Safety Data Sheet

ALUMINIUM HIGHT TEMPERATURE 500°C

Safety Data Sheet dated 3/3/2010, version 1

1. IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY

Trade name: ALUMINIUM HIGHT TEMPERATURE 500°C
Trade code: 175500
Product type and use: Siliconic enamel to hight temperature
Company:
Praticar srl - Via S. Ferrari, 20/1A – 15057 Tortona (AL) - Tel 0131/863125 Fax 0131/867753
Emergency telephone number of the company and/or of an authorised advisory centre:
TELEFONO - CENTRO ANTIVELENI- OSPEDALE DI NIGUARDA -MILANO
TEL. 02 66101029
Competent person responsible for the safety data sheet:
PierPaolo Cortesi tel. 0131/863125

2. HAZARDS IDENTIFICATION
Properties / Symbols:
F Highly flammable
Xn Harmful
Xi Irritant
N Dangerous for the environment
R Phrases:
R11 Highly flammable.
R20/21 Harmful by inhalation and in contact with skin.
R37/38 Irritating to respiratory system and skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.

3. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components within the meaning of EEC directive 67/548 and corresponding classification:
19.8 % cyclohexane
N.67/548/CEE: 601-017-00-1 CAS: 110-82-7 EC: 203-806-2
F,Xn,Xi,N; R11-38-50-53-65-67

14.7 % xylene [4]

N.67/548/CEE: 601-022-00-9 CAS: 1330-20-7 EC: 215-535-7
Xn,Xi; R10-20/21-38

12.4 % Solvent naphtha (petroleum), light arom

N.67/548/CEE: 649-356-00-4 CAS: 64742-95-6 EC: 265-199-0
Xn,Xi,N; R37-51-53-66-67-65

8.19 % 1,2,4-trimethylbenzene
N.67/548/CEE: 601-043-00-3 CAS: 95-63-6 EC: 202-436-9
Xn,Xi,N; R10-20-36/37/38-51-53

8 % 2-methoxy-1-methylethyl acetate
N.67/548/CEE: 607-195-00-7 CAS: 108-65-6 EC: 203-603-9
Xi; R10-36

2.25 % ethylbenzene
N.67/548/CEE: 601-023-00-4 CAS: 100-41-4 EC: 202-849-4
F,Xn; R11-20

2.2 % ethyl acetate

N.67/548/CEE: 607-022-00-5 CAS: 141-78-6 EC: 205-500-4
F,Xi; R11-36-66-67

0.4 % 2-methylpropan-1-ol

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 N.67/548/CEE: 603-108-00-1 CAS: 78-83-1 EC: 201-148-0
Xi; R10-37/38-41-67

0.14 % methanol
N.67/548/CEE: 603-001-00-X CAS: 67-56-1 EC: 200-659-6
F,T; R11-23/24/25-39/23/24/25

4. FIRST AID MEASURES

Contact with skin:
Immediately take off all contaminated clothing.
Areas of the body that have - or are only even suspected of having - come into contact with the product must be
rinsed immediately with plenty of running water and possibly with soap.
Contact with eyes:
Do not use eyewash or ointment of any kind (before obtaining an examination or advice from an eye specialist).
Wash immediately with water for at least 10 minutes.
Swallowing:
Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION IMMEDIATELY.
Give liquid paraffin to drink; do not give milk or animal or vegetable fats of any kind.
Inhalation:
Ventilate the premises. The patient is to be removed immediately from the contaminated premises to rest in a well
ventilated area. OBTAIN MEDICAL ATTENTION.

5. FIRE-FIGHTING MEASURES
Recommended extinguishers:
In case of fire, use... (indicate in the space the precise type of fire-fighting equipment.If water increases risk, add -
'Never use water')
Extinguishers not to be used:
None in particular.
Risks arising from combustion:
Avoid inhaling the fumes.
Protective equipment:
Use protection for the respiratory tract.
Cool the containers exposed to the fire with water.

6. ACCIDENTAL RELEASE MEASURES

Measures for personal safety:
Use a mask, gloves and protective clothing.
Environmental measures:
Limit leakages with earth or sand.
Eliminate all unguarded flames and possible sources of ignition. Do not smoke.
If the product has escaped into a water course, into the drainage system, or has contaminated the ground or
vegetation, notify the competent authorities.
Cleaning methods:
Rapidly recover the product. To do so, wear a mask and protective clothing.
If the product is in a liquid form, stop it from entering the drainage system.
Recover the product for re-use if possible, or for elimination. The product might, where appropriate, be absorbed by
inert material.
After the product has been recovered, rinse the area and materials involved with water.

7. HANDLING AND STORAGE

Handling precautions:
Avoid contact and inhalation of the vapours. See, too, paragraph 8 below.
Do not eat or drink while working.
Do not smoke while working.
Incompatible materials:
None in particular.
Storage conditions:
Always keep the containers tightly closed.
Always keep in a well ventilated place.
Keep away from unguarded flame, sparks, and heat sources. Avoid direct exposure to sunlight.
Instructions as regards storage premises:
Cool and adequately ventilated.

8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Precautionary measures:
Give adequate ventilation to the premises where the product is stored and/or handled.
Respiratory protection:
Use respiratory protection where ventilation is insufficient or exposure is prolonged, e.g. CEN/FFP-2(S) or CEN/FFP-
3(S).
Use adequate protective respiratory equipment, e.g. CEN/FFP-2(S) or CEN/FFP-3(S).
Protection for hands:

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 Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
Eye protection:
Use close fitting safety goggles and/or visor conforming to BS 2092 GRADE 1).
Protection for skin:
Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or viton.
Exposure limit(s) (ACGIH):
cyclohexane
VLE 8h: ppm 200 mg/m3 700 TLV TWA: ppm 100
xylene [4]
VLE 8h: ppm 50 - mg/m3 221 ,Skin VLE short: ppm 100 - mg/m3 442 ,Skin TLV TWA: ppm 100 ,A4 TLV STEL:
ppm 150 ,A4
Solvent naphtha (petroleum), light arom
TLV TWA: 100 mg/mc (19 ppm) Oel
1,2,4-trimethylbenzene
VLE 8h: ppm 20 mg/m3 100
2-methoxy-1-methylethyl acetate
VLE 8h: ppm 50 mg/m3 275 ,Skin VLE short: ppm 100 mg/m3 550 ,Skin TLV TWA: 274 mg/mc 50 ppm TLV
STEL: 100 ppm
ethylbenzene
VLE 8h: ppm 100 mg/m3 442 ,Skin VLE short: ppm 200 mg/m3 884 ,Skin TLV TWA: ppm 100 A3 TLV STEL:
ppm 125 A3
ethyl acetate
TLV TWA: ppm 400
2-methylpropan-1-ol
TLV TWA: ppm 50
methanol
VLE 8h: ppm 200 mg/m3 260 ,Skin TLV TWA: ppm 200,Skin TLV STEL: ppm 250,Skin

9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance and colour: liquido argento
Odour: caratteristico
pH: n.a.
Melting point: N.A.
Boiling point: 73 -91 °C
Flash point: - 20 ° C
Solid/gas flammability: N.A.
Autoignition temperature: > 200°C
Explosive properties: N.A.
Oxidizing properties: N.A.
Vapour pressure: N.A.
Relative density: 1.040 a 20°C
Solubility in water: insolubile può reagire con acqua svil. gas CO2
Lipid solubility: solventi organici,aromatici,acetati
Partition c. (n-octanol/H2O): N.A.
Vapour density: > 1 (aria=1)

10. STABILITY AND REACTIVITY

Conditions to avoid:
Stable under normal conditions.
Substances to avoid:
Avoid contact with combustible materials. The product could catch fire.
Hazardous decomposition products:
None.

11. TOXICOLOGICAL INFORMATION

The concentration of each substance should be borne in mind in assessing the toxicological effects deriving from the
preparation.
Set out below is the toxicological information relating to the main substances in the preparation.
cyclohexane
Tossicità acuta:DL50 tossicità orale > 5000 mg/kg (ratto)
CL50 inalazione/4 ore/ratto 39615 ppm (13,9 mg/l)
Nell'uomo la tossicità acuta è molto bassa, e solo esposizioni ad alteconcentrazioni possono esercitare un effetto
depressivo sul sistema nervoso centrale con vertigini,nausea e perdita di conoscenza.Negli animali alla dose letale,si
notano imponente diarrea,danno vascolare, e gravi danni a carico di fegatoe reni;i vapori,ad alte
concentrazioni,inducevano irritazione di occhi,cute e tratto respiratorio.
Ingestione:quantità anche piccole introdotte nei polmoni per l'ingestione o il vomito possono provocare
broncopèolmonite chimica e edema polmonare.
Contatto con la pelle: praticamente non nocivo,nessuna mortalità riscontrata su coniglio a 2000 mg/kg.Può causare
dermatiti a contatti prolungati.
Contatto con gli occhi:leggermente irritante (coniglio)
Sensibilizzazione:non sensibilizzante cutaneo
Tossicità cronica:dagli studi per inalazione prolungata sull'animale non hanno messo in evidenza effet.

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 xylene [4]
LD50 (RAT) ORAL: 5000 MG/KG
sono di seguito riportate le informazioni tossicologiche riguardanti le principali sostanze nel preparato:
Xilolo,miscela di isomeri

Acuta:
Inalazione:le conc.di vapore superiori ai livelli di esposizione raccomandati sono irritanti per gli occhi e il tratto
respiratorio,possonoessere causa di mal di testa e capogiri,sono anestetici e possono causare altri effetti al sistema
nervoso centrale.Contatto con la pelle: Irritante.Moderato indice di tossicità sistemica per assorbimento cutaneo.
Contatto con gli occhi: Causerà disagio agli occhi, ma non danneggerà il tessuto oculare.Ingestione:quantità di
liquido anche piccole introdotte nel sistema respiratorio durante l'ingestione o peri il vomito possono provocare
broncopolmonite o edema polmonare.
Minimo indice di tossicità.
Solvent naphtha (petroleum), light arom
Nafta solvente(petrolio),aromatica leggera
Tossicità acuta:
Inalazione:le concentrazioni di vapore superiori ai livelli di esposizione raccomandati sono irritanti per gli occhi e il
tratto respiratorio,possono essere causa di mal di testa e capogiri,sono anestetici e possono causare altri effetti al
sistema nervoso centrale.
Contatto con la pelle: Basso indice di tossicità contatti frequenti o prolungati possono sgrassare e seccare la
pelle,favorendo disagio e dermatiti.
Contatto con gli occhi:causerà disagio per gli occhi,ma non danneggerà il tessuto oculare.
Ingestione:quantità di liquido anche piccole introdotte nel sistema respiratorio durante l'ingestione o per il vomito
possono provocare broncopolmonite o edema polmonare.Basso indice di tossicità.
1,2,4-trimethylbenzene
LD50 (RAT) ORAL: 7000 MG/KG BW
2-methoxy-1-methylethyl acetate
sono di seguito riportate le informazioni tossicologiche riguardanti le principali sostanze nel preparato:
1-metossi-2-propil acetato
Tossicità acuta:basso grado di tossicità acuta. LD50= orale ratto> 5155 mg/kg
LCLO ratto =4345 ppm 6h
LD50 cutanea coniglio > 2000 mg/kg
Potere irritante occhi: L'irritazione oculare è stata testata con il metodo 405 dell' OECD.
L'applicazione oculare singola nel coniglio ha causato irritazione congiuntivale e lesioni corneali
transitorie(punteggiatura/lesioni epiteliari minori).
Potere irritante pelle:l'irritazione cutanea è stata esaminata come prescritto dal metodo 404 dall'OECD.L'applicazione
singola semi-occlusiva,di 4 ore,sulla pelle intatta di coniglio,ha provocato segni minimi di irritazione(punteggio medio
di eritema o edema inferiore a 2).Il grado di irritazione era insufficiente per poter classificare il prodotto come irritante
per la pelle.
ethylbenzene
LD50 (RAT) ORAL: 3500 MG/KG
LD50 (RAT) ORAL: 4710 MG/KG BW
l'agenzia internazionale per la ricerca sul cancro ha valutato l'etilbenzane e classificato come possibile cancerogeno
umano(gruppo 2 B)
basandosi su sufficiente prove di cancerogenicità negli animali da laboratorio,ma pur sempre inadeguata evidenza di
cancro negli uomini.
ethyl acetate
LD50 (RABBIT) ORAL: 4935 MG/KG
basso grado di tossicità acuta.
LD50 orale ratto: 5600 mg/kg
LC50 inalazione ratto: 56mg/1/4h.
LC50 dermica coniglio > 18000 mg/kg.
Potere irritante occhi:
L'irritazione ochulare è stata testata con il metodo 405 dellOECD,l'applicazione oculare singola nel coniglio ha
causato irritazione congiuntivale e lesioni corneali transitorie
Potere irritante cute:Sul coniglio nessun segno di irritazione dermica.
Tossicità sub-acuta/subcronica:
l'esposizione dei topi a 4300 ppm per 6 ore per 7 gg ha indotto alterazioni ematiche minori e perdita di appetito.I
conigli esposti a 4400 ppm per 1 ora al giorno per 40 gg hanno sviluppato anemia secondaria,effetti ematici minori e
splenomegalia.
Tossicità cronica/cancerogenicità:
Nessuna evidenza di cancerogenicità nelle seguenti specie: topi.
Genotossicità:complessivamente,non è stata osservata sostanziale attività mutagena.
methanol
LD50 (RAT) ORAL SINGLE DOSE: 5628 MG/KG
LD50 (RABBIT) SKIN SINGLE DOSE: 15800 MG/KG

12. ECOLOGICAL INFORMATION

Adopt good working practices, so that the product is not released into the environment.
List of substances dangerous for the environment and corresponding classification:
15% - 20% cyclohexane
N.67/548/CEE: 601-017-00-1 CAS: 110-82-7 EC: 203-806-2

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 R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
10% - 12.5% Solvent naphtha (petroleum), light arom
N.67/548/CEE: 649-356-00-4 CAS: 64742-95-6 EC: 265-199-0
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
7% - 10% 1,2,4-trimethylbenzene
N.67/548/CEE: 601-043-00-3 CAS: 95-63-6 EC: 202-436-9
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

13. DISPOSAL CONSIDERATIONS

Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so doing, comply
with the local and national regulations currently in force.
Where applicable, refer to the following regulatory provisions : 91/156/EEC, 91/689/EEC, 94/62/EC and subsequent
amendments.

14. TRANSPORT INFORMATION

ADR-UN number: 1263
ADR-Class: 3
ADR-Label: fiamma
ADR-Packing Group: II

15. REGULATORY INFORMATION

Council Directive 67/548/EEC (Classification, packaging and labelling of dangerous substances) and subsequent
amendments. Council Directive 1999/45/EC (Classification, packaging and labelling of dangerous preparations) and
subsequent amendments. Commission Directive 98/24/EC (Protection of the health and safety of workers from the risk
related to chemical agent). Commission Directive 2000/39/EC (Occupational exposure limit values). Regulation (EC) No
1907/2006 (REACH).

Symbols:
Xn Harmful
F Highly flammable
N Dangerous for the environment
R Phrases:
R11 Highly flammable.
R20/21 Harmful by inhalation and in contact with skin.
R37/38 Irritating to respiratory system and skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
S Phrases:
S16 Keep away from sources of ignition - No smoking.
S25 Avoid contact with eyes.
S29/56 Do not empty into drains, dispose of this material and its container to hazardous or special waste collection
point.
S36/37 Wear suitable protective clothing and gloves.
S43 In case of fire, use... (indicate in the space the precise type of fire-fighting equipment.If water increases risk, add
- 'Never use water')
S7/9 Keep container tightly closed and in a well-ventilated place.
Contents:
cyclohexane
xylene [4]
Solvent naphtha (petroleum), light arom

Where applicable, refer to the following regulatory provisions :

Regulation (EC) nr 648/2004 (Detergents).
Directive 2003/105/CE ('Activities linked to risks of serious accidents') and subsequent amendments.

16. OTHER INFORMATION

Text of R phrases referred to under heading 3:
R10 Flammable.
R11 Highly flammable.
R20 Harmful by inhalation.
R20/21 Harmful by inhalation and in contact with skin.
R23/24/25 Toxic by inhalation,in contact with skin and if swallowed.
R36 Irritating to eyes.
R36/37/38 Irritating to eyes, respiratory system and skin.
R37 Irritating to respiratory system.

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 R37/38 Irritating to respiratory system and skin.
R38 Irritating to skin.
R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
R41 Risk of serious damage to eyes.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.

Main bibliographic sources:

ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre, Commission of the
European Communities
SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van Nostrand Reinold
ACGIH - Threshold Limit Values - 2004 edition
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely to the
product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific use intended.
This MSDS cancels and replaces any preceding release.

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