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Second-Law Analysis of Solar Collectors PDF
Second-Law Analysis of Solar Collectors PDF
Introduction
The objective of this study is to illustrate quantitatively the maximize the collection of exergy from the insolation stream.
exergy delivery potential of solar collectors and to show how This task is analgous to finding ways to avoid the irreversible
this potential can be maximized by design. The second-law destruction of exergy in the process of collection and delivery
analysis of energy systems (otherwise known as exergy or to a potential user. With this objective in mind, Bejan,
availability analysis) has drawn considerable attention during Kearney, and Kreith [14] showed that the exergy delivered by
the past two decades especially in the wake of the oil crisis of a flat-plate solar collector operating in the steady state is a
the early 1970s. Tutorial presentations of the method of
second-law analysis and some of its applications are available
in references [1-4].
In the field of solar energy engineering, it was recognized as INSOLATION
early as 1964 that the discussion of the "efficient" use of solar l"AC
energy must rest on an understanding of the ther-
modynamically maximum work-producing potential
associated with solar thermal radiation [5,6]. In simultaneous
communications, Petela [5] and Spanner [6] presented two
different theoretical arguments whose practical conclusion is
essentially the same, namely, that relative to the ambient
temperature of 300 K the stream of thermal energy received as
solar radiation could be converted up to 93 percent into
available work. The discrepancy between Petela's and
Spanner's analysis and the growing interest in the utilization
of solar energy in the 1970s have stimulated an entire sequence
of studies all aimed at clarifying the issue of the exergy
content of solar radiation [7-12]. A much needed critical
review of these studies has just been published by Gribik and
Osterle [13] who show that although the practical conclusion
that the solar thermal radiation is rich in exergy, the correct
theoretical approach to this conclusion is that of Spanner [6]. Qo
HEAT LOSS
In view of the high exergy content of solar thermal
radiation, an important engineering task is to find ways to
AMBIENT, h
Contributed by the Solar Energy Division for publication in the JOURNAL OF '//////////////////////////A
SOLAR ENERGY ENGINEERING. Manuscript received by the Solar Energy Division, Fig. 1 Schematic of solar collector with fluid thermal energy storage
November, 1984. element
a = insolation period
Ac = collector cross-sec- * peak = peak insolation (Fig. 2) t = time
tional area k = duration of the to = daily operating cycle
b = time marking the draining phase Tc = collector temperature
b e g i n n i n g of the K0 = dimensionless heat loss T0 = ambient temperature
draining phase parameter TA = parameter, equation
C = specific heat of in- I = duration of the filling (25)
compressible fluid, or phase Uc = overall heat transfer
specific heat at con- m = flow rate coefficient
stant pressure of ideal min = inlet flow rate X = parameter, equation
gas m out = outlet flow rate (24)
Ex = exergy delivery rate, M = fluid inventory
e= dimensionless collector
equation (4) MoMmax = maximum fluid in- temperature
Ex = total exergy delivered ventory ^max = dimensionless stagna-
during one cycle N = number of heat transfer tion temperature,
F = integrand, equations units, equation (24) equation (11)
(6), (7); function, NE = exergy number T = dimensionless time,
equation (38) N
x y
- = number of heat transfer equation (24)
nun
h = specific euthalpy units, equation (45) V I opt = optimum
H = function, equation (41) Q = insolation parameter, ( )o = properties of the dead
i" = dimensionless in- equation (24) state
solation function Go = heat loss rate ( )• = dimensionless notation,
I" = insolation s = specific entropy following equation (5)
Tc
collector temperature
T0
UCT0
heat loss parameter
1
peak
insolation function
* peak n
In I rh!
out,opt/K0
* " peak-^t- Fig. 3 Optimum collector temperature versus optimum outlet flow-
time
CT0M0 rate
M(t)
M*{t*)=-~^ fluid inventory Let us assume that on a clear day the sun radiates with an
M0
intensity that is approximately a sinusoidal function of time,
EK as shown in Fig. 2,
NE=—^~~ exergy number
M CT 0 0
/"(/*) = sin (10)
Parameter 7" peak and M 0 appearing in the preceding « ) •
definitions represent the peak insolation and the maximum The maximum or stagnation temperature of the collector,
storage capacity of the collector, respectively. 8,„ax> occurs at no-load conditions, i.e., when all the radiation
Considering now the integrand of equation (5), we see that coming from the sun is lost to the ambient,
it depends on two functions of time and their first derivatives,
0(r*), dd/dt*, M(t*), and dMIdt*. To maximize the NE in- .= ! + • (11)
tegral, we rely on the method of variational calculus [18] to K„
determine the optimum collector temperature history Bop, and The optimum history of the inlet and outlet flow rates can
the optimum stored mass history Mnpl. We must solve the two now be derived by combining equations (3) and (4)
Euler equations
out,op! (0OP, + 1)2
-1 (12)
v0pt*'ln{Bop,)-Bop, + \
(6)
' in,opt
J"(t*)/Ko
(13)
v
0 u
opt 1
where the dimensionless flow rates are defined as
(7) CTn
(m* 'UODt \^in,out)o (14)
* peak A,
We conclude that the optimum outlet flow rate is a constant
where/ 7 is the integrand of equation (5), F = F{6, dd/dt*, M*, that depends solely on 6opl and K0, equation (12). As shown in
dM*/dt*, t*). The conditions necessary for achieving Fig. 3, m0 increases monotonically with both 6op, and K0.
maximum exergy output are obtained by solving equations (6) The optimum inlet flow rate, on the other hand, is not a
and (7), constant as indicated by equation (13): minopl varies in step
with the insolation function. The total exergy number NE can
WOPI - 1 " u
opt now be calculated as a function of only 6opl and the heat loss
=0 (8)
"opt\"opl •1) dt* characteristics of the collector. The results displayed
graphically in Fig. 4 have been obtained by substituting into
3 (8opl-l)dM*
i"(t*) Wop, - I) the NE integral (5) the result d = dopn constant, and the op-
(9) timum inventory history M*opl obtained by combining
9oPlln(dopl)~eopl +l Kn dt*
equations (12), (13), and (2). Figure 4 shows that for a given
Equation (8), which depends only on 6opl and ddop,/dt*, collector (i.e., given heat loss characteristics, 6maXilKllk being
shows that the NE integral will be maximum only if the equal to 1 + KQ~l) there exists a "best" d„pl for which NE
collector temperature history is a constant. The analytical reaches a relatively sharp maximum. The exergy number is
form of 8 ,, namely, d,opt constant, is the contribution of zero when d„.„ = 1 (i.e., when Tc = r 0 ) , because in this case the
the variational calculus presented in the foregoing. The best collector is in thermal equilibrium with the environment. At
Bopl constant and the necessary flow rates for maximum NE the other end of the NE(Bopl) curve, where B„pl = 6„mxpeak, the
can be determined once the insolation function i"(t*) is entire insolation is lost to the ambient and, consequently,
known. there is not extraction of exergy.
I"
(24)
mC
Ex
maCT 0 and where TA is the dimensionless form of the collector
temperature history in regime ///, equation (21),
T,. ,yVN
/T-\-b/a\
TA=^-=l+x(- (25)
1
o x -b/a
The analysis of collectors operating according to the
scenario sketched in Fig. 5(6), b > a, yields the following
results for the sequence of three regimes:
Regime I (Fig. 5(6)), 0<t<a): M(t) and Tc.(t) are given
by equations (16) and (17), respectively.
1 a-
a
mC T T
'- >-T>"-(T„)
dt (22)
solation level (Q). A birdseye view of the effect of b/a and N
on the exergy harvest is presented in Fig. 6. In a given
collector with N and Q fixed, the total exergy delivered by the
The total exergy output of a collector that is drained before collector decreases sharply as the start of the withdrawal
the end of the filling phase (b < a, Fig. 5(a)) may be sum- phase is delayed (i.e., as b/a increases on the abscissa of Fig.
marized in the following dimensionless notation: 6). This effect is present in relatively lossy collectors, where N
is of order one or greater. If the collector is well insulated (N
small), the total exergy delivered to the external user becomes
(l-^jlX-lnO+X)] insensitive to b/a as the system becomes a good storage
maCTa
h element for exergy. The trends revealed by Fig. 6 for Q = 1
p1+ - are present also at Q values greater and smaller than one, as
+ 1 * [TA - I - ln(TA)]dr (23) shown in reference [19]: in the interest of brevity, only Fig. 6
is exhibited in this report.
where Physically, varying N and holding Q constant (Fig. 6)
N=0.1
JM.O
N=10.0
a-i.o
00.00
1.00
0.01
I I 1
Time (b/a) 0. 00 0.25 0.50 0.75
Fig. 8 The effect of the timing of draining on the total exergy output of
the system of Fig. 7 (Q = 1,fc/a = 1,//a = 0.5)
Time ( I n )
Fig. 10 The effect of the duration of the filling phase on the total
means one of the following scenarios: (/) the collector area/I c exergy output of the system of Fig. 7(Q = 1,b/a = 1.5, k/a = 1)
varies while / " and Uc are held fixed, or (/"/) the product UCAL.
varies while the ratio I"/Uc is held fixed. Note that m is
assumed fixed and is used in nondimensionalizing the exergy
total Ex. The most likely physical interpretation of Fig. 6 is (a) is in general different than both / and k. We are focusing
scenario (/). on the more practical situation where the filling of the pool
happens quickly in the beginning of the sunlight period (b <
Four-Regime Model of Collector With Temporary a), and where the draining is delayed until times following the
end of the sunlihgt period (b > a). When finite, the insolation
Storage flux and the inlet and outlet flow rates are constant in time.
In this section we focus on the exergy-delivery potential of a The operation of the present collector is a sequence of four
more general model of a solar collector with temporary fluid distinct regimes, as indicated in the lower drawing of Fig. 7.
storage capability. As shown in Fig. 7, the earlier assumption The M(r) and Tc(t) functions that characterize each of these
that the filling and discharge phases last as long as the in- regimes can easily be derived by applying the mass and energy
solation is dropped. In the present model the filling phase conservation statements (2, 3) and by properly accounting for
occupies a time interval of length /, the draining of the pool the continuity of M and Tt. from one regime to the next. The
occupies a time interval of length k, and the insolation time main results of the analysis are listed in the following.