WORKSHEET – ASSIGNING OXIDATION NUMBERS

Name _______________________________________ Period _____

Oxidation Number Rules:

1. A pure element has an oxidation number of 0.

2. The oxidation number of an element in a monatomic ion equals the charge of the ion.
3. The sum of the oxidation number of all the elements in a compound equals 0.
4. The sum of the oxidation numbers of all the elements in a polyatomic ion equals the charge on
the ion.

Directions: In the following questions, give the oxidation number of the indicated atoms/ion.

1. N in N2O3 N3+ 16. C in CH4 C4+

2. S in H2SO4 S6+ 17. Mn in MnO2 Mn4+

3. C C0 18. S in SO32- S4+

4. C in CO C2+ 19. Mg2+ Mg2+

5. Na in NaCl Na+ 20. Cl- Cl-

6. H in H2O H+ 21. O2 O20

7. Ba in BaCl2 Ba2+ 22. P4 P40

8. N in NO2- N3+ 23. Na in Na2S Na+

9. S in Al2S3 S2- 24. S in H2S S2-

10. S in HSO4- S6+ 25. Ca2+ Ca2+

11. Cl in Fe(ClO2)3 Cl3+ 26. C in CN- C4+

12. Fe in Fe(ClO2)3 Fe3+ 27. H in OH- H+

13. N in NO3- N5+ 28. Mn in KMnO4 Mn7+

14. Cu2+ Cu2+ 29. I in Mg(IO3)2 I5+

15. Zn2+ Zn2+ 30. C in C2O42- C2+