USA), 2(2), pp
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